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At least 1,459 records · Page 81

P.L. 100-357, "National Appliance Energy Supply Amendments" (1988)

Amends the Energy Policy and Conservation Act to include fluorescent lamp ballasts within the list of products covered by the Act. Amends the definition of "consumer product" to include fluorescent lamp ballasts distributed in commerce for personal or commercial use or consumption.

appliance, fluorescent lamp ballasts, consumer pro↗

Multiple objective optimization in reliability demonstration test

Reliability demonstration tests are usually performed in product design or validation processes to demonstrate whether a product meets specified requirements on reliability. For binomial demonstration tests, the zero-failure test has been most commonly used due to its simplicity and use of minimum sample size to achieve an acceptable consumer’s risk level. However, this test can often result in unacceptably high risk for producers as well as a low probability of passing the test even when the product has good reliability. This paper explicitly explores the interrelationship between multiple objectives that are commonly of interest when planning a demonstration test and proposes structured decision-making procedures using a Pareto front approach for selecting an optimal test plan based on simultaneously balancing multiple criteria. Different strategies are suggested for scenarios with different user priorities and graphical tools are developed to help quantify the trade-offs between choices and to facilitate informed decision making. As a result, potential impacts of some subjective user inputs on the final decision are studied to offer insights and useful guidance for general applications.

97 MATHEMATICS AND COMPUTING↗

Energy Saver: Tips on Saving Money & Energy at Home

Provides consumers with home energy and money savings tips such as insulation, weatherization, heating, cooling, water heating, energy efficient windows, landscaping, lighting, and energy efficient appliances.

Energy Savers, Tips, Money, Home, Saver, Consumer↗

Light-Duty Vehicle Choice Modeling and Benefits Analysis (van018)

The U.S. Department of Energy’s Vehicle Technologies and Hydrogen and Fuel Cell Technologies Offices (VTO and HFTO) support research and development of efficient and sustainable transportation technologies that will improve energy efficiency, minimize emissions, and enable America to use less petroleum. The analysis in this poster is based on technical progress goals established in VTO and HFTO in the years immediately prior to and including 2020, and it summarizes the estimated energy and emissions benefits corresponding with achievement of those goals. The goals span research activities on batteries, electric drive technologies (EDT), combustion, lightweight materials, fuel cells, and hydrogen storage. The Automotive Deployment Options Projection Tool (ADOPT) is used to estimate the benefits for light-duty vehicles. ADOPT is a vehicle choice and stock model that estimates vehicle technology improvement impacts on sales, energy, and emissions. It includes all the existing vehicle options for realism, estimates their sales using extensively validated consumer preferences, creates new market-driven vehicle options through time, and rolls up sales to estimate energy and emissions. ADOPT takes in technology progress assumptions and applies these to the modeled vehicles through time. The assumptions are represented by a No Program scenario that reflects the technology improvements assumed to occur without further contributions from VTO or HFTO, and a Program Success scenario under which VTO and HFTO program goals are realized. The benefits are calculated by comparing ADOPT's estimated national-level energy and emissions resulting from the Program Success relative to the No Program scenario. By 2050, the Program Success scenario results in 11% less annual petroleum consumption and 10% less annual carbon emissions than the No Program scenario.

ADVANCED PROPULSION SYSTEMS↗

Incentives for Methane Mitigation and Energy-Efficiency Improvements in Case of Ukraine’s Natural Gas Transmission System

