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A comprehensive review of solar only and hybrid solar driven multigeneration systems: Classifications, benefits, design and prospective

Depending on the application and demands, different products can be generated utilizing multigeneration systems. To drive such systems, solar energy can be used as a primary energy source or in hybridization with other renewable or nonrenewable energy sources. Solar driven multigeneration systems are appealing due to the broad availability of solar energy and related technologies. Here, the objective of this study is to review, categorize and discuss different configurations, benefits, potentials, challenges, future research directions and market perspectives of solar energy-driven multigeneration systems, comprehensively. This study also reviews how solar energy systems can be used to hybridize systems for multigeneration purposes. Regardless of using fossil fuel backup sources, these systems are classified as (1) solar only-driven and (2) hybrid solar-driven, in which solar energy is used together with other renewable sources. Reviewing the literature demonstrates numerous ways to build solar energy-driven multigeneration systems by coupling a variety of different cycles and devices. Such systems offer multiple benefits such as enhancing the efficiency, reducing capital and operating costs and carbon dioxide emission. Hybridizing solar with other renewable energies enables continuous operation and dispatchability management. This review shows that for configuration selection and design, different thermodynamics, economic and environmental aspects should be considered. To advance the solar driven multigeneration systems development, further multidisciplinary research on different aspects of such systems is necessary. Particularly, investigations should focus on building different prototypes and on conducting experimental assessments. Also, new incentives and long-term purchase agreements for the products must be established.

14 SOLAR ENERGY↗

Materials Fingerprinting Classification

Significant progress in many classes of materials could be made with the availability of experimentally-derived large datasets composed of atomic identities and three-dimensional coordinates. Methods for visualizing the local atomic structure, such as atom probe tomography (APT), which routinely generate datasets comprised of millions of atoms, are an important step in realizing this goal. However, state-of-the-art APT instruments generate noisy and sparse datasets that provide information about elemental type, but obscure atomic structures, thus limiting their subsequent value for materials discovery. The application of a materials fingerprinting process, a machine learning algorithm coupled with topological data analysis, provides an avenue by which here-to-fore unprecedented structural information can be extracted from an APT dataset. As a proof of concept, the material fingerprint is applied to high-entropy alloy APT datasets containing body-centered cubic (BCC) and face-centered cubic (FCC) crystal structures. A local atomic configuration centered on an arbitrary atom is assigned a topological descriptor, with which it can be characterized as a BCC or FCC lattice with near perfect accuracy, despite the inherent noise in the dataset. Finally, this successful identification of a fingerprint is a crucial first step in the development of algorithms which can extract more nuanced information, such as chemical ordering, from existing datasets of complex materials.

36 MATERIALS SCIENCE↗

Classification of igneous rocks analyzed by ChemCam at Gale crater, Mars

Several recent studies have revealed that Mars is not a simple basalt-covered planet, but has a more complex geological history. In Gale crater on Mars, the Curiosity rover discovered 59 igneous rocks. This article focuses on their textures (acquired from the cameras such as MAHLI and MastCam) and their geochemical compositions that have been obtained using the ChemCam instrument. Light-toned crystals have been observed in most of the rocks. They correspond to feldspars ranging from andesines/oligoclases to anorthoclases and sanidines in the leucocratic vesiculated rocks. Darker crystals observed in all igneous rocks (except the leucocratic vesiculated ones) were analyzed by LIBS and mainly identified as Fe-rich pigeonites and Fe-augites. Iron oxides have been observed in all groups whereas F-bearing minerals have been detected only in few of them. From their textural analysis and their whole-rock compositions, all these 59 igneous rocks have been classified in five different groups; from primitive rocks i.e. dark aphanitic basalts/basanites, trachybasalts, tephrites and fine/coarse-grained gabbros/norites to more evolved materials i.e. porphyritic trachyandesites, leucocratic trachytes and quartz-diorites. The basalts and gabbros are found all along the traverse of the rover, whereas the felsic rocks are located before the Kimberley formation, i.e. close to the Peace Vallis alluvial fan deposits. This suggests that these alkali rocks have been transported by fluvial activity and could come from the Northern rim of the crater, and may correspond to deeper strata buried under basaltic regolith (Sautter et al., 2015). Some of the basaltic igneous rocks are surprisingly enriched in iron, presenting low Mg# similar to the nakhlite parental melt that cannot be produced by direct melting of the Dreibus and Wanke (1986) martian primitive mantle. The basaltic rocks at Gale are thus different from Gusev basalts. They could originate from different mantle reservoirs, or they could have undergone a more extensive fractional crystallization. Lastly, Gale basaltic rocks could have been the parental magma of residual liquid extending into alkali field towards trachyte composition as magma fractionated under anhydrous condition on its way to the surface before sub adiabatic ascent.

58 GEOSCIENCES↗