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At least 1,477 records · Page 82

NDT System for Metal Components in Concrete Structures (Final Report)

Steel reinforcements embedded within concrete can corrode and crack, leading to weakening of the structures, and existing NDT (non-destructive testing) techniques do not provide the full picture. Condition assessment is critical in evaluating these structures in order to ensure safe, long-term operation of the nuclear power plants. Improved NDT techniques are needed as the nation’s generating stations age and require action based on increasingly critical inspection data. The power industry uses eddy current test (ECT) during in-service inspections to detect and monitor defects such as cracks and corrosion in metals, particularly metal pipes. However, the detection of defects in the reinforcing steel embedded in concrete is far more challenging for numerous reasons. Primary among them is the concrete layer’s thickness, which prevents the ability to have a close proximity between sensor and metallic sample. One solution to this problem is to create a higher sensitivity technique which can inspect at depth, with good spatial resolution and excellent directional sensitivity, to isolate the metal buried deep in the concrete and characterize defects in the metal. The goal of the phase II research program was to study and develop a new reinforced concrete NDT technology based on anisotropic magnetoresistive (AMR) sensors designed specifically for ECT of steel reinforcements in concrete. The first technical objective was to demonstrate the capability of inspecting steel reinforcement structures, including metal rebar and tensioning cable at or below 6” of depth embedded in concrete. Another objective was to be able to confidently identify multiple layers of reinforcements at varying depths. In addition, the technique needed to be able to provide condition assessment of the metal, providing data on the structure and positioning of the steel members, material loss, and detection of the presence of breaks. An important part of the research and development was aimed at achieving superior performance compared to existing technology. The ability to detect corrosion breaks in unbonded multi-wire and multi-strand tendons was another important objective. The final objective that led to a successful program was to build a complete prototype portable scanning system capable of demonstrating the probe performance in the field. All of these objectives were met, which provided data for the system development work going forward. RMD worked with the engineering firm Simpson Gumpertz & Heger to develop a detailed problem definition for concrete structures and the necessary sensor specifications. In addition, we developed finite element simulation models for the eddy current based NDT system through the analysis of the electromagnetic (EM) properties of sample materials and the orientation of the transmitter, sensor array (receivers), metal, and intervening materials like concrete and air. Based on the modeling and specifications, we designed and fabricated prototype sensor modules. We then acquired and fabricated test samples to characterize and optimize the sensors. Finally, we built a complete prototype for testing on actual concrete structures. This new NDT technology has high promise for greatly improving capabilities in the inspection of steel reinforcements within concrete structures, such as rebar, liners, anchors, and prestressing cables. This method could be valuable in the maintenance of nuclear power plants, and many other structures critical to our nation’s infrastructure.

42 ENGINEERING↗

The Effect of Environmental Relative Humidity on Carbonation and Oxidation in a Cementitious Waste Form - 18448

Cementitious material has been developed and used for the nuclear waste disposal. Cast Stone, a type of cementitious waste form, is considered for solidification and immobilization of part of low activity radioactive waste (LAW) at DOE Hanford Site in Richland, WA. During its life cycle, the waste form, which is produced from Portland cement, fly ash, blast furnace slag and liquid waste, is subject to reaction with carbon dioxide and oxygen, both in gaseous and dissolved form. The reactions may alter the physical and chemical properties of the waste form and thus change its retention ability for the radionuclides. Therefore, understanding the rate and the impact of oxidation and carbonation in the material is important for projecting the long-term performance of Cast Stone. However, the rate of carbonation and oxidation in Cast Stone closely depends on the moisture content in the material, which varies largely with the environmental relative humidity (RH). In this study, experiments are carried out to study the effect of environmental relative humidity on the carbonation and oxidation rate as well as the leaching of the constituents from Cast Stone. Cast Stone samples doped with Cr as a reaction indicator are aged for 16 to 32 weeks under N{sub 2}, air, and 2% CO{sub 2} (in nitrogen) environments with various relative humidities (15%, 40%, 68%, 100%). After aging, samples were tested for the pH-dependent leaching (EPA Method 1313) and mass transfer rate under diffusion-controlled leaching (EPA Method 1315) of constituents. The progress of the carbonation was measured for each condition to determine the rate of carbonation front ingress. The results show that environmental relative humidity strongly influences carbonation and oxidation in Cast Stone; however, the impact is different for the rate of reaction and for the extent of reactions. The former refers to the rate at which the reaction front ingresses, while the latter refers to the fraction of the material reacted. For both carbonation and oxidation, the largest impact of the reactions at the exposure surface is observed at intermediate relative humidity (68%). However, for carbonation, the reaction front evolves more rapidly under drier conditions, with the highest rate observed at 15% RH. As a result, carbonation and oxidation have different degree of impact on the leaching behavior of Cast Stone samples aged under various relative humidities. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Performance Testing of Tracer Gas and Tracer Aerosol Detectors for use in Radionuclide NESHAP Compliance Testing

