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At least 1,459 records · Page 81
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Intra-Molecular Isotope Study of Light Hydrocarbons

Light hydrocarbons (C 1 -C 10 ) are the largest fraction of petroleum hydrocarbons and some of the most ubiquitous and mobile fluids within sedimentary basins. It has been increasingly recognized that hydrocarbons of varying chain-lengths can be stable even under mantle conditions and that their fluxes may play a key role in the carbon dynamics of the Earth. Major formation mechanisms of these light hydrocarbons include microbial, thermogenic, and abiogenic origins. Despite their proven utility, conventional approaches using the bulk or global stable isotopes of light hydrocarbons are often not sufficient to distinguish their sources (particularly, biogenic vs. abiogenic), maturation stages/temperatures, and migration-degradation processes. Most natural compounds, including light hydrocarbons, are composed of a set of diverse isotopic molecules that differ in the number of isotopic substitutions and/or positions of isotopic substitution within a given molecules. Many of light hydrocarbon molecules contain hydrogen and carbon in energetically non-equivalent positions: isotopomers or position-specific (intra-molecular) isotope fractionation. Position-specific isotopic compositions can differ due either to equilibrium or to path-dependent kinetic or biological processes. Thus, the position-specific isotopic fractionation between different carbon and hydrogen positions within a single molecular compound could be used regardless of their reactants and other products. We hypothesize that the formation, transport and degradation processes of light hydrocarbons in the subsurface induce and control significant, perhaps unique position-specific 13 C/ 12 C and 2 H/ 1 H isotope fractionation. In this proposal, we propose to develop a new dimension in stable isotope geochemistry of light hydrocarbons: intra-molecular isotope study of light hydrocarbons. The specific objectives of our proposal include: (a) develop robust and routine quantitative nuclear magnetic resonance (NMR) methods for high-precision/high-accuracy isotopomer analysis of propane and other light hydrocarbons (C 3 -C 10 ), (b) gain a first clear picture on position-specific δ 2 H and δ 13 C values of select light hydrocarbons of both natural and industrial sources, including samples of natural gases (C 3 and possibly C 4 -C 5 ) collected from select sedimentary basins with conventional and unconventional reservoirs, (c) acquire information on position-specific 13 C/ 12 C and 2 H/ 1 H isotope fractionation of light hydrocarbons in key natural processes (thermogenic formation and oxidative degradation) based on well-controlled laboratory experiments, and (d) establish a general framework for interpreting/modeling position-specific 13 C/ 12 C and 2 H/ 1 H isotope compositions of light hydrocarbons. Intra-molecular isotope study of light hydrocarbons is expected to open up great potentials that the bulk and position-specific isotope fractionation of light hydrocarbons, in combination with mathematical/theoretical kinetic models, could provide unprecedented wealth of information on the sources, transport, and sinks of light hydrocarbons in sedimentary basins and deep Earth.

03 NATURAL GAS↗
DOE OSTI2020

Project Methods to Enhance Wellbore Cement Integrity with Microbially-Induced Calcite Precipitation (MICP) (Final Scientific/Technical Report)

The goal of this project was to develop improved methods for sealing compromised wellbore cement in leaking oil and gas wells, thereby reducing the risk of unwanted upward fluid migration. Novel methods for improving wellbore integrity, such as microbially induced calcite precipitation (MICP), can reduce leakage potential, improve the safety of fossil fuel extraction, improve the public perception of hydraulic fracturing, and promote environmentally-prudent unconventional oil and gas development. Microbes, with the urease enzyme, can catalyze the chemical reaction of urea hydrolysis to induce the precipitation of calcium carbonate which can be used as a cementitious material to seal leakage pathways. In this project, methods to promote robust bio-composite cementitious materials were designed and tested in the laboratory. Scale-up of those methods were tested in meso-scale reactor systems and in field applications. In this report, in Section One, we describe laboratory efforts to develop injection strategies to promote precipitation in wellbore analogs and determine the strength of the bio-composite cements as compared to fine cement. In Section Two, we describe the efforts to scale up the work and study the use of materials that can be used in field application, for example exploring the use of calcium chloride ice melt or urea fertilizer as source chemicals. In Section Three, the three field trials (methods and results) performed as part of the project are described and summarized. At the end of the report is a comprehensive summary and conclusion section which highlights the key findings of the project. The work performed during this project significantly advanced the technology readiness level (TRL) of the MICP wellbore sealing strategy.

