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At least 1,459 records · Page 81

Consequences of utilizing a redox-active polymeric binder in Li-ion batteries

Development of new polymeric binders can help enable the use of silicon-rich anodes in Li-ion batteries, by providing stronger adhesion to the active material particles. The compositional features that improve interfacial interactions and mechanical properties can often impart electronic conductivity and redox activity to these polymers, which are generally seen as beneficial to cell performance. Alternatively, it is also possible that the addition of charge-transferring centers to the electrode can accelerate cell degradation. Here, we use an aromatic polyimide (∼320 mA h/g of reversible capacity) to explore how a redox-active conductive polymer can affect cell performance. We demonstrate that the lithiated polymer is less stable than the traditional binders upon storage, leading to increased rates of calendar aging. Furthermore, we determine that the adhesion properties of the polymer deteriorate upon repeated cycling, to an extent that is proportional to the degree of delithiation of the binder. More critically, we establish that progressive degradation of the redox behavior of the polymer leads to the release of “extra” Li + into the cell, which can give the false perception of good performance even under conditions of poor stability. In conclusion, our work suggests that redox-active conductive binders can sometimes be detrimental to cell performance, and that works evaluating new polymers must include careful experimental validation under realistic conditions.

25 ENERGY STORAGE↗

The feasibility of electron beam slip stacking in EIC Rapid Cycling Synchrotron

Announced in 2020, the Electron Ion Collider will be constructed at Brookhaven National Lab (BNL) by modifying the existing Relativistic Heavy Ion Collider (RHIC) facility. Among the alterations include the installation of an electron storage ring (ESR) and a Rapid Cycling Synchrotron (RCS) in the existing RHIC tunnel. The RCS will accelerate polarized electrons from 400MeV to 5GeV,10GeV and 18 GeV and transfer it to the ESR. The LINAC source produces 7nC per shot meanwhile the RCS requires 28nC per bunch of charge. Currently, it is planned to inject 4 bunches into adjacent RF buckets and then merge them into a single RF bucket using fields from several RF cavities. However, this requires a kicker with an exceptionally fast rise and fall time to inject into adjacent RF bucket without disturbing the existing circulating bunch and this requires harmonic RF kickers. Our study focuses on determining the feasibility of an alternate particle injection method that will utilize slip stacking, a method that accommodates the circulation of multiple beams with different momentum in the same azimuthal space of the beampipe, thus permitting the accumulation of charge from several shots into a single RF bucket. We find the momentum aperture required for slip stacking using current RCS beam parameters exceeds the RCS’s momentum deviation limit,dp/p = 1.5%. We determine the appropriate dimensions the beam must have to enable slip stacking and conduct a literature review of slip stacking schemes in other facilities. The literature review tentatively indicates that slip stacking has not been attempted on electron beams at a major accelerator facility.. The slip stacking approach has the potential to save the cost of the harmonic RF kicker and bunch merging cavities.

43 PARTICLE ACCELERATORS↗

Indium Tin Oxide-Magnesium Fluoride Co-Deposited Films for Spacecraft Applications

Highly transparent coatings with a maximum sheet resistivity between 10(exp 8) and 10(exp 9) ohms/square are desired to prevent charging of solar arrays for low Earth polar orbit and geosynchronous orbit missions. Indium tin oxide (ITO) and magnesium fluoride (MgF2) were ion beam sputter co-deposited onto fused silica substrates and were evaluated for transmittance, sheet resistivity and the effects of simulated space environments including atomic oxygen (AO) and vacuum ultraviolet (VUV) radiation. Optical properties and sheet resistivity as a function of MgF2 content in the films will be presented. Films containing 8.4 wt.% MgF2 were found to be highly transparent and provided sheet resistivity in the required range. These films maintained a high transmittance upon exposure to AO and to VUV radiation, although exposure to AO in the presence of charged species and intense electromagnetic radiation caused significant degradation in film transmittance. Sheet resistivity of the as-fabricated films increased with time in ambient conditions. Vacuum beat treatment following film deposition caused a reduction in sheet resistivity. However, following vacuum heat treatment, sheet resistivity values remained stable during storage in ambient conditions.