The Rad-NESHAP program, part of the Air Quality Compliance team of LANL’s Compliance Programs group (EPC-CP), and the Radiation Instrumentation & Calibration team, part of the Radiation Protection Services group (RP-SVS), frequently partner on issues relating to characterizing air flow streams. This memo documents the most recent example of this partnership, involving performance testing of sulfur hexafluoride detectors for use in stack gas mixing tests. Additionally, members of the Rad-NESHAP program performed a functional trending test on a pair of optical particle counters, comparing results from a non-calibrated instrument to a calibrated instrument. Prior to commissioning a new stack sampling system, the ANSI Standard for stack sampling requires that the stack sample location must meet several criteria, including uniformity of tracer gas and aerosol mixing in the air stream. For these mix tests, tracer media (sulfur hexafluoride gas or liquid oil aerosol particles) are injected into the stack air stream and the resulting air concentrations are measured across the plane of the stack at the proposed sampling location. The coefficient of variation of these media concentrations must be under 20% when evaluated over the central 2/3 area of the stack or duct. The instruments which measure these air concentrations must be tested prior to the stack tests in order to ensure their linear response to varying air concentrations of either tracer gas or tracer aerosol. The instruments used in tracer gas and aerosol mix testing cannot be calibrated by the LANL Standards and Calibration Laboratory, so they would normally be sent off-site for factory calibration by the vendor. Operational requirements can prevent formal factory calibration of some instruments after they have been used in hazardous settings, e.g., within a radiological facility with potential airborne contamination. The performance tests described in this document are intended to demonstrate the reliable performance of the test instruments for the specific tests used in stack flow characterization.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Texas A&M University Mobile Facility Measurements during TRACER (Field Campaign Report)

One of the main goals of the U.S Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Tracking Aerosol Convection Interactions Experiment (TRACER) near Houston, Texas is to improve understanding of how meteorology and aerosols impact storm dynamical and microphysical processes in deep convection to better constrain and improve their model representation. The Houston area is strongly influenced by sea- and bay-breeze circulations that generate convergence and help to initiate and organize deep convection. To properly isolate and understand the roles of varied meteorological conditions and cloud condensation nuclei (CCN) and ice nucleation particles (INP) distributions in different air masses, co-located thermodynamic, kinematic, and aerosol vertical profile observations are needed. The focus of this campaign was to provide key measurements in air masses both in front of and behind sea/bay breeze fronts moving through the greater Houston area to sample the airmass heterogeneity. The overarching scientific goal of this campaign is to understand how the vertical distributions of both CCN and INP correspond to the inflow layer of deep convection in maritime, background continental, and polluted continental air masses, and how these variations influence deep convection. To fully sample the heterogeneity in both meteorological conditions and aerosols across the sea-breeze front (SBF), Texas A&M University (TAMU) deployed a InterMet 3050A 403 MHz mobile unit launching iMet-4 radiosondes and the new Rapid Onsite Atmospheric Measurement Van (ROAM-V) for aerosol sampling during the TRACER intensive operational period (IOP) from June to September 2022. The suite of instruments deployed on ROAM-V included a condensation particle counter (CPC; GRIMM Model 5.403 CPC), scanning mobility particle sizer (SMPS; TSI 3750 detector, TSI 3082 classifier, TSI 3088 neutralizer, TSI 3081A differential mobility analyzer), cloud condensation nuclei counter (Droplet Measurement Technologies CCN counter), micropulse lidar (Droplet Measurement Technologies micropulse lidar [miniMPL]), and a Davis Rotating Uniform size-cut Monitor (DRUM; DRUMAir 4-DRUM). Before sampling at each location, the latitude and longitude were recorded using the Global Positioning System (GPS) on the phone application “My Altitude”. The DRUM data were collected as part of a closely related ARM field campaign and also supported by DOE Atmospheric System Research grant DE-SC0021047. The TAMU team sampled these airmass heterogeneities by strategically choosing deployment sites in a different airmass than the ARM fixed sites in La Porte and Guy, Texas. On days when the sea/bay breeze boundary was pushing inland, the TAMU team would usually sample the airmass on the maritime side of the SBF at a coastal site in Galveston, Texas in the early afternoon (1730-1900 UTC) and then move inland ahead of the SBF to sample the airmass on the continental side during late afternoon (2030-2230). Figure 1 shows the Galveston maritime site and the array of sites for the late afternoon continental measurements.

