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At least 1,477 records · Page 82

Influence of Al{sub 2}O{sub 3} layer insertion on the electrical properties of Ga-In-Zn-O thin-film transistors

To investigate the influence of ionic/covalent interface of Al{sub 2}O{sub 3}/SiO{sub 2} gate insulator on the electrical properties of thin-film transistors (TFTs) with ionic Ga-In-Zn-O (GIZO) semiconducting channel layers, Al{sub 2}O{sub 3} layers of different thickness were introduced between SiO{sub 2} and GIZO using plasma-enhanced atomic layer deposition. The GIZO layers were obtained by DC magnetron sputtering using a GIZO target (Ga:In:Zn = 1:1:1 mol. %). The GIZO TFTs with an Al{sub 2}O{sub 3}/SiO{sub 2} gate insulator exhibited positive threshold voltage (V{sub th}) shift (about 1.1 V), V{sub th} hysteresis suppression (0.23 V), and electron mobility degradation (about 13%) compared with those of a GIZO TFT with SiO{sub 2} gate insulator by the influence of ionic/ionic and ionic/covalent interface at Al{sub 2}O{sub 3}/GIZO and Al{sub 2}O{sub 3}/SiO{sub 2}, respectively. To clarify the origin of the positive V{sub th} shift, the authors estimated the shifts of flatband voltage (0.4 V) due to the dipole and the fixed charge (−1.1 × 10{sup 11}/cm{sup 2}) at Al{sub 2}O{sub 3}/SiO{sub 2} interface, from capacitance–voltage data for Pt/Al{sub 2}O{sub 3}/SiO{sub 2}/p-Si capacitors. Based on these experimental data, the authors found that the positive V{sub th} shift (1.1 V) could be divided into three components: the dipole (−0.4 V) and fixed charge (0.15 V) at the SiO{sub 2}/Al{sub 2}O{sub 3} interface, and the fixed charge (1.35 V) at the Al{sub 2}O{sub 3}/GIZO interface. Finally, it is noted that heterointerface of SiO{sub 2}/Al{sub 2}O{sub 3}/GIZO stacks is important not only to recognize mechanism of V{sub th} shift but also to design future TFTs with high-k dielectrics and low operating voltage.

42 ENGINEERING↗

Low-temperature SiON films deposited by plasma-enhanced atomic layer deposition method using activated silicon precursor

It has not been an easy task to deposit SiN at low temperature by conventional plasma-enhanced atomic layer deposition (PE-ALD) since Si organic precursors generally have high activation energy for adsorption of the Si atoms on the Si-N networks. In this work, in order to achieve successful deposition of SiN film at low temperature, the plasma processing steps in the PE-ALD have been modified for easier activation of Si precursors. In this modification, the efficiency of chemisorption of Si precursor has been improved by additional plasma steps after purging of the Si precursor. As the result, the SiN films prepared by the modified PE-ALD processes demonstrated higher purity of Si and N atoms with unwanted impurities such as C and O having below 10 at. % and Si-rich films could be formed consequently. Also, a very high step coverage ratio of 97% was obtained. Furthermore, the process-optimized SiN film showed a permissible charge-trapping capability with a wide memory window of 3.1 V when a capacitor structure was fabricated and measured with an insertion of the SiN film as the charge-trap layer. The modified PE-ALD process using the activated Si precursor would be one of the most practical and promising solutions for SiN deposition with lower thermal budget and higher cost-effectiveness.

36 MATERIALS SCIENCE↗

SU-E-T-447: Growth of Metal Whiskers Under External Beam Irradiation: Experimental Evidence and Implications in Medical Electronic Devices for Radiation Therapy Treatments

