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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,441 records · Page 80
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Development of graphite/copper composites utilizing engineered interfaces

In situ measurements of graphite/copper alloy contact angles were made using the sessile drop method. The interfacial energy values obtained from these measurements were then applied to a model for the fiber matrix interfacial debonding phenomenon found in graphite/copper composites. The formation obtained from the sessile drop tests led to the development of a copper alloy that suitably wets graphite. Characterization of graphite/copper alloy interfaces subjected to elevated temperatures was conducted using Scanning Electron Microscopy, Energy Dispersive Spectroscopy, Auger Electron Spectroscopy, and X Ray Diffraction analyses. These analyses indicated that during sessile drop tests conducted at 1130 C for 1 hour, copper alloys containing greater than 0.98 at pct chromium form continuous reaction layers of approx. 10 microns in thickness. The reaction layers are adherent to the graphite surface. The copper wets the reaction layer to form a contact angle of 60 deg or less. X ray diffraction results indicate that the reaction layer is Cr3C2.

Devincent, Sandra M.↗
NASA NTRS1987

Method for stabilizing thick honeycomb core composite articles

A method of stabilizing thick honeycomb core composites is disclosed. The method comprises bonding a layer of resin impregnated woven graphite fibers to one surface of the honeycomb core, then curing the resin impregnates forming a stabilized honeycomb core. This stabilized core is then cut to net shape and the composite structure is formed by laying one or more resin impregnated fiber layers onto the stabilized core surf aces and curing the lay-up under heat and pressure forming the composite article. Also disclosed is a stabilized honeycomb subassembly formed by bonding a graphite fiber, resin impregnated layer onto one of the honeycomb core surfaces and curing the resins, then shaping the stabilized honeycomb core to the desired form.

Gary J Jacaruso↗
NASA NTRS1991

Ion beam sputtering in electric propulsion facilities

Experiments were undertaken to determine sputter yields of potential ion beam target materials, to assess the impact of charge exchange on beam diagnostics in large facilities, and to examine material erosion and deposition after a 957 hr test of a 5 kW-class ion thruster. The xenon ion sputter yield of flexible graphite was lower than other graphite forms especially at high angles of incidence. Ion beam charge exchange effects were found to hamper beam probe current collection diagnostics even at pressures from 0.7 to 1.7 mPa. Estimates of the xenon ion beam envelope were made and predictions of the thickness of sputter deposited coatings in the facility were compared with measurements.

Sovey, James S.↗
NASA NTRS1990

Chemical interactions in the aluminum-carbon and aluminum-silicon carbide systems

XPS was used to investigate the influence of O2 and H2O on the formation of aluminum carbide at Al-C and Al-SiC interfaces. It was determined that dosing the interfaces with H2O catalyzed the formation of aluminum carbide in both systems. This result is consistent with the oxidation model of carbide formation (developed to understand the kinetics of aluminum carbide formation at graphite-aluminum interfaces). These results imply that the formation of aluminum carbide in graphite- and SiC-reinforced metal-matrix composites, which severely degrades the composite mechanical properties by degrading the fiber and interface strength is catalyzed.

Maruyama, Benji↗
NASA NTRS1991

Large amounts of extinct Al-26 in interstellar grains from the Murchison meteorite

It is reported here that interstellar graphite and SiC grains recovered from the Murchison CM2 chondritic meteorite have large abundances of Mg-26 from the decay of extinct Al-26. The deduced initial Al-26/Al-27 ratios range up to 0.06 in graphite and 0.2 in SiC. This is 1200 to 4000 times the maximum values found in refractory inclusions in primitive meteorites. All proposed stellar sources of carbonaceous dust also produced Al-26, but the highest Al-26/Al-27 ratios found in these grains seem to rule out Wolf-Rayet stars and supernovae. The aluminum abundance correlates with that of nitrogen, suggesting that the aluminum condensed as aluminum nitride.

Zinner, Ernst↗
NASA NTRS1991

Atomic oxygen testing with thermal atom systems - A critical evaluation

The use of thermal atom (kinetic energy near 0.04 eV) test methods as a materials selection and screening technique for LEO spacecraft is critically evaluated in this paper. The physics and chemistry of the thermal atom environments are shown to produce specific mass loss rates (mg/sq cm per min) and reaction efficiencies (Re) radically different from those produced in the LEO environment. A response surface study shows that specific mass loss rates change rapidly with plasma-asher parameters and seldom agree with flight data. FEP Teflon is shown to react by a different mechanism than Kapton, polyethylene, or graphite. The Re (Re = volume of material removed/oxygen atom) of Kapton, polyethylene, Mylar, Tedlar, FEP Teflon, and graphite measured in a flowing afterglow apparatus are 0.001 to 0.0001 those measured with high-energy atoms (kinetic energy 1.5 eV or greater) in beam systems or in LEO. The effect of sample temperature and atom impact energy on Re is discussed. A simple kinetic model describing the reaction of atomic oxygen with polymer surfaces is developed. Guidelines and recommendations for thermal atom testing and interpretation of test results are presented.