54 ENVIRONMENTAL SCIENCES↗

Perform Tests and Document Results and Analysis of Oxide Layer Effects and Comparisons

During the initial feasibility test using actual used nuclear fuel (UNF) cladding in FY 2012, an incubation period of 30–45 minutes was observed in the initial dry chlorination. The cladding hull used in the test had been previously oxidized in a dry air oxidation pretreatment prior to removal of the fuel. The cause of this incubation period was attributed to the resistance to chlorination of an oxide layer imparted by the dry oxidation pretreatment on the cladding. Subsequently in 2013, researchers at the Korea Atomic Energy Institute (KAERI) reported on their chlorination study [R1] on ~9-gram samples of unirradiated ZirloTM cladding tubes that had been previously oxidized in air at 500oC for various time periods to impart oxide layers of varying thickness. In early 2014, discussions with Indefinite Delivery, Indefinite Quantity (IDIQ) contracted technical consultants from Westinghouse described their previous development (and patents) [R2] on methods of chemical washing to remove some or all of the hydrous oxide layer imparted on UNF cladding during irradiation in light water reactors (LWRs) . Thus, the Oak Ridge National Laboratory (ORNL) study, described herein, was planned to extend the KAERI study on the effects of anhydrous oxide layers, but on larger ~100-gram samples of unirradiated zirconium alloy cladding tubes, and to investigate the effects of various methods of chemical pretreatment prior to chlorination with 100% chlorine on the average reaction rates and Cl2 usage efficiencies.

Korea Atomic Energy Institute (KAERI)↗

Real time outdoor exposure testing of solar cell modules and component materials

Plastic samples, solar cell modules, and sub-modules were exposed at test sites in Florida, Arizona, Puerto Rico, and Cleveland, Ohio, in order to determine materials suitable for use in solar cell modules with a proposed 20-year lifetime. Various environments were encountered including subtropical, subtropical with a sea air atmosphere, desert, rain forest, normal urban, and urban-polluted. The samples were exposed for periods up to six months. Materials found not suitable were polyurethane, polyester, Kapton, Mylar, and UV-stabilized Lexan. Suitable materials were acrylic, FEP-A, and glass. The results of exposure of polyvinylidene fluoride were dependent on the specific formulation, but several types appear suitable. RTV silicone rubber (clear) appears to pick up and hold dirt both as a free film and as a potting medium for modules. The results indicate that dirt accumulation and cleanability are important factors in the selection of solar cell module covers and encapsulants.

