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Characterization facility for magneto-optic media and systems

Objectives of this research are: (1) to measure the hysteresis loop, Kerr rotation angle, anisotropy energy profile, Hall voltage, and magnetoresistance of thin-film magneto-optic media using our loop-tracer; (2) measure the wavelength-dependence of the Kerr rotation angle, Theta(sub k), and ellipticity, epsilon(sub k), for thin-film media using our magneto-optic Kerr spectrometer (MOKS); (3) measure the dielectric tensor of thin-film and multilayer samples using our variable-angle magneto-optic ellipsometer (VAMOE); (4) measure the hysteresis loop, coercivity, remanent magnetization, saturation magnetization, and anisotropy energy constant for thin film magnetic media using vibrating sample magnetometry; (5) observe small magnetic domains and investigate their interaction with defects using magnetic force microscopy; (6) perform static read/write/erase experiments on thin-film magneto-optic media using our static test station; (7) integrate the existing models of magnetization, magneto-optic effects, coercivity, and anisotropy in an interactive and user-friendly environment, and analyze the characterization data obtained in the various experiments, using this modeling package; (8) measure focusing- and tracking-error signals on a static testbed, determine the 'feedthrough' for various focusing schemes, investigate the effects of polarization and birefringence, and compare the results with diffraction-based calculations; and (9) measure the birefringence of optical disk substrates using two variable angle ellipsometers.

Mansuripur, M.↗

Helical Photonic Metamaterials for Encrypted Chiral Holograms

Helical structures are among the most quintessential three-dimensional (3D) forms that exhibit mirror asymmetry, a hallmark of chirality. Various structural parameters of helices directly linked to chiroptical properties highlight their importance as essential optical metamaterials for polarization-resolved sensors, imaging, and spectroscopies. However, such function-defining properties remain incompletely understood due to fabrication challenges and the lack of a relationship between structure and optical properties. Here, helical structures are analyzed parametrically, and correlations are established that are applicable to the design of chiral helical optical metamaterials. By systematically varying independent parameters—such as from single-turn to five-turn helices and from small major radii to larger ones optimized to fit the unit cell—the underlying relationships with ellipticty are revealed. In addition to theoretical modeling, the findings are experimentally validated using 3D printing and terahertz spectroscopy. The results demonstrate that optimized helical structures are mechanically tunable and exhibit unprecedented optical properties, including broadband and high-magnitude ellipticity spectra. Being embedded in soft elastomers, helical arrays can serve as soft, stretchable optical-mechanical sensors and holograms containing encoded information, such as barcodes and quick response (QR) codes. Chiral QR codes are realized using pixelated single helices with different handedness, demonstrating their potential as advanced encryption/decryption systems for security applications and chiral metaholograms.

Encrypted QR codes↗

Lunar and Planetary Science XXXVI, Part 18

Topics discussed include: PoDS: A Powder Delivery System for Mars In-Situ Organic, Mineralogic and Isotopic Analysis Instruments Planetary Differentiation of Accreting Planetesimals with 26Al and 60Fe as the Heat Sources Ground-based Observation of Lunar Surface by Lunar VIS/NIR Spectral Imager Mt. Oikeyama Structure: First Impact Structure in Japan? Central Mounds in Martian Impact Craters: Assessment as Possible Perennial Permafrost Mounds (Pingos) A Further Analysis of Potential Photosynthetic Life on Mars New Insight into Valleys-Ocean Boundary on Mars Using 128 Pixels per Degree MOLA Data: Implication for Martian Ocean and Global Climate Change; Recursive Topography Based Surface Age Computations for Mars: New Insight into Surficial Processes That Influenced Craters Distribution as a Step Toward the Formal Proof of Martian Ocean Recession, Timing and Probability; Laser-induced Breakdown Spectroscopy: A New Method for Stand-Off Quantitative Analysis of Samples on Mars; Milk Spring Channels Provide Further Evidence of Oceanic, >1.7-km-Deep Late Devonian Alamo Crater, Southern Nevada; Exploration of Martian Polar Residual Caps from HEND/ODYSSEY Data; Outflow Channels Influencing Martian Climate: Global Circulation Model Simulations with Emplaced Water; Presence of Nonmethane Hydrocarbons on Pluto; Difference in Degree of Space Weathering on the Newborn Asteroid Karin; Circular Collapsed Features Related to the Chaotic Terrain Formation on Mars; A Search for Live (sup 244)Pu in Deep-Sea Sediments: Preliminary Results of Method Development; Some Peculiarities of Quartz, Biotite and Garnet Transformation in Conditions of Step-like Shock Compression of Crystal Slate; Error Analysis of Remotely-Acquired Mossbauer Spectra; Cloud Activity on Titan During the Cassini Mission; Solar Radiation Pressure and Transient Flows on Asteroid Surfaces; Landing Site Characteristics for Europa 1: Topography; and The Crop Circles of Europa.