Dever, Joycer A.↗

Long duration battery sizing, siting, and operation under wildfire risk using progressive hedging

Battery sizing and siting problems are computationally challenging due to the need to make long-term planning decisions that are cognizant of short-term operational decisions. This paper considers sizing, siting, and operating batteries in a power grid to maximize their benefits, including price arbitrage and load shed mitigation, during both normal operations and periods with high wildfire ignition risk. Here we formulate a multi-scenario optimization problem for long duration battery storage while considering the possibility of load shedding during Public Safety Power Shutoff (PSPS) events that de-energize lines to mitigate severe wildfire ignition risk. To enable a computationally scalable solution of this problem with many scenarios of wildfire risk and power injection variability, we develop a customized temporal decomposition method based on a progressive hedging framework. Extending traditional progressive hedging techniques, we consider coupling in both placement variables across all scenarios and state-of-charge variables at temporal boundaries. This enforces consistency across scenarios while enabling parallel computations despite both spatial and temporal coupling. The proposed decomposition facilitates efficient and scalable modeling of a full year of hourly operational decisions to inform the sizing and siting of batteries. With this decomposition, we model a year of hourly operational decisions to inform optimal battery placement for a 240-bus WECC model in under 70 min of wall-clock time.

25 ENERGY STORAGE↗

Hypochlorite Redox Chemistry Enables High-Voltage and High-Power Saltwater Batteries

Saltwater batteries (SWBs) are promising alternatives to lithium-ion batteries for large-scale stationary energy storage. However, the performance of conventional oxygen redox-based saltwater battery systems is often constrained by sluggish oxygen evolution and reduction reactions (OER/ORR) at the cathode, leading to low voltage efficiency and limited power density. Here, OER and ORR are replaced by hypochlorite-based redox reactions through the introduction of sodium hypochlorite into saltwater. Operando pH and dissolved oxygen measurements confirm that OER and ORR are minimized and that hypochlorite redox reactions dominate the cathode behavior. Owing to the higher operating potential and faster reaction kinetics, the hypochlorite-redox-based SWBs delivers a higher discharge voltage of 3.3 V and reduced charge-discharge voltage polarization to 0.66 V. Further improvement is achieved by adjusting the saltwater pH to near-neutral conditions, increasing the discharge voltage to 3.5 V and more than doubling the peak power. The hypochlorite redox environment also exhibits chemical stability with key cell components, including the solid electrolyte and cathode current collectors. Operation of series-connected cells and cells employing hard carbon anodes demonstrates scalability and compatibility with alternative anode materials. These results provide a strong foundation for next-generation SWBs targeting large-scale stationary energy storage applications.

Go, Wooseok [ORNL]↗

Uncovering the predictive pathways of lithium and sodium interchange in layered oxides

Ion exchange is a powerful method to access metastable materials with advanced functionalities for energy storage applications. However, high concentrations and unfavourably large excesses of lithium are always used for synthesizing lithium cathodes from parent sodium material, and the reaction pathways remain elusive. Here, using layered oxides as model materials, we demonstrate that vacancy level and its corresponding lithium preference are critical in determining the accessible and inaccessible ion exchange pathways. Taking advantage of the strong lithium preference at the right vacancy level, we establish predictive compositional and structural evolution at extremely dilute and low excess lithium based on the phase equilibrium between Li 0.94 CoO 2 and Na 0.48 CoO 2 . Such phase separation behaviour is general in both surface reaction-limited and diffusion-limited exchange conditions and is accomplished with the charge redistribution on transition metals. Guided by this understanding, we demonstrate the synthesis of Na y CoO 2 from the parent Li x CoO 2 and the synthesis of Li 0.94 CoO 2 from Na y CoO 2 at 1-1,000 Li/Na (molar ratio) with an electrochemical assisted ion exchange method by mitigating the kinetic barriers. Our study opens new opportunities for ion exchange in predictive synthesis and separation applications. Ion exchange is a powerful method to access metastable materials for energy storage, but identifying lithium and sodium interchange in layered oxides remains challenging. Using such model materials, vacancy level and corresponding lithium preference are shown to be crucial for ion exchange pathway accessibility.

