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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,459 records · Page 81
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Microscopic Characterization of Pb 10−x Cu x (PO 4 ) 6 O by 31 P and 63/65 Cu NMR Measurements

The report of the first room-temperature, ambient-pressure superconductivity in copper-doped lead apatite Pb 10−x Cu x (PO 4 ) 6 O has attracted lots of attention. However, subsequent studies revealed the presence of numerous impurity phases in the polycrystalline sample, and the sharp superconducting-like transition is not due to a superconducting transition but most likely due to a reduction in resistivity caused by the first-order structural phase transition of Cu 2 S at around 385 K from the β phase at high temperature to the γ phase at low temperature. Before now, only bulk measurements have been performed on a Pb 10−x Cu x (PO 4 ) 6 O powder sample, which could be affected by the impurity phases, masking the intrinsic properties of Pb 10−x Cu x (PO 4 ) 6 O. In this study, 31 P and 63/65 Cu nuclear magnetic resonance (NMR) measurements have been performed on a Pb 10−x Cu x (PO 4 ) 6 O powder sample to investigate its physical properties from a microscopic point of view. Our NMR data evidence the non-magnetic insulating nature of Pb 10−x Cu x (PO 4 ) 6 O without any trace of electron correlation effects. Furthermore, the 63/65 Cu NMR results suggest that no copper or very little copper is substituted for Pb in Pb 10 (PO 4 ) 6 O prepared by sintering Pb 2 SO 5 and Cu 3 P.

lead apatite↗
DOE OSTI2022

Overview of recent progress in 3D field physics in KSTAR

Various 3D field physics challenges of magnetically confined plasmas arise when the driving source comes from either externally applied non-axisymmetric 3D magnetic perturbations or plasma instabilities inside the plasma. Recently, several key outstanding topics of 3D field physics have been extensively studied in the Korean Superconducting Tokamak Advanced Research (KSTAR), such as edge-localized-mode (ELM) control by resonant magnetic perturbation (RMP), error field (EF) control, 3D field effects on rotation and transport, and RMP-induced alteration of divertor heat flux and detachment. KSTAR has a few physically unique features (i.e., high rotation and long-pulse plasmas with a low intrinsic EF) and machine/diagnostic capabilities (i.e., 3-row in-vessel control coil and state-of-the-art 2D/3D imaging diagnostics), which have been taken advantage of until now to address critical 3D field physics issues relevant to ITER and K-DEMO. Among many remarkable achievements are the robust access to and control of n = 1 RMP ELM suppression, along with a development of its physics basis tools, parameter expansion, optimization, and long-pulse control techniques. Nonetheless, a series of unresolved 3D physics themes, as well as limited coverage of 3D field operating regimes, have also been identified as future works for the 3D field research in KSTAR. In this paper, we provide an overview about the recent progress of KSTAR 3D field physics and present future plans of KSTAR 3D research toward a future fusion reactor.

3D field physics↗
DOE OSTI2020

Results from the Alfvén Eigenmode Active Diagnostic during the 2019-2020 JET deuterium campaign

This paper presents results of extensive analysis of mode excitation observed during the operation of the Alfvén Eigenmode Active Diagnostic (AEAD) in the JET tokamak during the 2019-2020 deuterium campaign. Here, six of eight toroidally spaced antennas, each with independent power and phasing, were successful in actively exciting stable MHD modes in 479 plasmas. In total, magnetic resonances were detected with up to fourteen fast magnetic probes. In this work, we present the calculations of resonant frequencies $f_0$, damping rates γ < 0, and toroidal mode numbers $\textit{n}$, spanning the parameter ranges $f_0$ ≈ 30–250 kHz, –γ ≈ 0–13 kHz, and $\vert n \vert \leq {30}$. In general, good agreement is seen between the resonant and the calculated toroidal Alfvén Eigenmode frequencies, and between the toroidal mode numbers applied by the AEAD and estimated of the excited resonances. We note several trends in the database: the probability of resonance detection decreases with plasma current and external heating power; the normalized damping rate increases with edge safety factor but decreases with external heating. These results provide key information to prepare future experimental campaigns and to better understand the physics of excitation and damping of Alfvén Eigenmodes in the presence of alpha particles during the upcoming DT campaign, thereby extrapolating with confidence to future tokamaks.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Extending the operational boundaries of RMP-ELM suppression with optimized 3D field control

