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At least 1,459 records · Page 81

Heralded Multiplexed High-Efficiency Cascaded Source of Dual-Rail Entangled Photon Pairs Using Spontaneous Parametric Down-Conversion

Deterministic sources of high-fidelity entangled qubit pairs encoded in the dual-rail photonic basis, i.e., presence of a single photon in one of two orthogonal modes, are a key enabling technology of many applications of quantum information processing, including high-rate, high-fidelity quantum communications over long distances. The most popular and mature sources of such photonic entanglement, e.g., those that leverage spontaneous parametric down-conversion (SPDC) or spontaneous four-wave mixing, generate an entangled (so-called continuous-variable) quantum state that contains contributions from high-order photon terms that lie outside the span of the dual-rail basis, which is detrimental to most applications. One often uses low pump power to mitigate the effects of those high-order terms. However, that reduces the pair generation rate, and the source becomes inherently probabilistic. We investigate a cascaded source that performs a linear-optical entanglement swap between two SPDC sources, to generate a heralded photonic entangled state that has a higher fidelity (to the ideal Bell state) compared to a free-running SPDC source. Furthermore, with the Bell swap providing a heralding trigger, we show how to build a multiplexed source, which despite reasonable switching losses and detector loss and noise, yields a fidelity versus success probability trade-off of a high-efficiency source of high-fidelity dual-rail photonic entanglement. We find, however, that there is a threshold of 1.5 dB of loss per switch, beyond which multiplexing hurts the fidelity versus success probability trade-off.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

An Assessment of Global Ocean Thermal Energy Conversion Resources With a High-Resolution Ocean General Circulation Model

Global rates of ocean thermal energy conversion (OTEC) are assessed with a high-resolution (1 deg × 1 deg) ocean general circulation model (OGCM). In numerically intensive simulations, the OTEC process is represented by a pair of sinks and a source of specified strengths placed at selected water depths across the oceanic region favorable for OTEC. Results broadly confirm earlier estimates obtained with a coarse (4 deg × 4 deg) OGCM, but with the greater resolution and more elaborate description of key physical oceanic mechanisms in the present case, the massive deployment of OTEC systems appears to affect the global environment to a relatively greater extent. The maximum global OTEC power production drops to 14 TW, or about half of previously estimated levels, but it would be achieved with only one-third as many OTEC systems. Environmental effects at maximum OTEC power production are generally similar in both sets of simulations. The oceanic surface layer would cool down in tropical OTEC regions with a compensating warming trend elsewhere. Some heat would penetrate the ocean interior until the environment reaches a new steady state. A significant boost of the oceanic thermohaline circulation (THC) would occur. Although all simulations with given OTEC flow singularities were run for 1000 years to ensure stabilization of the system, convergence to a new equilibrium was generally achieved much faster, i.e., roughly within a century. Here, with more limited OTEC scenarios, a global OTEC power production of the order of 7 TW could still be achieved without much effect on ocean temperatures.

13 HYDRO ENERGY↗

Improved power conversion efficiency for bulk heterojunction solar cells incorporating CdTe-CdSe nanoheterostructure acceptors and a conjugated polymer donor

In this paper, we report photovoltaic devices based on composites of a branched nanoheterostructure containing a CdTe core and CdSe arms, CdTe(c)-CdSe(a), combined with either poly(3-hexylthiophene), P3HT, or poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)], PCPDTBT, with solar power conversion efficiencies of 1.2% and 1.8%, respectively. Finally, a comparison with previously reported composite devices of a related branched nanoheterostructure: CdSe(c)-CdTe(a) reveals an improved device performance that is attributed to a better electron percolation pathway provided by the dominant, higher electron affinity CdSe arms of the nanoheterostructures.

