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At least 1,459 records · Page 81

Incorporation of Nitrogen into Organics Produced by Fischer-Tropsch Type Chemistry

Laboratory simulations have demonstrated that hydrothermal systems have the potential to produce a range of organic compounds through Fischer-Tropsch type (FTT) chemistry. The distribution of products depends on several factors, including the abundance and composition of feed-stock molecules, reaction temperature, and the physical and chemical characteristics of catalytic materials included in the reactions. The majority of studies per-formed to date have focused solely on inclusion of CO2 or CO and H2 as the carbon, oxygen and hydrogen sources, which limits the possible products to hydro-carbons, alcohols and carboxylic acids. A few studies have included nitrogen in the form of ammonia, which led to the production of amino acids and nitrogenous bases; and a separate suite of studies included sulfur as sulfide minerals or H2S, which yielded products such as thiols and amino acids. Although these demonstrations provide compelling evidence that FTT reactions can produce compounds of interest for the origins of life, such reactions have been conducted under a very limited range of conditions and the synthetic reaction mechanisms have generally not been well-characterized. As a consequence, it is difficult to extrapolate these results to geologic systems or to evaluate how variations in reactant compositions would affect the distribution of products over time. We have begun a series of laboratory experiments that will incorporate a range of precursor molecules in varying compositions to determine how these variables affect the relative amounts and speciation of life-essential elements in organic molecules produced under FTT conditions. In the present work, we focus on systems containing C, H, O and N.

Burton, A. S.↗

HCN emissions from the explosive volcanic eruption of Mt. Pinatubo, Philippines, in June 1991

In June 1991, Mt. Pinatubo explosively erupted magma and overlying rock, with ejecta reaching stratospheric altitudes. The sulphate aerosol burden resulting from the 1991 eruption was still measurable in 1992 and its complete removal took 5-6 years. Here we present new analyses of measurements by the ATMOS instrument on the Atlas-1 Space Shuttle mission and the MkIV balloon interferometer in 1992 that show about 40-50 ppt of unexpected excess HCN in the middle stratosphere. HCN has no stratospheric sources and a lifetime of several years. Multi-year runs with the GEOS-Chem Chemistry-Transport model have been performed in order to derive the most plausible HCN injection amounts. The overall structure of the modeled HCN agrees reasonably well with observations by MkIV and ATMOS. The current best estimate is an emission of about 6 kt of HCN into the stratosphere at an altitude of about 23 km. This compares to a total gas emission in the order of 70-700 Mt, based on an emission of 14 Mt SO2 and an SO2/total gas ratio of 2% - 20%. We will discuss possible sources and formation mechanisms of the HCN. These include abiotic formation during or prior to the eruption and may involve HCN accumulated in the subaerial volcanic-hydrothermal system of Mt. Pinatubo. We present results from thermochemical equilibrium calculations as well as photochemical plume modeling in order to provide plausibility constraints on the source of the HCN.

Armin Kleinboehl↗

INCORPORATION OF NITROGEN INTO ORGANICS PRODUCED BY FISCHER-TROPSCH TYPE CHEMISTRY

Laboratory simulations have demonstrated that hydrothermal systems have the potential to produce a range of organic compounds through Fischer-Tropsch type (FTT) chemistry. The distribution of products depends on several factors, including the abundance and composition of feedstock molecules, reaction temperature, and the physical and chemical characteristics of catalytic materials included in the reactions. The majority of studies per-formed to date have focused solely on inclusion of CO2 or CO and H2 as the carbon, oxygen and hydrogen sources, which limits the possible products to hydrocarbons, alcohols and carboxylic acids. A few studies have included nitrogen in the form of ammonia, which led to the production of amino acids and nitrogenous bases. Although these demonstrations provide compelling evidence that FTT reactions can produce compounds of interest for the origins of life, such reactions have been conducted under a very limited range of conditions and the synthetic reaction mechanisms have generally not been well-characterized. We have begun a series of laboratory experiments that will incorporate a range of precursor molecules in varying compositions to determine how these variables affect the relative amounts and speciation of life-essential elements in organic molecules produced under FTT conditions. In the present work, we focus on systems containing C, H, O and N. Reaction mixtures contained CO (~60-80 mM), 150 mM ammonium chloride, and water with a native iron catalyst, which also served as a source of H2 through the reduction of water. Three initial experiments were conducted at 110, 154 and 185 °C and heated for several days. Following the reaction, samples were analyzed by gas chromatography-mass spectrometry, direct analysis in real time mass spectrometry and liquid chromatography-mass spectrometry.