Reducing methane losses is a concern for climate change policy and energy policy. The energy sector is the major source of methane emissions into the atmosphere. Reducing methane emissions and avoiding combustion can be very cost-effective, but various barriers prevent such energy-efficiency measures from taking place. To date, few examples of industry-wide improvements exist. One example of substantial investments into upgrading natural gas transmission system comes from Ukraine. The Ukrainian transmission company, Ukrtransgaz, reduced its own system’s natural gas consumption by 68 percent in 2011 compared to the level in 2005. Evaluating reductions in methane emissions is challenging because of lack of accurate data and gaps in accounting methodologies. At the same time, Ukraine’s transmission system has undergone improvements that, at the very least, have contained methane emissions, if not substantially reduced them. In this paper, we describe recent developments in Ukraine’s natural gas transmission system and analyze the incentives that forced the sector to pay close attention to its methane losses. Ukraine is one of most energy-intensive countries, among the largest natural gas consumers in the world, and a significant emitter of methane. The country is also dependent on imports of natural gas. A combination of steep increases in the price of imported natural gas, and comprehensive domestic environmental and energy policies, regional integration policy, and international environmental agreements has created conditions for successful methane emission and combustion reductions. Learning about such case studies can help us design better policies elsewhere.

Methane Mitigation, Energy Efficiency, Ukraine, Na↗

Pathways and transformations of dissolved methane and dissolved inorganic carbon in Arctic tundra watersheds: Evidence from analysis of stable isotopes

Arctic soils contain a large pool of terrestrial C and are of interest due to their potential for releasing significant carbon dioxide (CO 2 ) and methane (CH 4 ) to the atmosphere. Due to substantial landscape heterogeneity, predicting ecosystem-scale CH 4 and CO 2 production is challenging. This study assessed dissolved inorganic carbon (DIC = Σ (total) dissolved CO 2 ) and CH 4 in watershed drainages in Barrow, Alaska as critical convergent zones of regional geochemistry, substrates, and nutrients. In July and September of 2013, surface waters and saturated subsurface pore waters were collected from 17 drainages. Based on simultaneous DIC and CH 4 cycling, we synthesized isotopic and geochemical methods to develop a subsurface CH 4 and DIC balance by estimating mechanisms of CH 4 and DIC production and transport pathways and oxidation of subsurface CH 4 . We observed a shift from acetoclastic (July) toward hydrogenotropic (September) methanogenesis at sites located toward the end of major freshwater drainages, adjacent to salty estuarine waters, suggesting an interesting landscape-scale effect on CH 4 production mechanism. The majority of subsurface CH 4 was transported upward by plant-mediated transport and ebullition, predominantly bypassing the potential for CH 4 oxidation. Thus, surprisingly, CH 4 oxidation only consumed approximately 2.51± 0.82% (July) and 0.79 ± 0.79% (September) of CH 4 produced at the frost table, contributing to <0.1% of DIC production. DIC was primarily produced from respiration, with iron and organic matter serving as likely e- acceptors. Furthermore, this work highlights the importance of spatial and temporal variability of CH 4 production at the watershed scale and suggests broad scale investigations are required to build better regional or pan-Arctic representations of CH 4 and CO 2 production.

54 ENVIRONMENTAL SCIENCES↗

Pathways of sulfate enhancement by natural and anthropogenic mineral aerosols in China

China, the world’s largest consumer of coal, emits approximately 30 million tons of sulfur dioxide (SO₂) per year. SO₂ is subsequently oxidized to sulfate in the atmosphere. However, large gaps exist between model-predicted and measured sulfate levels in China. Long-term field observations and numerical simulations were integrated to investigate the effect of mineral aerosols on sulfate formation. We found that mineral aerosols contributed a nationwide average of approximately 22% to sulfate production in 2006. The increased sulfate concentration was approximately 2 μg m⁻³ in the entire China. In East China and the Sichuan Basin, the increments reached 6.3 μg m⁻³ and 7.3 μg m⁻³, respectively. Mineral aerosols led to faster SO₂ oxidation through three pathways. First, more SO₂ was dissolved as cloud water alkalinity increased due to water-soluble mineral cations. Sulfate production was then enhanced through the aqueous-phase oxidation of S(IV) (dissolved sulfur in oxidation state +4). The contribution to the national sulfate production was 5%. Second, sulfate was enhanced through S(IV) catalyzed oxidation by transition metals. The contribution to the annual sulfate production was 8%, with 19% during the winter that decreased to 2% during the summer. Third, SO₂ reacts on the surface of mineral aerosols to produce sulfate. The contribution to the national average sulfate concentration was 9% with 16% during the winter and a negligible effect during the summer. The inclusion of mineral aerosols does resolve model discrepancies with sulfate observations in China, especially during the winter. These three pathways, which are not fully considered in most current chemistry-climate models, will significantly impact assessments regarding the effects of aerosol on climate change in China.

