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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,459 records · Page 81
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Chronic exposure of a honey bee colony to 2.45 GHz continuous wave microwaves

A honey bee colony (Apis mellifera L.) was exposed 28 days to 2.45 GHz continuous wave microwaves at a power density (1 mW/sq cm) expected to be associated with rectennae in the solar power satellite power transmission system. Differences found between the control and microwave-treated colonies were not large, and were in the range of normal variation among similar colonies. Thus, there is an indication that microwave treatment had little, if any, effect on (1) flight and pollen foraging activity, (2) maintenance of internal colony temperature, (3) brood rearing activity, (4) food collection and storage, (5) colony weight, and (6) adult populations. Additional experiments are necessary before firm conclusions can be made.

Westerdahl, B. B.↗
NASA NTRS1990

A viscoplastic model with application to LiF-22 percent CaF2 hypereutectic salt

A viscoplastic model for class M (metal-like behavior) materials is presented. One novel feature is its use of internal variables to change the stress exponent of creep (where n is approximately = 5) to that of natural creep (where n = 3), in accordance with experimental observations. Another feature is the introduction of a coupling in the evolution equations of the kinematic and isotropic internal variables, making thermal recovery of the kinematic variable implicit. These features enable the viscoplastic model to reduce to that of steady-state creep in closed form. In addition, the hardening parameters associated with the two internal state variables (one scalar-valued, the other tensor-valued) are considered to be functions of state, instead of being taken as constant-valued. This feature enables each internal variable to represent a much wider spectrum of internal states for the material. The model is applied to a LiF-22 percent CaF2 hypereutectic salt, which is being considered as a thermal energy storage material for space-based solar dynamic power systems.

Freed, A. D.↗
NASA NTRS2014

Drought Prediction for Socio-Cultural Stability Project

The primary objective of this project is to answer the question: "Can existing, linked infrastructures be used to predict the onset of drought months in advance?" Based on our work, the answer to this question is "yes" with the qualifiers that skill depends on both lead-time and location, and especially with the associated teleconnections (e.g., ENSO, Indian Ocean Dipole) active in a given region season. As part of this work, we successfully developed a prototype drought early warning system based on existing/mature NASA Earth science components including the Goddard Earth Observing System Data Assimilation System Version 5 (GEOS-5) forecasting model, the Land Information System (LIS) land data assimilation software framework, the Catchment Land Surface Model (CLSM), remotely sensed terrestrial water storage from the Gravity Recovery and Climate Experiment (GRACE) and remotely sensed soil moisture products from the Aqua/Advanced Microwave Scanning Radiometer - EOS (AMSR-E). We focused on a single drought year - 2011 - during which major agricultural droughts occurred with devastating impacts in the Texas-Mexico region of North America (TEXMEX) and the Horn of Africa (HOA). Our results demonstrate that GEOS-5 precipitation forecasts show skill globally at 1-month lead, and can show up to 3 months skill regionally in the TEXMEX and HOA areas. Our results also demonstrate that the CLSM soil moisture percentiles are a goof indicator of drought, as compared to the North American Drought Monitor of TEXMEX and a combination of Famine Early Warning Systems Network (FEWS NET) data and Moderate Resolution Imaging Spectrometer (MODIS)'s Normalizing Difference Vegetation Index (NDVI) anomalies over HOA. The data assimilation experiments produced mixed results. GRACE terrestrial water storage (TWS) assimilation was found to significantly improve soil moisture and evapotransportation, as well as drought monitoring via soil moisture percentiles, while AMSR-E soil moisture assimilation produced marginal benefits. We carried out 1-3 month lead-time forecast experiments using GEOS-5 forecasts as input to LIS/CLSM. Based on these forecast experiments, we find that the expected skill in GEOS-5 forecasts from 1-3 months is present in the soil moisture percentiles used to indicate drought. In the case of the HOA drought, the failure of the long rains in April appears in the February 1, March 1 and April 1 initialized forecasts, suggesting that for this case, drought forecasting would have provided some advance warning about the drought conditions observed in 2011. Three key recommendations for follow-up work include: (1) carry out a comprehensive analysis of droughts observed over the entire period of record for GEOS-5 forecasts; (2) continue to analyze the GEOS-5 forecasts in HOA stratifying by anomalies in long and short rains; and (3) continue to include GRACE TWS, Soil Moisture/Ocean Salinity (SMOS) and the upcoming NASA Soil Moisture Active/Passive (SMAP) soil moisture products in a routine activity building on this prototype to further quantify the benefits for drought assessment and prediction.

