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At least 1,459 records · Page 81

Design and Synthesis of Nanosensor Based on CdSe Quantum Dots Functionalized with 8-Hydroxyquinoline: a Fluorescent Sensor for Detection of Al{sup 3+} in Aqueous Solution

A novel nanosensor based on CdSe quantum dots (QDs) capped with 8-hydroxyqunoline (HQ) was developed for Al{sup 3+} ions determination in aqueous solutions. The method is based on the fluorescence enhancement of the HQ functionalized QDs in the presence of Al{sup 3+} ions, due to the strong interaction between Al{sup 3+} and HQ. Prepared nanosensor exhibited an acceptable selectivity and sensitivity for Al{sup 3+} ions in the presence of other metal ions. Plot of Log(I/I{sub 0}) against Log[Al{sup 3+}] shows a good linearity in the range of 0.02–3.0 mM, and the method could be used for detection of Al{sup 3+} ions concentration in aqueous solutions.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Ultrasensitive Photothermal Spectroscopy: Harnessing the Seebeck Effect for Attogram-Level Detection

Molecular-level spectroscopy is crucial for sensing and imaging applications, yet detecting and quantifying minuscule quantities of chemicals remain a challenge, especially when they surface adsorb in low numbers. Here, we introduce a photothermal spectroscopic technique that enables the high selectivity sensing of adsorbates with an attogram detection limit. Our approach utilizes the Seebeck effect in a microfabricated nanoscale thermocouple junction, incorporated into the apex of a microcantilever. We observe minimal thermal mass exhibited by the sensor, which maintains exceptional thermal insulation. The temperature variation driving the thermoelectric junction arises from the nonradiative decay of molecular adsorbates’ vibrational states on the tip. We demonstrate the detection of photothermal spectra of physisorbed trinitrotoluene (TNT) and dimethyl methylphosphonate (DMMP) molecules, as well as representative polymers, with an estimated mass of 10 -18 g.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

New Algorithms Manage Fourfold Redundancy

Redundant sensors, actuators, and computers improve reliability of complex control systems, such as those in nuclear powerplants and aircraft. If one or more redundant elements fail, another takes over so that normal operation is not interrupted. Quad selection filter rejects data from null-failed and hardover-failed and hardover-failed units.

Gelderloos, H. C.↗

Report on the subpanel on remapping procedures

Problems associated with remapping procedures are defined and research tasks are proposed. It is noted that the remapping/rectification process could be significantly aided through engineering systems improvements in attitude control, with subsequent improvement in spacecraft ephemeris modeling accuracy. There is a need for state-of-the-art technology assessments prior to initiation of major programs, and the high potential return from well formulated testing of algorithms on selected data sets of actual and synthetic imagery. In addition, there is a need for tasks that incorporate standard photogrammetric methodology and formulas and that more fully utilize platform and calibration data from current and proposed sensors to reproject digital imagery. The impact of improved platform stability and integration of global positioning system measurements on reduced ground segment processing needs to be critically assessed. Also highlighted is the need for a substantial effort in the development of remapping software and systems that are modular and transportable.

Source record↗

EOS - The earth observing system of the 1990s

Attention is given to the deliberations of NASA's Earth Observing System (EOS) Science and Mission Requirements Working Group, which has addressed the requirements and prospects for low earth orbit sensor platforms in the 1990s. The proposed EOS network would link data users with mission data repositories. Three EOS instrument packages have been chosen on the basis of synergistic instrument groupings for making simultaneous observations of selected phenomena over a variety of wavelengths.

Arvidson, R. E.↗

Integrated analysis tools for trade studies of spacecraft controller and sensor locations

The present investigation was conducted with the aim to evaluate the practicality and difficulties of modern control design methods for large space structure controls. The evaluation is used as a basis for the identification of useful computer-based analysis tools which would provide insight into control characteristics of a spacecraft concept. A description is presented of the wrap-rib antenna and its packaging concept. Attention is given to active control requirements, a mathematical model of structural dynamics, aspects of sensor and actuator location, the analysis approach, controllability, observability, the concept of balanced realization, transmission zeros, singular value plots, analysis results, model reduction, and an interactive computer program. It is pointed out that the application of selected control analysis tools to the wrap-rib antenna demonstrates several capabilities which can be useful during conceptual design.

