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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,459 records · Page 81

Friction Stir Welding of Line-Pipe Steels

Friction stir welding (FSW) offers both economic and technical advantages over conventional fusion welding practices for welding line-pipe. For offshore line-pipe construction, the economic savings has been shown to be considerable, approaching a calculated 25%. Offshore pipe is relatively small diameter but heavy wall compared to onshore pipe. One concern is the ability to achieve consistent full weld penetration in an on-site offshore FSW operation, e.g., on a lay-barge. In addition, depending on the size and morphology of the unwelded zone, lack of penetration at the weld root can be difficult if not impossible to detect by conventional NDE methods. Thus, an approach to assure consistent full penetration via process control is required for offshore line-pipe construction using FSW. For offshore construction, an internal structural mandrel can be used offering the opportunity to use a sacrificial anvil FSW approach. With this approach, a small volume of sacrificial material can be inserted into the structural anvil. The FSW tool penetrates into the sacrificial anvil, beyond the inner diameter of the pipe wall, thus assuring full penetration. The sacrificial material is subsequently removed from the pipe inner wall. In the work presented herein, FSW studies were completed on both 6 mm and 12 mm wall thickness line-pipe. Lastly, post-FSW evaluations including radiography, root-bend tests, and metallography demonstrated the merits of the sacrificial anvil approach to achieve consistent full penetration.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

High Performance DNA Probes for Perinatal Detection of Numerical Chromosome Aberrations

Human reproduction is a tightly controlled process of stepwise evolution with multiple, mostly yet unknown milestones and checkpoints. Healthy halpoid gametes have to be produced by the parents, which will fuse to form the diploid zygote that implants in the female uterus and grows to become first an embryo, then a fetus and finally matures into a newborn. There are several known risk factors that interfere with normal production of gametes, spermatocytes or oocytes, and often cause embryonic mortality and fetal demise at an early stage. Yet some embryos with chomosomal abnormalities can develop beyond the critical first trimester of pregnancy and, while those with supernumary chromosomes in their hyperdiploid cells will be spontaneously aborted, a small fraction of fetuses with an extra chromosome continues to grow to term and will be delivered as a liveborn baby. While minor clinical symptoms displayed by children with trisomies are manageable for many parents, the burden of caring for a child with numerical chromosome abnormalities can be overwhelming to partners or individual families. It also poses a significant financial burden to the society and poses ethical dilemma. In this communication, we will review the progress that has been made in the development of molecular techniques to test individual fetal cells for chromosomal imbalances. We will focus our discussion on the direct visualization of chromosome-specific DNA sequences in live or fixed specimens using fluorescence in situ hybridization (FISH) and, more specifically, talk about the groundbreaking progress that in recent years has been achieved towards an improved diagnosis with novel, chromosome-specific DNA probes.

Fluorescence in situ hybridization (FISH)↗

Glass Property Models, Constraints, and Formulation Approaches for Vitrification of High-Level Nuclear Wastes at the US Hanford Site

The legacy nuclear wastes stored in underground tanks at the US Department of Energy’s Hanford site is planned to be separated into high-level waste and low-activity waste fractions and vitrified separately. Formulating optimized glass compositions that maximize the waste loading in glass is critical for successful and economical treatment and immobilization of nuclear wastes. Glass property-composition models have been developed and applied to formulate glass compositions for various objectives for the past several decades. The property models with associated uncertainties and combined with composition and property constraints have been used to develop preliminary glass formulation algorithms designed for vitrification process control and waste form qualification at the planned waste vitrification plant. This paper provides an overview of current status of glass property-composition models, constraints applicable to Hanford waste vitrification, and glass formulation approaches that have been developed for vitrification of hazardous and highly radioactive wastes stored at the Hanford site.

composition constraint↗

Distinguishing dynamics of dissolved organic matter components in a forested stream using kinetic enrichments

