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At least 1,441 records · Page 80

Modeling starch dynamics from seasonal variations of photosynthesis, growth and respiration

Abstract Nonstructural carbohydrates (NSCs) buffer differences in plant carbon supply (photosynthesis) and demand (respiration, growth, etc.), but the regulation of their dynamics remains unresolved. Seasonal variations in NSCs are well-documented, but differences in the time-average, amplitude, phase and other characteristics across ecosystems and functional types lack explanation; furthermore, observed dynamics do not always match expectations. The failure to match observed and expected dynamics has stimulated debate on whether carbon supply or demand drives NSC dynamics. To gain insight into how carbon supply and demand drive seasonal NSC dynamics, we derive a simple model of NSC dynamics based on carbon mass balance and linearizing the NSC demand to determine how supply-driven and demand-driven seasonal NSC dynamics differ. We find that supply-driven and demand-driven dynamics yield distinct timings of seasonal extrema, and supply overrides demand when carbon supply is low in winter (e.g., at high latitudes). Our results also suggest that NSC dynamics often lag changes carbon mass balance. We also predict differences in NSC dynamics across mass, suggesting that saplings are more dynamic and respond more quickly to the environment than mature trees. Our findings suggest that substrate-dependent regulation with environmental variation is sufficient to generate complex NSC dynamics.

Forestry↗

The prediction of sea-surface temperature variations by means of an advective mixed-layer ocean model

An advective mixed layer ocean model was developed by eliminating the assumption of horizontal homogeneity in an already existing mixed layer model, and then superimposing a mean and anomalous wind driven current field. This model is based on the principle of conservation of heat and mechanical energy and utilizes a box grid for the advective part of the calculation. Three phases of experiments were conducted: evaluation of the model's ability to account for climatological sea surface temperature (SST) variations in the cooling and heating seasons, sensitivity tests in which the effect of hypothetical anomalous winds was evaluated, and a thirty-day synoptic calculation using the model. For the case studied, the accuracy of the predictions was improved by the inclusion of advection, although nonadvective effects appear to have dominated.

Atlas, R. M.↗

Radar Observations of Asteroid 10115 (1992 SK)

The approach of 1992 SK to within 0.056 AU of Earth on 1999 March 26 provided an excellent opportunity for radar observations. We observed it daily between March 22-26 at Goldstone at a transmitter frequency of 8560 MHz (3.50 cm). Weighted, optimally smoothed sums of cw (Doppler-only) echoes achieve a signal-to-noise ratio of about 300. Our highest resolution cw setup places up to approx. 30 0.5-Hz Doppler cells on the target at echo powers exceeding two standard deviations of the noise. Our highest resolution imaging setup places about 20 0.25-us (37.5 m) x 2.0 Hz pixels on 1992 SK at echo powers above the same threshold. We completed nearly 300 runs with each setup and obtained thorough rotational phase coverage (period = 7.320 h, P. Pravec, pers. comm.). The dispersion of the echoes in time delay indicates a lower bound on 1992 SK's maximum pole-on breadth of approx. 0.4 km that is consistent with the echo bandwidth and rotation period. Variations in the cw spectral bandwidths and shapes and in the delay-Doppler images as a function of rotation phase are evident on each day, are consistent in bandwidth with each other and with the rotation period, and indicate that the asteroid is asymmetric and modesty elongated.

Benner, L. A. M.↗

Modeling the Observed Solar Cycle Variations of the Quasi-biennial Oscillation (QBO): Amplification by Wave Forcing

