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At least 1,459 records · Page 81

Condensed Phase Deactivation of Solid Brønsted Acids in the Dehydration of Fructose to Hydroxymethylfurfural

Catalyst deactivation resulting from the hydrothermal leaching of sulfonic acid residues and the deposition of carbonaceous residues was studied using condensed phase flow reactor experiments along with state-of-the-art solid-state NMR. Several commercially available sulfonic acid-containing heterogeneous Brønsted acids were compared by measuring the rates of sulfonic acid breakdown at hydrothermal flow conditions of 160 °C. Amberlyst 45 was found to show higher hydrothermal stability when compared to both Nafion and Amberlyst 15, with <10% loss in acidity after 48 h. The dehydration reaction of fructose to hydroxymethylfurfural (HMF) was used as a model system to compare deactivation rates from carbon deposition (fouling) to those from sulfur leaching, and deactivation from fouling was shown to be dramatically faster than that from sulfonic acid leaching alone. Fouling rates were then investigated in greater detail by comparing the influence of several factors including reactant, solvent, residence time, and feed concentration. The only successful approach to minimize fouling was the use of a polar aprotic solvent [dimethyl sulfoxide (DMSO)] with dilute (50 mM) reactant streams. In aqueous systems, operating the reactor in a regime with low conversion conditions (short residence times) does not significantly improve the longevity of the catalyst. Spent catalysts were characterized using 13C solid-state NMR spectroscopy enhanced by dynamic nuclear polarization. Additionally, in situ 1H and 13C high-resolution magic angle spinning (HR-MAS) solid-state NMR spectroscopies were used to investigate the solvent influence at the catalyst interface. The HR-MAS NMR studies showed that in polar aprotic solvents, the increased acidity leads to greater selectivity toward HMF; more importantly, that the dehydration products do not readily adhere to the surface in DMSO, in contrast to their behavior in water. The results demonstrate that more active and longer-lived acid catalysts could be obtained by tuning the solvent and surface polarity to allow for efficient desorption of products, thereby reducing the catalyst deactivation that occurs due to fouling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Combination of two Gas Electron Multipliers and a Micromegas as gain elements for a time projection chamber

We measured the properties of a novel combination of two Gas Electron Multipliers with a Micromegas for use as amplification devices in high-rate gaseous time projection chambers. The goal of this design is to minimize the buildup of space charge in the drift volume of such detectors in order to eliminate the standard gating grid and its resultant dead time, while preserving good tracking and particle identification performance. To characterize this micro-pattern gas detector configuration, we measured the positive ion back-flow and energy resolution at various element gains and electric fields, using a variety of gases, and additionally studied crosstalk effects and discharge rates. At a gain of 2000, this configuration achieves an ion back-flow below 0.4% and an energy resolution better than σ / E = 12 % for 55 Fe X-rays.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Finite difference schemes for long-time integration

Finite difference schemes for the evaluation of first and second derivatives are presented. These second order compact schemes were designed for long-time integration of evolution equations by solving a quadratic constrained minimization problem. The quadratic cost function measures the global truncation error while taking into account the initial data. The resulting schemes are applicable for integration times fourfold, or more, longer than similar previously studied schemes. A similar approach was used to obtain improved integration schemes.

Haras, Zigo↗

Automated Testing Experience of the Linear Aerospike SR-71 Experiment (LASRE) Controller

System controllers must be fail-safe, low cost, flexible to software changes, able to output health and status words, and permit rapid retest qualification. The system controller designed and tested for the aerospike engine program was an attempt to meet these requirements. This paper describes (1) the aerospike controller design, (2) the automated simulation testing techniques, and (3) the real time monitoring data visualization structure. Controller cost was minimized by design of a single-string system that used an off-the-shelf 486 central processing unit (CPU). A linked-list architecture, with states (nodes) defined in a user-friendly state table, accomplished software changes to the controller. Proven to be fail-safe, this system reported the abort cause and automatically reverted to a safe condition for any first failure. A real time simulation and test system automated the software checkout and retest requirements. A program requirement to decode all abort causes in real time during all ground and flight tests assured the safety of flight decisions and the proper execution of mission rules. The design also included health and status words, and provided a real time analysis interpretation for all health and status data.