Source record↗

On the Influence of Anthropogenic Forcings on Changes in the Stratospheric Mean Age

A common feature of stratospheric simulations of the past or future is an increase in tropical upwelling and a decrease in mean age. Possible causes or these changes include (1) increases in tropical sea surface temperatures (SSTs) driven by increases in well-mixed greenhouse gases (WMGHGs), (2) the direct radiative effect of increases in WMGHGs, and (3) changes in ozone. Here we examine a suite of simulations from the Goddard Earth Observing System chemistry-climate model (GEOS CCM) to isolate the relative role of these three factors. Our analysis indicates that all three factors cause changes in the mean age, but the relative impact of each factor depends on the time period analyzed. Over the past 30-40 years ozone depletion is the major factor causing the decrease in mean age, with negligible changes due to direct radiative impact of WMGHG's. However, ozone is predicted to recover back to 1970 levels during the next 50-60 years, and this causes an increase in the mean age, whereas the continued increase in SSTs from increased levels of WMGHGs and the direct radiative impact of WMGHGs will still cause a decrease in the mean age. The net impact of these factors will still result in a decreasing mean age although the rate will be smaller than that of the past. The decreases in mean age are primarily caused by increases in upwelling in the tropical lower stratosphere. The increased upwelling from both increased tropical SSTs and polar ozone loss appears to be related to changes in zonal winds and increases in wave activity propagating into the stratosphere. The different contributions of changes in SSTs, WMGHGs, and ozone to the circulation of the stratosphere may help explain the large spread in the rate of change of tropical upwelling seen in previous studies.

Oman, Luke↗

Hyperspectral Microwave Atmospheric Sounder (HyMAS) Architecture and Design Accommodations

The Hyperspectral Microwave Atmospheric Sounder (HyMAS) is being developed at Lincoln Laboratories and accommodated by the Goddard Space Flight Center for a flight opportunity on a NASA research aircraft. The term "hyperspectral microwave" is used to indicate an all-weather sounding that performs equivalent to hyperspectral infrared sounders in clear air with vertical resolution of approximately 1 km. Deploying the HyMAS equipped scanhead with the existing Conical Scanning Microwave Imaging Radiometer (CoSMIR) shortens the path to a flight demonstration. Hyperspectral microwave is achieved through the use of independent RF antennas that sample the volume of the Earth s atmosphere through various levels of frequencies, thereby producing a set of dense, spaced vertical weighting functions. The simulations proposed for HyMAS 118/183-GHz system should yield surface precipitation rate and water path retrievals for small hail, soft hail, or snow pellets, snow, rainwater, etc. with accuracies comparable to those of the Advanced Technology Microwave Sounder. Further improvements in retrieval methodology (for example, polarization exploitation) are expected. The CoSMIR instrument is a packaging concept re-used on HyMAS to ease the integration features of the scanhead. The HyMAS scanhead will include an ultra-compact Intermediate Frequency Processor (IFP) module that is mounted inside the door to improve thermal management. The IFP is fabricated with materials made of Low-Temperature Co-fired Ceramic (LTCC) technology integrated with detectors, amplifiers, A/D conversion and data aggregation. The IFP will put out 52 channels of 16 bit data comprised of 4-9 channel data streams for temperature profiles and 2-8 channel streams for water vapor. With the limited volume of the existing CoSMIR scanhead and new HyMAS front end components, the HyMAS team at Goddard began preliminary layout work inside the new drum. Importing and re-using models of the shell, the scan head computer, and the slip rings developed for CoSMIR was the starting point. The next step was to modify the antenna faceplate to accommodate the dimensions of the three dual polarization Gaussian Optics Antenna (GOA) assemblies. Two mechanical concepts for the core technology, the hyperspectral IFP, were captured in a design tradeoff. Connector models considered minimum bend radii for the IFP analog connectors. Hyperspectral imaging is accomplished by strategically using a short wavelength intermediate frequency of 18-29 GHz, and thus reducing the size of components in the connection of the front end to the IFP. The SMK (2.92mm) Series connector will lay near the hinge line to minimize its flexing. The digital output of the IFP will use a Serial Peripheral Interface (SPI) that must be accommodated by the scan head computer. To make that computer more reliable, maintainable, and forward compatible with the 52 HyMAS channels, a testbed of the scan head, calibration, and archive computers and the PIC24 microprocessor that resides on the IFP is in development. The computers will be programmed using a new framework application called Interoperable Remote Component (IRC). This software allows flexibility to program computers that communicate with each other and can adapt easily to the emerging HyMAS requirements for data format, algorithms, and graphical user interface (GUI). It is expected that the CoSMIR instrument will cut over to the IRC after it is adapted on an updated CoSMIR testbed.