In several papers, the solar cycle (SC) effect in the lower atmosphere has been linked observationally to the Quasi-biennial Oscillation (QBO) of the zonal circulation, which is generated primarily by small-scale gravity waves (GW). Salby and Callaghan (2000) in particular analyzed the QBO, covering more than 40 years, and discovered that it contains a large SC signature at 20 km. With our Numerical Spectral Model (NSM), we conducted a 3D study to describe the QBO under the influence of the SC, and some results have been published (Mayr et al., GRL, 2005,2006). For a SC period of 10 years, the relative amplitude of radiative forcing is taken to vary exponentially with height, i.e., 0.2% at the surface, 2% at 50 km, 20% at 100 km and above. Applying spectral analysis to filter out and identify the SC signature, the model generates a relatively large modulation of the QBO, which reproduces the observations qualitatively. Our numerical results demonstrate that the modulation of the QBO, with constant phase relative to the SC, persist at least for 60 years. The same model run generates in the seasonal variations a hemispherically symmetric Equatorial Annual Oscillation (EAO, with 12-month period), which is confined to low latitudes like the QBO and is also modulated by the SC. Although the amplitude of the EAO is relatively small, its SC modulation is large, and it is in phase with that of the QBO. The SC modulated EAO is evidently the pathway and pacemaker for the solar influence on the QBO. To shed light on the dynamical processes involved, we present model results that show how the seasonal cycle induces the SC modulations of the EAO and QBO. Our analysis further demonstrates that the SC modulations of the QBO and EAO are amplified by the GW interaction with the flow. The GW momentum source clearly shows a SC modulation that is in phase with the corresponding modulations of the QBO and EAO. By tapping the momentum from the upward propagating GWs, the QBO and EAO apparently serve as conduits to amplify and transfer to lower altitudes the larger SC variations in the UV absorbed in the mesosphere. Our model also produces in the temperature variations of the QBO and EAO measurable SC modulations at polar latitudes near the tropopause, and such signatures have been reported in the literature. Contrary to conventional interpretation, however, we suggest that the effects are generated at least in part by the meridional circulation, and planetary waves presumably, which redistribute the energy from the equatorial region where wave forcing is very efficient and thereby amplifies the SC influence.

Mayr, Hans G.↗

Residual Stress Modeling with Phase Transformation for Wire Arc Additive Manufacturing of B91 Steel

Wire arc additive manufacturing (WAAM) is an energy-efficient manufacturing technique used for near-net-shape production of functional industrial components. However, heat accumulation during deposition and the associated mechanical and metallurgical changes result in complex residual stress profiles across the cross section of the fabricated components. These residual stresses are detrimental to the service life of the components. In this study, sequentially coupled thermomechanical analysis of WAAM B91 steel is conducted to quantify the residual stress variation across the component. The thermomechanical analysis includes a transient heat transfer model and a static stress model that incorporates the transformation-induced plasticity due to martensitic phase transformation. Here, the experimentally calibrated heat transfer model mirrors the temperature variation of the system during the deposition. The results from the stress model are validated via x-ray diffraction measurements, and the numerical results are in good agreement with the experimental data.

20 FOSSIL-FUELED POWER PLANTS↗

Primal and dual formulations of sequential gradient-restoration algorithms for trajectory optimization problems

One of the most effective first-order algorithms for solving trajectory optimization problems is the sequential gradient-restoration algorithm (SGRA). Originally developed in the primal formulation, this algorithm is extended to incorporate a dual formulation. Both the primal formulation and the dual formulation involve a sequence of two-phase cycles, each cycle including a gradient phase and a restoration phase. In turn, each iteration of the gradient phase and the restoration phase requires the solution of an auxiliary minimization problem (AMP). In the primal formulation, the AMP is solved with respect to the variations of the state, the control, and the parameter. In the dual formulation, the AMP is solved with respect to the Lagrange multipliers. A characteristic of the dual formulation is that the AMPs associated with the gradient phase and the restoration phase of SGRA can be reduced to mathematical programming problems involving a finite number of parameters as unknowns. A comparison of the primal formulation and the dual formulation is presented. The comparison is done in terms of several trajectory optimization problems having current aerospace interest.

Miele, A.↗

Mode characteristics of nonplanar double-heterojunction and large-optical-cavity laser structures

Mode behavior of nonplanar double-heterojunction (DH) and large-optical-cavity (LOC) lasers is investigated using the effective index method to model the lateral field distribution. The thickness variations of various layers for the devices discussed are correlated with the growth characteristics of liquid-phase epitaxy over topographical features (channels, mesas) etched into the substrate. The effective dielectric profiles of constricted double-heterojunction (CDH)-LOC lasers show a strong influence on transverse mode operation: the fundamental transverse mode (i.e., in the plane perpendicular to the junction) may be laterally index-guided, while the first (high)-order mode is laterally index-antiguided. The analytical model developed uses a smoothly varying hyperbolic cosine distribution to characterize lateral index variations. The waveguide model is applied to several lasers to illustrate conditions necessary to convert leaky modes to trapped ones via the active-region gain distribution. Theoretical radiation patterns are calculated using model parameters, and matched to an experimental far-field pattern.

