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At least 1,459 records · Page 81

Calibration and modification of the constitutive model for the mechanical response of P91

The objective of this first milestone was to calibrate and if necessary, modify a constitutive model predicting the primary and secondary creep response of P91. The overall path to be followed consists of first calibrating this constitutive model against experimental data available from the literature (this milestone). In parallel, data acquired by indentation tests will be used to calibrate the model (this involves transforming the indentation data into equivalent uniaxial tests). An overall comparison of model parameters will allow assessing to what extent these rapid tests can be used to calibrate models predicting the overall mechanical response of the bulk. Given that COVID naturally hindered the gathering of new experimental data, the choice was made to ensure that LANL would have sufficient funds in year two to perform the bulk of the new calibration work. The following report details (i) how and which of the bulk experimental data was selected, (ii) constitutive model formulation, (iii) predictions of the constitutive model: effects of imposed stress, temperature and precipitate content, (iv) future work.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Transition Core Modeling for Extended Enrichment & Accident-Tolerant Fuels Using Polaris/PARCS

Commercial light water reactor (LWR) operators and fuel vendors are currently interested in increasing the low-enriched uranium (LEU) fuel enrichments from the current limit of 5.0 $^w/_o$ $^{235}U$ up to 10 $^ w/_o$ $^{235}U$ (referred to as "LEU+") in their current fleets; they are also interested in using accident-tolerant fuel (ATF) with both LEU and LEU+ fuel. This report aims to identify modeling challenges and accuracy concerns in transition core analysis using the SCALE Polaris lattice physics code and U.S. Nuclear Regulatory Commission core simulator PARCS. At the time this study was started, no publicly available LEU+ core designs existed for boiling water reactor (BWR) or pressurized water reactor (PWR) systems. Therefore, fuel lattices were shuffled within a multi-assembly model to mimic neutronically challenging lattice combinations seen in transition cores, such as a fresh LEU+ lattice next to depleted LEU lattices. In addition to multi-assembly models, whole-core BWR transition core calculations were performed for ATF and LEU+ fuel using an existing Hatch-1 Cycle 3 core model. A whole-core BWR model was chosen due to the more heterogeneous core designs compared to those for a PWR core. Since the original core is an old checkerboard core design and no core or fuel design optimization was performed for the modeled fuel types, these core calculations were intended only to provide: (1) Comparisons of core characteristics of interest, such as the pin power distributions and peaking factors, Doppler temperature coefficients (DTCs), and control blade worths (CBWs) under challenging core designs, (2) Identification of reactor physics challenges in modeling LEU+ and ATF cores, and (3) A stress test for the Polaris/PARCS two-step modeling approach, including characterization of the relative accuracy for predicting characteristics of interest such as pin power distributions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

On the constitutive stress-strain relationships and evaluation of the softening coefficient in work hardening mechanisms

The constitutive stress-strain relationships for structural alloys, such as additively manufactured Ti- 6Al-4V, are reconstructed by assessing the form and mechanism of work hardening relationships. The stress-strain relationships are best fit using both the Hollomon and Voce expressions wherein the Voce expression well-reproduces the later stage(s) of work hardening whereas the Hollomon relationship provides a better fit just beyond the proportional limit.

36 MATERIALS SCIENCE↗

Development of Novel Small-Molecule Activators of Pyruvate Kinase Muscle Isozyme 2, PKM2, to Reduce Photoreceptor Apoptosis

Treatment options are lacking to prevent photoreceptor death and subsequent vision loss. Previously, we demonstrated that reprogramming metabolism via the pharmacologic activation of PKM2 is a novel photoreceptor neuroprotective strategy. However, the features of the tool compound used in those studies, ML-265, preclude its advancement as an intraocular, clinical candidate. This study sought to develop the next generation of small-molecule PKM2 activators, aimed specifically for delivery into the eye. Compounds were developed that replaced the thienopyrrolopyridazinone core of ML-265 and modified the aniline and methyl sulfoxide functional groups. Compound 2 demonstrated that structural changes to the ML-265 scaffold are tolerated from a potency and efficacy standpoint, allow for a similar binding mode to the target, and circumvent apoptosis in models of outer retinal stress. To overcome the low solubility and problematic functional groups of ML-265, compound 2’s efficacious and versatile core structure for the incorporation of diverse functional groups was then utilized to develop novel PKM2 activators with improved solubility, lack of structural alerts, and retained potency. No other molecules are in the pharmaceutical pipeline for the metabolic reprogramming of photoreceptors. Thus, this study is the first to cultivate the next generation of novel, structurally diverse, small-molecule PKM2 activators for delivery into the eye.