02 PETROLEUM↗
DOE OSTI2020

Methods to Enhance Wellbore Cement Integrity with Microbially-Induced Calcite Precipitation (MICP) (Final Scientific/ Technical Report)

The goal of this project was to develop improved methods for sealing compromised wellbore cement in leaking oil and gas wells, thereby reducing the risk of unwanted upward fluid migration. Novel methods for improving wellbore integrity, such as microbially induced calcite precipitation (MICP), can reduce leakage potential, improve the safety of fossil fuel extraction, improve the public perception of hydraulic fracturing, and promote environmentally-prudent unconventional oil and gas development. Microbes, with the urease enzyme, can catalyze the chemical reaction of urea hydrolysis to induce the precipitation of calcium carbonate which can be used as a cementitious material to seal leakage pathways. In this project, methods to promote robust bio-composite cementitious materials were designed and tested in the laboratory. Scale-up of those methods were tested in meso-scale reactor systems and in field applications. In this report, in Section One, we describe laboratory efforts to develop injection strategies to promote precipitation in wellbore analogs and determine the strength of the bio-composite cements as compared to fine cement. In Section Two, we describe the efforts to scale up the work and study the use of materials that can be used in field application, for example exploring the use of calcium chloride ice melt or urea fertilizer as source chemicals. In Section Three, the three field trials (methods and results) performed as part of the project are described and summarized. At the end of the report is a comprehensive summary and conclusion section which highlights the key findings of the project. The work performed during this project significantly advanced the technology readiness level (TRL) of the MICP wellbore sealing strategy.

03 NATURAL GAS↗
DOE OSTI2021

Raman Microscopy Analysis of Wyoming CarbonSAFE Pilot Well Thin Sections for Mineralogy and Organic Matter Characterization

Scanning confocal Raman microspectroscopy (RMS) was used to analyze thin sections for inorganic mineral content and for evaluation of organic material (OM). Thin sections were selected from a stratigraphic test well core in the Powder River Basin, Wyoming under the Wyoming CarbonSAFE project. The well was analyzed with a variety of rock and fluid characterization techniques to determine the feasibility of a commercial-scale CO2 storage site. RMS complements other analyses, including traditional petrography, SEM, porosity and permeability, and XRD For this aspect of the study, RMS is especially important in the evaluation of OM in sealing lithologies. At prospective geologic CO2 storage sites, it is imperative to assess the unconventional oil and gas potential of seals to ensure that any future development would not compromise the integrity of the seals. Whole-slide mineralogical surveys were performed on thin sections from various shale and sandstone formations. Surveys were analyzed with Direct Classical Least Squares to identify and quantify minerals. The location and concentration of minerals was color-coded and overlaid on optical images for visualization of the distribution of minerals. Dense hyperspectral Raman mapping of OM was performed on five thin sections. Eleven spectral parameters diagnostic of organic type and thermal maturity were used to train a Partial Least Squares (PLS) calibration against a set of artificially matured samples spanning the pre- to mid-oil window. The PLS was applied to the study set and a post-mature set. Additionally, the PLS was applied to each point in hyperspectral maps for visualization of trends in maturity across sample sets and discrimination of organic matter types within a given map. In inorganic surveys on thin sections, a total of 14 unique inorganic minerals were identified in Raman spectra including quartz, dolomite, calcite, hematite and anhydrite. Shale thin sections tended to be dominated by organic material. OM was often observed mixed with inorganic minerals. Sand- and mudstones were dominated by inorganic minerals. The PLS extrapolated the post-mature set to reflectances >1.2%. The study set ranged from very immature to postmature in the median of map fit-peak parameters. However, point maturity maps indicate that matrix OM in all study samples is immature and that discreet organic particles selected for mapping, which may be inertinites, bias medians towards more-mature. The work demonstrates the capabilities of RMS to perform both whole-slide mineralogy and OM analysis with applications to formation evaluation in oil & gas, carbon sequestration and mining. Here, analysis of sealing formations in the well indicates high levels of immature organic matter that would not be a viable target for future oil production that could compromise the CO2 storage site. The work brings together diverse disciplines from geology and petrography to analytical chemistry, big data and microscopy.