A. S. Burton↗

The Detection of Aromatic Amino Acids in CR Chondrites Suggests They are Prebiotically Plausible

Amino acids (AAs) are the building blocks of proteins and are essential for life on Earth. Sources of AAs on early Earth range from exogenous sources such as delivery from extraterrestrial materials(i.e., meteorites, interplanetary dust particles, comets, etc.) to endogenous sources including chemical reactions in hydrothermal vents or atmospheric mixtures. Analyses of AAs of extraterrestrial origin from meteorites and laboratory studies of simulated prebiotic environments revealed that a diverse set of abiotically produced AAs may have been present on early Earth. However only a fraction of these AAs is found within the proteins of living organisms. Of the22 genetically encoded (proteinogenic) AAs, 20 occur in the standard genetic code (SGC) and are used by nearly all living organisms to build proteins. The universality of this AA alphabet suggests the presence and incorporation of these specific AAs occurred early in the evolution of life.

A. S. Burton↗

PRESOLAR GRAIN ABUNDANCE VARIATION IN THE MILLER RANGE 090019 CO3.1 CHONDRITE

Presolar grains condensed in the outflows of evolved red giant stars and the ejecta of supernovae (SNe) and novae. These grains have greatly anomalous isotopic compositions compared to solar system material, reflecting their stellar origins [1]. They have been identified in primitive meteorites, interplanetary dust particles (IDPs), Antarctic micrometeorites, and comet Wild 2 samples returned by NASA’s Stardust mission. Presolar silicates are one of the most abundant presolar phases and their concentrations extend up to 1.5% in primitive IDPs believed to derive from comets [2]. These grains are highly susceptible to alteration and destruction by secondary processing in the interstellar medium, nebula, and asteroid or comet parent body. Presolarsilicate abundance variations between primitive meteorites and chemical and mineralogical studies provide indications of the extent of secondary hydrothermal alteration [3, 4]. The abundance of presolar SiC grains is generally consistent among chondrites, but lower abundances in some meteorites have been attributed to thermal alteration [5, 6]. Presolar grain abundance variations attributed to localized alteration have also been reported within different regions of a chondrite [e.g., 7].Carbonaceous chondrites from the CO and CR groups have the highest abundances of presolar silicates among meteorites, attesting to their primitive nature. The CO3 chondrite Dominion Range (DOM) 08006 has the highest presolar O-rich grain abundance of ~260 ppm [8, 9]. MillerRange (MIL) 090019 is classified as a CO3.1 chondrite and has affinities to Acfer 094, DOM 08004/6 and Allan Hills (ALH) 77307. These chondrites have high presolar silicate abundances and contain high abundances of various types of refractory inclusions. We previously conducted detailed studies of CAIs in MIL 090019 [10, 11]. Here we evaluate its presolar grain inventory to assess the degree of parent body alteration and compare to other chondrites

A. N. Nguyen↗

Jarosite Formation in Deep Antarctic Ice, an Earth Analogue to Unveil the Origin of Jarosite on Mars?