Butler, J. K.↗

LB 1800 - A bright eclipsing cataclysmic variable and a transient X-ray source

The star LB 1800 has been discovered to be a 13th mag high-excitation cataclysmic variable exhibiting novalike characteristics and partial eclipses in its light curve. It has subsequently been identified as the optical counterpart of the transient hard X-ray source 4U 0608-49 following analysis of HEAO 1 data. Both the radial velocity and photometric variations have a period of 5.56 hr, while the K-velocity of the relatively uncomplicated radial velocity curves is 134 + or - 9 km/s, leading to a mass function of 0.058 + or - 0.003 solar mass. The dynamical and eclipse solutions point to an orbital inclination of 87 deg + or - 3 deg and a mass ratio of 0.46 + or - 0.04 for the empirical secondary mass 0.55 solar mass. The implied white dwarf mass is therefore quite high at about 1.2 solar mass. The disk size, from timings of first and last contact, was estimated to be very close to that of the secondary star. Phase-dependent, double-peak emission lines are sometimes observed. It is argued that the orbital variations in the relative strengths of the red and blue peaks arise from changing hot-spot visibility.

Buckley, D. A. H.↗

From Space Weather Toward Space Climate Time Scales: Substorm Analysis from 1993 to 2008

Magnetic activity in the Northern Hemisphere auroral region was examined during solar cycles 22 and 23 (1993- 2008). Substorms were identified from ground-based magnetic field measurements by an automated search engine. On average, 550 substorms were observed per year, which gives in total about 9000 substorms. The interannual, seasonal and solar cycle-to-cycle variations of the substorm number (R(sub ss)), substorm duration (T(sub ss)), and peak amplitude (A(sub ss)) were examined. The declining phases of both solar cycles 22 and 23 were more active than the other solar cycle phases due to the enhanced solar wind speed. The spring substorms during the declining solar cycle phase (absolute value of A(sub ss,decl)) - 500 nT) were 25% larger than the spring substorms during the ascending solar cycle years ((absolute value of A(sub ss,asc) = 400 nT). The following seasonal variation was found: the most intense substorms occurred during spring and fall, the largest substorm frequency in the Northern Hemisphere winter, and the longest-duration substorms in summer. Furthermore, we found a winter-summer asymmetry in the substorm number and duration. which is speculated to be due to the variations in the ionospheric conductivity. The solar cycle-Io-cycle variation was found in the yearly substorm number and peak amplitude. The decline from the peak substorm activity in 1994 and 2003 to the following minima took 3 years during solar cycle 22, while it took 6 years during solar cycle 23.

Tanskanen, E. I.↗

Dark Matter Velocity Distributions for Direct Detection: Astrophysical Uncertainties Are Smaller Than They Appear

The sensitivity of direct detection experiments depends on the phase-space distribution of dark matter near the Sun, which can be modeled theoretically using cosmological hydrodynamical simulations of Milky Way–like galaxies. However, capturing the halo-to-halo variation in the local dark matter speeds—a necessary step for quantifying the astrophysical uncertainties that feed into experimental results—requires a sufficiently large sample of simulated galaxies, which has been a challenge. In this Letter, we quantify this variation with nearly 100 Milky Way–like galaxies from the tng50 simulation, the largest sample to date at this resolution. Moreover, we introduce a novel phase-space scaling procedure that endows every system with a reference frame that accurately reproduces the local standard-of-rest speed of our Galaxy, providing a principled way of extrapolating the simulation results to real-world data. The ensemble of predicted speed distributions is well characterized by the standard halo model, a Maxwell-Boltzmann distribution truncated at the escape speed, though the individual distributions can deviate from it, especially at high speeds. The dark matter–nucleon cross section limits placed by these speed distributions vary by ∼ 60% about the median. This places the 1⁢𝜎 astrophysical uncertainty at or below the level of the systematic uncertainty of current ton-scale detectors, even down to the energy threshold. The predicted uncertainty remains unchanged when subselecting on those TNG 50 galaxies with merger histories similar to the Milky Way. Tabulated speed distributions, as well as Maxwell-Boltzmann fits, are provided for use in computing direct detection bounds or projecting sensitivities.