Myers, Grant↗
DOE OSTI2020

Proposed Potential Mitigation of Wastewater Disposal Through Treated Produced Water in Bakken Formation

The recent global expansion in the development of unconventional oil and gas assets has also resulted in a tremendous increase in the number of extended horizontal drilling and hydraulic fracturing projects in the Bakken. The United States is presently the largest global crude oil producer, and the Bakken Formation in North Dakota is one of the major contributors to this achievement. However, the wastewater produced from these increased oilfield activities are highly saline (∼170,000 to 350,000 ppm TDS) and no technology currently available can satisfactorily treat it. As a result, more than 90% of wastewater in the Bakken is disposed of by deep injection into disposal wells. However, there are growing environmental and operational concerns about the sustainability and impacts of this approach. Research has shown that cumulative wastewater injection in some areas could increase the chances of earthquakes in those areas. However, if this produced water is efficiently treated, it could be reused in hydraulic fracturing operations or to support coal mining and irrigation activities. All these applications would reduce the need for wastewater injection and reduce the demand for fresh water used in hydraulic fracturing operations across North Dakota. For this purpose, we propose an enhanced supercritical technology we call Supercritical Water Extraction – Enhance Targeted Recovery to handle the issue of high TDS of flowback and produced water in the Bakken.

04 OIL SHALES AND TAR SANDS↗
DOE OSTI2021

Implementing a Stochastic Soot Model in a 3D Domain

In this document a highly detailed stochastic soot model limited to 0D simulations is coupled to 3D domains through the use of a Lagrangian parcel-Eulerian fluid method. Although both the stochastic soot model used and the Lagrangian parcel-Eulerian fluid method have long histories of development, their use, as described in this document, is novel and useful. Previous works significant to the model's development include documents from both the stochastic and simpler soot model genre and the fuel, aerosol, and other particle tracking and Lagrangian parcel-Eulerian fluid genres. Developing the theory behind the model is crucial to its implementation because of the unconventional Lagrangian parcel-Eulerian fluid representation. In fact, the Lagrangian parcel-Eulerian fluid coupling is only a means of simplifying the much more difficult theoretical model. Despite the accompanying assumptions, the complete model is validated from the bottom up and then again in a holistic fashion with promising results. Then the model is used in multiple case studies, showcasing capabilities not had by other models. The optical properties of soot generated in a Spray A simulation are calculated to find measured results are likely overpredicting the mass of soot along the central axis via KL extinction measurements. A thermophoresis submodel that calculates force based on the soot particles' shape is installed to find it has a high influence on the path of the heaviest soot particles. Investigations into the HACA mechanism for soot growth and the effect of syngas on soot in 3D domains are performed with much more detail than has been available before.