Anagnostou, E.↗

SU-F-T-362: Quantification and Modelling of the Ionization Chamber Simulation Effective Points On Monaco Treatment Planning System

Purpose: Because of statistical noise in Monte Carlo dose calculations, effective point doses may not be accurate. Volume spheres are useful for evaluating dose in Monte Carlo plans, which have an inherent statistical uncertainty.We use a user-defined sphere volume instead of a point, take sphere sampling around effective point make the dose statistics to decrease the stochastic errors. Methods: Direct dose measurements were made using a 0.125cc Semiflex ion chamber (IC) 31010 isocentrically placed in the center of a homogeneous Cylindric sliced RW3 phantom (PTW, Germany).In the scanned CT phantom series the sensitive volume length of the IC (6.5mm) were delineated and defined the isocenter as the simulation effective points. All beams were simulated in Monaco in accordance to the measured model. In our simulation using 2mm voxels calculation grid spacing and choose calculate dose to medium and request the relative standard deviation ≤0.5%. Taking three different assigned IC over densities (air electron density(ED) as 0.01g/cm3 default CT scanned ED and Esophageal lumen ED 0.21g/cm3) were tested at different sampling sphere radius (2.5, 2, 1.5 and 1 mm) statistics dose were compared with the measured does. Results: The results show that in the Monaco TPS for the IC using Esophageal lumen ED 0.21g/cm3 and sampling sphere radius 1.5mm the statistical value is the best accordance with the measured value, the absolute average percentage deviation is 0.49%. And when the IC using air electron density(ED) as 0.01g/cm3 and default CT scanned EDthe recommented statistical sampling sphere radius is 2.5mm, the percentage deviation are 0.61% and 0.70%, respectivly. Conclusion: In Monaco treatment planning system for the ionization chamber 31010 recommend air cavity using ED 0.21g/cm3 and sampling 1.5mm sphere volume instead of a point dose to decrease the stochastic errors. Funding Support No.C201505006.

60 APPLIED LIFE SCIENCES↗

Phase transition and luminescence properties of GdTiNbO6:Eu3+ formed by hydrothermal route

Highlights: • Phase transition and luminescence of hydrothermal GdTiNbO{sub 6}:Eu{sup 3+} were investigated. • RE{sup 3+} radius 0.1061 nm was the boundary between the aeschynite and euxenite. • GdTiNbO{sub 6}:0.30Eu{sup 3+} was preferred for UV-B excitation, 0.50Eu{sup 3+} for Vis-light excitation. • The decay lifetime of 615 nm emission (ex = 405 nm) was 570∼571 μs. - Abstract: The dependences of phase transition and luminescence properties upon both Eu{sup 3+} concentration and heating temperature in air were investigated for GdTiNbO{sub 6}:Eu{sup 3+} fine crystals formed hydrothermally at 240 °C as aeschynite-type Eu{sub x}Gd{sub 1-x}TiNbO{sub 6} solid solution. The as-prepared aeschynite solid solution in the concentration range x ≥ 0.70 did not show the phase transformation from an aeschynite- to an euxenite-type structure caused by heating at 1300 °C for 1 h in air. The present study suggested that the phase boundary between the aeschynite- and euxenite-type RETiNbO{sub 6} in the EuTiNbO{sub 6}-GdTiNbO{sub 6} system, where RE was a rare earth, lay in the average RE{sup 3+} ionic radius 0.1061 nm. The intense emissions attributed to the {sup 5}D{sub 0}→{sup 7}F{sub 1} and {sup 5}D{sub 0}→{sup 7}F{sub 2} transitions of Eu{sup 3+} for the as-prepared samples were more improved by heating at 1100–1300°C in air. The material doped with 30 mol% Eu{sup 3+} was preferred for UV-B excitation, in contrast, the material with 50 mol% Eu{sup 3+} was preferred for visible light excitation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Model Study of the Sources of Upper Tropospheric Ozone Over The Atlantic, with Emphasis on Interhemispheric Asymmetries

Measurements of ozone and aerosols from ships transecting the Atlantic Ocean reveal considerable interhemispheric asymmetries in the vertical structure of the ozone distribution. There is much more upper tropospheric ozone to the South of the Equator than in the northern hemisphere. These profiles suggest that the air in the southern hemispheric tropics and subtropics has a source in the stratosphere, while that in the northern hemisphere originates in the boundary layer. A model experiment designed to investigate this problem will be discussed. They are based on a new general circulation model, based on a Finite-Volume dynamical core and the physical parametrizations from the Community Climate Model at the National Center for Atmospheric Research (NCAR). The model simulates a climatological state in reasonable agreement with observations, comparable to other contemporary climate models, but has a much more accurate transport capability than most other present-day models. The experiment involves using a suite of tracers, designed to highlight air from different source regions. Some of these (water vapor and ozone) represent real atmospheric quantities, while others are markers which indicate whether the air originates in the stratosphere, the boundary layer, or has traversed regions of convection (for example). The experiments were run for periods of up to one month, initialized from snapshots from a long climate integration of the model. A sample of results will be presented, chosen to illustrate the different sources of air in the upper troposphere and the physical mechanisms by which these air parcels arrived there.