14 SOLAR ENERGY↗

Processes of conversion of a hot metal particle into aerogel through clusters

Processes are considered for conversion into a fractal structure of a hot metal micron-size particle that is located in a buffer gas or a gas flow and is heated by an external electric or electromagnetic source or by a plasma. The parameter of this heating is the particle temperature, which is the same in the entire particle volume because of its small size and high conductivity. Three processes determine the particle heat balance: particle radiation, evaporation of metal atoms from the particle surface, and heat transport to the surrounding gas due to its thermal conductivity. The particle heat balance is analyzed based on these processes, which are analogous to those for bulk metals with the small particle size, and its high temperature taken into account. Outside the particle, where the gas temperature is lower than on its surface, the formed metal vapor in a buffer gas flow is converted into clusters. Clusters grow as a result of coagulation until they become liquid, and then clusters form fractal aggregates if they are removed form the gas flow. Subsequently, associations of fractal aggregates join into a fractal structure. The rate of this process increases in medium electric fields, and the formed fractal structure has features of aerogels and fractal fibers. As a result of a chain of the above processes, a porous metal film may be manufactured for use as a filter or catalyst for gas flows.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Power Conversion Efficiencies of Perovskite and Dye-Sensitized Solar Cells under Various Solar Radiation Intensities

We present the results of a comparative study on behaviour of the photovoltaic parameters in perovskite (PSC), dye-sensitized (DSC) and crystalline silicon (c-Si) solar cells under various intensities of solar radiation (10–1000 W/m{sup 2}). It was found that unlike c-Si, the power conversion efficiencies of PSC and DSC under low radiation intensities are comparable with the corresponding values observed under standard light intensity of 1000 W/m{sup 2} (AM1.5G). We have shown that high performance of the PSC and DSC at low and diffuse lighting conditions can be explained by the properties of the nanostructured TiO{sub 2}-based photoelectrodes depending on the structure, morphology and the thickness of the TiO{sub 2} layers.

14 SOLAR ENERGY↗

The interference enhancement of light polarization conversion from structures with a quantum well

The optical activity of crystals leads to the occurrence of ellipticity at the reflection of light which is linearly polarized in the interface plane or normally to it. The effect experimentally discovered in the investigated structures with quantum wells is due to a spin-orbit interaction and birefringence. The qualitative dependence of the effect on the change in the orientation of the linear polarization of the incident light has been revealed. A sharp increase in the degree of the polarization conversion in a narrow range of incidence angles for light polarized in the incidence plane has been detected. The latter is due to the influence of the interference of the reflected wave on the structure thickness.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Rise Kinetics of Up-Conversion Luminescence of the LiY{sub 0.8}Yb{sub 0.2}F{sub 4}:Tm{sup 3+} (0.2 at %) Crystal with Pulsed Excitation

The regression analysis of the rise kinetics of up-conversion luminescence of the LiY{sub 0.8}Yb{sub 0.2}F{sub 4}:Tm{sup 3+} (0.2 at %) crystal is performed. The kinetics curve is obtained with rectangular pulsed excitation by radiation from a laser diode (IR LD) with a wavelength of λ{sub p} = 933 nm. The most important—in these experimental conditions—mechanisms of the energy transfer from Yb{sup 3+} ions to Tm{sup 3+} ions are established, which are responsible for the transitions between the ground {sup 3}H{sub 6} and excited {sup 3}F{sub 4}, {sup 3}H{sub 4}, {sup 1}G{sub 4}, {sup 1}D{sub 2}, and {sup 1}I{sub 6} terms of the Tm{sup 3+} ions. The durations of the relevant energy transfer processes are determined. It is shown that the energy transfer between rare earth ions in the LiY{sub 0.8}Yb{sub 0.2}F{sub 4}:Tm{sup 3+} (0.2 at %) crystal occurs through the dipole–dipole interactions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Energy Conversion in Gd{sub 2}O{sub 3} Nanocrystals Doped with Er{sup 3+} Ions

The conversion of the energy absorbed by cubic Gd{sub 2}O{sub 3} nanocrystals doped with Er{sup 3+} and codoped with Yb{sup 3+} and Zn{sup 2+} ions in a temperature range of 95–425 K is studied at various concentrations of dopants. The photoluminescence spectra confirm the ability of excitation energy transfer from the Gd{sup 3+} ions or the matrix towards the Er{sup 3+} ions. The population of upper excited states in the Er{sup 3+} ions depends on the way of excitation, which cause the alterations in the probability of multiphonon relaxation from the excited states to the radiative levels. The kinetics of photoluminescence decay exhibit the possible energy transfer from anionic defects created by extra doping with Zn{sup 2+} ions. The temperature dependences of the upconversion luminescence yield for emission lines of 560 and 660 nm are found to be different.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Electrophysical Setup for the Conversion of Natural Gas at Atmospheric Pressure