Strickland, Tyler↗
DOE OSTI2022

Track-Based Triggers for Exotic Signatures

Standard triggers at the Large Hadron Collider are designed to select events with high momentum Standard Model particles which originate from the proton-proton collision of interest. However, several Beyond the Standard Model scenarios predict signatures with displaced or extremely low momentum charged particles, and pose significant challenges for LHC triggers. This article presents a study of track-based triggers for long-lived particles and other unconventional exotic signatures at the upcoming High Luminosity LHC. Representative scenarios studied include soft-unclustered-energy-patterns resulting in large multiplicities of low momentum tracks, a GMSB Supersymmetry scenario with long-lived staus resulting in displaced leptons or anomalous prompt tracks, and a higgs portal scenario with long-lived scalars resulting in displaced hadronic tracks. Trigger efficiency is measured as a function of the baseline parameters of a track trigger, including transverse momentum and impact parameters. Recommendations for future hardware-based track triggers are presented.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

Pair Fluctuation Effects on Quasiparticle Transport in Fermi Systems

The leading corrections to Fermi liquid theory for non-equilibrium quasiparticle transport near a Cooper instability arise from the virtual emission and absorption of incipient Cooper pairs. We formulate the corrections to the Landau-Boltzmann transport equation starting from Keldysh's field theory for non-equilibrium, strongly interacting Fermions. The theory is applicable to quasiparticle transport in conventional and unconventional superconductors, dense nuclear matter and the low temperature phases of liquid $^3$He. Validation of the theory is provided by our analysis, and quantitative agreement between theory and experiment, of the excess attenuation of zero sound in liquid $^3$He near the superfluid transition. We propose an additional experimental test of the theory based on the effects of a Zeeman field on the spectrum of pairing fluctuations for the Cooper instability in spin-triplet superfluids.

Lin, Wei-Ting↗
DOE OSTI2022

Reverse-mode differentiation in arbitrary tensor network format: with application to supervised learning.

This paper describes an efficient reverse-mode differentiation algorithm for contraction operations of tensor networks that may have arbitrary and unconventional network topologies. The approach leverages the tensor contraction tree of Evenbly and Pfeifer (2014), which provides an instruction set for the contraction sequence of a network. We show that this tree can be efficiently leveraged for differentiation of a full tensor network contraction using a recursive scheme that exploits (1) the bilinear property of contraction and (2) the property that trees have single path from root to leaves. While differentiation of tensor-tensor contraction is already possible in most automatic differentiation packages, we show that exploiting these two additional properties in the specific context of contraction sequences can improve efficiency. Following a description of the algorithm and computational complexity analysis, we investigate its utility for gradient-based supervised learning for low-rank function recovery and for fitting real-world unstructured datasets. We demonstrate improved performance over alternating least-squares optimization approaches and the capability to handle heterogeneous and arbitrary tensor network formats. When compared to alternating minimization algorithms, we find that the gradient-based approach requires a smaller oversampling ratio (number of samples compared to number model parameters) for recovery. This increased efficiency extends to fitting unstructured data of varying dimensionality and when employing a variety of tensor network formats. Here, we show improved learning using the hierarchical Tucker method over the tensor-train in high-dimensional settings on a number of benchmark problems.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2022

OPTIMIZATION OF A NUCLEAR VESSEL OUTLET FOR INCIDENT MONITORING

Classical nuclear core fluidic design techniques require improvement to better align with modern technological innovations. The US Department of Energy’s Office of Nuclear Energy (DOE-NE) Transformational Challenge Reactor (TCR) program is deploying additive manufacturing and advanced modeling and simulation to reimagine these designs. With the aid of modern computing power, computerized design optimization can be implemented to remove unwanted pressure drop while simultaneously optimizing flow structures, resulting in new opportunities to enable advanced instrumentation and monitoring capabilities.Previous development of geometric specifications for the TCR pressure vessel’s outlet plenum used design optimization to (1) limit pressure losses below 3.5 kPa (~0.5 psi) and (2) create a fluidic plane in which the temperature variation would not exceed ±5°C. This significant limit of the allowable pressure drop stems from the overarching goal of the TCR program to apply cutting edge techniques and unconventional thinking to demonstrate potential opportunities in additive manufacturing (AM).This paper expands the previous work by optimizing thermowell locations for robust measurements by explicitly modeling them and the resulting flow impacts. Additionally, a single core coolant channel was chosen to represent an event that causes an increased bulk flow temperature increase of 100°C.High fidelity unsteady Reynolds-averaged Navier-Stokes (URANS) simulations of the conjugate heat transfer problem were run in Siemen’s Star-CCM+ for this study. Next, the bulk flow temperature of a single coolant channel was increased by 100°C and was allowed to converge again. Finally, statistical analysis using a sequential probability ratio test (SPRT) was used to determine the elapsed time the thermocouples took to discover the increased bulk flow temperature.