On Earth, jarosite is a weathering product forming in acidic-oxidative environments from the alteration of iron-bearing minerals in presence of liquid water. Typical settings where this iron-potassium hydrated sulphate is found, are weathering zones of pyrite-rich deposits, evaporative basins and fumaroles. Jarosite is not only known on Earth, it also occurs on Mars, where it has been identified by the Opportunity rover. The mineral was in fact recognized in the finely layered formations outcropping at Meridiani Planum and that were accurately investigated by the rover (Klingelhöfer et al. 2004). Since jarosite requires liquid water to form, its occurrence on Mars has been regarded as an evidence for the occurrence of liquid water in the geologic past of Mars (Elwood-Madden et al., 2004). Since then, many models have been proposed to describe the environments where the precipitation of Martian jarosite took place. The most accepted ones deal with evaporative basins similar to Earth’s playas, others concern volcanic activity and hydrothermal processes. An alternative proposal predicted that jarosite may have formed as a consequence of weathering of mineral dust trapped in massive ice deposits, i.e. the ice-weathering model (Niles & Michalsky, 2009). The hypothesis that jarosite formed on Mars because of low-temperature, acidic and water limited weathering, is not new (Burns, 1987), but until now no direct evidences were available to support it.A potential Earth analogue to investigate such processes is deep Antarctic ice. We present a first investigation of deep ice samples from the Talos Dome ice core (East Antarctica) aimed at the identification of englacial jarosite, so as to support the ice-weathering model. Evidences gathered through independent techniques showed that jarosite is actually present in deep Antarctic ice and results from the weathering of dust trapped into ice. The process is controlled by the re-crystallization of ice grains and the concurrent re-location of impurities at grain-junctions, which both depend on ice depth. This study demonstrates that the deep englacial environment is suitable for jarosite precipitation. Our findings support the hypothesis that, as originally predicted by the ice-weathering model, paleo ice-related processes have been important in thegeologic and geochemical history of Mars.

Lindsay P Keller↗

Simulated ASTER data for Geologic Studies

The Advanced Spaceborne Thermal Emission and Reflectance Radiometer (ASTER) is a high spatial resolution imaging instrument, due to be launched on NASA's Earth Observing System AM-1 satellite platform in 1998. ASTER acquires data in 14 bands, spanning the wavelength region from the visible, near infrared, short wavelength infrared, and thermal infrared, with spatial resolution varying from 15 m to 90 m, depending on wavelength region. In order to evaluate our ability to use ASTER data for geological mapping, we used aircraft data over Cuprite, Nevada to create a simulated 14-band ASTER data set. The study site has sparse vegetation, and exposes a wide range of unaltered and hydrothermally altered volcanic rocks. The wide range of wavelengths covered by ASTER allowed us to recognize or separate iron oxide minerals, clay-bearing minerals, sulfate minerals, ammonia minerals, siliceous rocks, and carbonates. Combined with laboratory spectral measurements, we were able to identify these constituents. Based on both sets of information, we produced an alteration map showing the distribution of argillized rocks, opalized rocks with alunite, silicified rocks, and areas dominated by kaolinite and buddingtonite. The map was as accurate as published maps made by traditional field methods. ASTER promises to be a major improvement over existing satellite systems for geologic mapping.

Advanced↗

A Technology Architecture for Accessing the Oceans of Icy Worlds

The icy moon oceans beckon with ingredients that potentially may harbour extant life. Beginning with the Galileo and Cassini missions, measurements have revealed the presence of global oceans under the icy crust of several moons of Jupiter and Saturn. Among those moons, Europa and Enceladus have their ocean in contact with the rocky core, providing an environment similar to the conditions existing on the terrestrial sea-floor where life has developed at hydrothermal vents Accessing these oceans presents considerable difficulty due to a number of issues including the depth and composition of the icy crust, the time needed to travel through the crust, the power needed to propel a probe, communication of scientific and engineering data though the ice and back to Earth, entry and mobility in the ocean and autonomous operations for the life of the mission. A detailed trade space study was conducted to develop a technology architecture defining a system that would access an icy moon’s ocean. To specifically bound the architecture, Jupiter’s moon Europa was chosen as the target body though the work can apply to other bodies. The current understanding of the scientific properties of the ice crust and ocean was used to guide the development. A strawman scientific payload was devised to further develop a baseline set of requirements. Beginning with a launch and trajectory that can bring a system to Europa’s orbit, a complete trade space was developed outlining the engineering systems needed to access the ocean. The architecture was divided into specific phases for i) deorbit, descent and landing, ii) surface operations, iii) ice descent and iv) ocean access. The technical maturity of each of sub-system for the phases was assessed for systems that could be developed to a maturity ready for a preliminary design in less than ten years. Integrated system parameters on power, communication capacity, and mass were developed to further define the overall system. To constrain the design, a total time in the ice, from the ice crust surface to accessing the ocean was limited to three years, and 15Km of ice was baselined with a temperature profile through the ice estimated from the scientific literature.