The use of 3D magnetic fields is one of the promising approaches to control edge localized modes (ELMs), and ITER has plans to utilize a flexible 3D coil set for ELM suppression using 3D fields. This study focuses on optimizing the 3D field spectrum to expand the operational window for n = 1 resonant magnetic perturbation (RMP) ELM suppression in KSTAR. The optimized n = 1 RMP effectively suppresses ELMs throughout the entire H-mode discharge, including the first ELM crash, while avoiding the onset of disruptive locked modes in low-density L-mode plasmas. The predicted suppression window aligns well with experimental data, highlighting the challenges and solutions of using n = 1 RMP at low densities. Moreover, the optimization successfully achieved n = 1 RMP ELM suppression for the first time in ITER-relevant q 95 and shaping conditions, including cases with q95 as low as 3.6, as well as other q 95 and shape configurations. This highlights the importance and utility of 3D coil optimization while emphasizing the potential of long-wavelength low-n RMP, which will be valuable for ex-vessel coils designed to avoid complications of nuclear degradation.

3D magnetic field control↗
DOE OSTI2022

Cryogenic probe for low-noise, high-frequency electronic measurements

The design and performance of a low-noise, modular cryogenic probe, which is applicable to a wide range of measurements over a broad range of working frequencies, temperatures, and magnetic fields, is presented. The design of the probe facilitates the exchange of sample holders and sample-stage amplifiers, which, combined with its characteristic low transmission and reflection loss, make this design suitable for high precision or low sensitivity measurements. The specific example of measuring the shot noise of magnetic tunnel junctions is discussed. We highlight various design characteristics chosen specifically to expand the applicability of the probe to measurement techniques such as nuclear magnetic resonance.

47 OTHER INSTRUMENTATION↗
DOE OSTI2015

Negative bias-and-temperature stress-assisted activation of oxygen-vacancy hole traps in 4H-silicon carbide metal-oxide-semiconductor field-effect transistors

We use hybrid-functional density functional theory-based Charge Transition Levels (CTLs) to study the electrical activity of near-interfacial oxygen vacancies located in the oxide side of 4H-Silicon Carbide (4H-SiC) power Metal-Oxide-Semiconductor Field-Effect Transistors (MOSFETs). Based on the “amorphousness” of their local atomic environment, oxygen vacancies are shown to introduce their CTLs either within (permanently electrically active) or outside of (electrically inactive) the 4H-SiC bandgap. The “permanently electrically active” centers are likely to cause threshold voltage (V{sub th}) instability at room temperature. On the other hand, we show that the “electrically inactive” defects could be transformed into various “electrically active” configurations under simultaneous application of negative bias and high temperature stresses. Based on this observation, we present a model for plausible oxygen vacancy defects that could be responsible for the recently observed excessive worsening of V{sub th} instability in 4H-SiC power MOSFETs under high temperature-and-gate bias stress. This model could also explain the recent electrically detected magnetic resonance observations in 4H-SiC MOSFETs.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Electronic Structure and Quadrupole Interactions in Promising Cathode Materials Na{sub x}M{sub y}(MoO{sub 4}){sub 3}, M = Mn, Fe, Co, and Ni

The electronic structure and the magnetic properties of molybdates Na{sub x}M{sub y}(MoO{sub 4}){sub 3} (M = Mn, Fe, Co, and Ni) which are promising materials for sodium batteries have been studied in the framework of the density functional theory with the GGA and GGA+U approximations for the first time. The calculations show that all the compounds are insulators. An important role of the correlation effects, provided by the on-site Coulomb interactions, was established in the formation of the band gap in these compounds. The quadrupole constants of {sup 23}Na nuclei are calculated in the nonmagnetic and ferromagnetic states within the GGA and GGA+U approaches. It is shown that the quadrupole frequencies for nonequivalent crystallographic positions of sodium are in different frequency ranges, which allows to study the diffusion of sodium in these compounds by the Nuclear Magnetic Resonance method.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Magnetometry in a diamond anvil cell using nitrogen vacancy centers in a nanodiamond ensemble