Hilliard, Lawrence↗

HydroCube Mission Concept: P-Band Signals of Opportunity for Remote Sensing of Snow and Root Zone Soil Moisture

We have developed the HydroCube mission concept with a constellation of small satellites to remotely sense Snow Water Equivalent (SWE) and Root Zone Soil Moisture (RZSM). The HydroCube satellites would operate at sun-synchronous 3-day repeat polar orbits with a spatial resolution of about 1-3 Km. The mission goals would be to improve the estimation of terrestrial water storage and weather forecasts. Root-zone soil moisture and snow water storage in land are critical parameters of the water cycle. The HydroCube Signals of Opportunity (SoOp) concept utilizes passive receivers to detect the reflection of strong existing P-band radio signals from geostationary Mobile Use Objective System (MUOS) communication satellites. The SWE remote sensing measurement principle using the P-band SoOp is based on the propagation delay (or phase change) of radio signals through the snowpack. The time delay of the reflected signal due to the snowpack with respect to snow-free conditions is directly proportional to the snowpack SWE. To address the ionospheric delay at P-band frequencies, the signals from both MUOS bands (360-380 MHz and 250-270 MHz) would be used. We have conducted an analysis to trade off the spatial resolution for a space-based sensor and measurement accuracy. Through modeling analysis, we find that the dual-band MUOS signals would allow estimation of soil moisture and surface roughness together. From the two MUOS frequencies at 260 MHz and 370 MHz, we can retrieve the soil moisture from the reflectivity ratio scaled by wavenumbers using the two P-band frequencies for MUOS. A modeling analysis using layered stratified model has been completed to determine the sensitivity requirements of HydroCube measurements. For mission concept demonstration, a field campaign has been conducted at the Fraser Experimental Forest in Colorado since February 2016. The data acquired has provided support to the HydroCube concept.

Derksen, Chris↗

Modeling Nonperturbative Field-Driven Vibronic Dynamics: Selective State Preparation and Nonlinear Spectroscopy

The partially linearized density matrix formalism for nonadiabatic dynamics is adapted to incorporate a classical external electromagentic field into the system Hamiltonian. This advancement encompasses the possibility of describing field-driven dynamics and computing a variety of linear and nonlinear spectroscopic signals beyond the perturbative limit. Here, the capabilities of the developed approach are demonstrated on a simple two-state vibronic model coupled to a bath, for which we (a) perform an exhaustive search in the field parameter space for optimal state preparation and (b) compute time-resolved transient absorption spectroscopy to monitor the effect of different pulse shapes on measurable experimental signals. While no restrictions on the form of the field have to be assumed, we focus here on Gaussian shaped (linearly) chirped pulses.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Many-Exciton Quantum Dynamics in a Ruddlesden–Popper Tin Iodide