Milky Way↗

Estimation of unsteady lift on a pitching airfoil from wake velocity surveys

The results of a joint experimental and computational study on the flowfield over a periodically pitched NACA0012 airfoil, and the resultant lift variation, are reported in this paper. The lift variation over a cycle of oscillation, and hence the lift hysteresis loop, is estimated from the velocity distribution in the wake measured or computed for successive phases of the cycle. Experimentally, the estimated lift hysteresis loops are compared with available data from the literature as well as with limited force balance measurements. Computationally, the estimated lift variations are compared with the corresponding variation obtained from the surface pressure distribution. Four analytical formulations for the lift estimation from wake surveys are considered and relative successes of the four are discussed.

Zaman, K. B. M. Q.↗

Estimation of unsteady lift on a pitching airfoil from wake velocity surveys

The results of a joint experimental and computational study on the flowfield over a periodically pitched NACA0012 airfoil, and the resultant lift variation, are reported in this paper. The lift variation over a cycle of oscillation, and hence the lift hysteresis loop, is estimated from the velocity distribution in the wake measured or computed for successive phases of the cycle. Experimentally, the estimated lift hysteresis loops are compared with available data from the literature as well as with limited force balance measurements. Computationally, the estimated lift variations are compared with the corresponding variation obtained from the surface pressure distribution. Four analytical formulations for the lift estimation from wake surveys are considered and relative successes of the four are discussed.

Zaman, K. B. M. Q.↗

Periodic variations in the activity of Comet P/Halley during the 1985/1986 apparition

A search for periodic variation in the production of gas and dust by Comet Halley has been performed using narrowband photometric measurements from four sites - Lowell Observatory, Mauna Kea Observatory, Perth Observatory, and Cerro Tololo Inter-American Observatory. The method of phase dispersion minimization was applied to observations made during 164 observing nights between September 1985 and June 1986. A clear-cut variation, with a period near 7.4 days, was present throughout the postperihelion window. Less conclusive evidence of a similar period has been found in the pre-perihelion data. No indication of a shorter period or of strong sporadic activity exists in the data. The observations require that Halley's nucleus returns to essentially the same orientation with respect to the sun approximately every 7.4 days except for longer-timescale seasonal evolution. This fact precludes certain proposed models of nuclear motion.

Schleicher, David G.↗

The Lunar Opposition Surge: Observations by Clementine

The Clementine mission to the Moon in 1994 provided the first multispectral observations of the lunar opposition surge below a few degrees. The brightness of the Moon increases more than 40% between solar phase angles of 4 deg and 0 deg. The opposition effect exhibits a small wavelength dependence: the surge is -3-4% larger at 0.41 microns than at 1.00 microns. This result suggests that the principal cause of the lunar opposition surge is shadow hiding, while coherent backscatter, if present, makes only a minor contribution. The amplitude of the effect depends significantly on terrain: the surge is about 10% greater in the lunar highlands. This difference is attributed to textural variations between the two terrains. The Clementine measurements provide a new basis for deriving spectral geometric albedos, phase integrals, and Bond albedos. A value of 0.11 +/- 0.01 was found for the lunar bolometric Bond albedo. This value is at the low end of the historical published values, but not as low as the recent result of 0.080 +/- 0.002.