Huang, Xin↗

Effects of simulated spring thaw of permafrost from mineral cryosol on CO 2 emissions and atmospheric CH 4 uptake

Abstract Previous studies investigating organic‐rich tundra have reported that increasing biodegradation of Arctic tundra soil organic carbon (SOC) under warming climate regimes will cause increasing CO 2 and CH 4 emissions. Organic‐poor, mineral cryosols, which comprise 87% of Arctic tundra, are not as well characterized. This study examined biogeochemical processes of 1 m long intact mineral cryosol cores (1–6% SOC) collected in the Canadian high Arctic. Vertical profiles of gaseous and aqueous chemistry and microbial composition were related to surface CO 2 and CH 4 fluxes during a simulated spring/summer thaw under light versus dark and in situ versus water saturated treatments. CO 2 fluxes attained 0.8 ± 0.4 mmol CO 2 m −2 h −1 for in situ treatments, of which 85 ± 11% was produced by aerobic SOC oxidation, consistent with field observations and metagenomic analyses indicating aerobic heterotrophs were the dominant phylotypes. The Q 10 values of CO 2 emissions ranged from 2 to 4 over the course of thawing. CH 4 degassing occurred during initial thaw; however, all cores were CH 4 sinks at atmospheric concentration CH 4 . Atmospheric CH 4 uptake rates ranged from −126 ± 77 to −207 ± 7 nmol CH 4 m −2 h −1 with CH 4 consumed between 0 and 35 cm depth. Metagenomic and gas chemistry analyses revealed that high‐affinity Type II methanotrophic sequence abundance and activity were highest between 0 and 35 cm depth. Microbial sulfate reduction dominated the anaerobic processes, outcompeting methanogenesis for H 2 and acetate. Fluxes, microbial community composition, and biogeochemical rates indicate that mineral cryosols of Axel Heiberg Island act as net CO 2 sources and atmospheric CH 4 sinks during summertime thaw under both in situ and water saturated states.

Stackhouse, Brandon T.↗

Effects of electron temperature anisotropy on proton mirror instability evolution

Proton mirror modes are large amplitude nonpropagating structures frequently observed in the magnetosheath. It has been suggested that electron temperature anisotropy can enhance the proton mirror instability growth rate while leaving the proton cyclotron instability largely unaffected, therefore causing the proton mirror instability to dominate the proton cyclotron instability in Earth's magnetosheath. In this paper we use particle-in-cell simulations to investigate the electron temperature anisotropy effects on proton mirror instability evolution. Contrary to the hypothesis, electron temperature anisotropy leads to excitement of the electron whistler instability. Finally, our results show that the electron whistler instability grows much faster than the proton mirror instability and quickly consumes the electron-free energy so that there is no electron temperature anisotropy left to significantly impact the evolution of the proton mirror instability.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Integrating Algae with Bioenergy Carbon Capture and Storage (ABECCS) Increases Sustainability