We present a study on the many-body exciton interactions in a Ruddlesden–Popper tin halide, namely, (PEA) 2 SnI 4 (PEA = phenylethylammonium), using coherent two-dimensional electronic spectroscopy. The optical dephasing times of the third-order polarization observed in these systems are determined by exciton many-body interactions and lattice fluctuations. We investigate the excitation-induced dephasing (EID) and observe a significant reduction of the dephasing time with increasing excitation density as compared to its lead counterpart (PEA) 2 PbI 4 , which we have previously reported in a separate publication [J. Chem. Phys. 2020, 153, 164706]. Surprisingly, we find that the EID interaction parameter is four orders of magnitude higher in (PEA) 2 SnI 4 than that in (PEA) 2 PbI 4 . This increase in the EID rate may be due to exciton localization arising from a more statically disordered lattice in the tin derivative. This is supported by the observation of multiple closely spaced exciton states and the broadening of the linewidth with increasing population time (spectral diffusion), which suggests a static disordered structure relative to the highly dynamic lead-halide. Additionally, we find that the exciton nonlinear coherent lineshape shows evidence of a biexcitonic state with low binding energy (<10 meV) not observed in the lead system. We model the lineshapes based on a stochastic scattering theory that accounts for the interaction with a nonstationary population of dark background excitations. Our study provides evidence of differences in the exciton quantum dynamics between tin- and lead-based Ruddlesden–Popper metal halides (RPMHs) and links them to the exciton–exciton interaction strength and the static disorder aspect of the crystalline structure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Oxygen magnetic polarization, nodes in spin density, and zigzag spin order in oxides

Recent studies on Ba 2 CoO 4 (BCO) and SrRuO 3 (SRO) have unveiled a variety of intriguing phenomena, such as magnetic polarization on oxygens, unexpected nodes in the spin density profile along bonds, and unusual zigzag spin patterns in triangular lattices. Here, using simple model calculations supplemented by density functional theory we explain the presence of nodes based on the antibonding character of the dominant singly occupied molecular orbitals along the transition metal (TM) to oxygen bonds. Our simple model also allows us to explain the net polarization on oxygen as originated from the hybridization between atoms and mobility of the electrons with spins opposite to those of the closest TM atoms. Overall, our results are not limited to BCO and SRO, but they are generic and qualitatively predict the net polarization expected on any ligands, according to the spin order of the closest TM atoms and the number of intermediate ligand atoms. Finally, we propose that a robust easy-axis anisotropy would suppress the competing 120° antiferromagnetic order to stabilize the zigzag pattern order as ground state in a triangular lattice. Our generic predictions should be applicable to any other compound with characteristics similar to those of BCO and SRO.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Stratospheric Heterogeneous Chemistry and Microphysics: Model Development, Validation and Applications

