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At least 1,459 records · Page 81

Developing in-situ capabilities for synchrotron light source relevant to PNNL mission research areas

The main objective of the proposed research is to engage synchrotron light source capabilities to address the critical mission areas at PNNL. We have carried out Multi-model chemical analysis and imaging to unravel the role of surface chemistry during realistic heterogeneous interfacial processes - through a close collaboration that will help BES and BER research projects. In particular, we performed the following activities to understand role of surface chemistry on metal and oxide reactivity and metal ion transfer across oxide surface and aqueous solutions: 1) Perform light source experiments utilizing samples generated at PNNL; 2) Develop early career PNNL scientists utilizing light sources; 3) Build collaborations with ALS scientists in developing new in-situ capabilities; 4) Complete AMBER capabilities in collaboration with ALS scientists and make those available to the scientific community including PNNL scientists.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Laser-assisted high-energy proton pulse extraction for feasibility study of co-located muon source at the SNS

Here, we have experimentally demonstrated the first non-intrusive 1-GeV proton beam extraction for the generation of muons with a temporal structure optimized for Muon Spin Relaxation/Rotation/Resonance (μSR) applications. The proton pulses are extracted based on the laser neutralization of 1 GeV hydrogen ion (H - ) beam in the high energy beam transport of the Spallation Neutron Source (SNS) accelerator. The maximum flux of the extracted proton beam based on laser neutralization causes only 0.2% reduction of the total proton beam used for neutron production, a marked difference from the 20% reduction at other co-located muon and neutron facilities, and thus the proposed method will result in negligible impact on the SNS operation. This paper describes the development of a fiber/solid-state hybrid laser system that has high flexibility of pulse structure and output power, initial experiments on laser neutralization of beam and separation of H 0 beam from the existing SNS accelerator beam line, conversion of H 0 to proton at the SNS linac dump, and measurement results of 30 ns/50 kHz proton pulses. This system conclusively demonstrates the feasibility of laser-based proton beam extraction to power a world-leading μSR facility at the SNS.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Circulation of energetic ions of terrestrial origin in the magnetosphere

Shelley et al. (1972) have first reported that ions of terrestrial origin might represent a nonnegligible component of the hot magnetospheric plasmas. The present paper is concerned with those observational results which provide keys to the circulation of energetic magnetospheric ions of terrestrial origin, taking into account ions having energies greater than approximately 10-100 eV. It is pointed out that these are the ions which might be expected to circulate through the plasma sheet. On the basis of the observed ion composition of plasma storage regions (the plasma sheet and ring current) and the source and transport regions (auroral zone acceleration region, polar cap, boundary layers and magnetotail lobes), it is concluded that during magnetically active periods the primary circulation of energetic terrestrial ions is directly from the auroral acceleraton region into the plasma sheet boundary layer and central plasma sheet.

Shelley, E. G.↗

The equilibrium of atmospheric sodium

We now have four examples of planetary objects with detectable sodium (and potassium) in their atmospheres: Earth, Io, Mercury and the moon. After a summary of the observational data, this survey discusses proposed sources and sinks. It appears that Io's surface material is rich in frozen SO2, but with around 1 percent of some sodium compound. The Io plasma torus contains ions of S, O and Na, also with at least one molecular ion containing Na. In turn, impact by these ions probably sustains the torus, as well as an extended neutral corona. A primary source for the Earth, Mercury and the moon is meteoroidal bombardment; at Mercury and perhaps the moon it may be supplemented by degassing of atoms from the regolith. Photoionization is important everywhere, although hot electrons are dominant at Io.

Hunten, Donald M.↗

Characteristics of Escaping Magnetospheric Ions Associated with Magnetic Field Fluctuations

The four Magnetospheric Multiscale (MMS) spacecraft observed a hot ow anomaly (HFA) at the boundary of the quasi-parallel and quasi-perpendicular bow shock and energetic (E > 50 keV) ion bursts exhibitinginverse dispersion in the magnetosheath on 28 December 2015. We consider the possibility that the ions seen both upstream in the foreshock and down-stream in the magnetosheath originate from the magnetosphere. The ion composition ratios, flux levels, and the spectral slopes of the energetic ion energy spectra observed in the region upstream from the bow shock and in themagnetosheath are similar to those in the outer magnetosphere but significantly differ from those seen further upstream from the bow shock at ACE. We can exclude an explanation of the particle source in terms of HFA acceleration. A simulation shows that escaping magnetospheric ions can be scattered and transported across the magnetosheath. Ground magnetometer observations indicate that a solar wind pressure decrease subsequently allows the bow shock to move outward past the MMS spacecraft placing them in the magnetosheath. This was followed by a pressure increase in the magnetosphere. We posit that the enhanced pressure applied to the magnetosphere accelerates the escaping magnetospheric ions (the betatron acceleration), resulting in the inverse dispersion.