Abstract Bioenergy carbon capture and storage (BECCS) has been proposed to reduce atmospheric CO 2 concentrations, but concerns remain about competition for arable land and freshwater. The synergistic integration of algae production, which does not require arable land or freshwater, with BECCS (called “ABECCS”) can reduce CO 2 emissions without competing with agriculture. This study presents a technoeconomic and life‐cycle assessment for colocating a 121‐ha algae facility with a 2,680‐ha eucalyptus forest for BECCS. The eucalyptus biomass fuels combined heat and power (CHP) generation with subsequent amine‐based carbon capture and storage (CCS). A portion of the captured CO 2 is used for growing algae and the remainder is sequestered. Biomass combustion supplies CO 2 , heat, and electricity, thus increasing the range of sites suitable for algae cultivation. Economic, energetic, and environmental impacts are considered. The system yields as much protein as soybeans while generating 61.5 TJ of electricity and sequestering 29,600 t of CO 2 per year. More energy is generated than consumed and the freshwater footprint is roughly equal to that for soybeans. Financial break‐even is achieved for product value combinations that include 1) algal biomass sold for $1,400/t (fishmeal replacement) with a $68/t carbon credit and 2) algal biomass sold for $600/t (soymeal replacement) with a $278/t carbon credit. Sensitivity analysis shows significant reductions to the cost of carbon sequestration are possible. The ABECCS system represents a unique technology for negative emissions without reducing protein production or increasing water demand, and should therefore be included in the suite of technologies being considered to address global sustainability.

09 BIOMASS FUELS↗

Sea Level Rise Impacts on Wastewater Treatment Systems Along the U.S. Coasts

As sea levels rise, coastal communities will experience more frequent and persistent nuisance flooding, and some low-lying areas may be permanently inundated. Critical components of lifeline infrastructure networks in these areas are also at risk of flooding, which could cause significant service disruptions that extend beyond the flooded zone. Thus, identifying critical infrastructure components that are exposed to sea level rise is an important first step in developing targeted investment in protective actions and enhancing the overall resilience of coastal communities. Wastewater treatment plants are typically located at low elevations near the coastline to minimize the cost of collecting consumed water and discharging treated effluent, which makes them particularly susceptible to coastal flooding. For this analysis, we used geographic information systems to assess the exposure of wastewater infrastructure to various sea level rise projections at the national level. We then estimated the number of people who would lose wastewater services, which could be more than five times as high as previous predictions of the number of people at risk of direct flooding due to sea level rise. We also performed a regional comparison of wastewater exposure to marine and groundwater flooding in the San Francisco Bay Area. Overall, this analysis highlights the widespread exposure of wastewater infrastructure in the United States and demonstrates that local disruptions to infrastructure networks may have far-ranging impacts on areas that do not experience direct flooding.Plain Language Summary Wastewater treatment plants are susceptible to flooding resulting from sea level rise. Previous estimates of wastewater exposure have only considered the impacts of marine flooding at the local or regional scale. In this analysis, we quantify the exposure to marine flooding across the coastal United States and then consider the relative impacts of marine and groundwater flooding at the regional scale in the San Francisco Bay Area. We also estimate the number of people who may lose access to wastewater services if no actions are taken to prevent flooding at wastewater treatment plants. We find that the number of people impacted by sea level rise due to loss of wastewater services could be five times as high as previous predictions of the number of people who experience direct flooding of their homes or property. We also find that groundwater flooding poses a significant threat to wastewater plants in the San Francisco Bay region.

54 ENVIRONMENTAL SCIENCES↗

Mass Spectrometry-based Assay for High Throughput and High Sensitivity Biomarker Verification