59 BASIC BIOLOGICAL SCIENCES↗

Photoviscoelasticity

Stress analysis method of photoelasticity extended to viscoelastic materials by manufacturing mathematical model from transparent birefringent material properties

MATHEMATICAL MODEL↗

Review of deformation behavior of tungsten at temperature less than 0.2 absolute melting temperature

The deformation behavior of tungsten at temperatures 0.2 T sub m is reviewed, with primary emphasis on the temperature dependence of the yield stress and the ductile-brittle transition temperature. It appears that a model based on the high Peierls stress of tungsten best accounts for the observed mechanical behavior at low temperatures. Recent research is discussed which suggests an important role of electron concentration and bonding on the mechanical behavior of tungsten. It is concluded that future research on tungsten should include studies to define more clearly the correlation between electron concentration and mechanical behavior of tungsten alloys and other transition metal alloys.

Stephens, J. R.↗

Bolt installation tool for tightening large nuts and bolts

Large bolts and nuts are accurately tightened to structures without damaging torque stresses. There are two models of bolt installation tool. One is rigidly mounted and one is hand held. Each model includes torque-multiplier unit.

Mcdougal, A. R.↗

A review of the deformation behavior of tungsten at temperatures less than 0.2 of the melting point /K/

The deformation behavior of tungsten at temperatures below 0.2 times the absolute melting temperature is reviewed with primary emphasis on the temperature dependence of the yield stress and the ductile-brittle transition. It is concluded that a model based on the high Peierls stress of tungsten best accounts for the observed mechanical behavior at low temperatures. Recent research suggests an important role of electron concentration and bonding on the mechanical behavior of tungsten. Future research on tungsten should include studies to define more clearly the correlation between electron concentration and mechanical behavior of alloys of tungsten and other transition metal alloys.

Stephens, J. R.↗

Calculation of unsteady two-dimensional laminar and turbulent boundary layers with fluctuations in external velocity

A numerical method is proposed for calculating unsteady two-dimensional laminar and turbulent boundary layers with allowance for fluctuations in external flow velocity. An eddy-viscosity formulation is used to model the Reynolds shear stress term appropriate to turbulent flow, and the governing boundary layer equations are solved by a two-point finite-difference scheme. For illustration, the method is applied to the calculation of the phase angles between the shear stress at the wall and an oscillating external laminar boundary layer on a flat plate. The effectiveness of the method (for engineering purposes) is demonstrated by comparing calculations for turbulent flows with experimental data.

Cebeci, T.↗

A computer program for calculating laminar and turbulent boundary layers for two-dimensional time-dependent flows

A computer program is described which provides solutions of two dimensional equations appropriate to laminar and turbulent boundary layers for boundary conditions with an external flow which fluctuates in magnitude. The program is based on the numerical solution of the governing boundary layer equations by an efficient two point finite difference method. An eddy viscosity formulation was used to model the Reynolds shear stress term. The main features of the method are briefly described and instructions for the computer program with a listing are provided. Sample calculations to demonstrate its usage and capabilities for laminar and turbulent unsteady boundary layers with an external flow which fluctuated in magnitude are presented.

Cebeci, T.↗

Numerical solution of two-dimensional turbulent blunt body flows with an impinging shock

An implicit finite-difference method has been developed to compute two-dimensional, turbulent, blunt body flows with an impinging shock wave. The full time-averaged Navier-Stokes equations are solved with algebraic eddy viscosity and turbulent Prandtl number models employed for shear stress and heat flux. The irregular-shaped bow shock is treated as a discontinuity across which the Rankine-Hugoniot equations are applied. A Type III turbulent shock interference flow field has been computed and the numerical results compare favorably with existing experimental data. In addition, comparisons are made between the present implicit code and a previous explicit code.

Tannehill, J. C.↗

Structure development in silicon sheet by shaped crystallization

Models are presented for the development of a parallel twinned structure of the 110 plane type and the 112 line type in silicon ribbons. The models are believed to be mutually compatible and operable. The first model relates the requirements for super-cooling during crystallization. The existence of reentrant angles associated with the twin structure is proposed to provide a rough interface to reduce super-cooling. The spacing of the twins is proposed to be limited by the geometrical relationship between the thermal gradient in the liquid and the dimensions of the twinned crystallization front. The second model relates the thermal stress configuration to detail dislocation reactions which would be expected to develop twins. While a specific dislocation mechanism cannot yet be defined, a number of alternatives are presented. All of these various dislocation mechanisms would result in the observed crystalline configuration and the choice among them is not critical.

Leipold, M. H.↗

CF6 jet engine performance improvement: New fan

As part of the NASA sponsored engine component improvement program, and fan package was developed to reduce fuel consumption in current CF6 turbofan aircraft engine. The new fan package consist of an improved fan blade, reduced fan tip clearance due to a fan case stiffener, and a smooth fan casing tip shroud. CF6 engine performance and acoustic tests demonstrated the predicted 1.8% improvement in cruise sfc without an increase in engine noise. Power management thrust/fan speed characteristics were defined. Mechanical and structural integrity was demonstrated in model fan rotor photoelastic stress tests, full-size fan blade bench fatigue tests, and CF6 engine bird ingestion, crosswind, and cyclic endurance tests. The fan was certified in the CF6-500c2/E2 engines and is in commerical service on the Boeing 747-200, Douglas DC-10-30, and Atrbus industrie A300B aircraft.

Fasching, W. A.↗