Koontz, Steven L.↗
NASA NTRS1991

Ion beam sputtering in electric propulsion facilities

Experiments were undertaken to determine sputter yields of potential ion beam target materials, to assess the impact of charge exchange on beam diagnostics in large facilities, and to examine material erosion and deposition after a 957-hour test of a 5 kW-class ion thruster. The xenon ion sputter yield of flexible graphite was lower than other graphite forms especialy at high angles of incidence. Ion beam charge exchange effects were found to hamper beam probe current collection diagnostics even at pressures from 0.7 to 1.7 mPa. Estimates of the xenon ion beam envelope were made and predictions of the thickness of sputter deposited coatings in the facility were compared with measurements.

Sovey, James S.↗
NASA NTRS1992

Carborane Dopant Strengthens Pitch Char

Addition of small amount of soluble, organic boron compound to matrix precursor of carbon-fiber/carbon-matrix (carbon/carbon) composite increases strength and toughness of composite. Compound catalyzes graphitization of matrix, giving rise to greater degree of graphitization at lower processing temperature. Technique used to advantage in carbon/carbon materials requiring lower temperature processing, such as those with inhibited matrices or materials sensitive to changes in fiber properties.

D Kyle Brown↗
NASA NTRS1990

Automated eddy current analysis of materials

This research effort focused on the use of eddy current techniques for characterizing flaws in graphite-based filament-wound cylindrical structures. A major emphasis was on incorporating artificial intelligence techniques into the signal analysis portion of the inspection process. Developing an eddy current scanning system using a commercial robot for inspecting graphite structures (and others) has been a goal in the overall concept and is essential for the final implementation for expert system interpretation. Manual scans, as performed in the preliminary work here, do not provide sufficiently reproducible eddy current signatures to be easily built into a real time expert system. The expert systems approach to eddy current signal analysis requires that a suitable knowledge base exist in which correct decisions as to the nature of the flaw can be performed. In eddy current or any other expert systems used to analyze signals in real time in a production environment, it is important to simplify computational procedures as much as possible. For that reason, we have chosen to use the measured resistance and reactance values for the preliminary aspects of this work. A simple computation, such as phase angle of the signal, is certainly within the real time processing capability of the computer system. In the work described here, there is a balance between physical measurements and finite element calculations of those measurements. The goal is to evolve into the most cost effective procedures for maintaining the correctness of the knowledge base.

Workman, Gary L.↗
NASA NTRS1991

Measurement of the spectral signature of small carbon clusters at near and far infrared wavelengths

A significant percentage of the carbon inventory of the circumstellar and interstellar media may be in the form of large refractory molecules (or small grains) referred to as carbon clusters. At the small end, uneven numbers of carbon atoms seem to be preferred, whereas above 12 atoms, clusters containing an even number of carbon atoms appear to be preferred in laboratory chemistry. In the lab, the cluster C-60 appears to be a particularly stable form and has been nicknamed Bucky Balls because of its resemblance to a soccer ball and to geodesic domes designed by Buckminster Fuller. In order to investigate the prevalence of these clusters, and their relationship to the polycyclic aromatic hydrocarbons (PAHs) that have become the newest focus of IR astronomy, it is necessary to determine the spectroscopic characteristics of these clusters at near and far infrared wavelengths. Described here is the construction of a near to far IR laser magnetic resonance spectrometer that has been built at the University of California Berkeley in order to detect and characterize these spectra. The equipment produces carbon clusters by laser evaporation of a graphitic target. The clusters are then cooled in a supersonic expansion beam in order to simulate conditions in the interstellar medium (ISM). The expansion beam feeds into the spectrometer chamber and permits concentrations of clusters sufficiently high as to permit ultra-high resolution spectroscopy at near and far IR wavelengths. The first successful demonstration of this apparatus occurred last year when the laboratory studies permitted the observational detection of C-5 in the stellar outflow surrounding IRC+10216 in the near-IR. Current efforts focus on reducing the temperature of the supersonic expansion beam that transport the C clusters evaporated from a graphite target into the spectrometer down to temperatures as low as 1 K.