Searching for disease specific biomarkers has become a major undertaking in the biomedical research field as the effective diagnosis, prognosis and treatment of many complex human diseases are largely determined by the availability and the quality of the biomarkers. A successful biomarker as an indicator to a specific biological or pathological process is usually selected from a large group of candidates by a strict verification and validation process. To be clinically useful, the validated biomarkers must be detectable and quantifiable by the selected testing techniques in their related tissues or body fluids. Due to its easy accessibility, protein biomarkers would ideally be identified in blood plasma or serum. However, most disease related protein biomarkers in blood exist at very low concentrations (<1ng/mL) and are “masked” by many none significant species at orders of magnitude higher concentrations. The extreme requirements of measurement sensitivity, dynamic range and specificity make the method development extremely challenging. The current clinical protein biomarker measurement primarily relies on antibody based immunoassays, such as ELISA. Although the technique is sensitive and highly specific, the development of high quality protein antibody is both expensive and time consuming. The limited capability of assay multiplexing also makes the measurement an extremely low throughput one rendering it impractical when hundreds to thousands potential biomarkers need to be quantitatively measured across multiple samples. Mass spectrometry (MS)-based assays have recently shown to be a viable alternative for high throughput and quantitative candidate protein biomarker verification. Among them, the triple quadrupole MS based assay is the most promising one. When it is coupled with liquid chromatography (LC) separation and electrospray ionization (ESI) source, a triple quadrupole mass spectrometer operating in a special selected reaction monitoring (SRM) mode, also known as multiple reaction monitoring (MRM), is capable of quantitatively measuring hundreds of candidate protein biomarkers from a relevant clinical sample in a single analysis. The specificity, reproducibility and sensitivity could be as good as ELISA. Furthermore, SRM MS can also quantify protein isoforms and post-translational modifications, for which traditional antibody-based immunoassays often don’t exist.

Environmental Molecular Sciences Laboratory↗

Reinforcement Learning for Intelligent Building Energy Management System Control *

A building energy management system (BEMS) is a computer-based system designed to monitor and control a building's energy needs. Modern BEMS rely on the sensing and connectivity capabilities of Internet of Things (IoT) technology to intelligently adjust the energy consumption to reduce cost while respecting the consumers' preferences. Increasingly, control decisions are made based on predictions by models trained using supervised machine learning methods, which still requires control policies to be formulated in a rule-based fashion. When using reinforcement learning (RL) instead, control policies are learned by observing the utility in terms of cost and comfort associated with actions such as a change in the heating system's setpoint. The resulting RL-based controllers can capture not only the dynamics of the building and the associated electrical devices, but also fluctuations in electricity prices and user demand, avoiding the need to combine multiple predictive models with tailored control policies. This chapter will provide an overview of RL-based approaches for BEMS. After sketching the taxonomy of general RL methods, we discuss the implications of relying on the individual methods in a BEMS context. Existing work applying RL is presented along the key devices controlled by BEMS systems. Finally, we summarize the state-of-the-art and sketch limitations and open research directions.

Kotevska, Olivera↗

Analysis and Design for Sustainable Circularity of Barrier Films Used in Sheet Molding Composites Production

Sheet molding composites (SMC) are thermoset based molding compounds with a global market size of USD 2.1 billion in 2020. SMC is usually processed with multilayer barrier/carrier films to prevent emissions from volatile organic compounds (VOC). The plastic barriers are separated from SMC after the curing process and discarded. To illustrate the high consumption volume of SMC barrier/carrier films, Kohler Co., a company which uses SMC in their bath and showering product lines, alone generates over 1M lb/year of SMC barrier/carrier film waste. Therefore, high amount of SMC barrier/carrier film plastic waste creates a great opportunity for reusing, recycling, or valorization at its end of life. This can be achieved through transition from a linear to a circular supply chain design. However, this transition will not be feasible without overcoming the technical and economic barriers. This project aims to tackle this by making the film circular. Different end of life alternatives will be evaluated experimentally. The reusability of the film will be studied through applying different mechanical and solvent cleaning techniques. The operability concerns regarding the utilization of the cleaned film for long run operations will be addressed by thermally stitching the film. Pelletizing of the cleaned film will also be investigated as a viable technique for recycling or downcycling of the film as molded products. In addition to technical barriers, designing a sustainable circular supply chain for SMC carrier film products requires uncovering the collaboration opportunities between suppliers and users at different stages of the value chain to expand its use to other products. These opportunities will be investigated by finding companies willing to buy or treat the plastic film waste. Finally, the economic viability and environmental impacts of these circular design alternatives will be evaluated through techno-economic assessment (TEA) and life cycle analysis (LCA). Techno-economic and life cycle inventory data for various pathways will also be made available as one of the main outcomes of this project. Preliminary LCA results indicate that the current SMC film supply chain (base case) emits 5.81 tonne CO2 eq. and consumes 104 GJ energy per tonne of SMC film. It is estimated that alternative circular pathways result in 14-20% less CO2 emissions and 34-44% reduction in embodied energy. This project will develop a tool to analyze the circularity and sustainability of hundreds of combinations of alternatives in different life cycle stages. Users of this tool will be able to choose the best combination among these alternatives with respect to the selected economic, environmental and circularity objectives.