The emerging field of optical magnetometry utilizing negative-charged nitrogen vacancy (NV – ) centers provides a highly sensitive lab bench technique for spatially resolved physical property measurements. Their implementation in high pressure diamond anvil cell (DAC) environments will become common as other techniques are often limited due to the spatial constraints of the sample chamber. Apparatus and techniques are described here permitting for more general use of magnetic field measurements inside a DAC using continuous wave optical detected magnetic resonance in NV – centers in a layer of nanodiamonds. A microstrip antenna delivers a uniform microwave field to the DAC and is compatible with simple metal gaskets, and the sensor layer of deposited nanodiamonds allows for simple determination of the magnetic field magnitude for B in the 1–100 G range. The ferromagnetic transition in iron at 18 GPa is measured with the apparatus, along with its hysteretic response.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Results from the Alfven Eigenmode Active Diagnostic during the 2019-2020 JET deuterium campaign

This paper presents results of extensive analysis of mode excitation observed during the operation of the Alfven Eigenmode Active Diagnostic (AEAD) in the JET tokamak during the 2019-2020 deuterium campaign. Six of eight toroidally spaced antennas, each with independent power and phasing, were successful in actively exciting stable MHD modes in 479 plasmas. In total, 4768 magnetic resonances were detected with up to fourteen fast magnetic probes. In this work, we present the calculations of resonant frequencies f0, damping rates \gamma < 0, and toroidal mode numbers n, spanning the parameter range f0 = 30 - 250 kHz, -\gamma = 0 - 13 kHz, and |n| < 30. In general, good agreement is seen between the resonant and the calculated toroidal Alfven Eigenmode frequencies, and between the toroidal mode numbers applied by the AEAD and estimated of the excited resonances. We note several trends in the database: the probability of resonance detection decreases with plasma current and external heating power; the normalized damping rate increases with edge safety factor but decreases with external heating. These results provide key information to prepare future experimental campaigns and to better understand the physics of excitation and damping of Alfven Eigenmodes in the presence of alpha particles during the upcoming DT campaign, thereby extrapolating with confidence to future tokamaks.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1994

Metabolic myopathies

Metabolic myopathies are disorders of muscle energy production that result in skeletal muscle dysfunction. Cardiac and systemic metabolic dysfunction may coexist. Symptoms are often intermittent and provoked by exercise or changes in supply of lipid and carbohydrate fuels. Specific disorders of lipid and carbohydrate metabolism in muscle are reviewed. Evaluation often requires provocative exercise testing. These tests may include ischemic forearm exercise, aerobic cycle exercise, and 31P magnetic resonance spectroscopy with exercise.

Review↗
DOE OSTI2020

Generation and suppression of runaway electrons in MST tokamak plasmas

This paper discusses the behavior of runaway electrons in tokamak plasmas at low electron density, plasma current, and magnetic field using experimental data from the Madison Symmetric Torus and computational data from the NIMROD nonlinear resistive 3D MHD code. Density thresholds for the onset and suppression of runaway electrons are determined experimentally in steady tokamak plasmas, and in plasmas with a population of runaway electrons, resonant magnetic perturbations with different poloidal mode numbers are applied. Poloidal mode number m = 3 perturbations suppress the runaway electrons, while perturbations with m = 1 have little effect. This difference is consistent with the difference in computed magnetic topologies. The m = 1 RMP has minimal effect on the topology, while the m = 3 RMP produces a broad region of stochasticity, which can allow for rapid loss of the runaway electrons.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2018

Monaco treatment planning system tools and optimization processes

The Monaco treatment planning system combines Monte Carlo dose calculation accuracy with robust optimization tools to provide high-quality radiotherapy treatment plans for three-dimensional conformal radiotherapy (3D CRT), intensity modulated radiotherapy (IMRT), volumetric modulated arc therapy (VMAT), stereotactic radiosurgery (SRS), and stereotactic body radiotherapy (SBRT). Recent technology advances have allowed for fast calculation speeds, which allow clinicians and patients to benefit from the accuracy of the Monte Carlo algorithm while reducing overall planning time. A collection of biological and physical dose-based planning tools and templates simplify the planning process and allow for consistent results across organizations. At the same time, multicriteria optimization (MCO) ensures critical organs are spared to the greatest possible degree while maintaining target coverage. Monaco encompasses a full suite of treatment modalities, including conventional radiotherapy and particle therapy, and is paving the way for real-time adaptive treatments with developments in magnetic resonance (MR)-guided radiation therapy.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2025

Short-range spin freezing in the double trillium lattice spin-liquid candidate KSrFe 2 ⁢(PO 4 ) 3 revealed via 31 P NMR