See, Nate↗
DOE OSTI2022

Electron subband degeneracy heat pump for cryogenic cooling

An unconventional method of solid-state cryogenic cooling utilizing the electron subband degeneracy of semiconductor heterostructures is discussed in this Letter. The working principle of using the electrons as the working medium to perform cyclic heat pumping under electrostatic subband "expansion" and "compression" is discussed. The calculated base temperature can reach below dilution refrigeration temperatures with the fundamental limit set by electron-phonon interaction. Using an ultra-wide GaAs quantum well as an example, the cooling power per unit volume is estimated to reach $0.85\ \rm \mu W/cm^3$ at $25\ \rm mK$ with a hot-side temperature of $42.5\ \rm mK$, suitable for applications such as quantum computing.

Wang, Chulin↗
DOE OSTI2023

Advanced Mineral Separations with Novel Simulated Moving Beds

Lithium is a critical mineral that is widely used in batteries and energy storage applications, making it increasingly important in the next few decades. To meet the growing demand for lithium and secure domestic supply chains, there is a need to exploit unconventional lithium resources. However, utilizing current lithium extraction processes is challenging due to the high salinity in those resources. Thus, it is essential to develop energy-efficient, and less chemical-intensive separation processes that can exploit high-salinity lithium resources. Accordingly, this project aims to design a novel zwitterionic stationary phase and use it to develop a continuous chromatography process to recover LiCl minerals from traditionally unexploited domestic saline resources. The developed zwitterionic stationary phase allows fractionating minerals based on their different sorbent affinities under water elution. A systematically designed continuous process can separate lithium from other minerals, reducing the risk of material fouling and the overall chemical consumption to produce battery-grade lithium. This approach is expected to significantly enhance the efficiency and sustainability of the lithium extraction process while also reducing the environmental impact associated with traditional processes. At the end of the project, the technology will be demonstrated in continuous mode using a simulated moving bed (SMB) to recover >100 g of LiCl from real resource waters. The U.S.-based resources that this project targets for LiCl recovery are formation water, oil-produced water, and geothermal brines, supplied by Standard Lithium Ltd. and Shell Inc, respectively.

critical minerals↗
DOE OSTI2023

Novel Geochemistry Determined from High P-T Simulation Experiments of HFTS 2

A standard method in unconventional oil and gas production is the process of hydraulic fracturing followed by a shut-in period, during which the fracture fluid remains pressurized in the reservoir for up to three weeks before production begins. Despite this widely used process, very little is known about what occurs in the reservoir during this shut-in process. In order to properly delineate potential reservoir reactions that may occur during shut-in that would lead to corrosion and scaling events, experiments were conducted in high pressure, high temperature reactors to simulate conditions of the Wolfcamp Formation in the Delaware Basin. Experimental design allowed the assessment of the effect of proppant, microbiology, and time on the mineralogy and fluid chemistry in the reservoir. Results suggest the biggest impact on fluid chemistry and shale mineralogy during shut-in is time. Analyses demonstrate dissolution of the shale material, with maximum dissolved ions occurring after 7 days of the shut-in period. After 21 days, results suggest precipitation occurs. The Delaware Basin is demonstrated to be high in sulfate content, which further increases in the fluid due to dissolution reactions during shut-in. The pressure vessel experiments suggest there was no significant contribution to reactions from microbiology during the shut-in period. However, early production samples demonstrate a significant selection of the microorganism Caminicella, a genus of which has previously been correlated to corrosion and sulfide production. Results suggest shut-in conditions may provide high sulfate concentrations that could later be utilized by a shifted microbial community to drive potential well infrastructure failure. This is the first study to incorporate microbiology, mineralogy, and fluid chemistry to investigate the fundamental geochemical reactions that occur during shut-in and early phase production of the Delaware Basin. Results from this study can complement observations from the Hydraulic Fracture Test Site 2 observations.