Rowell, L. F.↗

Controls and guidance: Aeronautics

The overall objective is to provide a validated technology base leading to the development and exploitation of new concepts, analysis and design methodologies, and flight systems for future civil and military aircraft. This will provide increased efficiency, effectiveness, reliability, and safety. The program is organized into generic elements and vehicle-specific elements. The generic elements are control theory, guidance and display concepts, and flight crucial systems. Vehicle-specific elements are generic hypersonics, subsonic transport/commuter/general aviation, rotorcraft, and fighter/attack. Research in the control theory element is directed toward the improved flight control analysis and design methodologies for highly integrated, robust flight control designs. Flight Crucial Systems research is directed toward the development of design, assessment, and validation methodologies for flight crucial systems. The generic hypersonics research concentrates on the integration of flight control, propulsion control, sensors, and displays. The Aeronautical Controls and Guidance Program involves analytical and experimental research by in-house, university, and industry personnel. Extensive use of ground-based simulation is a characteristic of the program with selected flight experiments in a variety of aircraft.

Dibattista, John D.↗

Robust decentralized control laws for the ACES structure

Control system design for the Active Control Technique Evaluation for Spacecraft (ACES) structure at NASA Marshall Space Flight Center is discussed. The primary objective of this experiment is to design controllers that provide substantial reduction of the line-of-sight pointing errors. Satisfaction of this objective requires the controllers to attenuate beam vibration significantly. The primary method chosen for control design is the optimal projection approach for uncertain systems (OPUS). The OPUS design process allows the simultaneous tradeoff of five fundamental issues in control design: actuator sizing, sensor accuracy, controller order, robustness, and system performance. A brief description of the basic ACES configuration is given. The development of the models used for control design and control design for eight system loops that were selected by analysis of test data collected from the structure are discussed. Experimental results showing that very significant performance improvement is achieved when all eight feedback loops are closed are presented.

Collins, Emmanuel G., Jr.↗

Satellite Ocean-Color Validation Using Ships of Opportunity

The investigation s main objective is to collect from platforms of opportunity (merchant ships, research vessels) concomitant normalized water-leaving radiance and aerosol optical thickness data over the world s oceans. A global, long-term data set of these variables is needed to verify whether satellite retrievals of normalized water-leaving radiance are within acceptable error limits and, eventually, to adjust atmospheric correction schemes. To achieve this objective, volunteer officers, technicians, and scientists onboard the selected ships collect data from portable SIMBAD and Advanced SIMBAD (SIMBADA) radiometers. These instruments are specifically designed for evaluation of satellite-derived ocean color. They measure radiance in spectral bands typical of ocean-color sensors. The SIMBAD version measures in 5 spectral bands centered at 443, 490, 560, 670, and 870 nm, and the Advanced SIMBAD version in 11 spectral bands centered at 350, 380, 412, 443, 490, 510, 565, 620, 670, 750, and 870 nm. Aerosol optical thickness is obtained by viewing the sun disk like a classic sun photometer. Normalized water-leaving radiance, or marine reflectance, is obtained by viewing the ocean surface through a vertical polarizer in a specific geometry (nadir angle of 45o and relative azimuth angle of 135deg) to minimize direct sun glint and reflected sky radiation. The SIMBAD and SIMBADA data, after proper quality control and processing, are delivered to the SIMBIOS project office for inclusion in the SeaBASS archive. They complement data collected in a similar way by the Laboratoire d'Optique Atmospherique of the University of Lille, France. The SIMBAD and SIMBADA data are used to check the radiometric calibration of satellite ocean-color sensors after launch and to evaluate derived ocean-color variables (i.e., normalized water-leaving radiance, aerosol optical thickness, and aerosol type). Analysis of the SIMBAD and SIMBADA data provides information on the accuracy of satellite retrievals of normalized water-leaving radiance, an understanding of the discrepancies between satellite and in situ data, and algorithms that reduce the discrepancies, contributing to more accurate and consistent global ocean color data sets.

Frouin, Robert↗

Corrosion of Bare Carbon Steel as a Passive Sensor to Assess Moisture Availability for Biological Activity in Atacama Desert Soils

In this work we suggest the corrosion of polished bared metal coupons as a passive sensor to detect or identify the lower limit of water availability that could be suitable for biological activity in the Atacama Desert on soil or solid substrates. For this purpose, carbon steel coupons were deposited in selected sites along a west-east transect and removed at predetermined times for morphological inspection. The advantage of this procedure is that the attributes of the oxide layer (corrosion extent, morphology and oxide phases) can be considered as a fingerprint of the atmospheric moisture history at a given time interval. Two types of coupons were used, a long rectangular shape that are half-buried in a vertical position, and square shape that are deposited on the soil surface. The morphological attributes observed by SEM inspection is correlated to the so-called humectation time which is determined from local meteorological parameters. The main result is that the decreasing trend of atmospheric moisture along the transect is closely related to corrosion behavior and water soil penetration. For instance, while in the coastal site oxide phases formed on the coupon surface rapidly evolve to well- crystallized species, in the driest inland site Lomas Bayas only amorphous oxide is observed.