A comprehensive 31 P nuclear magnetic resonance (NMR) study, combined with thermodynamic measurements and first-principles band-structure calculations, has been conducted to explore the ground state of the 𝑆=5/2 double trillium lattice antiferromagnet KSrFe 2 ⁢(PO 4 ) 3 . Our experimental results indicate that the magnetic ground state is neither a conventional three-dimensional (3D) long-range order (LRO) nor a pure gapless spin-liquid state, as conjectured previously [Boya et al., APL Mater. 10, 101103 (2022)]. Specifically, the observation of a nearly field-independent NMR linewidth below 𝑇* = (3.5 ± 0.4)⁢ K, and a significant enhancement of spin-spin relaxation rate 1/𝑇 2 below 2⁢𝑇* (where 𝑇* is the characteristic temperature identified from the magnetic susceptibility), indicate a complex magnetic ground state where spin freezing coexists with persistent dynamics. Furthermore, we argue that the lack of magnetic LRO and the persistence of strong magnetic fluctuations in KSrFe 2 ⁢(PO 4 ) 3 are unlikely to originate from intersite K/Sr disorder, rather they arise due to intrinsic magnetic frustration. In conclusion, our findings position KSrFe 2 ⁢(PO 4 ) 3 into a broader family of geometrically frustrated magnets characterized by coexisting spin freezing and pronounced antiferromagnetic fluctuations, marking it as a promising platform for investigating exotic phenomena in 3D frustrated magnets.

Exotic phases of matter↗
NASA NTRS1999

Probing porous media with gas diffusion NMR

We show that gas diffusion nuclear magnetic resonance (GD-NMR) provides a powerful technique for probing the structure of porous media. In random packs of glass beads, using both laser-polarized and thermally polarized xenon gas, we find that GD-NMR can accurately measure the pore space surface-area-to-volume ratio, S/V rho, and the tortuosity, alpha (the latter quantity being directly related to the system's transport properties). We also show that GD-NMR provides a good measure of the tortuosity of sandstone and complex carbonate rocks.

NASA Discipline Environmental Health↗
DOE OSTI2014

Optimization of esterification of oleic acid and trimethylolpropane (TMP) and pentaerythritol (PE)

Vegetable oil (VO) is the most potential alternative to replace mineral oil for lubricant due to better lubricating properties and great physicochemical properties. Chemical modification has to be done to overcome low temperature performance and low oxidation instability due to the presence of β-hydrogen atoms of glycerol molecule. The optimization of esterification of oleic acid and polyhydric alcohol with sulfuric acid catalyst was carried out to find the optimum conditions with the highest yield. Reeaction variables such as; molar ratio, temperature, duration and catalyst concentration. Two types of polyhydric alcohol have been used; TMP and PE. The optimum results showed oleic acid successfully converted 91.2% ester TMP and 92.7% ester PE at duration: 5 hours (Ester TMP), 6 hours (Ester PE); temperature: 150°C (ester TMP), 180°C (Ester PE); catalyst concentration: 1.5% (w/w); and mol ratio: 3.9:1 (ester TMP), 4.9:1 (ester PE). From the data obtained, mole ratio showed most influenced factors to the increasing yields of ester conversions.. The TMP/PE ester was confirmed using gas chromatography (GC-FID), Fourier Transform Infrared Spectroscopy (FTIR) and Nuclear Magnetic Resonance (NMR)

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

NMR diffusion-encoding with axial symmetry and variable anisotropy: Distinguishing between prolate and oblate microscopic diffusion tensors with unknown orientation distribution

We introduce a nuclear magnetic resonance method for quantifying the shape of axially symmetric microscopic diffusion tensors in terms of a new diffusion anisotropy metric, D{sub Δ}, which has unique values for oblate, spherical, and prolate tensor shapes. The pulse sequence includes a series of equal-amplitude magnetic field gradient pulse pairs, the directions of which are tailored to give an axially symmetric diffusion-encoding tensor b with variable anisotropy b{sub Δ}. Averaging of data acquired for a range of orientations of the symmetry axis of the tensor b renders the method insensitive to the orientation distribution function of the microscopic diffusion tensors. Proof-of-principle experiments are performed on water in polydomain lyotropic liquid crystals with geometries that give rise to microscopic diffusion tensors with oblate, spherical, and prolate shapes. The method could be useful for characterizing the geometry of fluid-filled compartments in porous solids, soft matter, and biological tissues.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Organic matter concentration and composition of experimentally burned open air and muffle furnace vegetation chars across differing burn severity and feedstock types from Pacific Northwest, USA (v4).