Traditional methods for investigating stream solute biogeochemistry measure longitudinal rates of uptake by increasing either the concentration or isotopic composition of solutes. These methods cannot be applied to dissolved organic matter (DOM) because we cannot replicate the heterogeneous native DOM pool. We explored an alternative approach, attempting to displace or enhance benthic uptake of native DOM by supplying an exogenous source of labile carbon or by enriching the stream with inorganic nitrogen. This approach allows us to measure uptake rates of enriched solutes, as well as changes in the concentration and composition of native DOM resulting from the experimental manipulations. We examined DOM composition using fluorescence characterization. We were able to elicit changes in the chemical composition of native DOM by differentially altering the dynamics of autotrophic production and heterotrophic uptake within the second-order reach of Walker Branch, a well-studied stream in eastern Tennessee. Supplying heterotrophs with labile carbon resulted in an increase in fluorescence associated with terrestrially derived DOM. Stimulating algae by adding inorganic nitrogen increased autochthonous production and indirectly displaced heterotrophic demand for terrestrial DOM due to increased in-stream production of bioavailable DOM. While we were able to alter the composition of the native DOM pool, we observed little change in DOM concentrations. The ability to differentiate between DOM subcomponents provides insight into processes controlling DOM production and consumption that cannot be gained by treating DOM as a single bulk pool.

59 BASIC BIOLOGICAL SCIENCES↗

Exploring dimethyl sulfide (DMS) oxidation and implications for global aerosol radiative forcing

Abstract. Aerosol indirect radiative forcing (IRF), which characterizes how aerosols alter cloud formation and properties, is very sensitive to the preindustrial (PI) aerosol burden. Dimethyl sulfide (DMS), emitted from the ocean, is a dominant natural precursor of non-sea-salt sulfate in the PI and pristine present-day (PD) atmospheres. Here we revisit the atmospheric oxidation chemistry of DMS, particularly under pristine conditions, and its impact on aerosol IRF. Based on previous laboratory studies, we expand the simplified DMS oxidation scheme used in the Community Atmospheric Model version 6 with chemistry (CAM6-chem) to capture the OH-addition pathway and the H-abstraction pathway and the associated isomerization branch. These additional oxidation channels of DMS produce several stable intermediate compounds, e.g., methanesulfonic acid (MSA) and hydroperoxymethyl thioformate (HPMTF), delay the formation of sulfate, and, hence, alter the spatial distribution of sulfate aerosol and radiative impacts. The expanded scheme improves the agreement between modeled and observed concentrations of DMS, MSA, HPMTF, and sulfate over most marine regions, based on the NASA Atmospheric Tomography (ATom), the Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA), and the Variability of the American Monsoon Systems (VAMOS) Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx) measurements. We find that the global HPMTF burden and the burden of sulfate produced from DMS oxidation are relatively insensitive to the assumed isomerization rate, but the burden of HPMTF is very sensitive to a potential additional cloud loss. We find that global sulfate burden under PI and PD emissions increase to 412 Gg S (+29 %) and 582 Gg S (+8.8 %), respectively, compared to the standard simplified DMS oxidation scheme. The resulting annual mean global PD direct radiative effect of DMS-derived sulfate alone is −0.11 W m−2. The enhanced PI sulfate produced via the gas-phase chemistry updates alone dampens the aerosol IRF as anticipated (−2.2 W m−2 in standard versus −1.7 W m−2, with updated gas-phase chemistry). However, high clouds in the tropics and low clouds in the Southern Ocean appear particularly sensitive to the additional aqueous-phase pathways, counteracting this change (−2.3 W m−2). This study confirms the sensitivity of aerosol IRF to the PI aerosol loading and the need to better understand the processes controlling aerosol formation in the PI atmosphere and the cloud response to these changes.

54 ENVIRONMENTAL SCIENCES↗

Boundary layer moisture variability at the Atmospheric Radiation Measurement (ARM) Eastern North Atlantic observatory during marine conditions