Pawson, Steven↗

Precision Measurement of the Microwave Dielectric Loss of Sapphire in the Quantum Regime with Parts-per-Billion Sensitivity

Dielectric loss is known to limit state-of-the-art superconducting qubit lifetimes. Recent experiments imply upper bounds on bulk dielectric loss tangents on the order of 100 parts per billion but because these inferences are drawn from fully fabricated devices with many loss channels, these experiments do not definitely implicate or exonerate the dielectric. To resolve this ambiguity, we devise a measurement method capable of separating and resolving bulk dielectric loss with a sensitivity at the level of 5 ×10 –9 . The method, which we call the dielectric dipper, involves the in situ insertion of a dielectric sample into a high-quality microwave cavity mode. Smoothly varying the participation of the sample in the cavity mode enables a differential measurement of the dielectric loss tangent of the sample. The dielectric dipper can probe the low-power behavior of dielectrics at cryogenic temperatures and does so without the need for any lithographic process, enabling controlled comparisons of substrate materials and processing techniques. We demonstrate the method with measurements of sapphire grown by edge-defined film-fed growth (EFG) in comparison to high-grade sapphire grown by the heat-exchanger method (HEMEX). For EFG sapphire, we infer a bulk loss tangent of 63⁢(8) ×10 –9 and a substrate-air interface loss tangent of 15⁢(3) ×10 –4 (assuming a sample surface thickness of 3 nm). For a typical transmon, this bulk loss tangent would limit device quality factors to Q ≲20 ×10 6 , suggesting that bulk loss is likely the dominant loss mechanism in the longest-lived transmons on sapphire. We also demonstrate this method on HEMEX sapphire and bound its bulk loss tangent to be less than 19⁢(6) ×10 –9 . As this bound is about 3 times smaller than the bulk loss tangent of EFG sapphire, the use of HEMEX sapphire as a substrate would lift the bulk dielectric coherence limit of a typical transmon qubit to several milliseconds.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Factors affecting the sticking of insects on modified aircraft wings

Previous work showed that the total number of insects sticking to an aluminum surface was reduced by coating the aluminum surface with elastomers. Due to a large number of possible experimental errors, no correlation between the modulus of elasticity, the elastomer, and the total number of insects sticking to a given elastomer was obtained. One of the errors assumed to be introduced during the road test is a variable insect flux so the number of insects striking one surface might be different from that striking another sample. To eliminate this source of error, the road test used to collect insects was simulated in a laboratory by development of an insect impacting technique using a pipe and high pressure compressed air. The insects are accelerated by a compressed air gun to high velocities and are then impacted with a stationary target on which the sample is mounted. The velocity of an object exiting from the pipe was determined and further improvement of the technique was achieved to obtain a uniform air velocity distribution.