Sengupta, Anita↗

A technology architecture for accessing the oceans of icy worlds

The icy moon oceans beckon with ingredients that potentially may harbour extant life. Beginning with the Galileo and Cassini missions, measurements have revealed the presence of global oceans under the icy crust of several moons of Jupiter and Saturn. Among those moons, Europa and Enceladus have their ocean in contact with the rocky core, providing an environment similar to the conditions existing on the terrestrial seafloor where life has developed at hydrothermal vents. A detailed trade space study was conducted to develop a technology architecture defining a system that would access an icy moon’s ocean. This paper outlines the architecture with specific consideration to the power source necessary to drive the system.

Smith, Miles↗

Program Options to Explore Ocean Worlds

Including Earth, roughly a dozen water ocean worlds exist in the solar system: the relict worlds Ceres and Mars, vast oceans inside most of the large Jovian and Saturnian icy moons, and Kuiper Belt Objects like Triton, Charon, and Pluto whose geologies are dominated by water and ammonia. Key pieces of the ocean-world science puzzle – which when completed may reveal whether life is widespread in the cosmos, why it exists where it does, and how it originates – are distributed among them. The eventual exploration of all these worlds will yield humanity’s total tangible knowledge about life in the universe, essentially forever. Thus, their exploration has existential significance for humanity’s self-regard, and indeed perhaps of our place in the natural scheme. The matter of planning how to pursue such a difficult and unprecedented exploration opportunity is therefore historic. The technical challenges are formidable, far harder than at Mars: missions to the Jovian and Saturnian ocean worlds are severely power-limited; trip times can be as much as a half decade and decade, respectively. And the science targets are global-scale oceans beneath kilometers of cryogenic ice. Reaching and exploring them would be a multi-generational undertaking, so again it is essential to plan and prepare. Today, we lack the instrumentation, subsystems, and remote operational-intelligence technologies needed to build and use exploration avatars as good as what we can envision needing. Each ocean world holds a piece of the puzzle, but the three priority targets are Europa at Jupiter, and Enceladus and Titan at Saturn. As with the systematic exploration of Mars, exploring these diverse worlds poses a complex technical and programmatic challenge – a strategic challenge – that needs to be designed and managed if each generation is to see its work bear fruit, and if the space science community is to make most effective use of the public money devoted to the quest. Strategic programs benefit from coherence. In only 15 years, the Mars Exploration Program (MEP) has transformed humanity’s view of Mars as a once and future habitable place, a world quite possibly holding relict evidence of life. Finding such evidence, we would study it to know if that life shared an origin common with Earth life. However, life in the ocean worlds could not have shared our origin, so exploring them opens another level in our quest to understand life in the universe: not only to places with vast salt-water seas known to contain organics and hydrothermal seafloors active today, but to places where anything alive cannot be related to us. MEP’s success – from its presence in the public consciousness to its rewriting of planetary habitability – make it an obvious template and source of lessons learned for a viable ocean worlds exploration program (OWEP). Six attributes of the MEP are analyzed for application to a potential OWEP. From this, five hypothetical programmatic scenarios are compared to the default case, and conclusions drawn. A coherent OWEP should have several parts: first, dedicated continuous investment in enabling technologies; and second, two directed-purpose, medium-class (~$1B) missions per decade that conduct pivotal investigations on a documented roadmap. Science could start in 2035, informing development of decadal flagship missions after Europa Clipper, to the places revealed to hold the most promise. The fastest pace of scientific discoveries would require access to high-performance propulsion infrastructure, e.g., the Space Launch System, Falcon Heavy, and high-power in-space solar electric propulsion, all capable of halving trip time. Not including these boosts, such a program would cost about a half-billion dollars more per year than NASA’s existing mission portfolio; the program architecture funded today cannot deliver a strategic OWEP while also sustaining balance among other solar system exploration priorities and opportunities.

