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(K)3Zn crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional and consists of one K framework and two zinc dust molecules. In the K framework, there are two inequivalent K sites. In the first K site, K is bonded in a 8-coordinate geometry to four equivalent K atoms. All K–K bond lengths are 4.19 Å. In the second K site, K is bonded in a 8-coordinate geometry to eight equivalent K atoms.
(K)3Zn is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is zero-dimensional and consists of three potassium molecules and one zinc molecule.
CaF2Zn crystallizes in the cubic Fd-3m space group. The structure is three-dimensional and consists of one CaF2 framework and sixteen zinc molecules. In the CaF2 framework, Ca is bonded in a 6-coordinate geometry to six equivalent F atoms. All Ca–F bond lengths are 2.35 Å. F is bonded in a trigonal non-coplanar geometry to three equivalent Ca atoms.
ZnNi2Si crystallizes in the tetragonal P4/mmm space group. The structure is two-dimensional and consists of one Ni2Si sheet oriented in the (0, 0, 1) direction and one zinc molecule. In the Ni2Si sheet, Ni1+ is bonded in a 4-coordinate geometry to four equivalent Si4- atoms. All Ni–Si bond lengths are 2.35 Å. Si4- is bonded in a body-centered cubic geometry to eight equivalent Ni1+ atoms.
Zn(CN3)2(Br)4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four diaziridinimine molecules, eight hydrobromic acid molecules, and two zinc dust molecules.
Mg4ZnN4Zn is Tetraauricupride structured and crystallizes in the cubic P-43m space group. The structure is zero-dimensional and consists of one Mg4ZnN4 cluster and one zinc molecule. In the Mg4ZnN4 cluster, Mg2+ is bonded in a single-bond geometry to one N3- atom. The Mg–N bond length is 1.98 Å. Zn2+ is bonded in a tetrahedral geometry to four equivalent N3- atoms. All Zn–N bond lengths are 1.92 Å. N3- is bonded in a linear geometry to one Mg2+ and one Zn2+ atom.
ZnO6GeF6 is Tetraauricupride structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three GeF6 clusters and three zinc;hexahydrate molecules. In each GeF6 cluster, Ge is bonded in an octahedral geometry to six equivalent F atoms. All Ge–F bond lengths are 1.83 Å. F is bonded in a single-bond geometry to one Ge atom.
(FeH8(SO6)2)2Zn(H2O)6 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one FeH8(SO6)2 sheet oriented in the (0, 0, 1) direction and one zinc hexahydrate molecule. In the FeH8(SO6)2 sheet, Fe3+ is bonded to six O2- atoms to form FeO6 octahedra that share corners with two SO4 tetrahedra. There are a spread of Fe–O bond distances ranging from 1.97–2.09 Å. There are eight inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a distorted single-bond geometry to two O2- atoms. There is one shorter (1.01 Å) and one longer (1.66 Å) H–O bond length. In the second H1+ site, H1+ is bonded in a distorted single-bond geometry to two O2- atoms. There is one shorter (1.01 Å) and one longer (1.65 Å) H–O bond length. In the third H1+ site, H1+ is bonded in a distorted single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to two O2- atoms. There is one shorter (1.00 Å) and one longer (1.71 Å) H–O bond length. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. In the sixth H1+ site, H1+ is bonded in a distorted single-bond geometry to two O2- atoms. There is one shorter (1.01 Å) and one longer (1.64 Å) H–O bond length. In the seventh H1+ site, H1+ is bonded in a distorted single-bond geometry to two O2- atoms. There is one shorter (1.00 Å) and one longer (1.68 Å) H–O bond length. In the eighth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. There are two inequivalent S6+ sites. In the first S6+ site, S6+ is bonded to four O2- atoms to form SO4 tetrahedra that share a cornercorner with one FeO6 octahedra. The corner-sharing octahedral tilt angles are 34°. There are a spread of S–O bond distances ranging from 1.47–1.51 Å. In the second S6+ site, S6+ is bonded to four O2- atoms to form SO4 tetrahedra that share a cornercorner with one FeO6 octahedra. The corner-sharing octahedral tilt angles are 32°. There are a spread of S–O bond distances ranging from 1.48–1.51 Å. There are twelve inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Fe3+ and one S6+ atom. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one H1+ and one S6+ atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to one S6+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one S6+ atom. In the fifth O2- site, O2- is bonded in a bent 150 degrees geometry to one Fe3+ and one S6+ atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to one S6+ atom. In the seventh O2- site, O2- is bonded in a distorted trigonal planar geometry to two H1+ and one S6+ atom. In the eighth O2- site, O2- is bonded in a distorted trigonal planar geometry to two H1+ and one S6+ atom. In the ninth O2- site, O2- is bonded in a distorted water-like geometry to one Fe3+ and two H1+ atoms. In the tenth O2- site, O2- is bonded in a distorted water-like geometry to one Fe3+ and two H1+ atoms. In the eleventh O2- site, O2- is bonded in a distorted water-like geometry to one Fe3+ and two H1+ atoms. In the twelfth O2- site, O2- is bonded in a distorted water-like geometry to one Fe3+ and two H1+ atoms.