Larson, Richard R.↗

Utilizing Small Telescopes Operated by Citizen Scientists for Transiting Exoplanet Follow-up

Due to the efforts by numerous ground-based surveys and NASA's Kepler and Transiting Exoplanet Survey Satellite (TESS), there will be hundreds, if not thousands, of transiting exoplanets ideal for atmospheric characterization via spectroscopy with large platforms such as James Webb Space Telescope and ARIEL. However their next predicted mid-transit time could become so increasingly uncertain over time that significant overhead would be required to ensure the detection of the entire transit. As a result, follow-up observations to characterize these exoplanetary atmospheres would require less-efficient use of an observatory's time—which is an issue for large platforms where minimizing observing overheads is a necessity. Here we demonstrate the power of citizen scientists operating smaller observatories (≤1 m) to keep ephemerides "fresh," defined here as when the 1σ uncertainty in the mid-transit time is less than half the transit duration. We advocate for the creation of a community-wide effort to perform ephemeris maintenance on transiting exoplanets by citizen scientists. Such observations can be conducted with even a 6 inch telescope, which has the potential to save up to ∼10,000 days for a 1000-planet survey. Based on a preliminary analysis of 14 transits from a single 6 inch MicroObservatory telescope, we empirically estimate the ability of small telescopes to benefit the community. Observations with a small-telescope network operated by citizen scientists are capable of resolving stellar blends to within 5''/pixel, can follow-up long period transits in short-baseline TESS fields, monitor epoch-to-epoch stellar variability at a precision 0.67% ± 0.12% for a 11.3 V-mag star, and search for new planets or constrain the masses of known planets with transit timing variations greater than two minutes.

Robert T. Zellem↗

Optimal trajectories for aeroassisted orbital transfer

Consideration is given to classical and minimax problems involved in aeroassisted transfer from high earth orbit (HEO) to low earth orbit (LEO). The transfer is restricted to coplanar operation, with trajectory control effected by means of lift modulation. The performance of the maneuver is indexed to the energy expenditure or, alternatively, the time integral of the heating rate. Firist-order optimality conditions are defined for the classical approach, as are a sequential gradient-restoration algorithm and a combined gradient-restoration algorithm. Minimization techniques are presented for the aeroassisted transfer energy consumption and time-delay integral of the heating rate, as well as minimization of the pressure. It is shown that the eigenvalues of the Jacobian matrix of the differential system is both stiff and unstable, implying that the sequential gradient restoration algorithm in its present version is unsuitable. A new method, involving a multipoint approach to the two-poing boundary value problem, is recommended.

Miele, A.↗

Optical detection of large meteoroids in space

CCD sensors placed across the focal plane of large Schmidt telescopes have great potential for detecting and measuring the very low flux in space of meteoroids with diameters larger than 1 meter. With the Palomar 'Big Schmidt', a detection rate of 1.4 per hour is obtained for meteoroids between 0.6 and 200 meters in diameter. For the Baker-Nunn 'Satellite Tracking Camera', the corresponding rate is about 0.8 per hour. The key to obtaining such high detection rates derives from approximately setting the sensor integration time equal to the time it takes a meteoroid to cross a pixel field of view. This minimizes signal to noise problems and is accomplished, in practice, by multiple summing of short integration time data records to obtain data records of longer effective integration times.

Zook, H. A.↗

OPTIM: Computer program to generate a vertical profile which minimizes aircraft fuel burn or direct operating cost. User's guide

A profile of altitude, airspeed, and flight path angle as a function of range between a given set of origin and destination points for particular models of transport aircraft provided by NASA is generated. Inputs to the program include the vertical wind profile, the aircraft takeoff weight, the costs of time and fuel, certain constraint parameters and control flags. The profile can be near optimum in the sense of minimizing: (1) fuel, (2) time, or (3) a combination of fuel and time (direct operating cost (DOC)). The user can also, as an option, specify the length of time the flight is to span. The theory behind the technical details of this program is also presented.