Naderi, F.↗

Sampling tool concepts for Enceladus Lander in-situ analysis

A potential future in-situ lander mission to the surface of Enceladus could be the lowest cost mission to determine if life exists beyond Earth since material from the subsurface ocean, where the presence of hydrothermal activity has been strongly suggested by the Cassini mission, is available on its surface after being ejected by plumes and then settling on the surface. In addition, the low radiation environment of Enceladus would not significantly alter the chemical makeup of samples recently deposited on the surface. A study was conducted to explore various sampling devices that could be used by an in-situ lander mission to provide 1cc to 5cc volume samples to instruments. In addition to temperature and vacuum environmental conditions, the low surface gravity of Enceladus (1% of Earth gravity) represents a new challenge for surface sampling that is not met by sampling systems developed for microgravity (e.g., comets and asteroids) or higher gravity (e.g., Europa 13%g, Moon 16%g, or Mars 38%g) environments. It is desired to acquire surface plume material that has accumulated in the top 1cm to ensure acquisition of the least processed material. Several sampling devices were developed or adapted and then tested in simulated conditions that resemble the Enceladus surface properties. These devices and test results are presented in this paper.

Genta, Giancarlo↗

Evidence for Multiple Diagenetic Episodes in Ancient Fluvial‐Lacustrine Sedimentary Rocks in Gale Crater, Mars

The Curiosity rover's exploration of rocks and soils in Gale crater has provided diverse geochemical and mineralogical data sets, underscoring the complex geological history of the region. We report the crystalline, clay mineral, and amorphous phase distributions of four Gale crater rocks from an 80‐m stratigraphic interval. The mineralogy of the four samples is strongly influenced by aqueous alteration processes, including variations in water chemistries, redox, pH, and temperature. Localized hydrothermal events are evidenced by gray hematite and maturation of amorphous SiO 2 to opal‐CT. Low‐temperature diagenetic events are associated with fluctuating lake levels, evaporative events, and ground water infiltration. Among all mudstones analyzed in Gale crater, the diversity in diagenetic processes is primarily captured by the mineralogy and X‐ray amorphous chemistry of the drilled rocks. Variations indicate a transition from magnetite to hematite and an increase in matrix‐associated sulfates suggesting intensifying influence from oxic, diagenetic fluids up section. Furthermore, diagenetic fluid pathways are shown to be strongly affected by unconformities and sedimentary transitions, as evidenced by the intensity of alteration inferred from the mineralogy of sediments sampled adjacent to stratigraphic contacts.

C N Achilles↗

Constraining Venus Cloud Habitability: Earth's Aerobiosphere as an Analogue Environment

The potential habitability of Venus's cloud and haze layers has been debated for decades, with interest fueled by observations including disequilibria in atmospheric chemistry, strongly UV-absorbing particles, and (most recently) a controversial phosphine detection. Venus cloud temperature and pressure are clement by Earth standards; however, the calculated high acid activity and low water activity may exceed the limits of Earth biochemistry, based on observed life in extreme environments. A significant challenge in understanding Venus's habitability is the lack of an appropriate terrestrial analogue environment. Life has not been found in hydrothermal systems approaching Venus aerosol acidities, but these systems also contain high levels of other harsh solutes. Earth's stratospheric sulfate layer is a partial match in terms of acidity, desiccation, size, and isolation from the surface, but the few samples returned from these altitudes have yielded only sparse, inactive cells. Earth's tropospheric cloud droplets have an active microbial presence, but are larger and far more water-rich than Venus aerosols; tropospheric times aloft are also similar to microbial generation times, making Earth's aerobiosphere dependent on continuous surface replenishment. Direct detection of potential biosignatures from a single transect is challenging; Earth's cloud microbiota yields 102 - 108 viable cells per mL, equivalent to one per 103 - 109 particles, with highly dynamic and heterogeneous distribution. The most important in situ measurement for Venus cloud habitability is detailed aerosol composition: confirmation of acid and water activity, presence of potentially bioavailable nutrients and energy, and potential presence of organic matter. Modeling Venus cloud aerosol residence time in comparison to periodic influxes of water and photochemical energy, and thus the ability of an ecosystem to maintain itself over time, would also address a significant habitability constraint particular to aerobiospheres.

