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At least 1,441 records · Page 80

Structural and vibrational study of 2-MethoxyEthylAmmonium Nitrate (2-OMeEAN): Interpretation of experimental results with ab initio molecular dynamics

In this work we report an analysis of the bulk phase of 2-methoxyethylammonium nitrate based on ab initio molecular dynamics. The structural and dynamical features of the ionic liquid have been characterized and the computational findings have been compared with the experimental X-ray diffraction patterns, with infrared spectroscopy data, and with the results obtained from molecular dynamics simulations. The experimental infrared spectrum was interpreted with the support of calculated vibrational density of states as well as harmonic frequency calculations of selected gas phase clusters. Particular attention was addressed to the high frequency region of the cation (ω > 2000 cm{sup −1}), where the vibrational motions involve the NH{sub 3}+ group responsible for hydrogen bond formation, and to the frequency range 1200-1400 cm{sup −1} where the antisymmetric stretching mode (ν{sub 3}) of nitrate is found. Its multiple absorption lines in the liquid arise from the removal of the degeneracy present in the D{sub 3h} symmetry of the isolated ion. Our ab initio molecular dynamics leads to a rationalization of the frequency shifts and splittings, which are inextricably related to the structural modifications induced by a hydrogen bonding environment. The DFT calculations lead to an inhomogeneous environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Harmonically structured ULF pulsations observed by the AMPTE CCE magnetic field experiment

Spectrograms of ULF waves in the 0 to 80 mHz frequency range have been prepared from magnetic field data obtained by the elliptically orbiting AMPTE/CCE satellite (with an apogee of approximately 8.8 earth radii). The most prominent feature of these spectrograms (which cover a full 15.6-h orbit) is the presence of harmonically structured, azimuthally polarized pulsations in the outer magnetosphere during daytime hours. The frequencies of these pulsations decrease with increasing radial distance from the earth, indicating that they represent independent resonances of local magnetic flux tubes. The latitudinal structure of these harmonic pulsations, observed as AMPTE/CCE traveled to + or - 16 deg magnetic latitude, is consistent with accepted field line resonance models.

Engebretson, M. J.↗

Dispersion in Nb microstrip transmission lines at submillimeter wave frequencies

We have measured the effects of dispersion on the resonant mode frequencies of open-ended Nb-SiO(x)-Nb microstrip transmission lines over a frequency range from 50 to 800 GHz. Submicron Nb/Al-AlOx/Nb Josephson junctions were used as both voltage-controlled oscillators and detectors to sample the high order modes of the resonators. The resonator modes are equally spaced up to about 550 GHz where the mode spacing start to decrease gradually to a minimum above the gap frequency of about 700 GHz and then increases. Results are in good agreement with the expected theoretical behavior based on the Mattis-Bardeen conductivity of the superconductor line.

Javadi, H. H. S.↗

Local Oscillator Sub-Systems for Array Receivers in the 1-3 THz Range

Recent results from the Heterodyne Instrument for the Far-Infrared (HIFI) on the Herschel Space Telescope have confirmed the usefulness of high resolution spectroscopic data for a better understanding of our Universe. This paper will explore the current status of tunable local oscillator sources with emphasis on building a multi-pixel LO subsystem for the scientifically important CII line around 1908 GHz. Recent results have shown that over 50 microwatts of output power at 1.9 THz are possible with an optimized single pixel LO chain. These power levels are now sufficient to pump array receivers in this frequency range. Further power enhancement can be obtained by cooling the chain to 120 K or by utilizing in-phase power combining technology.

local oscillators↗

Excitation of Coupled Slotline Mode in Finite Ground CPW with Unequal Ground Plane Widths

The coupling between the desired CPW mode and the unwanted coupled slotline mode is presented for finite ground coplanar waveguides with unequal ground plane widths. Measurements, quasi-static conformal mapping, and Finite-Difference Time-Domain analysis are performed to determine the dependence of the slotline mode excitation on the physical dimensions of the FGC line and on the frequency range of operation. It is shown that the ratio of the slotline mode to the CPW mode can be as high as 18 dB. The use of airbridges is shown to reduce the slotline mode by 15 dB, but that the slotline mode fully reestablishes itself after 2000 microns. Furthermore, these results are independent of frequency.