25 ENERGY STORAGE↗

Validating Phasing and Geometry of Large Focal Plane Arrays

The Kepler Mission is designed to survey our region of the Milky Way galaxy to discover hundreds of Earth-sized and smaller planets in or near the habitable zone. The Kepler photometer is an array of 42 CCDs (charge-coupled devices) in the focal plane of a 95-cm Schmidt camera onboard the Kepler spacecraft. Each 50x25-mm CCD has 2,200 x 1,024 pixels. The CCDs accumulate photons and are read out every six seconds to prevent saturation. The data is integrated for 30 minutes, and then the pixel data is transferred to onboard storage. The data is subsequently encoded and transmitted to the ground. During End-to-End Information System (EEIS) testing of the Kepler Mission System (KMS), there was a need to verify that the pixels requested by the science team operationally were correctly collected, encoded, compressed, stored, and transmitted by the FS, and subsequently received, decoded, uncompressed, and displayed by the Ground Segment (GS) without the outputs of any CCD modules being flipped, mirrored, or otherwise corrupted during the extensive FS and GS processing. This would normally be done by projecting an image on the focal plane array (FPA), collecting the data in a flight-like way, and making a comparison between the original data and the data reconstructed by the science data system. Projecting a focused image onto the FPA through the telescope would normally involve using a collimator suspended over the telescope opening. There were several problems with this approach: the collimation equipment is elaborate and expensive; as conceived, it could only illuminate a limited section of the FPA (.25 percent) during a given test; the telescope cover would have to be deployed during testing to allow the image to be projected into the telescope; the equipment was bulky and difficult to situate in temperature-controlled environments; and given all the above, test setup, execution, and repeatability were significant concerns. Instead of using this complicated approach of projecting an optical image on the FPA, the Kepler project developed a method using known defect features in the CCDs to verify proper collection and reassembly of the pixels, thereby avoiding the costs and risks of the optical projection approach. The CCDs composing the Kepler FPA, as all CCDs, had minor defects. At ambient temperature, some pixels look far brighter than they should. These ghot h pixels have a higher rate of charge leakage than the others due to manufacturing variations. They are usually stable over time, and appear at temperatures above 5 oC. The hot pixels on the Kepler FPA were mapped before photometer assembly during module testing. Selected hot pixels were used as target gstars h for the purposes of EEIS testing. gDead h pixels are permanently off, producing a permanently black pixel. These can also be used if there is some illumination of the FPA. During EEIS testing, Dark Current Full Frame Images (FFIs) taken at room temperature were used to create the hot pixel maps for all 84 Kepler photometer CCD channels. Data from two separate nights were used to create two hot pixel maps per channel, which were cross-correlated to remove cosmic ray events which appear to be hot pixels. These hot pixel maps obtained during EEIS testing were compared to the maps made during module testing to verify that the end-to-end data flow was correct.

Standley, Shaun P.↗

Material Failure Mechanisms of Alkaline Zn Rechargeable Conversion Electrodes

Zinc (Zn) alkaline electrodes hold great importance and promise in the battery technology community, yet their behavior in real-world applications is still poorly understood. Here, we report a study of failure mechanisms and material evolution during cycling of 27 zinc–manganese dioxide (Zn–MnO 2 ) cells wherein the percent utilization of the Zn electroactive material is systematically varied between 1 and 16%. Cell fabrication is kept typical of the prevailing industrial cell design. The cycle life ranges from 2800 to 60, depending inversely on the Zn utilization. In all cases, the Zn material microstructure sheds the polytetrafluoroethylene (PTFE) binder and forms zinc oxide (ZnO) rods, with longer rods formed by lower current per Zn mass. Irreversible side reactions such as the hydrogen evolution reaction (HER), short circuits, or gas crossover cause the Zn anode’s charging efficiency to average 92% (as low as 86%), which in turn causes the baseload of metallic Zn to gradually disappear. Cell failure occurs after the baseload of metallic Zn is exhausted. The total lifetime discharge capacity remains constant near 12 ± 5 Ah/g Zn invariant of Zn utilization, which suggests that the aforementioned processes of Zn microstructural evolution and side-reaction destruction of baseload metallic zinc both progress linearly with cell capacity throughput. Manual reproduction of individual Zn failure mechanisms is performed in 22 fresh cells. Tight packing of the microstructure can lead to poor mass transfer, which causes supersaturation of soluble Zn and finally produces a high overvoltage during discharge. Here, the low charging current density yields poor coulombic efficiency due either to the competitive HER or soft short circuits.