This dataset represents results from an experimental study designed to compare how the chemical composition of organic matter changes across different burn conditions and feedstock materials. The dataset provides both solid and dissolved phase bulk concentration and organic matter characterization data from experimentally generated chars. Chars were created in a closed muffle furnace or on an open burn table from four different feedstock species representing vegetation commonly impacted by fire regimes across the Pacific Northwest, USA. This data can be used to compare how different burn conditions may influence resultant organic matter chemistry and help further our understanding of potential biogeochemical impacts on river corridors post-fire. This dataset is comprised of one data package readme, one data dictionary (dd), one file level metadata (flmd), fourteen burn table videos, burn table video metadata and three folders containing (A) data; (B) metadata and protocols; and (C) photos. The folder names and the file name of the data package readme include a version number which will be updated with future iterations of this data package. The data folder includes (1) solid carbon and solid nitrogen; (2) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) and total dissolved nitrogen (TN); (3) pH; (4) thermocouple time series temperature; (5) methods codes; (6) installation methods; (7) excitation emissions matrix (EEM) methods information; (8) a folder of excitation emissions matrix (EEM) fluorescence and absorbance spectra in dissolved organic matter and EEMs processing instructions; (9) solid state carbon-13 and solution state phosphorus nuclear magnetic resonance (13-C NMR and 31-P NMR) data and methods; (10) benzene polycarboxylic acid (BPCA) concentration and stable isotope data; (11) FTICR-MS methods; (12) Inductively coupled plasma (ICP) data for total calcium, magnesium, iron, aluminum, potassium, phosphorus, sodium, and sulfur along with sodium hydroxide-ethylenediaminetetraacetic acid (sodium hydroxide-EDTA) extractable calcium, magnesium, iron, aluminum, potassium, phosphorus, and sulfur; (13) a folder of phosphorus, carbon, and nitrogen X-ray absorption near edge structure (P-XANES, N-XANES, C-XANES) data for samples and standards; (14) P-XANES, N-XANES, C-XANES methods; (15) molybdate reactive phosphorus; and (16) folder of high resolution characterization of organic matter via 21 Tesla Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) generated through the Environmental Molecular Sciences Laboratory (EMSL; https://www.pnnl.gov/environmental-molecular-sciences-laboratory). The FTICR folder contains .txt data files and a subfolder containing instruments for using Formularity (https://omics.pnl.gov/software/formularity) and an R script to process the data based on the user's specific needs. The metadata and protocols folder includes (1) international geo-sample number (IGSN) mapping file (2) burn and laboratory metadata; (3) burn protocol; (4) laboratory protocol; (5) vegetation collection metadata; and (6) vegetation collection protocol. The folder contains photos of the solid chars. All files are .csv, .txt, .pdf, .jpg, .jpeg, .R, .ref, or .mp4. The data package was originally published October 2022 (v1). It was updated April 2023 (v2; new data files), September 2023 (v3; new and corrected data files), and September 2024 (v4; new and added/updated files). Metadata files were also updated to reflect these changes. See the change history section in the readme for more details.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2013

Epitaxial films of Heusler compound Co{sub 2}FeAl{sub 0.5}Si{sub 0.5} with high crystalline quality grown by off-axis sputtering

Co{sub 2}FeAl{sub 0.5}Si{sub 0.5} films with a surface roughness of 0.12 nm have been grown epitaxially on lattice-matched MgAl{sub 2}O{sub 4} (001) substrates by off-axis sputtering. X-ray diffraction shows pronounced Laue oscillations, rocking curves as narrow as 0.0043°, and clear Co{sub 2}FeAl{sub 0.5}Si{sub 0.5} (111) peaks indicating L2{sub 1} ordering. Magnetic characterizations show a clear magnetocrystalline anisotropy comprising cubic and epitaxy-induced uniaxial terms. Nuclear magnetic resonance measurements reveal L2{sub 1} order of 81% in the Co{sub 2}FeAl{sub 0.5}Si{sub 0.5} films. Magnetotransport measurements show a distinct separation of anisotropic magnetoresistance and ordinary magnetoresistance. These results demonstrate the state-of-the-art crystalline quality and magnetic uniformity of the Co{sub 2}FeAl{sub 0.5}Si{sub 0.5} films.

36 MATERIALS SCIENCE↗