Peters-Lidard, Christa↗
DOE OSTI2025

Hawaii Threat Brief

The Digital Energy Transformation is redefining how power systems operate, integrating physical infrastructure with digital technologies to enhance efficiency, visibility, and resilience. For islanded and digitally modernizing systems like Hawai‘i’s, this shift presents both new opportunities and evolving challenges in cybersecurity, supply chain assurance, and environmental resilience. This brief provides an overview of critical infrastructure dependencies and systemic risks associated with increasing digital integration. It summarizes recent energy-sector threat activity and case studies that illustrate adversary tactics and supply chain vulnerabilities, and identifies pathways to strengthen resilience.

25 - ENERGY STORAGE↗
DOE OSTI2023

Hydropower Potential at Non-Powered Dams: A Multi-Criteria Decision Analysis Tool based on Grid, Community, Industry, and Environmental Impacts

Non-powered dams (NPDs) are dams that do not include hydraulic turbine (hydropower) equipment. Currently, there are more than 80,000 such dams in the United States, which provide a variety of non-energy benefits, including flood control, water supply, navigation, and recreation. Approximately 500 of these NPDs are identified as having the potential to add hydropower generation (totaling up to a capacity of more than 8200 MW). A large share of investment costs and environmental impacts of dam construction have already been incurred at these NPDs. Hence, adding power to the existing dam structure is hypothesized to be achieved at a lower cost, with less risk, and a shorter timeframe than the development required for new dam construction. The abundance of NPDs, the associated environmental favorability, and cost advantages, combined with the reliability, predictability, and dispatchability of hydropower, make NPDs a strong candidate in the nation’s renewable energy portfolio. To assess the NPD to hydropower conversion potential, in this study, we developed a GIS-based multi-criterial decision analysis tool, which allows users to rank these NPDs based on the grid, community, industry, and environmental impacts (i.e., GCIE impacts). This web-based interactive tool (developed using open-source Python and JavaScript) lets the user choose from a wide range of features to define each of the GCIE impact scores through a user-friendly graphical user interface. These features are related to dam operation, hydropower generation opportunity, power market economy, social vulnerability and risk, proximity to critical infrastructure and energy generating facilities, environmental concerns (air, water, and critical habitat), and exposure to natural hazards. The overall priority score of NPDs is calculated based on user-defined weights for each of the GCIE impact scores. Besides ranking NPDs, the tool can also be used to estimate the energy-storage feasibility (battery, hydrogen, and pump-storage hydropower) at each of the potential sites.