25 ENERGY STORAGE↗

A KMnO 4 -Generated Colloidal Electrolyte for Redox Mediation and Anode Protection in a Li–Air Battery

The rechargeable lithium-oxygen (Li-O 2 ) battery has the highest theoretical specific energy density of any rechargeable batteries and could transform energy storage systems if a practical device could be attained. However, among numerous challenges, which are all interconnected, are polarization due to sluggish kinetics, low cycle life, small capacity, and slow rates. Here, in this study, we report on use of KMnO 4 to generate a colloidal electrolyte made up of MnO 2 nanoparticles. The resulting electrolyte provides a redox mediator for reducing the charge potential and lithium anode protection to increase cycle life. This electrolyte in combination with a stable binary transition metal dichalcogenide alloy, Nb 0.5 Ta 0.5 S 2 , as the cathode enables the operation of a Li-O 2 battery at a current density of 1 mA center dot cm -2 and specific capacity ranging from 1000 to 10000 mA center dot h center dot g -1 (corresponding to 0.1-1 mA center dot h center dot cm -2 ) in a dry air environment with a cycle life of up to 150. This colloidal electrolyte provides a robust approach for advancing Li-air batteries.

25 ENERGY STORAGE↗

High-performance room-temperature sodium–sulfur battery enabled by electrocatalytic sodium polysulfides full conversion

Room-temperature sodium–sulfur (RT-Na–S) batteries are highly desirable for grid-scale stationary energy storage due to their low cost; however, short cycling stability caused by the incomplete conversion of sodium polysulfides is a major issue for their application. Herein, we introduce an effective sulfiphilic host, gold nanodots decorated on hierarchical N-doped carbon microspheres (CN/Au/S), to achieve completely reversible conversion reactions in the S cathode by electrocatalyzing the low-kinetics conversion of Na 2 S 4 into NaS 2 (discharge process) or S (charge process). Besides, gold nanodots and N-doped carbon can increase the conductivity of the S cathode and provide strong polar–polar adsorption of sodium polysulfides to alleviate the shuttling effects. When serving as the cathode, the CN/Au/S composite can realize enhanced sulfur utilization, excellent cycling stability, and outstanding rate capability. This work deepens our understanding of the catalytic effect of gold atoms on sulfur molecules, opening a new avenue for cathode design and development of advanced RT-Na–S batteries.

25 ENERGY STORAGE↗

Fast and Scalable Synthesis of LiNi 0.5 Mn 1.5 O 4 Cathode by Sol–Gel-Assisted Microwave Sintering

High-voltage spinel LiNi 0.5 Mn 1.5 O 4 (LNMO) is a promising cathode material for high-energy-density and high-power-density lithium-ion batteries (LIBs). The high cost of the currently available LIBs needs to be addressed urgently for wide application in the transport sector (electric vehicles, buses) and large-scale energy storage systems (ESS). Of significance, herein, novel fast and scalable microwave-assisted synthesis of LNMO is reported, which leads to a production cost cut. X-ray diffraction (XRD) analysis confirms the formation of the desired phase with high crystallinity. Field emission scanning (FE-SEM) and transmission electron microscopy (TEM) analyses indicate that the synthesized phase is of nanometric size (50–150 nm) due to an extremely short sintering time (20 min). The material synthesized at 750 °C shows a higher initial discharge capacity (130 mA h g -1 ) than that synthesized at 650 °C (115 mA h g -1 ). The materials heat treated at higher temperatures show better electrochemical performance in terms of initial capacity, rate capability, and improved cycling. The improved electrochemical performance of LNMO at 750 °C is attributed to the formation of a stable crystal structure, low charge transfer resistance at the electrode/electrolyte interface, high electrical conductivity due to the presence of a disorder structure, and improved ionic diffusivity.

25 ENERGY STORAGE↗

Simultaneous Control of Pore‐Space Partition and Charge Distribution in Multi‐Modular Metal–Organic Frameworks

Abstract We report here a strategy for making anionic pacs type porous materials by combining pore space partition with charge reallocation. The method uses the first negatively charged pore partition ligand (2,5,8‐tri‐(4‐pyridyl)‐1,3,4,6,7,9‐hexaazaphenalene, H‐tph) that simultaneously enables pore partition and charge reallocation. Over two dozen anionic pacs materials have been made to demonstrate their excellent chemical stability and a high degree of tunability. Notably, Ni 3 ‐bdt‐tph (bdt=1,4‐benzeneditetrazolate) exhibits month‐long water stability, while CoV‐bdt‐tph sets a new benchmark for C 2 H 2 storage capacity under ambient conditions for ionic MOFs. In addition to tunable in‐framework modules, we show feasibility to tune the type and concentration of extra‐framework counter cations and their influence on both stability and capability to separate industrial C 3 H 8 /C 3 H 6 and C 6 H 6 /C 6 H 12 mixtures.