The objectives of this project are to: define the chemical and physical processes leading to stratospheric ozone change that involve polar stratospheric clouds (PSCS) and the reactions occurring on the surfaces of PSC particles; study the formation processes, and the physical and chemical properties of PSCS, that are relevant to atmospheric chemistry and to the interpretation of field measurements taken during polar stratosphere missions; develop quantitative models describing PSC microphysics and heterogeneous chemical processes; assimilate laboratory and field data into these models; and calculate the extent of chemical processing on PSCs and the impact of specific microphysical processes on polar composition and ozone depletion. During the course of the project, a new coupled microphysics/physical-chemistry/ photochemistry model for stratospheric sulfate aerosols and nitric acid and ice PSCs was developed and applied to analyze data collected during NASA's Arctic Airborne Stratospheric Expedition-II (AASE-II) and other missions. In this model, detailed treatments of multicomponent sulfate aerosol physical chemistry, sulfate aerosol microphysics, polar stratospheric cloud microphysics, PSC ice surface chemistry, as well as homogeneous gas-phase chemistry were included for the first time. In recent studies focusing on AASE measurements, the PSC model was used to analyze specific measurements from an aircraft deployment of an aerosol impactor, FSSP, and NO(y) detector. The calculated results are in excellent agreement with observations for particle volumes as well as NO(y) concentrations, thus confirming the importance of supercooled sulfate/nitrate droplets in PSC formation. The same model has been applied to perform a statistical study of PSC properties in the Northern Hemisphere using several hundred high-latitude air parcel trajectories obtained from Goddard. The rates of ozone depletion along trajectories with different meteorological histories are presently being systematically evaluated to identify the principal relationships between ozone loss and aerosol state. Under this project, we formulated a detailed quantitative model that predicts the multicomponent composition of sulfate aerosols under stratospheric conditions, including sulfuric, nitric, hydrochloric, hydrofluoric and hydrobromic acids. This work defined for the first time the behavior of liquid ternary-system type-1b PSCS. The model also allows the compositions and reactivities of sulfate aerosols to be calculated over the entire range of environmental conditions encountered in the stratosphere (and has been incorporated into a trajectory/microphysics model-see above). Important conclusions that derived from this work over the last few years include the following: the HNO3 content of liquid-state aerosols dominate PSCs below about 195 K; the freezing of nitric acid ice from sulfate aerosol solutions is likely to occur within a few degrees K of the water vapor frost point; the uptake and reactions of HCl in liquid aerosols is a critical component of PSC heterogeneous chemistry. In a related application of this work, the inefficiency of chlorine injection into the stratosphere during major volcanic eruptions was explained on the basis of nucleation of sulfuric acid aerosols in rising volcanic plumes leading to the formation of supercooled water droplets on these aerosols, which efficiently scavenges HCl via precipitation.

Turco, Richard P.↗

Resolution Enhancement of Spaceborne Radiometer Images

Our progress over the last year has been along several dimensions: 1. Exploration and understanding of Earth Observatory System (EOS) mission with available data from NASA. 2. Comprehensive review of state of the art techniques and uncovering of limitations to be investigated (e.g. computational, algorithmic ...). and 3. Preliminary development of resolution enhancement algorithms. With the advent of well-collaborated satellite microwave radiometers, it is now possible to obtain long time series of geophysical parameters that are important for studying the global hydrologic cycle and earth radiation budget. Over the world's ocean, these radiometers simultaneously measure profiles of air temperature and the three phases of atmospheric water (vapor, liquid, and ice). In addition, surface parameters such as the near surface wind speed, the sea surface temperature, and the sea ice type and concentration can be retrieved. The special sensor microwaves imager SSM/I has wide application in atmospheric remote sensing over the ocean and provide essential inputs to numerical weather-prediction models. SSM/I data has also been used for land and ice studies, including snow cover classification measurements of soil and plant moisture contents, atmospheric moisture over land, land surface temperature and mapping polar ice. The brightness temperature observed by SSM/I is function of the effective brightness temperature of the earth's surface and the emission scattering and attenuation of the atmosphere. Advanced Microwave Scanning Radiometer (AMSR) is a new instrument that will measure the earth radiation over the spectral range from 7 to 90 GHz. Over the world's ocean, it will be possible to retrieve the four important geographical parameters SST, wind speed, vertically integrated water vapor, vertically integrated cloud liquid water L.

Krim, Hamid↗

The NASA Micro Pulse Lidar Network (MPLNET): Introduction of the New Version 3 Release

The NASA Micro-Pulse Lidar Network (MPLNET) is a global federated network of polarized Micro-Pulse Lidar (MPL) systems running continuously. MPLNET began in 2000, and there have been over 70 sites deployed worldwide, with 24 sites currently active and a few more planned over the next year. Seven of the long-term sites have 10+ years of data, and many more have 5+ years. Most sites are co-located with AERONET providing joint data on column and vertically resolved aerosol and cloud information. This presentation will introduce our new Version 3 MPLNET data. All sites in the network now feature eye-safe polarized backscatter MPL instruments, providing information on attenuated backscatter and particle shape. In addition to change with our signal data, we have an enhanced cloud product suite, a new PBL height product, and inclusion of the new AERONET lunar aerosol optical depth into MPLNET aerosol retrievals. A new quality flag process will be used to better describe all data products. Finally, a new data portal will provide near-real-time (NRT) access to all data products, including new quality assured NRT L1.5 products. Custom products developed for model specific applications will also be provided.