Yi, O.↗

Novel dense membrane for hydrogen separation for energy applications

The main objectives of this project are: (1) Characterization of the thermo mechanical properties of the novel dense HTM bulk sample; (2) Development of a correlation among the intrinsic factors (such as grain size and phase distribution), and the extrinsic factors (such as temperature and atmosphere) and the thermo-mechanical properties (such as strengths and stress) to predict the performance of a HTM system (HTM membrane and porous substrate) ; and (3) Evaluation of the stability of the novel HTM membrane and its property correlations after thermal cycling. Based on all results and analysis of the thermo mechanical properties for the HTM cermet bulk samples, several important conclusions were made. The mean σfs at room temperature is approximately 356 MPa for the HTM cermet. The mean σfs value decreases to 284 MPa as the temperature increases to 850?C. The Difference difference in atmosphere, such as air or N2, had an insignificant effect on the flexural strength values at 850?C for the HTM cermet. The HTM cermet samples at room temperature and at 500?C fractured without any significant plastic deformation. Whereas, at 850?C, the HTM cermet samples fractured, preceded by an extensive plastic deformation. It seems that the HTM cermet behaves more like an elastic material such as a nonmetal ceramic at the room temperature, and more like a ductile material at increased temperature (850?C). The exothermic peak during the TG/DTA tests centered at 600?C is most likely associated with both the enthalpy change of transformation from the amorphous phase into crystalline zirconia and the oxidation of Pd phase in HTM cermet in air. The endothermic peak centered at 800?C is associated with the dissociation of PdO to Pd for the HTM cermet sample in both inert N2 environment and air. There is a corresponding weight gain as oxidation occurs for palladium (Pd) phase to form palladium oxide (PdO) and there is a weight loss as the unstable PdO is dissociated back to Pd and oxygen. The normal stress and shear stresses from the Mohr?s circle indicate that the residual stress in the HTM cermet sample is mainly as compressive residual stress in the magnitude of -135 to -155 MP, and with very little shear stress (in the magnitude of 10 MPa). The magnitude of change in the normal stress and the shear stress is insignificant in the HTM after 120 thermal cycles. However, the principle normal stress changes from compressive to tensile residual stress and there is a significant increase in the shear stress after 500 thermal cycles. The calculated value based on the equation and the Mohr?s circle is found to be consistent with the experimental value for the as-received HTM cermet samples. At some rotation (φ) angle, the residual stress was found to be as tensile stress. Most ceramic material is weak in tension, and develops microscopic cracks. With treatment of 120 thermal cycles between 50?850?C, the HTM- sample exhibited thermally-induced cracks on the surface. Visually observable cracks appeared on the surface of HTM cermet with continuous thermal cycling, after 500 thermal cycles. The XRD powder diffraction analysis indicated an increased amount of crystalline PdO crystalline in HTM cermet after 120 and 500 thermal cycles as compare to the as-received samples. The Pd crystalline peaks were found to significantly decrease in peak intensity with thermal cycling. Higher peak intensity for PdO phase was observed with increased number of thermal cycles. A Monoclinic monoclinic zirconia phase was first identified in the as-received HTM as-received sample. However, with thermal cycling treatment of both 120 and 500 thermal cycles, the M-ZrO2 phase is transformed to the tetragonal YSZ, which is consistent with the thermal analysis results by TG/DTA. Correlations of the microstructural and thermo-mechanical properties of both selected reference material and ANL-3e HTM cermet bulk sample are affected mainly by porosity and microstructural features, such as grain size and pore size/distribution. The Young?s Modulus (E-value), especially, is positively proportional to the flexural strength for materials with similar crystallographic structure. For different crystallographic materials, physical properties such as E and density are independent of mechanical properties, such as flexural strength.. Microstructural properties, particularly, grain size and crystallographic structure, and thermodynamic properties are the main factors affecting the mechanical properties at both room and high temperatures. The oxidation and the plasticity of Pd phase mainly affect the mechanical properties of HTM cermet at high temperature or with thermal cycling treatment. Changes in the residual stress and microstructure affect the mechanical properties of HTM when subjected to high temperature or thermal cycling treatment.

08 HYDROGEN↗

Microorganism sample device

Device, based on gel-impingement technique, collects microorganism specimens from circulating air streams. Device is useful to air pollution studies involving the collection of airborne microbial specimens.

Reed, L. L.↗

On evaluating compliance with air pollution levels 'not to be exceeded more than once a year'

Under a sampling program operated in conformity with EPA guidelines, calculational procedures are described for estimating the corresponding ambient pollution level. The statistical independence of the data, the commutativity of expectation and exponential operations, and the statistical variability of the calculated results are quantitatively evaluated. It is shown that the recommended sampling frequencies of every third to every sixth day are inadequate in determining conformity when the standards are expressed as levels not to be exceeded more than once a year.

