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At least 1,459 records · Page 81

Screening of Gel Formation Methods in Paraffin Based Systems

The Savannah River National Laboratory (SRNL) has evaluated gel formation in kerosene using a lecithin-based system, the aluminum soap of naphthenic and palmitic acid or derivatives, and an acrylamide copolymerization. Some gelling was observed in the lecithin system, but not sufficient gelling to meet the customer’s needs. The napthenic systems provided a good degree of gelling yet required a larger wt.% than the customer desires. The acrylamide copolymerization gels easily in aqueous systems yet does not extend to an organic system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Supplemental Environmental Baseline Survey for Proposed Land Use Permit Modification for Expansion of the Dynamic Explosive Test Site (DETS) 9940 Main Complex Parking Lot

The proposed use of the subject property is for the purpose of adding a parking lot to serve the increase in customer vehicles that is occurring as the 9940 Main Complex is more heavily utilized, and as the 2009 Expansion areas come online as operational training facilities. The subject property would be used only for parking, not for testing or training activities. The parking lot would have a gravel surface. Current and future work at the 9940 Main Complex involves arming, fuzing, and firing of explosives and the testing of explosive systems components in both terrestrial and aquatic settings. It also involves specialized training activities for a variety of first responder customers, both DOE and non-DOE agencies.

54 ENVIRONMENTAL SCIENCES↗

Instrumented Lid Detailed Design

This report describes the design of an instrumented lid assembly for remote sampling, monitoring, and radiation testing (SMART) for demonstration and surveillance of the dry storage environment and fuel conditions of aluminum clad spent nuclear fuel (ASNF) in a Department of Energy (DOE) standardized canister. The lid assembly consists of a custom-designed lid and hat, together with a custom fuel basket. The functions and designs of each component of the lid assembly and the general arrangement of the lid assembly are provided in this report. The Piping and Instrumentation Diagram for the corresponding instruments which will be connected to the lid assembly is shown in the appendix. Details of the system to provide characterization are provided in SRNL-L2240-2019-00002, "Instrumented Lid - System Final Design". The detailed drawings of the lid assembly will be prepared following the specification of the demonstration and surveillance system, including canister, design, to which the lid will be matched. Individual testing of the lid assembly sensor components will be performed in cold testing. The lid assembly including connection ports for gas sampling and thermowells will be fabricated. The tubing of the lid assembly to which the sensor components will be connected will not be assembled. The final design of the lid assembly connections to instrumentation is dependent on the staging of the demonstration and surveillance canister.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Distributed Generation Valuation and Compensation

This white paper can help guide a state as it considers issues associated with distributed generation valuation and compensation. States may address a common set of questions and issues in the valuation process, but differences in market expectations, policy priorities, and regulations result in different responses. Key issues include: Context is important. Valuations and compensation strategies will vary based on goals and objectives they are being designed to achieve. Goals and objectives should be made clear up front and will drive the perspective used in performing valuations and how outcomes are applied. Utilities and stakeholders can have different interpretations of how value elements should be calculated. In some states, the objective of standardized calculators and methods is to reduce ambiguity and inconsistencies in how valuations are performed. Certain value elements are difficult or impossible to quantify and most efforts to establish workable value of solar or value of distributed energy resource tariffs are emerging and nascent. Assessing locational and temporal value of distributed generation and applying that in compensation schemes is a new and emerging field of study, being explored by a handful of research organizations and advanced states and utilities. The most advanced states, such as California, are using demonstration projects to test valuation and compensation methodologies or are applying valuation and compensation strategies to a subset of customer projects, such as for community solar projects (e.g., Oregon and New York) before rolling out programs to the full customer base. A variety of states are moving away from full net metering, in many cases substituting avoided cost rates (sometimes with an adder) in lieu of full retail rate compensation, instead of pursuing valuation of distributed energy resource approaches. For example, in Indiana a 25% adder is applied to average wholesale electricity prices and in Mississippi a 2.5 cents/kWh adder is applied to avoided cost rates. These adders appear to have been established through policy directives rather than a comprehensive cost of service valuations.