Tarter, J.↗
NASA NTRS1991

Analysis of delamination in cross ply laminates initiating from impact induced matrix cracking

Several two dimensional finite element analyses of (0 sub 2/90 sub 8/0 sub 2) glass/epoxy and graphite-epoxy composite laminates were performed to study some of the characteristics of damage development due to an impact load. A cross section through the thickness of the laminate with fixed ends, and carrying a transverse load in the center was analyzed. Inclined matrix cracks such as those produced by low velocity impact were modeled in the 90 deg ply group. The introduction of the matrix cracks caused large interlaminar tension and shear stresses in the vicinity of both crack tips in the 0/90 and 90/0 interfaces. The large interlaminar stresses at the ends of the matrix cracks indicate that matrix cracking may give rise to delamination. The ratio of mode I to total strain energy release rate at the beginning of delamination calculated at the two matrix crack tips was 60 and 28 pct., respectively, in the glass/epoxy laminate. The corresponding ratio was 97 and 77 pct. in the graphite-epoxy laminate. Thus, a significant mode I component of strain energy release rate may be present at the delamination initiation due to an impact load.

Salpekar, S. A.↗
NASA NTRS1992

Structure-to-property relationships in addition cured polymers. 4: Correlations between thermo-oxidative weight losses of norbornenyl cured polyimide resins and their composites

Relationships are identified between the thermo-oxidative stability (TOS) at 316 C of a wide variety of PMR (polymerization of monomeric reactants) addition cured polyimide resins and their corresponding graphite fiber composites. Weight loss results at 316 C confirmed the expected relationship of increasing aliphatic endcap content with decreasing TOS. Moreover, the resin TOS study also showed an unexpected linear correlation of decreasing weight loss to increasing ratio of benzylic diamine to aliphatic endcap in the range of the stoichiometries studied. Only after long term 316 C aging does the dianhydride used with the benzylic diamines become an additional factor in influencing the amount of PMR resin and composite weight losses. Also, the benzylic systems consistently showed much lower resin and composite weight losses at 316 C than the corresponding nonbenzylic norbornenyl resins and composites, except when the nonbenzylic diamine monomer does not contain a connecting group. Instead, this diamine resulted in a 316 C resin and composite weight loss that was only competitive with benzylic type diamines. Results show excellent correlation between TOS of all graphite fiber PMR composites and resins.

Alston, William B.↗
NASA NTRS1992

Reaction layer formation at the graphite/copper-chromium alloy interface

Sessile drop tests were used to obtain information about copper chromium alloys that suitably wet graphite. Characterization of graphite/copper-chromium alloy interfaces subjected to elevated temperatures were conducted using scanning electron micrography, energy dispersive spectroscopy, auger electron spectroscopy, and x ray diffraction analyses. These analyses indicate that during sessile drop tests conducted at 1130 C for one hour, copper alloys containing greater than 0.98 percent chromium form continuous reaction layers of approximately 10 micron thickness. The reaction layers adhere to the graphite surface. The copper wets the reaction layer to form a contact angle of 60 degrees or less. X ray diffraction results indicate that the reaction layer is chromium carbide. The kinetics of reaction layer formation were modelled in terms of bulk diffusion mechanisms. Reaction layer thickness is controlled initially by the diffusion of Cr out of Cu alloy and later by the diffusion of C through chromium carbide.

Devincent, Sandra M.↗
NASA NTRS1992

Composite material shear property measurement using the Iosipescu specimen

A detailed evaluation of the suitability of the Iosipescu specimen tested in the modified Wyoming fixture is presented. Finite element analysis and moire interferometry are used to assess the uniformity of the shear stress field in the test section of unidirectional and cross-ply graphite-epoxy composites. The nonuniformity of the strain field and the sensitivity of some fiber orientations to the specimen/fixture contact mechanics are discussed. The shear responses obtained for unidirectional and cross-ply graphite-epoxy composites are discussed and problems associated with anomalous behavior are addressed. An experimental determination of the shear response of a range of material systems using strain gage instrumentation and moire interferometry is performed.