Neustadter, H. E.↗

Induced Environment Contamination Monitor (IECM), air sampler - Results from the Space Transport System (STS-2) flight

An investigation involving sampling the rapidly changing environment of the Shuttle cargo bay is considered. Four time-integrated samples and one rapid acquisition sample were collected to determine the types and quantities of contaminants present during ascent and descent of the Shuttle. The sampling times for the various bottles were controlled by valves operated by the Data Acquisition and Control System (DACS) of the IECM. Many of the observed species were found to be common solvents used in cleaning surfaces. When the actual volume sampled is taken into account, the relative mass of organics sampled during descent is about 20 percent less than during ascent.

Peters, P. N.↗

Synthesis of single-phase Sr{sub 3}Co{sub 2}Fe{sub 24}O{sub 41} Z-type ferrite by polymerizable complex method

Highlights: {yields} Single-phase Sr{sub 3}Co{sub 2}Z was obtained in a very narrow temperature range. {yields} Sr{sub 3}Co{sub 2}Z ferrite prepared by polymerizable complex method showed typical M-H curve of soft ferrite. -- Abstract: Synthesis of single-phase Sr{sub 3}Co{sub 2}Fe{sub 24}O{sub 41} Z-type (Sr{sub 3}Co{sub 2}Z) ferrite was realized by adopting the polymerizable complex method. Crystal structure of samples has been investigated by powder X-ray diffraction (XRD). Single-phase Sr{sub 3}Co{sub 2}Z ferrite was obtained by heating at 1473 K for 5 h in air. Magnetic properties were discussed by measurements of M-H curves with vibrating sample magnetometer (VSM). Sr{sub 3}Co{sub 2}Z ferrite prepared by polymerizable complex method showed typical M-H curve of soft ferrite, with a saturation magnetization of 21.5{mu}{sub B}/formula unit (50.5 emu/g) and a coercive force of 0.014 T at room temperature.

36 MATERIALS SCIENCE↗

Synthesis and characterization of nanocrystalline Zn ferrites substituted with Ni

Highlights: {yields} Ni{sub x}Zn{sub 1-x}Fe{sub 2}O{sub 4} are synthesized by sol-gel auto-combustion method using tartaric acid. {yields} XRD patterns reveal spinel structure and the crystallite size is max. 40 nm. {yields} SEM images for Ni{sub 0.6}Zn{sub 0.4}Fe{sub 2}O{sub 4} confirm the nano-scale crystallite size. {yields} The highest value of samples porosity belongs to Ni{sub 0.6}Zn{sub 0.4}Fe{sub 2}O{sub 4}. {yields} The maximum value of the magnetization is 63 emu/g for Ni{sub 0.8}Zn{sub 0.2}Fe{sub 2}O{sub 4}. -- Abstract: Nanocrystalline powders of nickel substituted zinc ferrite with general formula Ni{sub x}Zn{sub 1-x}Fe{sub 2}O{sub 4} (x = 0, 0.2, 0.4, 0.6, 0.8, 1) have been synthesized via sol-gel auto-combustion method using tartaric acid as combustion-complexing agent. Samples were sintered at 773 K and 973 K in static air atmosphere. The absence of the organic phase and the spinel formation were monitored by using Fourier transform infrared spectroscopy. The structure and crystallite size were analyzed from X-ray diffraction data revealing spinel mono-phase formation in the range of nanometric crystallite size confirmed also through scanning electron microscopy. Mean size of crystallites lay in the range 20-40 nm. The influence of nickel content on the microstructure was investigated considering the crystallite size, distance between adjacent crystal planes, lattice parameter and porosity. The variation of magnetic properties of the samples was studied by using vibrating samples magnetometer and discussed considering the proposed cation distribution, relative bond angles and canting angles. The highest maximum value of the magnetization (63 emu/g) was found for Ni{sub 0.8}Zn{sub 0.2}Fe{sub 2}O{sub 4}.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Analysis of ablation debris from natural and artificial iron meteorites

Iron and nickel-iron samples subjected to treatment by an arc-heated plasma of ionized air were used to model meteor ablation. The artificial ablation debris and fusion crusts were compared to the fusion crusts of three natural iron meteorities and to magnetic spherules from deep-sea manganese nodules. An outer discontinuous crust of magnetite and wuestite, followed by an unoxidized metallic zone, was observed in the artificially produced samples. Fractionation of less volatile elements was also noted.

Blanchard, M. B.↗