S. H. Lee↗

X-ray emission-line spectra of photoionized plasmas - Density sensitivity of the Fe L-shell series

The circumsource environments of accretion-powered X-ray sources are likely to support relatively dense (greater than 10 exp 11/cu cm) photoionized X-ray emission-line regions. The Fe L-shell ions provide a versatile class of plasma diagnostics in this regime, their multielectron structures resulting in diverse spectral phenomena. Attention is given to the spectral response of Fe L-shell ions to variations in electron density over the range 10 exp 11 to 10 exp 16/cu cm. It is found that density-sensitive line ratios exist in the wavelength interval 12-17 A for the ions Fe XVII-XXI. The prominent role of radiative recombination in the population kinetics distinguishes the density-sensitive Fe lines in photoionized plasmas from those which operate in coronal equilibrium plasmas. The results of detailed atomic modeling of these ions are presented and applications to spectroscopic observations of accretion-driven X-ray sources are discussed.

Liedahl, Duane A.↗

Single-event burnout in homojunction GaN vertical PiN diodes with hybrid edge termination design

GaN devices play a major role in modern electronics, providing high-power handling, efficient high-frequency operation, and resilience in harsh environments. However, electric field crowding at the edge of the anode often limits its full potential, leading to single-event effects (SEEs) at lower bias voltages under heavy ion radiation. Here, in this work, we report on the performance of homojunction GaN vertical PiN diodes with a hybrid edge termination design under heavy ion irradiation, specifically, oxygen ions, chlorine ions, Cf-252 fission fragments, and alpha particles from an Am-241 source. The unique hybrid edge termination (HET) design provides better electric field management, preventing breakdown from occurring at the edge of the anode at lower voltages. The results of this study reveal that these devices exhibit excellent tolerance to 12-MeV oxygen and 16-MeV chlorine ions, owing to their low linear energy transfer (LET) and range in GaN. However, single-event burnout (SEB) is observed during the Cf-252 exposure at about 50% of the diodes' electrical breakdown voltage due to the presence of higher LET and longer-range ions. Optical and scanning electron microscopy (SEM) reveal that the damage that caused by SEB lies close to the center of these devices rather than the anode edge. Devices with junction termination extension (JTE) instead of HET edge termination also show similar SEB when irradiated with Cf-252 fission fragments. Physical damage due to SEB occurs at the edge of the anode for these devices. These comparative results show the benefits of HET for enhancing the resistance of GaN-based PiN diodes to heavy ion irradiation.

42 ENGINEERING↗

High-frequency modulation of ion-acoustic waves.

A large amplitude, high-frequency electromagnetic oscillation is impressed on a nonrelativistic, collisionless plasma from an external source. The frequency is chosen to be far from the plasma frequency (in fact, lower). The resulting electron velocity distribution function strongly modifies the propagation of ion-acoustic waves parallel to the oscillating electric field. The complex frequency is calculated numerically.

Albright, N. W.↗

A sustained high-temperature fusion plasma regime facilitated by fast ions

Nuclear fusion is one of the most attractive alternatives to carbon-dependent energy sources. Harnessing energy from nuclear fusion in a large reactor scale, however, still presents many scientific challenges despite the many years of research and steady advances in magnetic confinement approaches. State-of-the-art magnetic fusion devices cannot yet achieve a sustainable fusion performance, which requires a high temperature above 100 million kelvin and sufficient control of instabilities to ensure steady-state operation on the order of tens of seconds. Here, in this study, we report experiments at the Korea Superconducting Tokamak Advanced Research device producing a plasma fusion regime that satisfies most of the above requirements: thanks to abundant fast ions stabilizing the core plasma turbulence, we generate plasmas at a temperature of 100 million kelvin lasting up to 20 seconds without plasma edge instabilities or impurity accumulation. A low plasma density combined with a moderate input power for operation is key to establishing this regime by preserving a high fraction of fast ions. This regime is rarely subject to disruption and can be sustained reliably even without a sophisticated control, and thus represents a promising path towards commercial fusion reactors.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Tin removal by an annular surface wave plasma antenna in an extreme ultraviolet lithography source