Welton, Ellsworth J.↗

Ag-doped As–S–Se chalcogenide glasses: a correlative study of structural and dielectrical properties

This work is focused on investigating the effect of Ag doping on the dielectric and structural properties of the As–S–Se glass system and their suitability for potential applications in optoelectronics, such as electronic and switching components. A series of glasses from the system Agx(As40S30Se30)100-x (x = 5 at.% Ag) were prepared with melt-quenching technique. Morphological and compositional analysis was performed by scanning electron microscopy and energy-dispersive X-ray spectroscopy. Raman spectroscopy measurements have shown structural modifications of the glass network upon Ag doping, with creation of new Ag–(S,Se)–As structures, resulting in increased number of defect states. Variations in dielectric permittivity (e') and dielectric loss (e") were investigated in a wide frequency and temperature range, and explained by dominant dipolar and electronic polarization, as well as correlated with the observed structural changes. Improvement in dielectric properties is observed upon doping with Ag. Furthermore, the low dielectric tangent loss at high frequencies for all glassy samples points to a beneficial ability of the material to absorb energy of the external electric field. Good thermal stability of these glasses is confirmed by the calculated temperature coefficient of the dielectric permittivity. Density of localized states in all glasses was determined from AC conductivity and the dielectric tangent loss using a correlated barrier hopping model, and found to increase with Ag concentration. The overall results suggest that Ag doping enhances the electrical and optical quality of this type of glasses, making them suitable as nonlinear optical materials and their applications in devices.

36 MATERIALS SCIENCE↗

Adaptive Sampling for In Situ Cloud Probe (Final Report)

Clouds play a leading role in the Earth's global energy and solar radiation balance and hydrological cycle. Improving cloud models requires detailed information on the cloud microphysical properties, such as droplet size distribution and number density, liquid water content and cloud composition (droplets, ice particles), which can only be provided by aerial in situ measurements. However, for many atmospheric measurement instruments, the lack of flexibility in selecting the operational mode during operation can lead to uncertainties in sampling and measurement characteristics under continuously varying atmospheric conditions. This SBIR project is developing an advanced, compact optical imaging technology for in situ characterization of cloud hydrometeors. The development involves a deep modification of the existing Mesa Photonics’ Cloud Droplet Measurement System (CDMS) in order to implement real-time automatic adaptive sampling based on the acquired in situ data and environmental parameters. The new system, CDMS-2, implements two measurement modes: side-scatter imaging for smaller hydrometeors and direct bright-field-illumination imaging for larger hydrometeors in a significantly larger sample volume. The system measures the droplet size distribution (DSD) and number density with an added capability of discriminating between liquid water and ice hydrometeors (based on polarization-resolved side-scatter imaging). The instrument will implement automatic switching or alternating between the regular side-scatter imaging mode and sparse/large hydrometeor mode (based on the acquired data). Other adaptive sampling capabilities include variable sample volume and dynamic range (based on the measured DSD). The preferred deployment platforms are uncrewed aircraft systems (UAS) and tethered balloon/kite systems (TBS). The Phase I project achieved (or exceeded) the goals listed in the Work Plan. A CDMS-2 laboratory prototype implementing the polarization-resolved side-scatter imaging mode and direct bright-field-illumination imaging mode was designed and built. Additional capabilities included the variable illumination pulse energy and sample volume. The smallest detectable droplet diameter was improved to 3–4 μm (from the nominal 10 μm value specified for the original CDMS). Discrimination between water droplets and ice particles was experimentally demonstrated. The Phase I prototype was extensively tested and calibrated in the laboratory and also tested in the Pi Cloud Chamber at Michigan Technological University (MTU). The two intensive experimental campaigns at MTU provided unique opportunities of testing the CDMS-2 laboratory prototype under realistic warm and mixed-phase cloud conditions (stable for long periods of time), testing different sampling modes and intercomparing the CDMS-2 prototype to other co-located cloud characterization instruments. The Phase I project successfully demonstrated the feasibility of the proposed technology and identified the engineering challenges of designing a field deployable prototype instrument in Phase II. The Phase I study provides a solid basis for development, characterization and field-testing of the proposed advanced cloud probe with adaptive sampling in Phase II followed by commercialization of the technology in Phase III.