Hong, Anh N.↗

A high reliability battery management system

Over a period of some 5 years Canadian Astronautics Limited (CAL) has developed a system to autonomously manage, and thus prolong the life of, secondary storage batteries. During the development, the system was aimed at the space vehicle application using nickel cadmium batteries, but is expected to be able to enhance the life and performance of any rechargeable electrochemical couple. The system handles the cells of a battery individually and thus avoids the problems of over, and under, drive that inevitably occur in a battery of cells managed by an averaging system. This individual handling also allow cells to be totally bypassed in the event of failure, thus avoiding the losses associated with low capacity, partial short circuit, and the catastrophe of open circuit. The system has an optional capability of managing redundant batteries simultaneously, adding the advantage of on line reconditioning of one battery, while the other maintains the energy storage capability of the overall system. As developed, the system contains a dedicated, redundant, microprocessor, but the capability exists to have this computing capability time shared, or remote, and operating through a data link. As adjuncts to the basic management system CAL has developed high efficiency, polyphase, power regulators for charge and discharge power conditioning.

Moody, M. H.↗

Solar dynamic power for space station freedom

The Space Station Freedom Program is presently planned to consist of two phases. At the completion of Phase 1, Freedom's manned base will consist of a transverse boom with attached manned modules and 75 kW of available electric power supplied by photovoltaic (PV) power sources. In Phase 2, electric power available to the manned base will be increased to 125 kW by the addition of two solar dynamic (SD) power modules, one at each end of the transverse boom. Power for manned base growth beyond Phase 2 will be supplied by additional SD modules. Studies show that SD power for the growth eras will result in life cycle cost savings of $3 to $4 billion when compared to PV-supplied power. In the SD power modules for Space Station Freedom, an offset parabolic concentrator collects and focuses solar energy into a heat receiver. To allow full power operation over the entire orbit, the receiver includes integral thermal energy storage by means of the heat of fusion of a salt mixture. Thermal energy is removed from the receiver and converted to electrical energy by a power conversion unit (PCU) which includes a closed brayton cycle (CBC) heat engine and an alternator. The receiver/PCU/radiator combination will be completely assembled and charged with gas and cooling fluid on Earth before launch to orbit. The concentrator subassemblies will be pre-aligned and stowed in the orbiter bay before launch. On orbit, the receiver/PCU/radiator assembly will be installed as a unit. The pre-aligned concentrator panels will then be latched together and the total concentrator attached to the receiver/PCU/radiator by the astronauts. After final electric connections are made and checkout is complete, the SD power module will be ready for operation.

Labus, Thomas L.↗

Solar dynamic power for Space Station Freedom

The Space Station Freedom Program is presently planned to consist of two phases. At the completion of Phase 1, Freedom's manned base will consist of a transverse boom with attached manned modules and 75 kW of available electric power supplied by photovoltaic (PV) power sources. In Phase 2, electric power available to the manned base will be increased to 125 kW by the addition of two solar dynamic (SD) power modules, one at each end of the transverse boom. Power for manned base growth beyond Phase 2 will be supplied by additional SD modules. Studies show that SD power for the growth eras will result in life cycle cost savings of $3 to $4 billion when compared to PV-supplied power. In the SD power modules for Space Station Freedom, an offset parabolic concentrator collects and focuses solar energy into a heat receiver. To allow full power operation over the entire orbit, the receiver includes integral thermal energy storage by means of the heat of fusion of a salt mixture. Thermal energy is removed from the receiver and converted to electrical energy by a power conversion unit (PCU) which includes a closed brayton cycle (CBC) heat engine and an alternator. The receiver/PCU/radiator combination will be completely assembled and charged with gas and cooling fluid on earth before launch to orbit. The concentrator subassemblies will be pre-aligned and stowed in the orbiter bay before launch. On orbit, the receiver/PCU/radiator assembly will be installed as a unit. The pre-aligned concentrator panels will then be latched together and the total concentrator attached to the receiver/PCU/radiator by the astronauts. After final electric connections are made and checkout is complete, the SD power module will be ready for operation.