Venus↗

The Stop-and-Go Mechanism: Towards an Integrated Approach to Model Seismicity, Outgassing, Deformation, and Thermal Unrest at Active Volcanoes

Connecting the geophysical and geochemical signals recorded at and above the surface of volcanoes with source mechanisms is fundamental to understand transitions from quiescence to eruption, and to integrate the behavior of volcanoes with their regional seismotectonic and hydrological context. Some of these signals include shallow volcanic tremor, a long-lasting (minutes-to-years) ground vibration detected in volcanic areas during unrest; volcanic outgassing, which shows intriguing periodicities over multiple scales, as revealed by space-borne instruments and by ground-based, high-frequency (~1 Hz), sampling methods; inflation and deflation of volcanic edifices, commonly associated with subsurface volume changes; and large-scale (from a few to tens of km2), low-temperature, thermal anomalies, a newly-discovered signal that has been observed to emerge on volcanic flanks from months-to-years prior to gas- and magma-driven eruptions. Traditionally, these geophysical and geochemical signals have been modelled independently, which limits our interpretation of subsurface processes and thus our assessment of unrest. In this work, we show through lumped-parameter models, numerical simulations, and preliminary laboratory experiments that many of the signals recorded around volcanoes can be integrated into a common “stop-and-go” mechanism. In particular, we found that they can arise spontaneously when taking into account the feedbacks between the temporary accumulation of gas and/or magma in the crust (“stop”), and the diffusive transfer of gas and heat towards the surface (“go”). For example, we find that the “stop-and-go” mechanism can explain: (i) the emergence of monochromatic, broadband, and harmonic tremor; (ii) the periodic components commonly observed in volcanic outgassing time series; (iii) the link between large-scale thermal anomalies and shallow hydrothermal systems; (iv) the reported time lags between large-scale thermal anomalies and deformation; and (v) the breathing of potentially destructive volcanic calderas. The “stop-and-go” mechanism provides a consistent and realistic framework to link multiple geophysical and geochemical signals with the processes leading to volcanic unrest and eruption.

volcanoes↗

The Nature of Extraterrestrial Amino Acids in Carbonaceous Chondrites and Links to Their Parent Bodies

Meteorites and samples returned from asteroids and comets provide an important record of the physical and chemical processes that occurred in the early solar system and represent some of the oldest solid materials currently available for laboratory analyses. The delivery of organic matter by extraterrestrial material to the early Earth could have been an important source of complex prebiotic organic molecules available for the emergence of life. Analyses of primitive carbonaceous chondrites over the last five decades have revealed a major insoluble organic component [1,2], as well as a complex and highly diverse suite of soluble organic molecules of prebiotic importance [3,4] that includes carboxylic acids, N-heterocycles, sugars, amino acids, amines, and many other organic molecules that have not yet been identified [5]. Amino acids continue to be a primary focus of many soluble organic analyses in carbonaceous chondrites because (1) these molecules are essential components of life (as the monomers of proteins), (2) they have structural diversity (multiple possible isomers) that can be used to help constrain formation mechanisms and parent body conditions, and (3) most amino acids identified in carbonaceous chondrites are chiral, a property that can be used to distinguish between amino acids of extraterrestrial and terrestrial origins. The degree of parent body hydrothermal alteration has been shown to have a major influence on the formation and destruction of amino acids in carbonaceous meteorites as observed in the measured abundances and molecular distributions [6]. Aqueous alteration in primitive asteroids could have also led to the preferential enrichment of some left-handed amino acids over their right-handed forms, an astounding discovery that suggests that the origin of life on Earth or elsewhere was biased toward left-handed amino acid homochirality [7,8]. This talk will give an overview of what is known about the amino acid composition of carbonaceous chondrites, present some key unanswered questions, and discuss how the analysis of samples returned from asteroids Ryugu and Bennu will further advance our understanding of parent body chemistry and potential contributions from carbonaceous asteroids to the origin of life on Earth or elsewhere.