Source record↗

Minimizing Energy Consumption from Connected Signalized Intersections by Reinforcement Learning

Explicit energy minimization objectives are often discouraged in signal optimization algorithms due to its negative impact on mobility performance. One potential direction to solve this problem is to provide a balanced objective function to achieve desired mobility with minimized energy consumption. This research developed a reinforcement learning (RL) based control with reward functions considering energy and mobility in a joint manner-a penalty function is introduced for number of stops. Further, we proposed a clustering-based technique to make the state-space finite which is critical for a tractable implementation of the RL algorithm. We implemented the algorithm in a calibrated NG-SIM network within a traffic micro-simulator-PTV VISSIM. With sole focus on energy, we report 47% reduction in energy consumption when compared with existing signal control schemes, however causing a 65.6% increase in system travel time. In contrast, the control strategy focusing on energy minimization with penalty for stops yields 6.7% reduction in energy consumption with 27% increase in system travel time. The developed RL algorithm with a flexible penalty function in the reward will achieve desired energy goals for a network of signalized intersections without compromising on the mobility performance.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Reconstruction of phonon relaxation times from systems featuring interfaces with unknown properties

We present a method for reconstructing the phonon relaxation-time function $τ_ω = τ(ω)$ (including polarization) and associated phonon free-path distribution from thermal spectroscopy data for systems featuring interfaces with unknown properties. Our method does not rely on the effective thermal-conductivity approximation or a particular physical model of the interface behavior. The reconstruction is formulated as an optimization problem in which the relaxation times are determined as functions of frequency by minimizing the discrepancy between the experimentally measured temperature profiles and solutions of the Boltzmann transport equation for the same system. Interface properties such as transmissivities are included as unknowns in the optimization; however, because for the thermal spectroscopy problems considered here the reconstruction is not very sensitive to the interface properties, the transmissivities are only approximately reconstructed and can be considered as byproducts of the calculation whose primary objective is the accurate determination of the relaxation times. The proposed method is validated using synthetic experimental data obtained from Monte Carlo solutions of the Boltzmann transport equation. The method is shown to remain robust in the presence of uncertainty (noise) in the measurement.

42 ENGINEERING↗

Teeport: Break the Wall Between the Optimization Algorithms and Problems

Optimization algorithms/techniques such as genetic algorithm, particle swarm optimization, and Gaussian process have been widely used in the accelerator field to tackle complex design/online optimization problems. However, connecting the algorithm with the optimization problem can be difficult, as the algorithms and the problems may be implemented in different languages, or they may require specific resources. We introduce an optimization platform named Teeport that is developed to address the above issues. This real-time communication-based platform is designed to minimize the effort of integrating the algorithms and problems. Once integrated, the users are granted a rich feature set, such as monitoring, controlling, and benchmarking. Some real-life applications of the platform are also discussed.

97 MATHEMATICS AND COMPUTING↗

Advanced Langmuir Probe (LP)

The dynamic response of the MK-2 version of the Langmuir probe amplifier was studied. The settling time of the step response is increased by: (1) stray node-to-ground capacitance at series connections between high value feedback resistors; and (2) input capacitance due to the input cable, FET switches, and input source follower. The stray node-to-ground capacitances can be reduced to tolerable levels by elevating the string of feedback resistors above the printing board. A new feedback network was considered, with promising results. The design uses resistances having much lower nominal values, thereby minimizing the effect of stray capacitances. Faster settling times can be achieved by using an operational amplifier having a higher gain-bandwidth product.

Voronka, N. R.↗

Virtual Reality as a Medium for Sensorimotor Adaptation Training and Spaceflight Countermeasures