Caceres, Luis↗

Design Considerations for a Variable Autonomy Executive for UAS in the NAS

This paper describes research targeted towards an autonomy executive (AOS) for UAS in the National Air Space (NAS). The project goal is to incrementally provide the knowledge and intelligence onboard a UAS to safely fly in the National Air Space, eventually autonomous from remote human ground crews and communicating directly with air traffic control. Longer-term, the goal is to provide the capability for pilotless air vehicles such as air taxis that will be key for new transportation concepts such as air mobility-on-demand. For both of these targeted applications, AOS is incorporating artificial intelligence capabilities that operationally meet human pilot competencies. Even when autonomy is achieved from a remote human ground crew, AOS will have variable degrees of autonomy with respect to air traffic control (ATC), just as human pilots do now. AOS has the capability of interacting in natural language with ATC, as well as through data link protocols. AOS can adapt to varying levels of autonomy and control directed by ATC in standard and relaxed FAA phraseology- from being vectored moment by moment, to accepting broad directives such as following a specified aircraft or sighting and avoiding traffic. AOS can autonomously manage contingencies such as vehicle systems degradations and failures. It incorporates a decision maker that takes information from multiple diagnostic reasoners, disambiguates (if needed) sensor results to specific failures using active mode changes, then projects forward the impact of the degradation on the nominal plan. If the nominal plan is no longer viable, then alternative plans are formulated, and subsequently selected and executed, including abort options.

Lowry, Michael↗

U.S. IMERG Status

The U.S. Science Team’s Integrated Multi-satellitE Retrievals for the Global Precipitation Measurement (GPM) mission (IMERG) product provides estimates of surface precipitation rate and related information on a global 0.1° half-hour grid. It is run three times at increasingly longer latency and higher information input to serve different communities. This presentation will briefly summarize the major upgrades included in Version 07. The Goddard Profiling (GPROF) algorithm (applied to passive microwave sensor data from the GPM virtual constellation) and the Combined Radar-Radiometer Algorithm (CORRA) that provide input to IMERG V07 are both improved, and the new Precipitation Estimation from Remotely Sensed Information Using Artificial Neural Networks–Dynamic Infrared Rain Rate (PDIR) algorithm is being applied to infrared data, which employs an additional, warmer infrared temperature threshold than the previous infrared scheme and a deep neural network. V07 has improved bias performance as a result of calibrations that now employ the entire swath widths of CORRA and GPROF GPM Microwave Imager precipitation estimates. As well, time continuity in precipitation features is improved as a result of changes to the Kalman filter that approximately preserve the local histogram of precipitation rates (Scheme for Histogram Adjustment with Ranked Precipitation Estimates in the Neighborhood, or SHARPEN), and that better account for differences in sensor performance. A long-standing bug in the geolocation that shifted grid values 0.1° to the east in the latitude band 70°N-S has been corrected. Other changes in V07 include a hierarchical selection among motion vector sources to address deficiencies in the precipitation propagation near orography, an update to the precipitation phase specification for improved consistency with current inputs, and a renewed effort to implement climatological gauge adjustment to the near-real-time Runs. Early evaluations of V07 IMERG show interesting behavior across the TRMM orbit boost that is highly relevant to the planned orbit boost for the GPM Core observatory.

GPM↗

Axial load management system

An axial load management system for a turbomachine including a rotating drivetrain, a thrust bearing assembly, a sensor, and a valve supply line. The rotating drivetrain includes a compressor section and an expander section fluidly coupled together by a closed flowpath. The thrust bearing assembly includes a thrust runner, a thrust bearing housing, and a gas thrust bearing extending between the thrust runner and the thrust bearing housing. Further, the gas thrust bearing supports the rotating drivetrain. The sensor is attached to at least one of the thrust bearing housing or the gas thrust bearing. The valve supply line is fluidly coupled to the closed flowpath. A valve positioned within the valve supply line selectively allows a working fluid to flow between the closed flowpath and a thrust chamber defined by a rotating surface and a fixed surface to modify an axial load on the rotating drivetrain.