24 POWER TRANSMISSION AND DISTRIBUTION↗

The Sandia Matlab AnalysiS Hierarchy (SMASH) toolbox

The SMASH (Sandia Matlab AnalysiS Hierarchy) toolbox is a collection of MATLAB code for data analysis. The toolbox contains general purpose functions, custom class definitions, and self-contained programs aimed at the needs of experimental physicists working in pulsed power research. The initial release (version 1.0) supports file access, signal/image analysis, and user interface creation; custom graphics and generic system tools are also provided. Much of the package is object oriented, encouraging users to build new capabilities from established classes. Future releases will continue this goal, expanding capabilities and streamlining application development.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

FOAS4GEO - Fiber Optic Acoustic Sensors for Geophysical Applications (Final Report)

The motivation was to enhance interpretation of signals measured by distributed fiber optic seismic sensors, with primary emphasis on subsurface applications in energy production such as hydrocarbon production and geothermal energy although applications also exist in areas such as explosion monitoring. The work consisted of two major elements: 1) computational-based simulation of subsurface signals, with emphasis on hydraulic stimulation, as observed by distributed Fiber Optic Acoustic Sensors (FOAS), and 2) development of a capability to conduct lab-based measurements of distributed fiber optic acoustic sensors using a custom interrogator. Both goals were successfully achieved. For the first topic, simulations of hydraulic fracturing as measured by distributed fiber optic sensors were modeling using a computational rock mechanics code. Work on the second major element consisted of the design, construction, and testing of a distributed fiber optic interrogator and development of testbed to evaluate custom fibers. The results of this three-year effort have led to multiple conference presentations, one per-reviewed publication, and several new externally funded projects on topics directly related to the LDRD. Two post-doctoral researchers worked on the project.

15 GEOTHERMAL ENERGY↗

Instrumented Lid: Full Instrumentation System Testing

This report describes full system testing of an instrumentation system for the monitoring of aluminum clad spent nuclear fuel (ASNF). The requirements for this system were laid out in a previous document, with respect to former studies, and the details of project actualization were reported. The reader is directed to these references for more background information. In short, a team composed of personnel from Savannah River National Laboratory (SRNL) and Idaho National Laboratory have been tasked with the design and fabrication of an instrumented assembly for remote sampling, monitoring, and radiation testing (SMART) for demonstration and surveillance of the dry storage environment and conditions of ASNF in a DOE standardized canister. SRNL proposed the fabrication of two systems to accomplish this goal: 1) an instrumentation system consisting of gas and particle collection, temperature, humidity, pressure, and radiation monitoring; and 2) a lid assembly consisting of a custom-designed lid and hat, together with a custom fuel basket. The corresponding instrumentation system is shown in the piping and instrumentation diagram. The individual functionality tests of the instrument system sensor components were performed, and the results were reported in the report “Instrumented Lid- System Functionality Testing.” Savannah River National Laboratory, September 1, 2019.7 The sensor components of instrumentation system have been mounted and tested in-line with a 6” diameter test canister, and the results are reported in this document.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Milestone_24

This report documents the completion of milestone STPRO4-24 "Provide high quality (production) Kokkos support and consultation for ASC applications and libraries.". The Kokkos team resolved 344 issues reported to github (no explicit tracking of ASC vs non-ASC was performed). We engaged actively on the Kokkos slack channel, which now averages about 60 unique users per week. A survey of ASC customers was conducted with regards to the experienced support. The feedback indicates that the ASC customers are satisfied by Kokkos' support efforts.

97 MATHEMATICS AND COMPUTING↗

2019 CyberFire West: Malware Analysis Day 2 - Part 2

Summary: Stage 1 – IT: Attacker relied on common attack methods rather than zero-day vulnerabilities and exploits. Used native system tools and custom tools to move files, capture credentials, mapping the network. Stage 2 – ICS (OT): Persistence on the IT network allowed further mapping of resources and equipment, which allowed custom malware to target specific systems.