Ponchak, George E.↗

Metal Standards for Waveguide Characterization of Materials

Rectangular-waveguide inserts that are made of non-ferromagnetic metals and are sized and shaped to function as notch filters have been conceived as reference standards for use in the rectangular- waveguide method of characterizing materials with respect to such constitutive electromagnetic properties as permittivity and permeability. Such standards are needed for determining the accuracy of measurements used in the method, as described below. In this method, a specimen of a material to be characterized is cut to a prescribed size and shape and inserted in a rectangular- waveguide test fixture, wherein the specimen is irradiated with a known source signal and detectors are used to measure the signals reflected by, and transmitted through, the specimen. Scattering parameters [also known as "S" parameters (S11, S12, S21, and S22)] are computed from ratios between the transmitted and reflected signals and the source signal. Then the permeability and permittivity of the specimen material are derived from the scattering parameters. Theoretically, the technique for calculating the permeability and permittivity from the scattering parameters is exact, but the accuracy of the results depends on the accuracy of the measurements from which the scattering parameters are obtained. To determine whether the measurements are accurate, it is necessary to perform comparable measurements on reference standards, which are essentially specimens that have known scattering parameters. To be most useful, reference standards should provide the full range of scattering-parameter values that can be obtained from material specimens. Specifically, measurements of the backscattering parameter (S11) from no reflection to total reflection and of the forward-transmission parameter (S21) from no transmission to total transmission are needed. A reference standard that functions as a notch (band-stop) filter can satisfy this need because as the signal frequency is varied across the frequency range for which the filter is designed, the scattering parameters vary over the ranges of values between the extremes of total reflection and total transmission. A notch-filter reference standard in the form of a rectangular-waveguide insert that has a size and shape similar to that of a material specimen is advantageous because the measurement configuration used for the reference standard can be the same as that for a material specimen. Typically a specimen is a block of material that fills a waveguide cross-section but occupies only a small fraction of the length of the waveguide. A reference standard of the present type (see figure) is a metal block that fills part of a waveguide cross section and contains a slot, the long dimension of which can be chosen to tailor the notch frequency to a desired value. The scattering parameters and notch frequency can be estimated with high accuracy by use of commercially available electromagnetic-field-simulating software. The block can be fabricated to the requisite precision by wire electrical-discharge machining. In use, the accuracy of measurements is determined by comparison of (1) the scattering parameters calculated from the measurements with (2) the scattering parameters calculated by the aforementioned software.

Lambert, Kevin M.↗

Quantum metrology of low-frequency electromagnetic modes with frequency upconverters

We present the RF Quantum Upconverter (RQU) and describe its application to quantum metrology of electromagnetic modes between dc and the very high frequency band (VHF) ( ≲ 300 MHz). The RQU uses a Josephson interferometer made up of superconducting loops and Josephson junctions to implement a parametric interaction between a low-frequency electromagnetic mode (between dc and VHF) and a mode in the microwave C Band ( ∼ 5 GHz), analogous to the radiation pressure interaction between electromagnetic and mechanical modes in cavity optomechanics. We analyze RQU performance with quantum amplifier theory and show that the RQU can operate as a quantum-limited op-amp in this frequency range. It can also use nonclassical measurement protocols equivalent to those used in cavity optomechanics, including back-action evading (BAE) measurements, sideband cooling, and two-mode squeezing. These protocols enable experiments using dc VHF electromagnetic modes as quantum sensors with sensitivity better than the standard quantum limit (SQL). We demonstrate signal upconversion from low frequencies to the microwave C band using an RQU and show a phase-sensitive gain (extinction ratio) of 46.9 dB , which is a necessary step towards the realization of full BAE. Published by the American Physical Society 2025

Kuenstner, Stephen E. (ORCID:0000000346128846)↗

Shuttle electrical environment

Part of an AFGL payload flown on the STS-4 mission consisted of experiments to measure in-situ electric fields, electron densities, and vehicle charging. During this flight some 11 hours of data were acquired ranging from 5 minute snapshots up to continuous half-orbits. These experiments are described and results presented for such vehicle induced events as a main engine burn, thruster firings and water dumps in addition to undisturbed periods. The main characteristic of all the vehicle induced events is shown to be an enhancement in the low frequency noise (less than 2 kHz), in both the electrostatic and electron irregularity (delta N/N) spectra. The non-event results indicate that the electrostatic broadband emissions show a white noise characteristic in the low frequency range up to 2 kHz at an amplitude of 10 db above the shuttle design specification limit, falling below that limit above 10 kHz. The vehicle potential remained within the range of -3 to +1 volt throughout the flight which exhibits normal behavior for a satellite in a low equatorial orbit.

Smiddy, M.↗

Effects of local vibrations on the dynamics of space truss structures

The paper discusses the influence of local member vibrations on the dynamics of repetitive space truss structures. Several focus problems wherein local member vibration modes are in the frequency range of the global truss modes are discussed. Special attention is given to defining methods that can be used to identify the global modes of a truss structure amidst many local modes. Significant interactions between the motions of local member vibrations and the global behavior are shown to occur in truss structures when: (1) the natural frequencies of the individual members for clamped-clamped boundary conditions are in the vicinity of the global truss frequency; and (2) the total mass of the individual members represents a large portion of the mass of the whole structure. The analysis is carried out with a structural analysis code which uses exact member theory. The modeling detail required using conventional finite element codes to adequately represent such a class of problems is examined. The paper concludes with some practical considerations for the design and dynamic testing of structures which might exhibit such behavior.