Purpose: Thin metallic protrusions, termed “whiskers,” have been identified as a cause of failure in devices ranging from satellites to pacemakers. For decades, lead was used in tin-based soldering alloys to suppress whisker formation. With the adoption of the Restriction of Hazardous Substances act and the expiration of its exemption on medical devices, including implanted medical devices (IMDs), electronic circuits are required to be lead-free as of July 2014. The effect of radiation on such soldering components remains unknown. Methods: We have irradiated a thin (150 nm) tin metal layer, deposited on a 3 mm thick glass substrate, with a 6 MeV medical linac (Varian TrueBeam) electron beam in five 2-hour long sessions. After receiving ∼10 kGy, whisker growth on the sample was assessed with scanning electron microscopy and compared to a reference sample not exposed to radiation. Results: After 10 hours of irradiation, the sample was found to develop intense whisker infestation, while the reference sample remained in its pristine as-deposited condition. Repeating the same irradiation schedule generated more and longer whiskers. The observed phenomenon can be explained through charge accumulation in the glass substrate, generating an electric field that promotes whisker growth. The observed substrate glass darkening under irradiation points towards development of color centers related to charge trapping. Experiments on the same type of samples with direct application of the external field in a capacitor-like setting also resulted in intense whisker growth. Conclusion: Extreme care should be taken in dealing with all electronic devices, especially IMDs, produced with lead-free solder and components, subject to radiation exposure. While in our experiments strong electric fields were intentionally generated to accelerate whisker growth over hours, in everyday use the circuit soldering may cause problems in a matter of days or months. Designated reliability testing under radiation must be conducted. This work is partially supported by NRC grant No. NRC-HQ-12-G-38-0042.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

MO-F-CAMPUS-J-03: Development of a Human Brain PET for On-Line Proton Beam-Range Verification

Purpose: To develop a prototype PET for verifying proton beam-range before each fractionated therapy that will enable on-line re-planning proton therapy. Methods: Latest “edge-less” silicon photomultiplier arrays and customized ASIC readout electronics were used to develop PET detectors with depth-of-interaction (DOI) measurement capability. Each detector consists of one LYSO array with each end coupled to a SiPM array. Multiple detectors can be seamlessly tiled together to form a large detector panel. Detectors with 1.5×1.5 and 2.0×2.0 mm crystals at 20 or 30 mm lengths were studied. Readout of individual SiPM or signal multiplexing was used to transfer 3D interaction position-coded analog signals through flexible-print-circuit cables or PCB board to dedicated ASIC front-end electronics to output digital timing pulses that encode interaction information. These digital pulses can be transferred to, through standard LVDS cables, and decoded by a FPGA-based data acquisition of coincidence events and data transfer. The modular detector and scalable electronics/data acquisition will enable flexible PET system configuration for different imaging geometry. Results: Initial detector performance measurement shows excellent crystal identification even with 30 mm long crystals, ∼18% and 2.8 ns energy and timing resolutions, and around 2–3 mm DOI resolution. A small prototype PET scanner with one detector ring has been built and evaluated, validating the technology and design. A large size detector panel has been fabricated by scaling up from modular detectors. Different designs of resistor and capacitor based signal multiplexing boards were tested and selected based on optimal crystal identification and timing performance. Stackable readout electronics boards and FPGA-based data acquisition boards were developed and tested. A brain PET is under construction. Conclusion: Technology of large-size DOI detector based on SiPM array and advanced readout has been developed. PET imaging performance and initial phantom studies of on-line proton beam-range measurement will be conducted and reported. NIH grant R21CA187717; Cancer Prevention and Research Institute of Texas grant RP120326.

60 APPLIED LIFE SCIENCES↗

Entropy Signatures of Topological Phase Transitions

We review the behavior of the entropy per particle in various two-dimensional electronic systems. The entropy per particle is an important characteristic of any many-body system that tells how the entropy of the ensemble of electrons changes if one adds one more electron. Recently, it has been demonstrated how the entropy per particle of a two-dimensional electron gas can be extracted from the recharging current dynamics in a planar capacitor geometry. These experiments pave the way to the systematic studies of entropy in various crystal systems including novel two-dimensional crystals such as gapped graphene, germanene, and silicene. Theoretically, the entropy per particle is linked to the temperature derivative of the chemical potential of the electron gas by the Maxwell relation. Using this relation, we calculate the entropy per particle in the vicinity of topological transitions in various two-dimensional electronic systems. We show that the entropy experiences quantized steps at the points of Lifshitz transitions in a two-dimensional electron gas with a parabolic energy spectrum. In contrast, in doubled-gapped Dirac materials, the entropy per particle demonstrates characteristic spikes once the chemical potential passes through the band edges. The transition from a topological to trivial insulator phase in germanene is manifested by the disappearance of a strong zero-energy resonance in the entropy per particle dependence on the chemical potential. We conclude that studies of the entropy per particle shed light on multiple otherwise hidden peculiarities of the electronic band structure of novel two-dimensional crystals.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Nanosecond pulsed power generator for a voltage amplitude up to 300 kV and a repetition rate up to 16 Hz for fine disintegration of quartz