Daniel P. Glavin↗

Empirical Constraints on Progressive Shock Metamorphism of Magnetite from the Siljan Impact Structure, Sweden

Little is known about the microstructural behavior of magnetite during hypervelocity impact events, even though it is a widespread accessory mineral and important magnetic carrier in terrestrial and extraterrestrial rocks. We report systematic electron backscatter diffraction crystallographic analysis of shock features in magnetite, from a transect across the 52-km diameter ~380 Ma Siljan impact structure in Sweden. Magnetite grains in granitoid samples contain brittle fracturing, crystal-plasticity, and lamellar twins. Deformation twins along {111} with shear direction of <112> are consistent with spinel-law twins. Inferred bulk shock pressures for investigated samples, as constrained by planar deformation features (PDFs) in quartz and shock twins in zircon, range from 0–20 GPa; onset of shock-induced twinning in magnetite is observed at >5 GPa. These results highlight the utility of magnetite to record shock deformation in rocks that experience shock pressures >5 GPa, which may be useful in quartz-poor samples. Despite significant hydrothermal alteration, and variable transformation of host magnetite to hematite, shock effects are preserved, demonstrating that magnetite is a reliable mineral for preserving shock deformation over geologic time.

magnetite↗

In-situ Raman Instrumentation and Measurements in Supercritical Water Oxidation Systems

Due to the advent of recent advances in reactor designs and operational procedures, renewed attention has been given to a host of supercritical water oxidation (SCWO) technology applications. This includes resource recovery, water reclamation, and solid waste destruction. SCWO is often recognized as a “green technology” because of its ability to extract useful energy while producing benign products from environmentally challenging waste streams (e.g., wet organic wastes, pharmaceutical wastes, military wastes). The present work was motivated by NASA’s interests in solid waste management and water recovery for long-duration space missions. To that end, the main focus of this paper is to present work on characterizing the behavior of supercritical water oxidation systems utilizing state of the art laser Raman spectroscopy. The main benefit of Raman diagnostics is its ability to identify chemical composition and to measure concentrations of the compounds involved in the reaction. Two separate Raman systems for SCWO measurements that have been developed for this study will be described. The first system is a 2-D traversing system useful for making in-situ measurements in conditions where spatial gradients of species and temperature are important and has been successfully utilized in making species (ethanol, oxygen, water, nitrogen and carbon dioxide) concentrations and temperature measurements in ethanol hydrothermal jet flames. The second system is a packaged modular Raman probe unit for portable deployment to different reactors and is more suitable for relatively homogeneous systems such as a batch reactor. The design, development, and examples of obtained results from both systems will be presented for various reactant streams. Reaction rate and fuel conversion estimates from chemistry models will also be presented.

supercritical water oxidation↗

Desulfovulcanus ferrireducens gen. nov., sp. nov., A Thermophilic Autotrophic Iron and Sulfate-reducing Bacterium from Subseafloor Basalt That Grows on Akaganeite and Lepidocrocite

A deep-sea thermophilic bacterium, strain Ax17T, was isolated from 25 °C hydrothermal fluid at Axial Seamount. It was obligately anaerobic and autotrophic, oxidized molecular hydrogen and formate, and reduced synthetic nanophase Fe(III) (oxyhydr)oxide minerals, sulfate, sulfite, thiosulfate, and elemental sulfur for growth. It produced up to 20 mM Fe2+ when grown on ferrihydrite but < 5 mM Fe2+ when grown on akaganéite, lepidocrocite, hematite, and goethite. It was a straight to curved rod that grew at temperatures ranging from 35 to 70 °C (optimum 65 °C) and a minimum doubling time of 7.1 h, in the presence of 1.5–6% NaCl (optimum 3%) and pH 5–9 (optimum 8.0). Phylogenetic analysis based on 16S rRNA gene sequences indicated that the strain was 90–92% identical to other genera of the family Desulfonauticaceae in the phylum Pseudomonadota. The genome of Ax17T was sequenced, which yielded 2,585,834 bp and contained 2407 protein-coding sequences. Based on overall genome relatedness index analyses and its unique phenotypic characteristics, strain Ax17T is suggested to represent a novel genus and species, for which the name Desulfovulcanus ferrireducens is proposed. The type strain is Ax17T (= DSM 111878T = ATCC TSD-233T).

Srishti Kashyap↗