47 OTHER INSTRUMENTATION↗

Global MHD Magnetospheric Simulation of January 10, 1997 Encounter with Magnetic Cloud

We present a global MHD magnetospheric simulation of the encounter of the magnetic cloud with the terrestrial magnetosphere on January 10-11, 1997. The MHD simulation is driven by IMF and solar wind plasma measurements provided by Wind situated about 100 $R_E$ upstream from Earth. Field-aligned currents produced in the model are mapped down to the ionosphere and are directly compared to auroral images from the Polar UVI. Particular attention will be paid to the interval following the the initial shock wave arrival (around 0100 UT on the 1Oth) but preceding the passage of the magnetic cloud proper (commencing at about 0430 UT) for which there was continuous viewing of the entire auroral oval from apogee by Polar. This turbulent period is characterized by numerous dynamic pressure rises and dips and several northward and southward turnings of the IMF, all of which generate dynamic activity in the simulation that is reflected in the mapped field-aligned current patterns. As discussed by Brittnacher et al. in this session, the auroral morphology imaged by UVI during this period includes: shock wave-induced brightening of the oval followed by a pseudo-onset near midnight, several sun-aligned and curled arcs within the polar cap, an expanding polar cap cleared of arcs, and finally substorm onset at 0337 UT. These features will be directly compared to region 1 and 2 current systems as well as cusp currents in the simulation. Spacecraft magnetopause crossings are also predicted by the global simulation and will be compared to observed crossings, including numerous dayside crossings by Geotail on the 1Oth, and geosynchronous crossings early on January 11.

Elsen, R.↗

The Aquarius Salinity Retrieval Algorithm: Early Results

The Aquarius L-band radiometer/scatterometer system is designed to provide monthly salinity maps at 150 km spatial scale to a 0.2 psu accuracy. The sensor was launched on June 10, 2011, aboard the Argentine CONAE SAC-D spacecraft. The L-band radiometers and the scatterometer have been taking science data observations since August 25, 2011. The first part of this presentation gives an overview over the Aquarius salinity retrieval algorithm. The instrument calibration converts Aquarius radiometer counts into antenna temperatures (TA). The salinity retrieval algorithm converts those TA into brightness temperatures (TB) at a flat ocean surface. As a first step, contributions arising from the intrusion of solar, lunar and galactic radiation are subtracted. The antenna pattern correction (APC) removes the effects of cross-polarization contamination and spillover. The Aquarius radiometer measures the 3rd Stokes parameter in addition to vertical (v) and horizontal (h) polarizations, which allows for an easy removal of ionospheric Faraday rotation. The atmospheric absorption at L-band is almost entirely due to O2, which can be calculated based on auxiliary input fields from numerical weather prediction models and then successively removed from the TB. The final step in the TA to TB conversion is the correction for the roughness of the sea surface due to wind. This is based on the radar backscatter measurements by the scatterometer. The TB of the flat ocean surface can now be matched to a salinity value using a surface emission model that is based on a model for the dielectric constant of sea water and an auxiliary field for the sea surface temperature. In the current processing (as of writing this abstract) only v-pol TB are used for this last process and NCEP winds are used for the roughness correction. Before the salinity algorithm can be operationally implemented and its accuracy assessed by comparing versus in situ measurements, an extensive calibration and validation (cal/val) activity needs to be completed. This is necessary in order to tune the inputs to the algorithm and remove biases that arise due to the instrument calibration, foremost the values of the noise diode injection temperatures and the losses that occur in the feedhorns. This is the subject of the second part of our presentation. The basic tool is to analyze the observed difference between the Aquarius measured TA and an expected TA that is computed from a reference salinity field. It is also necessary to derive a relation between the scatterometer backscatter measurements and the radiometer emissivity that is induced by surface winds. In order to do this we collocate Aquarius radiometer and scatterometer measurements with wind speed retrievals from the WindSat and SSMIS F17 microwave radiometers. Both of these satellites fly in orbits that have the same equatorial ascending crossing time (6 pm) as the Aquarius/SAC-D observatory. Rain retrievals from WindSat and SSMIS F 17 can be used to remove Aquarius observations that are rain contaminated. A byproduct of this analysis is a prediction for the wind-induced sea surface emissivity at L-band.