97 MATHEMATICS AND COMPUTING↗

Integrated Solutions for Optimized Performance (ISOP) Final Technical Report

The goal of this project was to demonstrate technical feasibility of an integrated approach for deep energy retrofits by packaging innovative technologies with smart communicating controls that represent the next generation of energy efficiency. The integrated solutions for optimized performance (ISOP) package integrates (i) advanced lighting and plug load controls; (ii) intelligent daylight harvesting through automated self-powered shades and window films; (iii) advanced HVAC controls sequences (ASHRAE Guideline (GDL) 36); and (iv) fault detection and diagnosis (FDD) and continuous commissioning (CCx) using advanced analytics. These technologies address energy use across multiple building end uses that represent more than 60% of the energy consumption in all commercial buildings. The project was structured to be implemented over three budget periods: Budget Period 1 scope included site selection, project design, site-specific customization of technology packages, procurement of technologies, initiation of installation of technologies, the development of a measurement and verification plan and collection of pre-retrofit data collection. The first year go/no-go decision was based on securing host sites representing 250,000 sq. ft. of occupied operational spaces, savings analysis, technology procurement and initiation of installation. Budget Period 2 planned to complete technology installations and initiate data collection of post-retrofit performance data. The second year go/no-go was to be the completion of technology installations and commissioning, metering and data collecting to support the requirements laid out in site specific M&V plans. Budget Period 3 planned to collect and analyze post-retrofit performance data and provide data and reporting to support energy efficiency rebate programs. After the team completed activities planned for Budget Period 1, the team reached a Go/No-Go Decision Point. At that point, TRC recommended that DOE discontinue the project without prejudice due to challenges with securing demonstration sites to meet the full 250,000 sf of occupied operational spaces and DOE concurred. In Budget Period 1, the TRC team developed criteria to recruit and evaluate potential demonstration host sites. TRC worked with Princeton University, the project demonstration partner, to identify buildings on their campus as potential candidates for the demonstration. Following the selection of demonstration sites, the TRC team customized energy technology packages according to the needs and characteristics of each site. TRC defined technology specifications, identified vendors, and conducted analysis to estimate energy and cost savings potential. The project team then developed schedules for technology procurement processes and scheduled for installation at all selected demonstration sites. The project team worked with Princeton University and DOE to develop an approach to verify energy savings achieved through measurement and verification (M&V) 2.0 methods. Princeton University initiated open bids to procure the necessary materials and installation contractors. Bid results came back higher than estimates due to a couple of factors – lack of familiarity of the bidders with the proposed technologies and lack of local trained installers to execute the installation of these new measures. Due to the higher bids, projects no longer met the internal cost-effectiveness criteria used by Princeton to proceed with procurement of the full suite of technologies as proposed in ISOP. Princeton had already procured parts of the ISOP package as part of a campus-wide initiative for FDD and lighting retrofits, but with the higher costs for other ISOP components, Princeton could no longer commit to the full ISOP package on the selected sites. Based on this, the team reached the Go/No-Go decision point, where they decided not to proceed with the project. Princeton is separately installing portions of the ISOP package where they individually meet Princeton’s payback criteria but on a different schedule than would have been needed for the DOE ISOP project. The team has learned several lessons from project progress in the first budget period. The team will utilize these lessons in future projects, as should any team which proceeds with a project around the ISOP technology. The first lesson is that more information about the proposed sites is required earlier in the process (perhaps even at the proposal stage) in order to have a successful demonstration. Technical details not evident earlier in the process (such as the TLED limitations for ALCS) can derail project execution. The second lesson is that pricing of emerging technologies is highly variable due to lack of familiarity of local installers and distributor with the proposed technologies as well as alternate bids using products they were more familiar with, but that cost more than the ones proposed by TRC. Finally, the last major lesson is that the host site’s internal project criteria is of critical importance. Based on these higher installed costs and lack of an informed installer base for the products proposed for this project, the project does not meet Princeton’s simple payback goals of five years.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Advanced Control Methods for Particle Accelerators (ACM4PA) 2019