Ho, Henjen↗
NASA NTRS1992

Pregraphitic and poorly graphitised carbons in porous chondritic micrometeorites

Two forms of crystalline carbon in porous chondritic micrometeorites W7029E5, U2011C2, and U2022C7/C8 are mixed layered pregraphitic carbons with C/(C+H+O+N) (at. pct) about 0.45. This bulk composition is inferred from the presence of three groupings of d(002) basal spacings at 0.45 nm, 0.37 nm, and 0.348 nm. Mixed layered carbons represent incomplete carbonization and graphitization of precursor material. In U2022C7/C8, carbonization mostly involved volatile loss. The formation of pregraphitic carbons indicates a sustained thermal regime in parent bodies of these micrometeorities (i.e., short-period comets, outer-belt asteroids, or protocomet nuclei). Temperatures of the sustained thermal regime remain unspecified, but carbon reactions were probably facilitated by catalytic support from layer silicates in these samples. Poorly graphitized carbon in U2022C7/C8 formed during a transient thermal event which is most likely flash-heating during micrometeoroid deceleration in the earth's atmosphere.

Rietmeijer, Frans J. M.↗
NASA NTRS1992

Milling and mechanical alloying of inorganic nonmetallics

The versatility of high energy grinding for instigating mechanochemical reactions in inorganic systems has been studied. High-energy grinding can be used to produce amorphous carbon from synthetic graphite and some forms of natural graphite. Elemental sulfur can be amorphized by prolonged energy grinding. The presence of iron resulting from wear of the grinding media strongly affects phase transformations of alphaFe2O3 and mechanochemical reactions of this phase with ZnO and NiO. Data obtained confirm that low-temperature mechanochemical method is a robust process route for production of a wide range of materials.

Kosmac, T.↗
NASA NTRS1992

Design of a pressurized lunar rover

A pressurized lunar rover is necessary for future long-term habitation of the moon. The rover must be able to safely perform many tasks, ranging from transportation and reconnaissance to exploration and rescue missions. Numerous designs were considered in an effort to maintain a low overall mass and good mobility characteristics. The configuration adopted consists of two cylindrical pressure hulls passively connected by a pressurized flexible passageway. The vehicle has an overall length of 11 meters and a total mass of seven metric tons. The rover is driven by eight independently powered two meter diameter wheels. The dual-cylinder concept allows a combination of articulated frame and double Ackermann steering for executing turns. In an emergency, the individual drive motors allow the option of skid steering as well. Two wheels are connected to either side of each cylinder through a pinned bar which allows constant ground contact. Together, these systems allow the rover to easily meet its mobility requirements. A dynamic isotope power system (DIPS), in conjunction with a closed Brayton cycle, supplied the rover with a continuous supply of 8.5 kW. The occupants are all protected from the DIPS system's radiation by a shield of tantalum. The large amount of heat produced by the DIPS and other rover systems is rejected by thermal radiators. The thermal radiators and solar collectors are located on the top of the rear cylinder. The solar collectors are used to recharge batteries for peak power periods. The rover's shell is made of graphite-epoxy coated with multi-layer insulation (MLI). The graphite-epoxy provides strength while the thermally resistant MLI gives protection from the lunar environment. An elastomer separates the two materials to compensate for the thermal mismatch. The communications system allows for communication with the lunar base with an option for direct communication with earth via a lunar satellite link. The various links are combined into one signal broadcast in the S-band at 2.3 GHz. The rover is fitted with a parabolic reflector disk for S-band transmission, and an omnidirectional antenna for local extravehicular activity (EVA) communication. The rover's guidance, navigation, and control subsystem consists of an inertial guidance system, an orbiting lunar satellite, and an obstacle avoidance system. In addition, the rover is equipped with a number of external fixtures including two telerobotic arms, lights, cameras, EVA storage, manlocks, a docking fixture, solar panels, thermal radiators, and a scientific airlock. In conclusion, this rover meets all of the design requirements and clearly surpasses them in the areas of mobility and maneuverability.

Bhardwaj, Manoj↗
NASA NTRS1991

Comparison of hand laid-up tape and filament wound composite cylinders and panels with and without impact damage

The results of this experimental comparison of filament wound control (unimpacted) cylinders loaded to failure in axial compression indicates that one fiber cross-over location has no effect on the failure mode or strain in thick walled filament wound graphite-epoxy specimens with stacking sequence (plus or minus 45/90) sub 3s. A comparison between filament wound and hand laid-up tape control cylinders indicates that there is little or no difference in the response of cylinders constructed by using two different fabrication methods, however, unimpacted panels with many fiber cross-overs fail at up to 15 percent lower strains than panels with no fiber cross-overs. A comparison of samples subjected to low speed impact damage prior to compressive loading indicates that impact damage reduces the strain at failure by over 60 percent in tape and filament wound graphite-epoxy cylinders and in tape flat panels. The presence of fiber cross-overs was observed to reduce the strength of filament wound impact-damaged panels, but to have no significant effect on the strength of filament wound impact-damaged cylinders.

Jegley, Dawn C.↗