13 HYDRO ENERGY↗
DOE OSTI2021

DEVELOPMENT OF STABLE ANODE AND CATHODE MATERIALS FOR RECHARGEABLE BATTERIES

Batteries have been employed in a variety of applications, such as portable electronics, electric vehicles (EVs), and stationary energy storage to preserve energy from other renewable sources (like wind or solar energy). The ultimate goal is to develop high energy density, long life span, better safety, and low cost of the batteries. However, current commercialized batteries (like lead-acid, zinc-alkaline, lithium-ion batteries (LIBs)) could not fulfill all the demands of diversified applications. LIBs predominate the market because of their high energy density. To achieve a higher capacity of the cell, high-nickel layered (Ni > 90%) cathode materials are promising candidates since they compose high specific capacity and discharge voltage. In chapter 1, an introduction to cell energy density and the development of high-nickel layered cathode materials along with associated obstacles of poor cycling stability and thermal stability have been discussed. Associated works like doping or surface coating have also been mentioned in this section. In chapter 2, Al doping in high-nickel layered cathode materials to enhance the structural and thermal stability was introduced. Uniform incorporation of Al doping is achieved by mechanical fusion and calcination processes. The Al doping not only decreased the Li/Ni mixing ratio but also enhance the thermal resistance to oxygen evolution because of strong Al-O bonding, which leads to elevated electrochemical and thermal stability. In chapter 3, TiN is implemented as a Ti dopant for high-nickel layered cathode materials to improve the electrochemical performance in the LIBs. The Ti not only diffused within the bulk structure but also formed segregation on the surface, which improved the structural stability and led to better cycling performance. Although LIBs deliver high energy density, safety concerns of flammable organic electrolytes have not been resolved yet. Therefore, the aqueous rechargeable zinc-ion batteries (ZIB) have been praised for their safe, low-cost, eco-friendly stationary energy storage, which is considered as a complementary system to LIBs. In chapter 4, the mechanism, advantages, and challenges of ZIBs would be given and the strategies for solving the zinc metal anode issues have been discussed in this section. In chapter 5, a polymer coating method was reported to facilitate Zn deposition/ stripping by coordination with Zn2+ and prevented direct contact with aqueous electrolyte to block corrosion side-reactions. With this coating, a boost in a lifetime (up to 400 hours) and lower polarization under extremely high current conditions (10 mA cm-2) have been achieved in repeated Zn deposition/ stripping cycling.

25 ENERGY STORAGE↗
DOE OSTI2023

Tailoring the rheological properties of high protein suspension by thermal-mechanical treatment

The viscoelasticity of concentrated protein suspensions associates closely with the mixing efficiency and cleaning frequency of facility during high-protein food development. This study investigated the effects of thermal-mechanical treatment on the viscoelasticity of milk protein isolate (MPI) suspensions and their underlying mechanisms to develop protein ingredient with low viscoelasticity. MPI suspensions (20%) were treated at 25, 50 and 85°C for 10-60 min under constant shear (100 s -1 ), followed by storage at 4°C. The viscosity (η) of MPI suspension treated at 50°C and 85°C was similar to 1-10% as those treated at 25 ° C. After four days of storage at 4°C, η showed the least value in 50°C-treated samples compared to those at 25 ° C and 85 ° C. The η and storage modulus (G') was decreased with prolonged treatment at 25 and 50°C, whereas opposite trend was found in 85°C treated samples. Differential scanning calorimetry found proteins in 50°C treated samples had smaller enthalpy than those in the control and 25°C treated samples. Protein surface hydrophobicity was increased slightly from 25°C to 50°C, but remarkably in 85°C treated samples. Ultra-small angle x-ray scattering showed the radius of gyration (R-g) of casein micelle was similar to 38 nm at 25°C and 50°C treated samples but increased to similar to 44 nm 85°C treated samples with reduced compactness. A new sphere-like structure with R-g of 18 nm was generated in 85°C treated samples. These findings suggested modulating temperature during thermal-mechanical treatment is essential to alter protein structures and morphology for desirable rheological properties.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Costs of mitigating the environmental impacts of hydropower projects in the United States

Developers are required to mitigate the environmental impacts of hydropower projects in the United States (U.S.) but there is very little accessible information on the associated costs. This work compiles and analyses a dataset of environmental impacts mitigation costs for 182 hydropower projects based on documents obtained from the U.S. Federal Energy Regulatory Commission (FERC). The analysis shows that environmental costs vary wildly across hydropower project classes and mitigation measures, even when normalized by plant capacity. Capital costs per kilowatt are generally higher for relicensed conventional hydropower plants, and lower for new and relicensed pumped storage hydropower plants, relative to other project classes. Smaller plants tend to spend a higher share of total project costs on mitigating environmental impacts than larger plants, and measures related to Aquatic Species, Project Operations, and Recreation have the highest capital cost per kilowatt. These findings mean that environmental costs could become a key decision variable for new hydropower developments in the U.S. due to the small scale of most of the remaining potential and the increasing stringency of environmental requirements. Therefore, technologies to reduce the environmental impacts and costs of hydropower would be important for future project developments.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Emergent Trends Complicate the Interpretation of the United States Drought Monitor (USDM)