Los Alamos is currently developing novel particle accelerator controls and diagnostics algorithms to enable higher quality beams with lower beam losses than is currently possible. The purpose of this workshop was to consider tuning and optimization challenges of a wide range of particle accelerators including linear proton accelerators such as the Los Alamos Neutron Science Center (LANSCE), rings such as the Advanced Photon Source (APS) synchrotron, free electron lasers (FEL) such as the Linac Coherent Light Source (LCLS) and LCLS-II, the European X-ray Free Electron Laser (EuXFEL), the Swiss FEL, and the planned MaRIE FEL, and plasma wake- eld accelerators such as FACET, FACET-II, and AWAKE at CERN. One major challenge is an the ability to quickly create very high quality, extremely intense, custom current and energy pro le beams while working with limited real time non-invasive diagnostics and utilizing time-varying uncertain initial beam distributions and accelerator components. Currently, a few individual accelerator labs have been developing and applying their own diagnostics tools and custom control and ML algorithms for au- tomated machine tuning and optimization. The goal of this workshop was to bring together a group of accelerator physicists and accelerator related control and ML experts in order to de ne which controls and diagnostics would be most useful for existing and future accelerators and to create a plan for developing a new family of algorithms that can be shared and maintained by the community.

43 PARTICLE ACCELERATORS↗

Raman Spectroscopy for the On-Line Analysis of Oxidation States of Oxygen Carrier Particles

The need for cleaner energy systems, including CO 2 capture technologies, is driving the current development of chemical looping technologies such as chemical looping combustion (CLC) and chemical looping gasification (CLG). Specific processes that are under development for using solid fuels are in-situ Gasification Chemical-Looping Combustion (iG-CLC) and Chemical Looping with Oxygen Uncoupling (CLOU). Chemical looping is based on using oxygen carriers (e.g., iron oxides, copper oxides, calcium sulfates, etc.) to provide the oxygen for the reaction with the fuel. In order to optimize the overall process performance, it is critical that the properties of the oxygen carriers are well-defined and maintained for their specific purpose during the different stages of the CLC process. One of the critical properties of the oxygen carrier is its oxidation state (e.g., content of Fe 2 O 3 vs. Fe 3 O 4 ) as it affects the fundamental operation of the CLC process. Unfortunately, the ability to make on-line measurements of the oxidation state of oxygen carriers is lacking and new sensors need to be developed. The goal of this project was to evaluate the potential of Raman spectroscopy as a sensor for the on-line analysis of the oxidation state of oxygen carrier particles. Oxygen carrier particles (OCPs) of interest include iron oxides, copper oxides, calcium sulfite, and calcium sulfate, with particle sizes typically less than 0.5 mm diameter. The expected operating conditions of the sensor include OCP temperatures in the range of 800 °C to 1000 °C, and pressures of about 10 atm. We evaluated continuous wave (cw), Quasi cw, pulsed, and time-gated Raman spectroscopy at multiple wavelengths (355 nm, 360 nm, 532 nm, 633 nm, 785 nm). Samples included iron oxides, copper oxides, calcium sulfate, and a custom sample provided by NETL for temperatures beyond 1000 °C. Our findings can be summarized as follows: Calcium sulfate can be detected via cw and pulsed 532 nm Raman spectroscopy at temperatures above 1100 °C. Hematite (Fe 2 O 3 ) Raman spectra can be detected at temperatures of 700 °C via cw 360 nm, 1089 °C with cw 532 nm, 400 °C with cw 633 and 600 °C with cw 785 nm lasers. Magnetite (Fe 3 O 4 ) can be detected via cw 532 nm Raman spectroscopy up to 600 °C. Mixtures of Fe 2 O 3 and Fe 3 O 4 can be distinguished for temperatures up to 600 °C using 532 nm. Copper oxides did not yield suitable signals at elevated temperatures. The custom NETL samples did not yield suitable signals at elevated temperatures. Raman spectroscopy would be a suitable approach for calcium sulfate as this material provides a very strong Raman signal at high temperatures. Oxygen carrier particles of higher interest such as metal oxides, however, do not yield a strong-enough signal at elevated temperatures. As such, Raman spectroscopy is not suitable to differentiate the oxidation state of these materials at temperatures above 600 °C.