Astronauts experience a profound sensorimotor adaptation during transition to and from the microgravity environment of space. With the upcoming shift to extra‐long duration missions (upwards of 1 year) aboard the International Space Station, the immediate risks to astronauts during these transitory periods become more important than ever to understand and prepare for. Recent advances in virtual reality technology enable everyday adoption of these tools for entertainment and use in training. Embedding an individual in a virtual environment (VE) allows the ability to change the perception of visual flow, elicit automatic motor behavior and produce sensorimotor adaptation, not unlike those required during long duration microgravity exposure. The overall goal of this study is to determine the feasibility of present head mounted display technology (HMD) to produce reliable visual flow information and the expected adaptation associated with virtual environment manipulation to be used in future sensorimotor adaptability countermeasures. To further understand the influence of visual flow on gait adaptation during treadmill walking, a series of discordant visual flow manipulations in a virtual environment are proposed. Six healthy participants (3 male and 3 female) will observe visual flow information via HMD (Oculus Rift DK2) while walking on an instrumented treadmill at their preferred walking speed. Participants will be immersed in a series of VE's resembling infinite hallways with different visual characteristics: an office hallway, a hallway with pillars and the hallway of a fictional spacecraft. Participants will perform three trials of 10 min. each, which include walking on the treadmill while receiving congruent or incongruent visual information via the HMD. In the first trial, participants will experience congruent visual information (baseline) where the hallway is perceived to move at the same rate as their walking speed. The final two trials will be randomized among participants where the hallway is perceived to move at either half (0.5x) or twice (2.0x) their preferred walking speed. Participants will remain on the treadmill between trials and will not be warned of the upcoming change to visual flow to minimize preparatory adjustments. Stride length, step frequency and dual‐support time will be quantified during each trial. We hypothesize that participants will experience a rapid modification in gait performance during periods of adaptive change, expressed as a decrease in step length, an increase in step frequency and an increase in dual‐support time, followed by a period of adaptation where these movement parameters will return to near‐baseline levels. As stride length, step frequency and dual support times return to baseline values, an adaptation time constant will be derived to establish individual time‐to‐adapt (TTA). HMD technology represents a paradigm shift in sensorimotor adaptation training where gait adaptability can be stressed using off‐the‐shelf consumer products and minimal experimental equipment, allowing for greater training flexibility in astronaut and terrestrial applications alike.

Madansingh, S.↗

FPGA-Based X-Ray Detection and Measurement for an X-Ray Polarimeter

This technology enables detection and measurement of x-rays in an x-ray polarimeter using a field-programmable gate array (FPGA). The technology was developed for the Gravitational and Extreme Magnetism Small Explorer (GEMS) mission. It performs precision energy and timing measurements, as well as rejection of non-x-ray events. It enables the GEMS polarimeter to detect precisely when an event has taken place so that additional measurements can be made. The technology also enables this function to be performed in an FPGA using limited resources so that mass and power can be minimized while reliability for a space application is maximized and precise real-time operation is achieved. This design requires a low-noise, charge-sensitive preamplifier; a highspeed analog to digital converter (ADC); and an x-ray detector with a cathode terminal. It functions by computing a sum of differences for time-samples whose difference exceeds a programmable threshold. A state machine advances through states as a programmable number of consecutive samples exceeds or fails to exceed this threshold. The pulse height is recorded as the accumulated sum. The track length is also measured based on the time from the start to the end of accumulation. For track lengths longer than a certain length, the algorithm estimates the barycenter of charge deposit by comparing the accumulator value at the midpoint to the final accumulator value. The design also employs a number of techniques for rejecting background events. This innovation enables the function to be performed in space where it can operate autonomously with a rapid response time. This implementation combines advantages of computing system-based approaches with those of pure analog approaches. The result is an implementation that is highly reliable, performs in real-time, rejects background events, and consumes minimal power.

Gregory, Kyle↗

A Concept of Operations for Far-Term Surface Trajectory-Based Operations (STBO)

The goal of this far-term STBO (Surface Trajectory-Based Operations) ConOps (Concept of Operations) is to increase the efficiency and predictability of airport surface operations, and reduce the environmental impact, by incorporating a time-based component to surface operations. In the far-term NextGen timeframe, airport surface operations will transition from current-day first-come, first-served operations, to strategically scheduled operations in which pilots are recruited as active participants in meeting the precise time-based goals of NextGen surface operations. The far-term STBO concept includes two-phases. Phase 1 introduces time-based traffic flow constraint points, which divide the taxi route into segments with an assigned Required Time of Arrival (RTA). This Phase 1 approach provides temporal certainty only near the traffic flow constraint points, but not in between. Minimal augmentations to the flight deck are required to support required time of arrival (RTA) management. Phase 2 further increases precision and efficiency by introducing full four-dimensional (4D) trajectories, with an x-y location for all times t. This phase assumes adoption of advanced flight deck equipage enabling higher temporal precision sufficient to support aircraft conformance to 4D trajectories. This allows more precision and less temporal uncertainty at all times along the route.