Abstract Effective drought management must be informed by an understanding of whether and how current drought monitoring and assessment practices represent underlying nonstationary climate conditions, either naturally occurring or forced by climate change. Here we investigate the emerging climatology and associated trends in drought classes defined by the United States Drought Monitor (USDM), a weekly product that, since 2000, has been used to inform drought management in the United States. The USDM classifies drought intensity based in part on threshold percentiles in key hydroclimate quantities. Here we assess how those USDM‐defined drought threshold percentiles have changed over the last 23 years, examining precipitation, runoff, soil moisture (SM), terrestrial water storage (TWS), vapor pressure deficit (VPD), and near‐surface air temperature. We also assess underlying trends in the frequency of drought classifications across the U.S. Our analysis suggests that the frequency of drought class occurrence is exceeding the threshold percentiles defined by the USDM in a number of regions in the United States, particularly in the American West, where the last 23 years have emerged as a prolonged dry period. These trends are also reflected in percentile‐based thresholds in precipitation, runoff, SM, TWS, VPD, and temperature. Our results emphasize that while the USDM appears to be accurately reflecting observed nonstationarity in the physical climate, such trends raise critical questions about whether and how drought diagnosis, classification, and monitoring should address long‐term intervals of wet and dry periods or trends.

Geology↗
DOE OSTI2023

Fabrication and Testing of DOE Standard Canister Closure Leak Test Assembly – 24139

DOE manages over 300 types of spent nuclear fuel (SNF), many of which are located at the Idaho National Laboratory (INL) site. Managing this large variety of SNF for storage, transportation, and disposal poses a challenge to DOE. The Idaho Cleanup Project and INL are collaborating on the DOE SNF Road-Ready Demonstration (“Road-Ready Demonstration”), which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE-managed SNF for “road-ready dry storage.” Road-ready dry storage is an SNF management concept in which SNF is packaged into dry, sealed canisters that are then placed in onsite storage in anticipation of later transport and disposition. The forward-looking goal of the Road-Ready Demonstration is to establish the foundation for a large-scale road-ready dry storage program at the INL site. In support of establishing a large-scale road-ready dry storage program at the INL site, the Road-Ready Demonstration will first package Fort St. Vrain SNF currently in dry storage at INL into several DOE Standard Canisters (DOESCs). These DOESCs will in turn be loaded into another containment similar to commercial multi-purpose canisters. This multi-purpose canister will then be compatible with a transportation or storage system, such as a storage cask for interim storage or transportation package for offsite transport. These DOESCs will remain sealed over the course of their storage, transportation, and applicable disposal functions. The closure process for the DOESC will include fuel and basket loading, welding, inspection, leak testing, and, if needed, repair. As a follow-up to previous discussions on the design of the DOE Closure Leak Test Assembly (LTA), this report describes recent fabrication and testing efforts performed at INL. DOESCs are sealed by two sequential gas tungsten arc welds, both of which are performed by remotely operated and semiautomatic welding systems. The first weld is a circumferential pipe weld that completes the assembly of the canister body and lid assembly. The second and final closure weld attaches the vent plug to the vent socket via a butt joint. After the second weld is performed, the welds are helium leak tested using an evacuated envelope technique. The LTA was designed for both remote and manual operation. This report describes the fabrication and performance testing associated with the evacuated envelope technique. INL staff designed, fabricated, and tested the LTA at INL facilities. This testing included establishing technique and system sensitivities in accordance with ASME and American National Standards Institute N14.5 requirements. Forthcoming work will cover such areas as design optimization, process and personnel qualification, and implementation in Road-Ready Demonstration operations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