The conversion of hydrocarbons during the treatment of a methane–ethane mixture with a barrier discharge in an electrophysical setup was experimentally studied. The theoretical estimation of plasmakinetic processes occurring in a discharge was performed for the developed plasmachemical reactor using the ZDPlasKin algorithm. Experimental results were in agreement with theoretical estimates.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

High-Efficiency Conversion of High-Power-Density Laser Radiation

AlGaAs/GaAs-based semiconductor photovoltaic converters (PVCs) of laser radiation, capable of operating at an illuminance up to 9 kW/cm{sup 2} with retained isothermal state have been studied. This state was confirmed by the logarithmic shape of dependences of the open-circuit voltage on the power density of incident laser radiation. At maximum illuminance, the open-circuit voltage level was close to 1.33 V. It is shown that the proposed PVCs can provide laser radiation conversion at an 840-nm wavelength with efficiency above 51% at an incident radiation power density of 2.5 kW/cm{sup 2}.

14 SOLAR ENERGY↗

New Materials for Photoelectrochemical Energy Conversion

This review concerns light-to-chemical energy conversion, focusing on approaches that could be driven by terrestrial sunlight to produce hydrogen and/or reduce carbon dioxide. Recent advances in photocatalytic (PC) and photoelectrocatalytic (PEC) materials are covered. In both approaches, the electron-hole pairs that are created by photon absorption must travel in specific directions to the sites that mediate multielectron bond making/breaking redox reactions. Thermodynamic requirements for materials stability are described, although some recently discovered materials appear to be exceptions. For PC materials, the importance of rate matching between reduction and oxidation processes and the mass transfer of intermediates and products is emphasized. Surprisingly, metal sulfides appear to be promising for PC carbon dioxide reduction. For PEC materials, recent work elucidating the elementary step mechanism for oxygen evolution on metal oxides and the discovery of chalcogen-based photocathode materials capable of sustained light-driven CO 2 reduction are discussed.

energy conversion↗

Solar-Driven Reduction of 1 atm CO 2 to Formate at 10% Energy-Conversion Efficiency by Use of a TiO 2 -Protected III-V Tandem Photoanode in Conjunction with a Bipolar Membrane and a Pd/C Cathode Electrocatalyst

A solar-driven CO 2 -reduction (CO 2 R) cell, made up of a tandem GaAs/InGaP/TiO 2 /Ni photoanode in 1.0 M KOH(aq) (pH=13.7) to facilitate the oxygen-evolution reaction (OER), a Pd/C nanoparticle-coated Ti mesh cathode in 2.8 M KHCO 3 (aq) (pH=8.0) to perform the CO 2 R reaction, and a bipolar membrane to allow for steady-state operation of the catholyte and anolyte at different bulk pH values, was built. At the operational current density of 8.5 mA cm -2 , in 2.8 M KHCO 3 (aq), the cathode exhibited <100 mV overpotential and >94% Faradaic efficiency for the reduction of 1 atm of CO 2 (g) to formate. The anode exhibited 320 ± 7 mV overpotential for the OER in 1.0 M KOH(aq), and the bipolar membrane exhibited ~480 mV voltage loss with minimal product crossover as well as >90% and >95% selectivity for protons and hydroxide ions, respectively. The solar-driven CO 2 R cell converted sunlight to fuels at an energy-conversion efficiency of ~10%.

30 DIRECT ENERGY CONVERSION↗

Anodic Conversion of Cyclohexane, Methylcyclohexane, and 2-Propanol: Towards a Regenerable Liquid-Fed Fuel Cell

Liquid Organic Hydrogen Carriers (LOHCs) are promising for hydrogen and energy storage but require endothermic catalytic dehydrogenation. An alternative approach is a regenerable liquid-fed fuel cell which spontaneously converts an organic carrier from its hydrogen-rich to hydrogen-lean form while generating electrical power. The anodic electrooxidation of cyclohexane, methylcyclohexane and 2-propanol in a high temperature polybenzimidazole/phosphoric acid (PBI/PA) PEM fuel cell was investigated along with a quantitative analysis of reaction products. Cyclohexane and methylcyclohexane were predominantly converted to CO 2 with only a trace formation of the corresponding aromatic and cyclic olefin byproducts. This near-to-complete oxidation of the fuels is in sharp contrast to previous reports of a selective conversion of cyclohexane to benzene, with no CO 2 byproducts. In experiments with 2-propanol, acetone was produced, with diisopropylether, propylene and CO 2 as only minor side products. However, the extent of CO 2 formation greatly increased at higher current densities.