Surface Trajectory-Based Operations (STBO)↗

TH-E-BRE-11: Adaptive-Beamlet Based Finite Size Pencil Beam (AB-FSPB) Dose Calculation Algorithm for Independent Verification of IMRT and VMAT

Purpose: In current IMRT and VMAT settings, the use of sophisticated dose calculation procedure is inevitable in order to account complex treatment field created by MLCs. As a consequence, independent volumetric dose verification procedure is time consuming which affect the efficiency of clinical workflow. In this study, the authors present an efficient Pencil Beam based dose calculation algorithm that minimizes the computational procedure while preserving the accuracy. Methods: The computational time of Finite Size Pencil Beam (FSPB) algorithm is proportional to the number of infinitesimal identical beamlets that constitute the arbitrary field shape. In AB-FSPB, the dose distribution from each beamlet is mathematically modelled such that the sizes of beamlets to represent arbitrary field shape are no longer needed to be infinitesimal nor identical. In consequence, it is possible to represent arbitrary field shape with combinations of different sized and minimal number of beamlets. Results: On comparing FSPB with AB-FSPB, the complexity of the algorithm has been reduced significantly. For 25 by 25 cm2 squared shaped field, 1 beamlet of 25 by 25 cm2 was sufficient to calculate dose in AB-FSPB, whereas in conventional FSPB, minimum 2500 beamlets of 0.5 by 0.5 cm2 size were needed to calculate dose that was comparable to the Result computed from Treatment Planning System (TPS). The algorithm was also found to be GPU compatible to maximize its computational speed. On calculating 3D dose of IMRT (∼30 control points) and VMAT plan (∼90 control points) with grid size 2.0 mm (200 by 200 by 200), the dose could be computed within 3∼5 and 10∼15 seconds. Conclusion: Authors have developed an efficient Pencil Beam type dose calculation algorithm called AB-FSPB. The fast computation nature along with GPU compatibility has shown performance better than conventional FSPB. This completely enables the implantation of AB-FSPB in the clinical environment for independent volumetric dose verification.

60 APPLIED LIFE SCIENCES↗

The Mitigation Hierarchy

The mitigation hierarchy is a widely used framework to inform conservation decisions. The hierarchy offers a structured set of steps for how projects can lessen negative impacts or lead to an increase in biodiversity. In its simplest form, the mitigation hierarchy includes three stages: (1) avoid creating impacts from the outset, (2) minimize the impacts that cannot be avoided, and (3) compensate for or offset the impacts that cannot be minimized. Proper application of the hierarchy should decrease impacts of the project over time, such that most of the impact is alleviated through avoidance, leaving a modest amount remaining to minimize, and only a residual to compensate. In practice, avoidance should be prioritized and can be a cost-effective means of mitigation. Whereas compensation should be considered the lowest priority and should only be applied in situations in which the previous mitigation steps were unable to fully alleviate undesirable impacts.

biodiversity↗

La Jerarquia de Mitigacion (Spanish)

The mitigation hierarchy is a widely used framework to inform conservation decisions. The hierarchy offers a structured set of steps for how projects can lessen negative impacts or lead to an increase in biodiversity. In its simplest form, the mitigation hierarchy includes three stages: (1) avoid creating impacts from the outset, (2) minimize the impacts that cannot be avoided, and (3) compensate for or offset the impacts that cannot be minimized. Proper application of the hierarchy should decrease impacts of the project over time, such that most of the impact is alleviated through avoidance, leaving a modest amount remaining to minimize, and only a residual to compensate. In practice, avoidance should be prioritized and can be a cost-effective means of mitigation. Whereas compensation should be considered the lowest priority and should only be applied in situations in which the previous mitigation steps were unable to fully alleviate undesirable impacts. This is the Spanish translation of NREL/FS-5000-85363, "The Mitigation Hierarchy."

biodiversity↗