A Dose Assessment Model for Radioactive Waste Exposed by Gully Erosion at West Valley - 20513

The Western New York Nuclear Service Center (WNYNSC), located approximately 48 km south of Buffalo, New York, is the site of a former nuclear fuel reprocessing and radioactive waste disposal facility. Spent nuclear fuel was processed there from 1966 to 1972, leaving behind radioactive and chemical wastes in two disposal areas and a waste tank farm. Site operations also resulted in releases of radioactivity to site soils, groundwater, and to surface waters draining the site. The New York State Energy Research and Development Authority (NYSERDA) and the U.S. Department of Energy (DOE) are collaborating in a process of decision making for decommissioning those facilities remaining at the WNYNSC following the completion of Phase 1 decommissioning. Neptune and Company, Inc. (Neptune) was contracted to develop a probabilistic performance assessment (PPA) computer model to assist the agencies in this process. The PPA Model includes a contaminant transport component focusing on the movement of contaminants within and among environmental media including groundwater and surface water transport, contaminant translocation by plants and animals, diffusion, and erosion. The model also includes evaluation of potential exposure and health effects for a Resident Farmer exposure scenario, where the Resident Farmer represents a critical group, described as that group of individuals reasonably expected to receive the greatest exposure to residual radioactivity for any applicable set of circumstances. The West Valley Site is located in the glaciated Allegheny Plateau region of western New York State. The waste reprocessing and disposal areas were constructed on a relatively fat area of plateau dissected by drainages of Buttermilk Creek, including Erdman Brook, Franks Creek, and Quarry Creek. An important aspect of the contaminant transport component of the PPA model is consideration of erosive processes such as slumping of the stream slopes and the advance of gullies from these streams. These erosion processes remove material from the plateau, growing the size of the creek valleys and making them wider and deeper. Of particular interest for the impact of erosion is radioactive waste contained in the Nuclear Regulatory Commission (NRC)-Licensed Disposal Area (NDA), the New York State-Licensed Disposal Area (SDA), and residual radiological inventory in the underground storage tanks at the Waste Tank Farm (WTF). The PPA Model is organized around geographically-defined facilities which were constructed upon the plateau, including the NDA, SDA, and WTF. Ongoing stream erosion processes will potentially transfer radioactive waste and residual inventory from these facilities to the ground surface on adjacent hillslope areas where erosion has breached the facility. Hence, it is important to evaluate the consequences of potential exposures to a Resident Farmer on the hillslopes below a breached facility. Two interrelated aspects of the dose assessment model related to hillslope exposure are discussed: 1) representation of the physical processes related to transport of radionuclides from facilities onto the hillslopes, and from the hillslopes into adjoining creeks where contaminated material migrates downstream with surface water and sediment, and; 2) adaptation of the activities associated with the Resident Farmer scenario to assess potential exposures to contamination in the hillslope areas. This discussion will cover the conceptual basis of the hillslope exposure and transport models, and also implementation in the PPA computer model. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Adaptation of Temperature Dependent Thermal Neutron Libraries for Fast On-The-Fly Monte Carlo Sampling at Arbitrary Temperatures

Thermal neutron scattering data is necessary for reactor simulations of thermal reactors, but the data storage required can be unwieldy. This is exacerbated when simulations require a large temperature range, as is the case for accident scenarios and reactor start-up. Previous work conducted at RPI has explored and demonstrated a proof of concept of On-The-Fly (OTF) data storage with light water and crystalline graphite based on ENDF/B-VII.1. This provides an updated data storage paradigm for incoherent inelastic cross-sections that allow the data to be used to generate necessary sampling Cumulative Density Functions (CDFs) for any desired temperature. The work presented in this paper extends the previous work by implementing the proof of concept based on ENDF/B-VIII.0, instead of ENDF/B-VII.1, and to include additional materials, such as beryllium and oxygen in beryllium oxide and the new reactor grades of porous graphite. Completion of this work allows a single thermal data file to represent any thermal scattering event for a given material OTF for the temperature of interest, which greatly reduces the data storage needed with only a marginal cost in the calculation of the CDFs OTF. This paper will review the basic methodologies in generating the OTF data, as well as present the updates and improvements made in the generation process. Application of the methodologies covered in this paper show a significant reduction in the storage requirements for inelastic incoherent scattering events. In which, the evaluated ENDF/B-VIII.0 thermal scattering library can be reduced from 563.1 MB to 10.9 MB for light water and 339.3 MB to 13.6 MB for Be in BeO.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2020