Tin contamination of the collector mirror surface remains one of the crucial issues of EUV (Extreme Ultraviolet) sources, directly impacting the availability of the tool. Hydrogen plasma-based tin removal processes employ hydrogen radicals and ions to interact with tin deposits to form gaseous tin hydride (SnH 4 ), which can be removed through pumping. An annular surface wave plasma (SWP) source developed at the University of Illinois—Urbana Champaign is integrated into the cone and perimeter of the collection mirror for in situ tin removal. The SWP is characterized by high ion and radical densities, low electron temperature, and local generation where etching is needed. This method has the potential to significantly reduce downtime and increase mirror lifetime. Radical probe measurements show hydrogen radical densities in the order of 10 19 m -3 , while Langmuir probe measurements show electron temperatures of up to 6 eV and plasma densities on the order of 10 17–18 m -3 . The generated ions are essential to the tin cleaning and have sufficiently low energy to cause no damage to the collector capping layer. Tin etch rates of up to 270 nm/min were observed in a variety of experimental conditions, including various powers, pressures, flowrates, and temperatures. In conclusion, the high etch rates demonstrated in this study exceed the expected contamination rate of the EUV source.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Energetic oxygen - A direct coupling mechanism between the magnetosphere and thermosphere

The study investigates the effects of the precipitation of energetic O(+) ions (0.7 - 12 keV) into the atmosphere during magnetic storms. The energetic O(+) ion flux produces a splash of lower energy neutral oxygen atoms at the top of the atmosphere. As a result of the photo-ionization and charge exchange with H(+) ions in the plasmasphere, these backscattered atoms produce a low energy O(+) flux that is more than 10 times larger in magnitude than the original energetic O(+) flux. The energetic O(+) events thus provide a potential source mechanism for the lower energy (no greater than about 30 eV) O(+) ions observed in the plasmasphere. It is also suggested that the energetic ion events may be self-sustaining in that some of the ionized 'splash' particles (no greater than about 10%) are subsequently accelerated by an as yet unidentified mechanism to the higher observed energies. It is found that 96% of the incoming energy is transferred to the neutral atmosphere in the form of heating. Measured fluxes indicate heating rates as high as about 0.4 erg/sq cm/sec/ster.

Torr, M. R.↗

Kinetic plasma processes occurring in the outer plasmasphere

One area of data analysis work that was begun under this contract is the fitting of the perpendicular velocity distributions of equatorially trapped ions with a Kappa function. This type of characterization of the trapped ions will be very useful for comparison with velocity distributions produced by the model. A second area of data analysis is to study data from consecutive passes when DE 1's apogee was near the magnetic equator and the spacecraft was often skimming along nearly the same L shell. In 1982 three such periods occurred in May, June, and July. For these consecutive events we have Kp histories, density measurements from a number of sources (Whistler data, DE SFR, ISEE SFR) and consecutive samples of ion pitch angle distributions along field lines. It is clear from this data how the pitch angle distributions evolve during a flux tube refilling event. Our modeling of the flow of plasma along closed field lines is following two basic tracks. The first is a study of the basic refilling process without the effect of wave-particle heating near the equator or the effect of large or abrupt field-aligned electric potential drops. This model includes the effects of Coulomb self-collisions and collisions with the O+ ions in the topside ionosphere. The second track is a study of the effects of wave produced pitch-angle scattering and perpendicular heating occurring near the magnetic equator, in connection with the development of large potential drops that result from electron heating and the development of density gradients.

Wilson, Gordon R.↗

Possible detection of energetic Jovian heavy ions at Skylab orbit

Evidence for the presence of sodium ions at a concentration about 10% that of oxygen among the particles with energies 10 to 20 MeV/nucleon seen with a detector on Skylab suggests that Jupiter is a significant source of energetic heavy particles inside the earth's magnetosphere. A numerical estimate based on the density of energetic sodium ions at 50 Jupiter radii measured on Voyager 1 indicates that the source strength is adequate.

Price, P. B.↗

On Ba(+) production in the CRIT 2 experiment

Analysis of partical data from the CRIT 2 experiment, studying Alfven's critical ionization velocity (CIV) effect, shows that the density of newly created ions (presumably Ba(+) from the shaped-charge beam) is consistent with the increase in total plasma density measured by the independent RF plasma probe on board (Swenson et al., 1990) at the most active time period. We model this ion production using the measured electron flux data and the neutral barium model of Stenbaek-Nielsen et al. (1990a). To identify the main source mechanisms which may contribute most to the barium ionization, a simple model for the barium ion density at the payload location is developed based on Liouvilles theorem. We estimate that the electron impact ionization is responsible for 90% of the barium ion production observed by CRIT 2 in the first release and up to 45% in the second release. By employing a two-state approximation calculation (Rapp and Francis, 1962), the Ba-O(+) charge exchange cross section is found to range from about 2.0 X 10(exp -17) sq cm at a velocity of 4 km/s to 2.0 X 10(exp -15) sq cm at a velocity of 20 km/s. This result suggests that the Ba-O(+) charge exchange is probably dominant among all the non-CIV ionization processes. By considering the charge exchange process in our density model, the barrium ion densities are calculated for the two releases on CRIT II. The comparison between the model results and the observed data is found to be resonably consistent if the cross sections, as calculated above, are multiplied by 0.3 for the first release and 1.0 for the second release. Our result suggests that the charge exchange process could be the most important non-CIV ionization mechanism in the CRIT II experiment and it should be considered carefully case by case in CIV experiments.