A generator of high-power high-voltage nanosecond pulses is intended for electrical discharge disintegration of mineral quartz and other nonconducting minerals. It includes a 320 kV Marx pulsed voltage generator, a high-voltage glycerin-insulated coaxial peaking capacitor, and an output gas spark switch followed by a load, an electric discharge disintegration chamber. The main parameters of the generator are as follows: a voltage pulse amplitude of up to 300 kV, an output impedance of ≈10 Ω, a discharge current amplitude of up to 25 kA for a half-period of 80–90 ns, and a pulse repetition rate of up to 16 Hz.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

How to increase the efficiency of the electrical discharge method for destruction of nonconductive solid materials

The paper deals with the relevance of using electrical discharge technology for construction works in the city. The technical capabilities of the installation for the multi-borehole electro-discharge splitting off and destruction of rocks and concrete are described. The ways to increase the efficiency of the electrical discharge method for the destruction of solids are proposed. In order to augment the discharge circuit energy, the energy storage is separated into two individual capacitor batteries. The throttle with the inductance of 28.6 μH is installed in one of the batteries, which increases the duration of the channel energy release to 400 μs and the efficiency of electrical discharge splitting off of concrete.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Regimes of pulsed formation of a compact plasma configuration with a high energy input

Results of experiments on the formation of a compact toroidal magnetic configuration at the Compact Toroid Challenge setup are presented. The experiments were primarily aimed at studying particular formation stages. Two series of experiments, with and without an auxiliary capacitor bank, were conducted. The magnetic field was measured, its time evolution and spatial distribution over the chamber volume were determined, and its influence on the formation regimes was investigated.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Study of the Possibility to Use a Magnetoplasma Compressor for Plasma-Assisted Combustion in a High-Speed Flow

Results of experimental studies of the possibility to use a low-power magnetoplasma compressor for propane−air mixture ignition in a supersonic flow are presented. It is demonstrated that the regime of explosive combustion of the propane−air mixture can be stably implemented under the action of the magnetoplasma compressor. The maximum repetition rate of the magnetoplasma compressor is limited by the charging time of the storage capacitor.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Impedance Spectroscopy Study of the Electrical Properties of Cation-Substituted Barium Hexaaluminate Ceramics

We report on the behavior of frequency and temperature dependences of the impedance of a measuring cell in the form of a parallel-plate capacitor filled with barium hexaaluminate ceramics with four aluminum cations replaced by iron (BaO · 2Fe{sub 2}O{sub 3} · 4Al{sub 2}O{sub 3}). The measurements have been performed in the frequency range of 0.5–10{sup 8} Hz at temperatures of 20-375°C. A technique for determining the electrical properties of the investigated ceramics is proposed, which is based on an equivalent electric circuit allowing the recorded impedance spectra to be approximated with sufficiently high accuracy. The established spectral features are indicative of the presence of two electric relaxation times different from each other by three orders of magnitude. This fact is explained by the difference between the charge transport processes in the bulk of crystallites and thin intercrystallite spacers, for which the charge activation energies have been determined.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Determination of the Steady State Leakage Current in Structures with Ferroelectric Ceramic Films

Steady state leakage currents have been investigated in capacitor structures with ferroelectric solgel films of lead zirconate titanate (PZT) formed on silicon substrates with a lower Pt electrode. It is established that Pt/PZT/Hg structures, regardless of the PZT film thickness, are characterized by the presence of a rectifying contact similar to p–n junction. The steady state leakage current in the forward direction increases with a decrease in the film thickness and is determined by the ferroelectric bulk conductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Response of the Dielectric Parameters of (110)SrTiO{sub 3} Films to the Formation of Ferroelectric Domains in Their Volume

Three-layer SrRuO{sub 3}/SrTiO{sub 3}/SrRuO{sub 3} heterostructures were grown by laser evaporation on (110)LaAlO{sub 3} substrates. Photolithography and ion etching are used to form plane-parallel film capacitors, in which a layer of strontium titanate is placed between two film electrodes of strontium ruthenate. Data on the structure and orientation of the intermediate SrTiO{sub 3} layer in the grown heterostructures were obtained. The variation of the dielectric constant and dielectric loss of the SrTiO{sub 3} intermediate layer upon varying the temperature and intensity of an external electric field was studied.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Cascade Transformer Based on the Volume Coil for Power Transmission under High Voltage