Meissner, Thomas↗

Helical versus collinear antiferromagnetic order tuned by magnetic anisotropy in polar and chiral (Ni,Mn) 3 TeO 6

In this work, polar and chiral Ni 3 TeO 6 was found to exhibit a colossal magnetoelectric (ME) effect associated with collinear antiferromagnetic order. We have investigated the evolution of its magnetic state with the substitution of the Ni 2+ spins by isotropic Mn 2+ spins, namely (Ni, Mn) 3 TeO 6 (NMTO). The ground state of NMTO maintains an Ising nature, but a new phase with XY-type magnetic anisotropy is discovered at an intermediate temperature range. Neutron powder diffraction experiments reveal that (1) Mn ions tend to occupy a specific transition-metal site, consistent with the first-principle calculation, and (2) the intermediate phase is an incommensurate (IC) helical magnetic state propagating along the $\textit{c}$ axis with $\vec q_{\text{IC}}$ = (0, 0, 1.5 ± δ). We also found that the balance between these two magnetic states can be readily manipulated with magnetic fields, which results in significant ME effects. This selective site occupancy of NMTO allows for a unique competition between collinear and helical magnetic structures with minimal chemical disorder. Thus, NMTO serves as a model system to study site-specific chemical control of noncollinear magnetism and ME coupling.

36 MATERIALS SCIENCE↗

Radar Interferometry Studies of the Mass Balance of Polar Ice Sheets

The objectives of this work are to determine the current state of mass balance of the Greenland and Antarctic Ice Sheets. Our approach combines different techniques, which include satellite synthetic-aperture radar interferometry (InSAR), radar and laser altimetry, radar ice sounding, and finite-element modeling. In Greenland, we found that 3.5 times more ice flows out of the northern part of the Greenland Ice Sheet than previously accounted for. The discrepancy between current and past estimates is explained by extensive basal melting of the glacier floating sections in the proximity of the grounding line where the glacier detaches from its bed and becomes afloat in the ocean. The inferred basal melt rates are very large, which means that the glaciers are very sensitive to changes in ocean conditions. Currently, it appears that the northern Greenland glaciers discharge more ice than is being accumulated in the deep interior, and hence are thinning. Studies of temporal changes in grounding line position using InSAR confirm the state of retreat of northern glaciers and suggest that thinning is concentrated at the lower elevations. Ongoing work along the coast of East Greenland reveals an even larger mass deficit for eastern Greenland glaciers, with thinning affecting the deep interior of the ice sheet. In Antarctica, we found that glaciers flowing into a large ice shelf system, such as the Ronne Ice Shelf in the Weddell Sea, exhibit an ice discharge in remarkable agreement with mass accumulation in the interior, and the glacier grounding line positions do not migrate with time. Glaciers flowing rapidly into the Amudsen Sea, unrestrained by a major ice shelf, are in contrast discharging more ice than required to maintain a state of mass balance and are thinning quite rapidly near the coast. The grounding line of Pine Island glacier (see diagram) retreated 5 km in 4 years, which corresponds to a glacier thinning rate of 3.5 m/yr. Mass imbalance is even more negative on Thwaites Glacier. This sector of West Antarctica probably initiated its collapse decades or centuries ago, once the embaying ice shelves in front of them started to melt because of enhanced basal melting from warmer ocean waters. Additional information is contained in the original.

Rignot, Eric↗