01 COAL, LIGNITE, AND PEAT↗

Demand Response Optimization and Management System for Real-TIme (DROMS-RT)

To design and demonstrate DROMS-RT, a highly distributed Demand Response Optimization and Management System for Real-Time (DROMS-RT) power flow control to support large scale integration of distributed renewable generation into the grid. AutoGrid developed a novel control and communications platform to allow highly dispatchable demand response (DR) services in time frames suitable for providing ancillary services to the transmission grid. These services will be substantially less expensive and more efficient than other forms of ancillary services options currently available to manage the intermittency associated with large-scale renewable integration. DROMSRT successfully leveraged Automated Demand Response (ADR) by fundamentally re-thinking the architecture of the DR platform from the ground up and by developing innovative new technologies in a number of areas related to DR. DROMS-RT leveraged the low-cost, open, interoperable DR signaling technology, OpenADR, and low-cost, internet-protocol based telemetry solutions to reduce the cost of hardware. This allowed DROMS-RT to provide dynamic price signals to millions of OpenADR clients. Statistically rigorous signal processing techniques were developed to reliably detect even small load reductions in the presence of noisy baseline profiles. Novel forecasting engines based on modern online machine learning algorithms enabled accurate individualized forecasts for customer loads in the presence of dynamic pricing signals, and a real-time decision engines enabled continuous optimization and optimal dispatch of DR resources across a large portfolio of heterogeneous loads that respond at varying time-scales. Moreover, the real-time optimization conducted by the decision engine can utilize grid physics to maximize load reduction at the transmission system in addition to the distribution sites, for more efficient grid operation. Finally, the Software-as-a-Service (SaaS) availability of the DROMS-RT platform has reduced the cost of deployment and enable participation of small commercial and residential customers in DR who otherwise would not be able to do so.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Further Support of the Development of Advanced Multilayer Optics Coatings for X-Ray Imaging

The Smithsonian Astrophysical Observatory (SAO) is working with Lawrence Livermore National Laboratory (LLNL) to develop Wolter-I optics for x-ray imaging applications at energies of 15-50 keV and above for National Nuclear Security Administration (NNSA) facilities. SAO work includes R&D on advanced multilayer coatings as well as fabrication and testing of Wolter multilayer coated optics. It also includes delivery of custom 3.05-meter focal length Wolter optics with response at energies of interest to Sandia National Laboratories and LLNL. The optics are fabricated using an electroform nickel replication technique which has been used to fabricate optics for X-ray astronomy satellites over the past two decades. This technique starts with a figured, polished mandrel from which the optics are replicated. To carry this technique over to fabricate optics for NNSA facilities, several additional barriers had to be overcome to deposit multilayer coatings on integral optics with radii as small as 25 mm. These breakthroughs allow fabrication of optics which meet the spatial and spectral specifications required by NNSA facilities. During this present contract period SAO delivered four custom optics to LLNL with spectral response at or near the Kα line of silver, 22.16 keV.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Distributed Photovoltaic Economic Impact Analysis in Indonesia

Like other countries in the region, the Government of Indonesia aims to increase its use renewable energy in the near term from various technologies, including grid-connected distributed photovoltaics (DPV). While little DPV has been installed to date, the policy landscape has been shifting over the past few years with recent pronouncements from the state-run utility Perusahaan Listrik Negara (PLN) and the Ministry of Energy and Mines (MEMR) that have begun to provide a more supportive policy framework for the deployment of DPV. Nonetheless, many questions remain as to how DPV impacts customers, the utility, and the economy as a whole. This report presents a holistic view of DPV economic impacts in the Java-Bali region of Indonesia by assessing customer economic impacts, utility revenue impacts, and jobs and economic development impacts.