(ZnO3)2(SO3)2(O2)5 crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, four sulfur trioxide molecules, four trioxidane molecules, and four zinc trihydroxide molecules.
Zn(OsO4)2(N2)2 is Iron carbide-derived structured and crystallizes in the cubic F-43m space group. The structure is zero-dimensional and consists of sixteen ammonia molecules, eight OsO4 clusters, and four zinc molecules. In each OsO4 cluster, Os5+ is bonded in a tetrahedral geometry to four equivalent O2- atoms. All Os–O bond lengths are 1.73 Å. O2- is bonded in a single-bond geometry to one Os5+ atom.
Zn(N2)4(CO2)2 is Cyanogen Chloride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four carbon dioxide molecules, eight nitrogen molecules, and two zinc molecules.
(TbSb)2ZnSb crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one antimony molecule, two TbSb clusters, and one zinc molecule. In each TbSb cluster, Tb3+ is bonded in a single-bond geometry to one Sb+2.67- atom. The Tb–Sb bond length is 2.64 Å. Sb+2.67- is bonded in a single-bond geometry to one Tb3+ atom.
ZnO6(BrO3)2 is Fluorite structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight hypobromous acid;dihydrate molecules and four zinc;hexahydrate molecules.
ZnCl2(NCl)2 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight chloramine molecules and four zinc chloride molecules.
U2Zn17 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two U2Zn5 clusters and sixteen zinc molecules. In each U2Zn5 cluster, U is bonded in a bent 150 degrees geometry to two Zn atoms. There are one shorter (2.90 Å) and one longer (3.16 Å) U–Zn bond lengths. There are three inequivalent Zn sites. In the first Zn site, Zn is bonded in a linear geometry to two equivalent U atoms. In the second Zn site, Zn is bonded in a single-bond geometry to one Zn atom. The Zn–Zn bond length is 2.86 Å. In the third Zn site, Zn is bonded in a distorted bent 120 degrees geometry to one U and one Zn atom.
Zn(H2O)6ZnCl4(H2O)3 is alpha Pu-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of twelve water molecules, four ZnCl4 clusters, and four zinc hexahydrate molecules. In each ZnCl4 cluster, Zn2+ is bonded in a tetrahedral geometry to four Cl1- atoms. There are a spread of Zn–Cl bond distances ranging from 2.28–2.31 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom.
CaF2Zn crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional and consists of one CaF2 framework and eight zinc molecules. In the CaF2 framework, Ca is bonded in a 6-coordinate geometry to six equivalent F atoms. There are four shorter (2.33 Å) and two longer (2.36 Å) Ca–F bond lengths. F is bonded in a trigonal non-coplanar geometry to three equivalent Ca atoms.
Mn(O3Br)2ZnBr2 crystallizes in the orthorhombic Pbam space group. The structure is one-dimensional and consists of two Mn(O3Br)2 ribbons oriented in the (1, 0, 0) direction and four zinc dibromide molecules. In each Mn(O3Br)2 ribbon, there are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded in an octahedral geometry to six O2- atoms. There is two shorter (1.70 Å) and four longer (2.12 Å) Mn–O bond length. In the second Mn2+ site, Mn2+ is bonded in an octahedral geometry to six O2- atoms. There is two shorter (1.68 Å) and four longer (2.12 Å) Mn–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Mn2+ atom. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one Mn2+ and one Br2+ atom. The O–Br bond length is 1.72 Å. In the third O2- site, O2- is bonded in a single-bond geometry to one Mn2+ atom. In the fourth O2- site, O2- is bonded in a bent 120 degrees geometry to one Mn2+ and one Br2+ atom. The O–Br bond length is 1.72 Å. Br2+ is bonded in a water-like geometry to two O2- atoms.