Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Energy efficiency”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,459 records · Page 81

Photoluminescence properties and efficient energy transfer of Ce3+/Eu2+ activated K2Ba7Si16O40 phosphors

Highlights: • K{sub 2}Ba{sub 7}Si{sub 16}O{sub 40}:Ce{sup 3+}/Eu{sup 2+} phosphors have been synthesized by a high temperature solid-state method with CO atmosphere. • The resonance-type energy transfer by dipole-dipole interaction from Ce{sup 3+} to Eu{sup 2+} in K{sub 2}Ba{sub 7}Si{sub 16}O{sub 40} is demonstrated. • The critical distance between Ce{sup 3+} and Eu{sup 2+} ions is calculated to be 25.06 Å. • The thermal activation energy of K{sub 2}Ba{sub 7}Si{sub 16}O{sub 40} is calculated to be 0.26 eV. - Abstract: Ce{sup 3+}/Eu{sup 2+} activated K{sub 2}Ba{sub 7}Si{sub 16}O{sub 40} phosphors have been synthesized via a high-temperature solid-state method with CO atmosphere. Under ultraviolet (UV) light pump, the photoluminescence (PL) spectra of K{sub 2}Ba{sub 7}Si{sub 16}O{sub 40}: Ce{sup 3+} is composed of a broadband from 300 nm to 500 nm ascribed to the spin-allowed 5d–4f transition of Ce{sup 3+} ions. The optimal concentration is 8% for Ce{sup 3+} single doped K{sub 2}Ba{sub 7}Si{sub 16}O{sub 40} due to the ernergy dispersion between Ce{sup 3+} ions and the critical distance between Ce{sup 3+} ions is 15.05 Å. K{sub 2}Ba{sub 7}Si{sub 16}O{sub 40}: Eu{sup 2+} emits a broad green emission peaking at 498 nm. The spectral overlap between the emission of Ce{sup 3+} and the excitation of Eu{sup 2+} suggests the resonance-type energy transfer from Ce{sup 3+} to Eu{sup 2+}, which is further demonstrated by the decay curves of K{sub 2}Ba{sub 7}Si{sub 16}O{sub 40}: 8 mol% Ce{sup 3+}, m Eu{sup 2+}. The critical distance between Ce{sup 3+} and Eu{sup 2+} ions is calculated to be 25.06 Å by Dexter’s theory. Furthermore, the energy transfer mechanism is dipole-dipole interaction. In addition, the thermal activation energy is calculated to be 0.26 eV. The CIE coordinates can be tuned from blue to green by increasing Eu{sup 2+} ions. All results suggest that K{sub 2}Ba{sub 7}Si{sub 16}O{sub 40}: Ce{sup 3+}, Eu{sup 2+} is potentially useful for near-UV pumped white LEDs.

36 MATERIALS SCIENCE↗