Buratti, Bonnie J.↗

Imitating Architectural Mortise‐Tenon Structure for Stable Ni‐Rich Layered Cathodes

Ni-rich layered oxides are the most promising cathodes for Li-ion batteries, but chemo-mechanical failures during cycling and large first-cycle capacity loss hinder their applications in high-energy batteries. Herein, by introducing spinel-like mortise-tenon structures into the layered phase of LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811), the adverse volume variations in cathode materials can be significantly suppressed. Meanwhile, these mortise-tenon structures play the role of the expressway for fast lithium-ion transport, which is substantiated by experiments and calculations. Moreover, the particles with mortise-tenon structures usually terminate with the most stable (003) facet. The new cathode exhibits a discharge capacity of 215 mAh g –1 at 0.1 C with an initial Coulombic efficiency of 97.5%, and capacity retention of 82.2% after 1200 cycles at 1 C. Importantly, this work offers a viable lattice engineering to address the stability and low initial Coulombic efficiency of the Ni-rich layered oxides, and facilitates the implementation of Li-ion batteries with high-energy density and long durability.

25 ENERGY STORAGE↗

Review and construction of interatomic potentials for molecular dynamics studies of hydrogen embrittlement in Fe─C based steels

Abstract Reducing hydrogen embrittlement in the low‐cost Fe─C based steels have the potential to significantly impact the development of hydrogen energy technologies. Molecular dynamics studies of hydrogen interactions with Fe─C steels provide fundamental information about the behavior of hydrogen at microstructural length scales, although such studies have not been performed due to the lack of an Fe─C─H ternary interatomic potential. In this work, the literature on interatomic potentials related to the Fe─C─H systems are reviewed with the aim of constructing an Fe─C─H potential from the published binary potentials. We found that Fe─C, Fe─H, and C─H bond order potentials exist and can be combined to construct an Fe─C─H ternary potential. Therefore, we constructed two such Fe─C─H potentials and demonstrate that these ternary potentials can reasonably capture hydrogen effects on deformation characteristics and deformation mechanisms for a variety of microstructural variations of the Fe─C steels, including martensite that results from γ to α phase transformation, and pearlite that results from the eutectic formation of the Fe 3 C cementite compound.

Zhou, Xiaowang↗

Reaction Mechanism of Electrodeposited ε-MnO 2 : A Proton-Centered Pathway in Aqueous Zn-Ion Systems

Aqueous Zn/MnO 2 batteries have garnered significant interests owing to their abundance, high theoretical specific capacity, safety, and low cost. However, large-scale application of these systems is limited by the incomplete understanding of the MnO 2 reaction chemistry. The different crystal lattice structures among MnO 2 polymorphs contribute to the variations in reported reaction mechanisms. Among them, ε-MnO 2 polymorph, the dominant phase in electrolytic manganese dioxide (EMD), is notably observed during the charge cycles of aqueous Zn/MnO 2 batteries. Here, in this work, we investigate the electrochemical behavior of an ε-MnO 2 cathode synthesized via electrodeposition from a ZnSO 4 and MnSO 4 electrolyte, onto a 3-dimensional carbon cloth substrate. Proton intercalation emerges as the dominant charge storage mechanism, critically enabling the reversibility of ε-MnO 2 during cycling, as revealed by operando synchrotron X-ray diffraction and X-ray absorption spectroscopy. Additionally, a proton-coupled dissolution/redeposition pathway operates alongside minor Zn 2+ intercalation, as quantified by Rietveld refinement. Morphological and chemical heterogeneities are studied by transmission X-ray microscopy further validates this reaction mechanism. These mechanistic insights provide the foundation for rationally designing Zn/MnO 2 batteries with optimized proton dynamics and charge transfer, advancing these systems as a viable solution for safe, cost-effective grid-scale energy storage.

36 MATERIALS SCIENCE↗

Spectrally resolved polarization angle across the motional Stark effect spectrum

A new diagnostic technique has been developed that couples a spectrometer and an image-intensified camera into the traditional motional Stark effect (MSE) system on DIII-D. The image-intensified camera syncs with the photo-elastic modulators to spectrally resolve the Stokes parameters across the Stark multiplet. Polarization dependent phase shift, likely from a plasma facing mirror, leads to the spectropolarimeter measuring a variation in the polarization angle across the MSE spectrum of ∼8°.

Victor, B. S. (ORCID:0000000212512922)↗