Gulliver, Djuna↗
DOE OSTI2023

Critical Minerals from Waste Streams in the Powder River Basin of Wyoming and Montana, USA

Background/Objectives. Critical minerals (CM) are essential for numerous industrial and defense applications, including green technologies that will help to meet carbon emission reduction goals. Many CM are currently mined and processed in countries that lack stringent environmental and labor regulations. Unconventional sources such as existing industrial waste streams could play a part in building an ethical CM supply chain. Additionally, waste streams created in the extraction and processing of CM could be used for other industrial or commercial purposes, thereby reducing waste and advancing a circular economy. Approach/Activities. The Department of Energy funded Powder River Basin (PRB) CORE-CM project is exploring all aspects of the carbon ore, rare earth element (REE), and CM value chain, including the potential for extraction of CM from industrial waste streams in the basin. Waste streams that have potential as CM feedstocks are being inventoried to assess the concentration of CM in each waste stream and to estimate volume and accessibility. Although basin-specific technologies for extraction of CM are still in development, waste streams that may be produced during these processes are being cataloged and mapped to potential secondary uses. Results/Lessons Learned. Initial studies of the CM potential of PRB coal ash show that this waste stream contains concentrations of greater than 300 ppm total REE (Bagdonas et al., 2022, Renewable and Sustainable Energy Reviews). Moreover, calcium-rich PRB coal ash is amenable to REE extraction (Taggart et al., 2016, Environmental Science and Technology). Wyoming coal is shipped to 28 states, meaning that coal ash produced at power stations across the US represents a potential widespread resource for the extraction of REE. In addition to coal mining and coal fired electricity generation, the PRB is home to other energy industries including oil and gas production, in-situ uranium mining, and bentonite mining. Historically, precious and base metal mining has taken place on the perimeter of the PRB. Waste streams from these industries are currently being evaluated for their CM potential. Assessing the CM resource potential of waste streams could contribute to the development of an ethical CM supply chain. Results from these studies can be replicated for other waste streams, increasing the likelihood of successful creation of circular economies.

Phillips, Erin↗
DOE OSTI2023

CRITICAL MINERAL PARTITIONING IN COAL-HOSTED CLAYS OF THE POWDER RIVER BASIN, WY DETERMINED BY SEQUENTIAL EXTRACTION

Increasing demand for a more robust domestic supply of rare earth elements (REE) and critical minerals (CM) has led to significant investigation into unconventional sources. Coal and coal byproducts from the Powder River Basin (PRB) of Wyoming are potential sources of REE and CM. The association between strategic metals and their mineral hosts has important implications for extractability. Samples of overburden, underclays, and clay-rich partings were selected for analysis from core and bucket samples from three PRB coal mines. Quartz, illite, and kaolinite-group minerals are abundant in clay-rich portions of the PRB coal strata. We performed a five-step sequential extraction to constrain critical metal partitioning in samples of overburden and underclays (n=10). Unlike the occurrences of REE in other clay deposits, insignificant amounts of total REE + Y (TREY) were recovered in the ion-exchangeable fraction (< 0.5 ppm). A significant amount of TREY was leached from the acid-soluble fraction by 0.1M HCl, suggesting REE may be tied up within crystal lattices rather than sorbed to clay surfaces. The acid-soluble fraction contained between 3 and 250 ppm TREY, with an average TREY concentration of 60 ppm. Relative standard deviations for each extraction step were generally < ±10%. Whole-rock samples (n=72) contained greater TREY enrichment in overburden than in underclays and partings, however, the opposite is true for other CM, such as Ti and V. Other locations in the PRB show different enrichment trends. Our findings supplement a broader effort to couple REE and CM extraction with existing domestic coal production and contribute to the fundamental understanding of how these metals concentrate in low-temperature basin environments.