The use of an electronic cooling system at the High Intensity heavy ion Accelerator Facility (HIAF) accelerator complex, which is being developed at the Institute of Modern Physics (China), to improve the efficiency of ion injection into the accelerator and reduce the spread of ion pulses in the beam has been proposed. Electron cooling of the ion beam was carried out due to the interaction of ions with a continuous electron beam with a current of up to 3 A, energy of up to 450 keV, and energy stability at the level of 10{sup –4} or better. The electron beam energy recuperation was carried out at the expense of a power source with a power of 5–15 kW, which was located at the top of a high-voltage column—a high-voltage terminal. The operation of a prototype of power transmission system, which was based on a cascade transformer with a volumetric coil, has been considered. Such a transformer has a relatively low scattering inductance, which can significantly reduce the number of capacitors to compensate for it. It has been shown that this design made it possible to transfer power of up to 40 kW at small dimensions of the transformer and heat dissipation in it was not more than 10 kW.

43 PARTICLE ACCELERATORS↗

A Prism Mass-Spectrometer for Isotope Analysis of Hydrogen–Helium Mixtures

An original scheme of a special magnetic mass-spectrometer for isotope measurements in a mass range of hydrogen–helium mixtures and their main impurities is proposed. The ion optics system contains a two-dimensional magnetic prism supplemented with two identical cylindrical electrostatic capacitors matched so that the system operates in the regime of complete triple focusing of the ion beam in two orthogonal directions and with respect to ion energies. The system ensures high dispersion and allows the mass resolution (no less than 3500) required for analysis at high brightness and a central ion trajectory length on the order of 1 m.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Evaluation of Retrofit Variable-Speed Furnace Fan Motors

In conjunction with the New York State Energy Research and Development Authority (NYSERDA) and Proctor Engineering Group, Ltd. (PEG), the Consortium for Advanced Residential Buildings (CARB) has evaluated the Concept 3 (tm) replacement motors for residential furnaces. These brushless, permanent magnet (BPM) motors can use much less electricity than their PSC (permanent split capacitor) predecessors. This evaluation focuses on existing homes in the heating-dominated climate of upstate New York with the goals of characterizing field performance and cost-effectiveness. The results of this study are intended to be useful to home performance contractors, HVAC contractors, and home efficiency program stakeholders. The project includes eight homes in and near Syracuse, NY. Tests and monitoring was performed both before and after fan motors were replaced. Average fan power reductions were approximately 126 Watts during heating and 220 Watts during cooling operation. Over the course of entire heating and cooling seasons, these translated into average electric energy savings of 163 kWh. Average cost savings were $20 per year. Homes where the fan was used outside of heating and cooling mode saved an additional $42 per year on average. Results indicate that BPM replacement motors will be most cost-effective in HVAC systems with longer run times and relatively low duct static pressures. More dramatic savings are possible if occupants use the fan-only setting when there is no thermal load. There are millions of cold-climate, U.S. homes that meet these criteria, but the savings in most homes tested in this study were modest.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Evaluation of Retrofit Variable-Speed Furnace Fan Motors

In conjunction with the New York State Energy Research and Development Authority (NYSERDA) and Proctor Engineering Group, Ltd. (PEG), the Consortium for Advanced Residential Buildings (CARB) has evaluated the Concept 3™ replacement motors for residential furnaces. These brushless, permanent magnet (BPM) motors can use much less electricity than their PSC (permanent split capacitor) predecessors. This evaluation focuses on existing homes in the heating-dominated climate of upstate New York with the goals of characterizing field performance and cost effectiveness. The project includes eight homes in and near Syracuse, NY. Tests and monitoring was performed both before and after fan motors were replaced. Results indicate that BPM replacement motors will be most cost effective in HVAC systems with longer run times and relatively low duct static pressures. More dramatic savings are possible if occupants use the fan-only setting when there is no thermal load. There are millions of cold-climate, U.S. homes that meet these criteria, but the savings in most homes tested in this study were modest.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