Use of Multi-Attribute Utility Analyses to Assess Transportation Routes from ISFSIs - 20535

With two consolidated interim storage facilities for used nuclear fuel (UNF) having applied for storage licenses, there is the potential need to transport UNF in the U.S. from shutdown reactor sites to complete the site cleanup and from operating reactor sites who may be running out of storage options (e.g., spent fuel pools are nearly full and dry storage facilities are reaching licensed capacity). At some of the shutdown reactor sites, only the independent spent fuel storage installation (ISFSI) exists and often there remains a degraded transportation infrastructure for performing shipments from these sites. At other sites (e.g., operating reactor plants), the existing transportation infrastructure on the site is unchanged and sufficient for moving UNF, but the environment around the route may have changed (e.g., what was once a rural setting has transformed into a more urban setting) and/or local stakeholders want their input taken into consideration in UNF transportation activities. So, although preliminary evaluations have been performed to identify viable modes of transport from these sites using rail, barge, and/or heavy haul truck, if multiple options exist for moving the UNF from the site (e.g., multiple truck routes or a truck and a barge route both exist) then an evaluation that takes input from multiple stakeholders should be considered to identified the preference (e.g., ranking) of routes from a site. Orano has supported the development of several studies examining the viable routes for removing UNF from some of these sites and has utilized a multi-attribute utility analysis (MUA) to establish a ranking of routes and associated modes to move the UNF from the ISFSIs to a Class I rail carrier. The ultimate result from the MUA is a list(s) of the most to the least favored/preferred routes from the site. This paper provides an overview of the MUA methodology and provides an example of its application to a site with a shutdown reactor. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Skyrmion fluctuations at a first-order phase transition boundary

Magnetic skyrmions are topologically protected spin textures with promising prospects for applications in data storage. They can form a lattice state due to competing magnetic interactions and are commonly found in a small region of the temperature—magnetic field phase diagram. Recent work has demonstrated that these magnetic quasi-particles fluctuate at the μeV energy scale. Here, we use a coherent x-ray correlation method at an x-ray free-electron laser to investigate these fluctuations in a magnetic phase coexistence region near a first-order transition boundary where fluctuations are not expected to play a major role. Surprisingly, we find that the relaxation of the intermediate scattering function at this transition differs significantly compared to that deep in the skyrmion lattice phase. The observation of a compressed exponential behavior suggests solid-like dynamics, often associated with jamming. We assign this behavior to disorder and the phase coexistence observed in a narrow field-window near the transition, which can cause fluctuations that lead to glassy behavior.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Heterogenization of Homogeneous Ruthenium(II) Catalysts for Carbon-Neutral Dehydrogenation of Polyalcohols

Liquid organic hydrogen carrier (LOHC) systems are an excellent alternative to pressurized gas and liquid hydrogen storage technologies due to their high volumetric storage capacities and straightforward adaptation to existing infrastructure. Homogeneous catalysts are promising for the selective and reversible release of hydrogen from LOHC. However, separation from product mixtures and recycling inhibit their use, particularly when comprised of costly low-abundance elements, motivating the development of heterogeneous versions that are more easily recovered and reused. Here, we describe two methods for the heterogenization of molecular Ru catalysts that efficiently dehydrogenate the polyalcohol LOHCs ethylene glycol (EG) and 1,2-propanediol (1,2-PDO). The heterogeneous versions of these catalysts maintain catalytic activity for hydrogen production comparable to the homogeneous complexes, with up to 81% conversion and 99% selectivity. Further, DFT modeling indicates mechanistic similarities for the dehydrogenations of EG and 1,2-PDO, with the rate-limiting steps associated with protonation of the Ru–H bond to form H 2 and the alkoxide species coordinated to Ru(II), followed by β-hydride elimination to regenerate the Ru–H bond. Overall, the data suggest these heterogenized molecular catalysts have potential for practical use in polyalcohol-based LOHC systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Three Decades of Divergent Land Use and Plant Community Change Alters Soil C and N Content in Tallgrass Prairie