25 ENERGY STORAGE↗

The Selective Electrochemical Conversion of Preactivated CO 2 to Methane

This work reports the selective electrochemical conversion of CO 2 to methane, the reverse reaction of fossil fuel combustion. This reaction is facilitated by preactivation of the CO 2 molecule with an N-heterocyclic carbene (NHC) to form a zwitterionic species in the first step. In the presence of Ni(cyclam) 2+ and CF 3 CH 2 OH, this species is shown to undergo further electrochemical reduction of the bound-CO 2 fragment at glassy carbon cathodes in dichloromethane electrolyte solution. Labeling studies confirm the origin of the carbon and protons in the methane product are the preactivated CO 2 and trifluoroethanol respectively.

30 DIRECT ENERGY CONVERSION↗

Evaluation of bacterial hosts for conversion of lignin-derived p-coumaric acid to 4-vinylphenol

Abstract Hydroxycinnamic acids such as p -coumaric acid (CA) are chemically linked to lignin in grassy biomass with fairly labile ester bonds and therefore represent a straightforward opportunity to extract and valorize lignin components. In this work, we investigated the enzymatic conversion of CA extracted from lignocellulose to 4-vinylphenol (4VP) by expressing a microbial phenolic acid decarboxylase in Corynebacterium glutamicum , Escherichia coli, and Bacillus subtilis . The performance of the recombinant strains was evaluated in response to the substrate concentration in rich medium or a lignin liquor and the addition of an organic overlay to perform a continuous product extraction in batch cultures. We found that using undecanol as an overlay enhanced the 4VP titers under high substrate concentrations, while extracting > 97% of the product from the aqueous phase. C. glutamicum showed the highest tolerance to CA and resulted in the accumulation of up to 187 g/L of 4VP from pure CA in the overlay with a 90% yield when using rich media, or 17 g/L of 4VP with a 73% yield from CA extracted from lignin. These results indicate that C. glutamicum is a suitable host for the high-level production of 4VP and that further bioprocess engineering strategies should be explored to optimize the production, extraction, and purification of 4VP from lignin with this organism.

4-hydroxystyrene↗

Experimental Demonstration of 28.2% Thermophotovoltaic Conversion Efficiency

Efficient luminescence extraction enables us to use the photovoltaic band gap as the spectral filter for thermophotovoltaics. Using this concept, we demonstrate a 28.2% conversion efficiency, higher than the previously reported value for the range of the emitter temperature (700 degrees C-1250 degrees C) used.

14 SOLAR ENERGY↗

Microwave-optical quantum frequency conversion

Photons at microwave and optical frequencies are principal carriers for quantum information. While microwave photons can be effectively controlled at the local circuit level, optical photons can propagate over long distances. High-fidelity conversion between microwave and optical photons will allow the distribution of quantum states across different quantum technology nodes and enhance the scalability of hybrid quantum systems toward a future “Quantum Internet.” Despite a frequency difference of five orders of magnitude, there has been significant progress recently toward the transfer between microwave and optical photons with steadily improved efficiency in a coherent and bidirectional manner. In this review, we summarize this progress, emphasizing integrated device approaches, and provide a perspective for device implementation that enables quantum state transfer and entanglement distribution across microwave and optical domains.

74 ATOMIC AND MOLECULAR PHYSICS↗

Technical Support to SBIR Phase II Project: Improved Conversion of Cellulose Waste to Ethanol Using a Dual Bioreactor System: Cooperative Research and Development (Final Report)

Over-dependence on fossil fuel has spurred research on alternative energy. Inedible plant materials such as grass and corn stover represent abundant renewable natural resources that can be transformed into biofuel. Problems in enzymatic conversion of biomass to sugars include the use of incomplete synergistic enzymes, end-product inhibition, and adsorption and loss of enzymes necessitating their use in large quantities. Technova Corporation will develop a defined consortium of natural microorganisms that will efficiently break down biomass to energy-rich soluble sugars, and convert them to cleaner-burning ethanol fuel. The project will also develop a novel biocatalytic hybrid reactor system dedicated to this bioprocess, which embodies recent advances in nanotechnology. NREL will participate to develop a continuous fermentation process.

09 BIOMASS FUELS↗