Liou, K.↗

Development of a polysilicon process based on chemical vapor deposition, phase 1

The development of a dichlorosilane-based reductive chemical vapor deposition process for the production of polycrystalline silicon is discussed. Experimental data indicate that the ease of ignition and explosion severity of dichlorosilane (DCS)/air mixtures is substantially attenuated if the DCS is diluted with hydrogen. Redesign of the process development unit to accommodate safety related information is described. Several different sources of trichlorosilane were used to generate a mixture of redistributed chlorosilanes via Dowex ion exchange resin. The unseparated mixtures were then fed to an experimental reactor in which silicon was deposited and the deposited silicon analyzed for electrically active impurities. At least one trichlorosilane source provided material of requisite purity. Silicon grown in the experimental reactor was converted to single crystal material and solar cells fabricated and tested.

Mccormick, J.↗

Silicon ions below 100 km: A case for SiO2(+)

Silicon ions are normally detected at altitudes above 100 km and within sporadic E layers. Traces have rarely been observed within the more permanent metallic layer near 93 km. This is surprising since silicon is an important constituent of chondritic meteorites, which ablate material in this region to provide a primary source of the metallic species observed there. Evidence is presented that Si(+)ions form SiO2(+) at the lower altitudes, and exist in this ionic state prior to recombination. A rocket launched from El Arenosillo, Spain on 3 July 1972, at 0743 LMT, during the predicted period of the Beta Taurids meteor shower, passed through a continuous belt of metallic ions that began near 85 km, ended near 115 km, and exhibited an order of magnitude increase in the form of a layer near 114 km. Si(+)was measured in and below the ledge down to 103 km. It showed a rapid decrease below this height. Radiative association is offered as a primary mechanism for SiO2(+) production.

Goldberg, R. A.↗

Response of the thermosphere and ionosphere to geomagnetic storms

Four numerical simulations have been performed, at equinox, using a coupled thermosphere-ionosphere model, to illustrate the response of the upper atmosphere to geomagnetic storms. The storms are characterized by an increase in magnetospheric energy input at high latitude for a 12-hour period; each storm commences at a different universal time (UT). The initial response at high latitude is that Joule heating raises the temperature of the upper thermosphere and ion drag drives high-velocity neutral winds. The heat source drives a global wind surge, from both polar regions, which propagates to low latitudes and into the opposite hemisphere. The surge has the character of a large-scale gravity wave with a phase speed of about 600 m/s. Behind the surge a global circulation of magnitude 100 m/s is established at middle latitudes, indicating that the wave and the onset of global circulation are manifestations of the same phenomena. A dominant feature of the response is the penetration of the surge into the opposite hemisphere where it drives poleward winds for a few hours. The global wind surge has a preference for the night sector and for the longitude of the magnetic pole and therefore depends on the UT start time of the storm. A second phase of the meridional circulation develops after the wave interaction but is also restricted, in this case by the buildup of zonal winds via the Coriolis interaction. Conservation of angular momentum may limit the buildup of zonal wind in extreme cases. The divergent wind field drives upwelling and composition change on both height and pressure surfaces. The composition bulge responds to both the background and the storm-induced horizontal winds; it does not simply rotate with Earth. During the storm the disturbance wind modulates the location of the bulge; during the recovery the background winds induce a diurnal variation in its position. Equatorward winds in sunlight produce positive ionospheric changes during the main driving phase of the storm. Negative ionospheric phases are caused by increases of molecular nitrogen in regions of sunlight, the strength of which depends on longitude and the local time of the sector during the storm input. Regions of positive phase in the ionosphere persist in the recovery period due to decreases in mean molecular mass in regions of previous downwelling. Ion density changes, expressed as a ratio of disturbed to quiet values, exhibit a diurnal variation that is driven by the location of the composition bulge; this variation explains the ac component of the local time variation of the observed negative storm phase.

Fuller-Rowell, T. J.↗