Abstract. Boundary layer moisture variability at the Eastern North Atlantic (ENA) site during marine conditions is examined at monthly and daily timescales using 5 years of ground-based observations and output from the European Center for Medium range Weather Forecast (ECMWF) reanalysis model. The annual cycle of the mixed-layer total water budgets is presented to estimate the relative contribution of large-scale advection, local moisture tendency, entrainment, and precipitation to balance the moistening due to surface latent heat flux on monthly timescales. When marine conditions prevail, advection of colder and dry air from the north acts as an important moisture sink (∼ 50 % of the overall budget) during fall and winter driving the seasonality of the budget. Entrainment and precipitation contribute to the drying of the boundary layer (∼ 25 % and ∼ 15 % respectively), and the local change in moisture contributes to a small residual part. On a daily temporal scale, moist and dry mesoscale columns of vapor (∼ 10 km) are analyzed during 10 selected days of precipitating stratocumulus clouds. Adjacent moist and dry columns present distinct mesoscale features that are strongly correlated with clouds and precipitation. Dry columns adjacent to moist columns have more frequent and stronger downdrafts immediately below the cloud base. Moist columns have more frequent updrafts, stronger cloud-top cooling, and higher liquid water path and precipitation compared to the dry columns. This study highlights the complex interaction between large-scale and local processes controlling the boundary layer moisture and the importance of spatial distribution of vapor to support convection and precipitation.

54 ENVIRONMENTAL SCIENCES↗

The distribution of soil phosphorus for global biogeochemical modeling

We discuss that phosphorus (P) is a major element required for biological activity in terrestrial ecosystems. Although the total P content in most soils can be large, only a small fraction is available or in an organic form for biological utilization because it is bound either in incompletely weathered mineral particles, adsorbed on mineral surfaces, or, over the time of soil formation, made unavailable by secondary mineral formation (occluded). In order to adequately represent phosphorus availability in global biogeochemistry–climate models, a representation of the amount and form of P in soils globally is required. We develop an approach that builds on existing knowledge of soil P processes and databases of parent material and soil P measurements to provide spatially explicit estimates of different forms of naturally occurring soil P on the global scale. We assembled data on the various forms of phosphorus in soils globally, chronosequence information, and several global spatial databases to develop a map of total soil P and the distribution among mineral bound, labile, organic, occluded, and secondary P forms in soils globally. The amount of P, to 50cm soil depth, in soil labile, organic, occluded, and secondary pools is 3.6 ± 3, 8.6 ± 6, 12.2 ± 8, and 3.2 ± 2 Pg P (Petagrams of P, 1 Pg = 1 × 10 15 g) respectively. The amount in soil mineral particles to the same depth is estimated at 13.0 ± 8 Pg P for a global soil total of 40.6 ± 18 Pg P. The large uncertainty in our estimates reflects our limited understanding of the processes controlling soil P transformations during pedogenesis and a deficiency in the number of soil P measurements. In spite of the large uncertainty, the estimated global spatial variation and distribution of different soil P forms presented in this study will be useful for global biogeochemistry models that include P as a limiting element in biological production by providing initial estimates of the available soil P for plant uptake and microbial utilization.

58 GEOSCIENCES↗

Observational data from uncrewed systems over Southern Great Plains

Uncrewed Systems (UxS), including uncrewed aerial systems (UAS) and tethered balloon/kite systems (TBS), are significantly expanding observational capabilities in atmospheric science. Rapid adaptation of these platforms and the advancement of miniaturized instruments have resulted in an expanding number of data sets captured under various environmental conditions by the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) user facility. In 2021, observational data collected using ARM UxS platforms, including seven TigerShark UAS flights and 133 tethered balloon system (TBS) flights, were archived by the ARM Data Center and made publicly available to the user community https://adc.arm.gov/discovery/#/results/s::sgp*U3 and https://adc.arm.gov/discovery/#/results/s::sgp*tbs. These data streams provide new perspectives on spatial variability of atmospheric and surface parameters, helping to address critical science questions in Earth system science research. This manuscript describes the DOE UAS/TBS datasets, including information on the acquisition, collection, and quality control processes, and highlights the potential scientific contributions using UAS and TBS platforms.