14 SOLAR ENERGY↗

An Overview of Behind-the-Meter Solar-Plus-Storage Regulatory Design: Approaches and Case Studies to Inform International Applications

Behind-the-meter energy storage systems paired with distributed photovoltaic (DPV) - with the capability to act as both generation and load - represent a unique and disruptive power sector technology capable of providing a range of important services to customers, utilities, and the broader power system. How should regulators, utilities, and policymakers manage the range of challenges and opportunities that increased behind-the-meter energy storage deployment will bring to the power system, in particular when these systems are paired with DPV? This report is intended to offer key regulatory considerations for facilitating DPV-plus-storage programs for retail customers; relevant cases from U.S. states are provided as examples of how novel regulatory issues related to behind-the-meter energy storage systems paired with DPV are being addressed in practice. At a high level, designing a regulatory framework that aligns DPV-plus-storage deployment with larger policy objectives requires thoughtful deliberation across a range of technical and economic issues. While this report attempts to segment many of these issues into distinct topics to enhance reader understanding, in reality, DPV-plus-storage regulatory issues are all closely integrated, and design decisions on a single aspect often have broader implications. With that in mind, this report outlines a series of steps that can be employed by regulators to approach DPV-plus-storage regulatory design.

14 SOLAR ENERGY↗

sCO 2 Brayton System Market Analysis

Supercritical CO 2 Brayton cycle systems (sCO 2 ) offer potential benefits over traditional steam plants. The changing economics of the electricity sector favors solar photovoltaic (PV), wind, and natural gas combined cycle (NGCC). Ultimately, the ability of sCO 2 systems to compete depends on the economics and ability to offer additional benefits to the market, such as the ability for dry cooling and their compact size. Updated results show that the projected LCOE for Brayton systems in the 100 to 300 MWe size range are between ${$}$44.8 and ${$}$56.1/MWh (4.48 and 5.61 cents/kWh). This report presents screening tools for assessing the potential market size and concludes that while at these LCOE estimates sCO 2 systems can compete directly against NGCC, there are many hurdles to commercialization, including the need to demonstrate long-term operations at low-cost and ability to quickly ramp for integration with intermittent resources. Additional customer discovery is necessary to fully understand the ability of this technology to solve customer problems that other technologies cannot.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Bat Impact Minimization Technology: An Improved Bat Deterrent for the Full Swept Rotor Area of Any Wind Turbine

The growth in the number of wind turbine generators has led to a significant number of fatal interactions with bat species. The need to reduce the number of bat fatalities while minimizing power losses is the greatest conservation challenge for wind energy development in parts of the country, according to the American Wind Wildlife Institute. Technological solutions that can also allow turbines to operate normally would generate the maximum electricity and avoid financial losses. Bats use echolocation to perceive their surroundings by listening to features of echoes from their high frequency vocal signals reflecting from targets. In this project, Frontier Wind built on previous research demonstrating that ultrasonic noise can mask echolocation and act as a repellent or deterrent to bat flight activity. Whereas the initial study only broadcast ultrasonic transmissions from the center of the turbine, the Strike Free™ system developed for this project extended the ultrasonic coverage to the entire area swept by the turbine blades. Frontier Wind designed the system components and their integration and then tested them in the lab and in the field at Pattern Energy’s Hatchet Ridge Wind Facility near Redding, California. The researchers used an acoustic model to determine the optimal configuration of transmitters along the blades to provide sound transmission coverage across the turbine rotor swept area volume. The custom ultrasonic transmitters were designed specifically for the echolocation frequencies of the four main bat species that have been shown to have died at Hatchet Ridge, although the transmitters can be customized for different frequencies as needed in other geographic locations. The Strike Free™ system shows promise for reducing bat fatalities, and the path to commercialization requires further testing to validate and optimize performance in the field.

17 WIND ENERGY↗