Labus, Thomas L.↗

Metrics for Anomalous Charging currents in Polymer Tantalum Capacitors

Anomalous charging currents (ACC) in polymer tantalum capacitors may appear as a temporary short circuit that can last for dozens of milliseconds, cause failures to the parts, or cause malfunctions to fast operating electronic systems. Currently, there is no standard technique or set of metrics to evaluate the level of ACC which compares results obtained by different users and manufacturers. In this work, ACC in different types of capacitors were characterized by analysis of current transients during the constant voltage ramp or power surge testing (PST) techniques. It is shown that although the shape of transients may vary at different test conditions, the transfer charge and energy remain practically the same. The level of ACC is characterized by the energy dissipated in the part during PST. Variations of the dissipated energy with moisture content, test temperature, and voltage are evaluated. Effects of different reflow soldering conditions and long-term (up to 3000 hours) storage at 125 °C are discussed.

polymer tantalum capacitor↗

Measurement of the muon spin precession frequency using the straw tracking detectors at the Fermilab Muon g-2 experiment

The measurement of the anomalous magnetic dipole moment of the muon ($a_{\mu}$) has long stood as an excellent precision test of the Standard Model (SM). The Fermilab Muon g-2 experiment has recently finished data-taking and in July 2023 published its latest determination of $a_\mu$ with a world-leading precision of 0.2\,ppm. In this publication, it surpassed the systematic uncertainty goal defined in the TDR. The analyses of a dataset approximately four times larger than this recent publication is now underway. The principle measurement of the Muon g-2 experiment measures $a_{\mu}$ by taking the ratio of two frequencies; the anomalous precession frequency ($\omega_a$) and the muon-weighted magnetic field of the experiment's storage ring measured from the precession frequency of protons in water using nuclear magnetic resonance (NMR) probes. In all publications to date, $\omega_a$ has been determined using energy deposits in the 24 calorimeters. However, the Fermilab experiment has t wo straw tracker detectors measuring the time and momentum of charged particles which can in principle also be used to to measure $\omega_a$ and such a measurement can provide an invaluable cross-check of the calorimeter result with different, and reduced, systematic uncertainties. This thesis presents the first (blinded) determination of $\omega_a$ using just charged tracks from the straw tracking detectors as opposed to calorimeter energy deposits. This analysis was undertaken using the Run-2/3 dataset which represents approximately 25\% of the final dataset. A total uncertainty of 2.19\,ppm on $\omega_a$ was obtained which is dominated by the statistical uncertainty of 2.16\,ppm. Additionally two new methodologies important to the analysis of the straw tracking data have been developed: one to better determine the track arrival time ($t_0$) and one to determine the level of pileup in the tracking detectors. The new $t_0$ algorithm which incorporates angular information improves t he resolution on the determination of the $t_0$ by a factor of two and results in 19\% more tracks being successfully reconstructed. The data from the trackers is also used to determine the beam profile that weights the magnetic field in the determination of $a_\mu$ and in determining several of the systematic uncertainties in the calorimeter-based $\omega_a$ analysis. A detailed study of the impact of the internal alignment of the tracker, the $t_0$ and pileup on the determination of the beam position was undertaken and propagated through to an uncertainty in the $\omega_a$ determination. These uncertainties were used in the Fermilab Muon g-2 experiment's recent publication in Phys. Rev. Lett.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Outstanding Platinum Group Metal-free Bifunctional Catalysts for Rechargeable Zinc-Air Batteries

Developing highly active and durable catalysts for zinc-air batteries (ZAB) is critical for energy conversion and storage. Herein, we prepared Fe-N-C catalysts at a kilogram scale by the commercial VariPore™ method and the effect of synthesis conditions on the catalyst performance at ZAB air electrode was investigated. The results show the PA-450-HT exhibits excellent electrocatalytic activity toward oxygen reduction reaction (ORR) and it is the most suitable catalyst for primary ZAB with the galvanostatic polarization discharge peak power density of 149 mW cm -2 , outperforming commercial Pt-Ru/C catalysts. Additionally, the NCB-600-HT catalyst displays the half-wave potential of 0.87 V vs. RHE for ORR and ΔE value of 0.81 V (indicating outstanding ORR and OER reversibility) and exhibits excellent charge-discharge cycling durability similar to NCB-550-LT around 160 h for the secondary ZAB. This work reports outstanding bifunctional Fe-N-C catalysts for rechargeable ZAB at mass production for the first time.

25 ENERGY STORAGE↗