circular economy↗

Chapter 14: Electron Microscopy on Thin Films for Solar Cells

This chapter overviews the various techniques applied in scanning electron microscopy (SEM) and transmission electron microscopy (TEM), and highlights their possibilities and also limitations. It gives the various imaging and analysis techniques applied on a scanning electron microscope. The chapter shows that imaging is divided into that making use of secondary electrons (SEs) and of backscattered electrons (BSEs), resulting in different contrasts in the images and thus providing information on compositions, microstructures, and surface potentials. Whenever aiming for imaging and analyses at scales of down to the angstroms range, TEM and its related techniques are appropriate tools. In many cases, also SEM techniques provide the access to various material properties of the individual layers, not requiring specimen preparation as time consuming as TEM techniques. Finally, the chapter dedicates to cross-sectional specimen preparation for electron microscopy. The preparation decides indeed on the quality of imaging and analyses.

14 SOLAR ENERGY↗

A Simple Electrode-Level Chemical Presodiation Route by Solution Spraying to Improve the Energy Density of Sodium-Ion Batteries

The formation of a solid electrolyte interface (SEI) on the surface of a carbon anode consumes the active sodium ions from the cathode and reduces the energy density of sodium-ion batteries (SIBs). In this work, a simple electrode-level presodiation strategy by spraying a sodium naphthaline (Naph-Na) solution onto a carbon electrode is reported, which compensates the initial sodium loss and improves the energy density of SIBs. After presodiation, an SEI layer is preformed on the surface of carbon anode before battery cycling. It is shown that a large irreversible capacity of 60 mAh g –1 is replenished and 20% increase of the first-cycle Coulombic efficiency is achieved for a hard carbon anode using this presodiation strategy, and the energy density of a Na 0.9 [Cu 0.22 Fe 0.30 Mn 0.48 ]O 2 ||carbon full cell is increased from 141 to 240 Wh kg –1 by using the presodiated carbon anode. This simple and scalable electrode-level chemical presodiation route also shows generality and value for the presodiation of other anodes in SIBs.

25 ENERGY STORAGE↗

Knittable and Washable Multifunctional MXene-Coated Cellulose Yarns

Textile-based electronics enable the next generation of wearable devices, which have the potential to transform the architecture of consumer electronics. Highly conductive yarns that can be manufactured using industrial-scale processing and be washed like everyday yarns are needed to fulfill the promise and rapid growth of the smart textile industry. By coating cellulose yarns with Ti 3 C 2 T x MXene, highly conductive and electroactive yarns are produced, which can be knitted into textiles using an industrial knitting machine. It is shown that yarns with MXene loading of ≈77 wt% (≈2.2 mg cm -1 ) have conductivity of up to 440 S cm -1 . After washing for 45 cycles at temperatures ranging from 30 to 80 °C, MXene-coated cotton yarns exhibit a minimal increase in resistance while maintaining constant MXene loading. The MXene-coated cotton yarn electrode offers a specific capacitance of 759.5 mF cm -1 at 2 mV s -1 . Additionally, a fully knitted textile-based capacitive pressure sensor is also prepared, which offers high sensitivity (gauge factor of ≈6.02), wide sensing range of up to ≈20% compression, and excellent cycling stability (2000 cycles at ≈14% compression strain). This work provides new and practical insights toward the development of platform technology that can integrate MXene in cellulose-based yarns for textile-based devices.

36 MATERIALS SCIENCE↗