54 ENVIRONMENTAL SCIENCES↗

High nitrate variability on an Alaskan permafrost hillslope dominated by alder shrubs

Abstract. In Arctic ecosystems, increasing temperatures are driving the expansion of nitrogen (N) fixing shrubs across tundra landscapes. The implications of this expansion to the biogeochemistry of Arctic ecosystems are of critical importance and more work is needed to better understand the form, availability, and transportation potential of N from these shrubs across a variety of Arctic landscapes. To gain insights into the processes controlling N within a permafrost hillslope system, the spatiotemporal variability of nitrate (NO3-) and its environmental controls were investigated at an alder (Alnus viridis spp. fruticosa) dominated permafrost tundra landscape in the Seward Peninsula, Alaska, USA. Soil pore water was collected from locations within alder shrubland growing along a well-drained hillslope and was compared to soil pore water collected from locations outside (upslope, downslope, and between) the alder shrubland. Soil pore water collected within alder shrubland had an average NO3-N (nitrogen from nitrate) concentration of 4.27±8.02 mg L−1 and differed significantly from locations outside alder shrubland (0.23±0.83 mg L−1; p<0.05). Temporal variation in NO3-N within and downslope of alder shrubland co-occurred with precipitation events where NO3- that accumulated in the soil was likely flushed downslope during rainfall. These findings have important implications for nutrient availability and mobility in N-limited permafrost systems that are experiencing shrub expansion in response to a warming Arctic.

54 ENVIRONMENTAL SCIENCES↗

aosflow3 (a1)

The aerosol observing system (AOS) is the primary platform for in situ aerosol measurements at Earth’s surface. Each AOS has a different complement of instruments, which are selected to ensure the best measurements at each deployment site. The AOS measures aerosol optical properties to better understand how particles interact with solar radiation and influence the Earth's radiation balance. These measurements are useful for calculating parameters used in radiative forcing calculations, such as the aerosol single scattering albedo, asymmetry parameter, mass scattering efficiency, and hygroscopic growth. Measurements made with the AOS form a long-term record at the ARM fixed sites. Shorter measurement records are available from mobile deployments in a wide variety of geographical regions. These measurements are valuable for: identifying long-term changes in aerosol properties identifying atmospheric processes controlling aerosol life cycle and their influence on clouds providing experimental data for developing and testing atmospheric climate models.

54 ENVIRONMENTAL SCIENCES↗

aoshumidgr (01)

The aerosol observing system (AOS) is the primary platform for in situ aerosol measurements at Earth’s surface. Each AOS has a different complement of instruments, which are selected to ensure the best measurements at each deployment site. The AOS measures aerosol optical properties to better understand how particles interact with solar radiation and influence the Earth's radiation balance. These measurements are useful for calculating parameters used in radiative forcing calculations, such as the aerosol single scattering albedo, asymmetry parameter, mass scattering efficiency, and hygroscopic growth. Measurements made with the AOS form a long-term record at the ARM fixed sites. Shorter measurement records are available from mobile deployments in a wide variety of geographical regions. These measurements are valuable for: identifying long-term changes in aerosol properties identifying atmospheric processes controlling aerosol life cycle and their influence on clouds providing experimental data for developing and testing atmospheric climate models.

54 ENVIRONMENTAL SCIENCES↗

aosimpactor (a1)

The aerosol observing system (AOS) is the primary platform for in situ aerosol measurements at Earth’s surface. Each AOS has a different complement of instruments, which are selected to ensure the best measurements at each deployment site. The AOS measures aerosol optical properties to better understand how particles interact with solar radiation and influence the Earth's radiation balance. These measurements are useful for calculating parameters used in radiative forcing calculations, such as the aerosol single scattering albedo, asymmetry parameter, mass scattering efficiency, and hygroscopic growth. Measurements made with the AOS form a long-term record at the ARM fixed sites. Shorter measurement records are available from mobile deployments in a wide variety of geographical regions. These measurements are valuable for: identifying long-term changes in aerosol properties identifying atmospheric processes controlling aerosol life cycle and their influence on clouds providing experimental data for developing and testing atmospheric climate models.

54 ENVIRONMENTAL SCIENCES↗

Nickel solution prepared for precision electroforming

Lightweight, precision optical reflectors are made by electroforming nickel onto masters. Steps for the plating bath preparation, process control testing, and bath composition adjustments are prescribed to avoid internal stresses and maintain dimensional accuracy of the electrodeposited metal.

Source record↗