Stuart, Sophia↗
DOE OSTI2023

THE POTENTIAL FOR REUSE OF PRODUCED WATER IN THE CRITICAL MINERALS SUPPLY CHAIN IN THE POWDER RIVER BASIN OF WYOMING AND MONTANA

The Powder River Basin (PRB) Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) project is part of the Department of Energy sponsored CORE-CM initiative focused on domestic production of critical minerals and promoting economic development in traditionally fossil fuel producing basins. An important part of this project is regional assessment of waste streams and development of basinal strategies for waste stream reuse within the critical minerals (CM) supply chain. The availability of water for all parts of the CM supply chain is of particular concern in the arid mountain west. In the Wyoming PRB, average annual production of produced water (PW) by the oil and gas industry is more than 16 billion gallons (2015-2022). Through published data and engagement with industry partners, we conducted a preliminary investigation of PW in the PRB to understand volumes, quality, and the potential for use in the CM supply chain. PW was assessed for potential as a direct feedstock and for use in CM processing of a variety of conventional and unconventional feedstocks, including ore from the Bear Lodge Alkaline Complex, coal, and coal byproducts. Preliminary findings suggest that PRB PW contains significantly lower concentrations of rare earth elements (REE) and lithium than would be considered economic at this time. For example, concentrations of REE+Sc measured in PRB PW are <1 ppb (DE-EE0007603), and only seven PRB PW samples reported in the USGS PW database had lithium concentrations ≥50 ppm. However, enrichment of CM in residual brine and sludge from PW evaporation and solidification treatment ponds may yield concentrations of interest over a pond lifetime and should be considered in future studies. Coal bed methane (CBM) PW accounted for 42% of all PW in the Wyoming PRB in 2022. Compared to non-CBM PW, PRB CBM water quality generally meets standards allowing surface discharge and reuse in local industries such as livestock. CBM PW may help to fill water needs within the CM supply chain. Understanding the distribution of CBM PW that is discharged versus reused will help develop basinal reuse strategies.

Jackson, Lily↗
DOE OSTI2023

Space charge trap-assisted recombination suppressing layer for low-voltage diode operation

Shockley-Read-Hall (SRH) generation and/or recombination in heterojunction devices is suppressed by unconventional doping at or near the heterointerface. The effect of this doping is to shift SRH generation and/or recombination preferentially into the wider band gap material of the heterojunction. This reduces total SRH generation and/or recombination in the device by decreasing the intrinsic carrier concentration ni at locations where most of the SRH generation and/or recombination occurs. The physical basis for this effect is that the SRH generation and/or recombination rate tends to decrease as ni around the depletion region decreases, so decreasing the effective ni in this manner is a way to decrease SRH recombination.

Santhanam, Parthiban↗
DOE OSTI2024

Core Characterization: Computer Tomography, Geochemical, and Core Petrophysical Workflows for Emerging Critical Mineral Plays

The National Energy Technology Laboratory’s geoimaging lab in Morgantown, WV has been performing core characterization using multi-resolution Computed Tomography (CT) imaging and multisensor corelogger which allows for cm-resolution elemental and petrophysical measurements along whole core. This workflow has historically been used in unconventional gas plays and potential carbon storage locations. This rapid core characterization leads itself well as a first phase process in CM/REE evaluation efforts allowing for high-resolution, non-destructive investigation of elemental concentration using X-Ray Fluorescence and examination of core features through CT imaging.

Paronish, Thomas J.↗