42 ENGINEERING↗

Low Altitude AVIRIS Data for Mapping Land Form Types on West Ship Island, Mississippi

Barrier islands help protect the southern and southeastern U.S. shoreline from hurricanes and severe storms. They are important for coastal resource management and geologic research, especially in studies that involve changes in island areas and surface environments, and they display a dynamically changing and diverse mix of landform and vegetative cover habitats. Many Gulf Coast barrier islands have undergone dramatic decreases in areal extent, often due to hurricane and severe storm damage. For example, Louisiana's barrier islands have lost 55 percent of their surface area over the past 100 years. Aerial photography and Landsat data have been used to monitor changes in barrier island areal extent, although neither data source is optimal for making maps of detailed landform types at site-specific scales. High spatial resolution hyperspectral imagery, such as that obtained from the high spatial resolution Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) sensor, may enable improved mapping of landform types, which would benefit studies of the dynamics of barrier island environments. During the summers of 2000 and 2001, a study was conducted to assess low-altitude AVIRIS data for mapping the landform types of West Ship Island, a barrier island in Harrison County, Mississippi. This study area was selected because of the availability of low-altitude AVIRIS data acquired on July 22, 1999, and because of the area's accessibility to the investigating team. West Ship Island is one of the six barrier islands that belong to the Gulf Shores National Seashore, which is managed by the National Park Service. This island contains an impressive range of landform categories. Surface types include beach, dune, and sand flat environments. West Ship Island also harbors Fort Massachusetts, a historic fort used during the Civil War. Because it is located near Stennis Space Center, the island is frequently imaged by NASA's airborne and spaceborne sensors.

Spruce, Joseph P.↗

Procurement specifications report. IMBLS phase B-4

Procurement specifications to provide vendors of space systems with supporting information to accurately price the selected major buy items are illustrated. In performing this task, rigid constraints on specifications and drawing details are avoided beyond those necessary to define basic requirements. Described are digital processing equipment, mass spectrometer, body mass measuring device, sensors, bio-belt power source, vision tester and instrumentation for a biochemical station.

Source record↗

Orbital transfer vehicle oxygen turbopump technology. Volume 1: Design, fabrication, and hydrostatic bearing testing

The design, fabrication, and initial testing of a rocket engine turbopump (TPA) for the delivery of high pressure liquid oxygen using hot oxygen for the turbine drive fluid are described. This TPA is basic to the dual expander engine which uses both oxygen and hydrogen as working fluids. Separate tasks addressed the key issue of materials for this TPA. All materials selections emphasized compatibility with hot oxygen. The OX TPA design uses a two-stage centrifugal pump driven by a single-stage axial turbine on a common shaft. The design includes ports for three shaft displacement/speed sensors, various temperature measurements, and accelerometers.

Buckmann, P. S.↗

A satellite anemometer

We present the conceptual design of an instrument that can provide a continuous analog measure of the pitch and yaw angles of a low altitude satellite in the frame of the neutral atmosphere. The device, which uses pressure sensor orientation to provide its signal, can function in an attitude control loop and/or be used to measure atmospheric winds or wave motions. Any arbitrary angle of attack (pitch and yaw) less than +/- 45 deg can be selected for a heading. The sensitivity of the device is 0.1 deg but this would be limited by low ambient pressure at high altitudes and by multiple particle collisions in and below the slip flow region. The development of a prototype flight unit is in progress.

Hanson, W. B.↗

Attitude-Independent Magnetometer Calibration for Spin-Stabilized Spacecraft

The paper describes a three-step estimator to calibrate a Three-Axis Magnetometer (TAM) using TAM and slit Sun or star sensor measurements. In the first step, the Calibration Utility forms a loss function from the residuals of the magnitude of the geomagnetic field. This loss function is minimized with respect to biases, scale factors, and nonorthogonality corrections. The second step minimizes residuals of the projection of the geomagnetic field onto the spin axis under the assumption that spacecraft nutation has been suppressed by a nutation damper. Minimization is done with respect to various directions of the body spin axis in the TAM frame. The direction of the spin axis in the inertial coordinate system required for the residual computation is assumed to be unchanged with time. It is either determined independently using other sensors or included in the estimation parameters. In both cases all estimation parameters can be found using simple analytical formulas derived in the paper. The last step is to minimize a third loss function formed by residuals of the dot product between the geomagnetic field and Sun or star vector with respect to the misalignment angle about the body spin axis. The method is illustrated by calibrating TAM for the Fast Auroral Snapshot Explorer (FAST) using in-flight TAM and Sun sensor data. The estimated parameters include magnetic biases, scale factors, and misalignment angles of the spin axis in the TAM frame. Estimation of the misalignment angle about the spin axis was inconclusive since (at least for the selected time interval) the Sun vector was about 15 degrees from the direction of the spin axis; as a result residuals of the dot product between the geomagnetic field and Sun vectors were to a large extent minimized as a by-product of the second step.

Natanson, Gregory↗