Frequent fire and grazing by megafauna are important determinants of tallgrass prairie plant community structure. However, fire suppression and removal of native grazers have altered these natural disturbance regimes and changed grassland plant communities with potential long-term consequences for soil carbon (C) and nitrogen (N) storage. We investigated multidecade changes in soil C and N pools in response to contrasting long-term burning and grazing treatments. Fire suppression with or without grazers and exclusion of grazers in annually burned prairie increased soil C content and shifted the δ 13 C signature of soil C over time, concomitant with changes in plant community composition. Soil δ 13 C values indicated that increased soil C content was associated with an increased contribution from plants using a C 3 photosynthetic pathway (i.e., woody shrubs) under fire suppression. Soil N content also increased when fire was suppressed, relative to frequently burned grassland, but the rate of increase was slower when grazers were present. Additionally, changes in δ 15 N values suggested that grazing increased the openness of the N cycle, presumably due to greater N losses. By coupling long-term fire and grazing treatments with plant community data and soil samples archived over three decades, we demonstrate that human-caused changes to natural disturbance regimes in a tallgrass prairie significantly alter soil C and N cycles through belowground changes associated with shifts in the plant community. Since natural disturbance regimes have been altered in grasslands across the world, our results are relevant for understanding the long-term biogeochemical consequences of these ongoing land use changes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Unprecedented non-hysteretic superelasticity of [001]-oriented NiCoFeGa single crystals

Superelasticity associated with the martensitic transformation has found a broad range of engineering applications. However, the intrinsic hysteresis and temperature sensitivity of the first-order phase transformation significantly hinder the usage of smart metallic components in many critical areas. In this paper, we report a large superelasticity up to 15.2% strain in [001]-oriented NiCoFeGa single crystals, exhibiting non-hysteretic mechanical responses, a small temperature dependence and high-energy-storage capability and cyclic stability over a wide temperature and composition range. In situ synchrotron X-ray diffraction measurements show that the superelasticity is correlated with a stress-induced continuous variation of lattice parameter accompanied by structural fluctuation. Neutron diffraction and electron microscopy observations reveal an unprecedented microstructure consisting of atomic-level entanglement of ordered and disordered crystal structures, which can be manipulated to tune the superelasticity. The discovery of the large elasticity related to the entangled structure paves the way for exploiting elastic strain engineering and development of related functional materials. NiCoFeGa single crystals exhibit large non-hysteretic superelasticity over broad temperature and composition ranges. It is attributed to the continuous phase transition with applied stress, which is related to the fluctuation of entangled ordered and disordered crystal structures.

36 MATERIALS SCIENCE↗
DOE OSTI2020

A New Superconducting Undulator Cryostat for the APS Upgrade

The Advanced Photon Source (APS) is in the midst of a major facility upgrade including both a new electron storage ring (SR) and many new insertion devices ( IDs) providing x-ray photon beams to a new suite of experimental end stations. Included among the new IDs are four 4.8-meter superconducting undulator (SCU) cryostats, each containing two 1.8-meter planar undulator magnets operating at 4.2 K in either a phase shifted or canted configuration. We describe a new, compact cryocooler-based cryostat design which supports the magnets and associated subsystems and also fits the space constraints of the SR ID straight sections. The design is an evolution of earlier single-magnet 2-meter cryostats, retaining some subsystem commonality while incorporating lessons learned and several features unique to the challenge of supporting two independently operable undulator magnets in a single device.

Anliker, E.↗