Warnaar, Dirk B.↗

Active control of multi-dimensional random sound in ducts

Previous work has demonstrated how active control may be applied to the control of random noise in ducts. These implementations, however, have been restricted to frequencies where only plane waves are propagating in the duct. In spite of this, the need for this technology at low frequencies has progressed to the point where commercial products that apply these concepts are currently available. Extending the frequency range of this technology requires the extension of current single channel controllers to multi-variate control systems as well as addressing the problems inherent in controlling higher order modes. The application of active control in the multi-dimensional propagation of random noise in waveguides is examined. An adaptive system is implemented using measured system frequency response functions. Experimental results are presented illustrating attained suppressions of 15 to 30 dB for random noise propagating in multiple modes.

Silcox, R. J.↗

On-Wafer Measurement of a Silicon-Based CMOS VCO at 324 GHz

The world s first silicon-based complementary metal oxide/semiconductor (CMOS) integrated-circuit voltage-controlled oscillator (VCO) operating in a frequency range around 324 GHz has been built and tested. Concomitantly, equipment for measuring the performance of this oscillator has been built and tested. These accomplishments are intermediate steps in a continuing effort to develop low-power-consumption, low-phase-noise, electronically tunable signal generators as local oscillators for heterodyne receivers in submillimeter-wavelength (frequency > 300 GHz) scientific instruments and imaging systems. Submillimeter-wavelength imaging systems are of special interest for military and law-enforcement use because they could, potentially, be used to detect weapons hidden behind clothing and other opaque dielectric materials. In comparison with prior submillimeter- wavelength signal generators, CMOS VCOs offer significant potential advantages, including great reductions in power consumption, mass, size, and complexity. In addition, there is potential for on-chip integration of CMOS VCOs with other CMOS integrated circuitry, including phase-lock loops, analog- to-digital converters, and advanced microprocessors.

Samoska, Lorene↗

Miniature Packaging Concept for LNAs in the 200-300 GHz Range

In this work, we describe new miniaturized low noise amplifier modules which we developed for incorporation in small-scale satellites or Cubesats, and which exhibit similar or better performance compared to previously reported LNAs in the literature. We have targeted the WR4 (170-260 GHz) and WR3 (220-325 GHz) waveguide bands for the module development. The modules include two different methods of E-plane probes which have been developed for low loss, and stability at high frequencies. MMIC LNAs were also developed for these frequency ranges and fabricated in Northrop Grumman Corporation's 35 nm InP HEMT technology, and we have experimentally verified that noise performance is lower than reported in prior work. The best results include a miniature LNA module with 550K noise at 224 GHz, and a wideband LNA module with 15 dB gain from 230-280 GHz.

WR4↗

Theoretical Investigation of Relaxation Dynamics in Au 38 (SH) 24 Thiolate-Protected Gold Nanoclusters

A subtle change in the electronic structure of thiolate protected noble nanoparticles can result distinctive relaxation dynamics. Thus, relaxation dynamics investigations on different sizes and structures of thiolate protected gold nanocluster will reveal their physical and chemical properties for further development of catalytic applications. In this work, we performed nonradiative relaxation dynamics of the Au 38 (SH) 24 nanocluster theoretically to describe electron relaxation dynamics. The core and higher excited states involving semiring motifs lying in the energy range 0.00-2.01 eV are investigated using the time-dependent density functional theory (TDDFT). The surface hopping method with decoherence correction, augmented with a real-time approach to DFT technique is used to assess the quantum dynamics. The Au 23 core relaxations were found to be in a picosecond timescale in the range of 2.0 – 8.2 ps. The higher excited states that consist of core- semiring mixed or semiring states gave ultrafast decay time constants in the range of 0.6 - 4.9 ps. Our calculations predicted that the slowest individual state decay of S11 or the slowest combined S 11 -S 12 , S 1 -S 2 -S 6 -S 7 and S 4 -S 5 - S 9 -S 10 decay involves intracore relaxations. The analysis of the phonon spectral densities and the ground state vibrational frequencies suggested that the low frequency (25 cm -1 ) coherent phonon emission reported experimentally could be the bending of the biicosahedral Au 23 core or the “fan blade twisting” mode of two icosahedral units occurring in a similar frequency range.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The study of electrical conduction mechanisms

The dielectric response of lunar fines 74241,2 is presented in the audio-frequency range and under lunarlike conditions. Results suggest that volatiles are released during storage and transport of the lunar sample. Apparently, subsequent absorption of volatiles on the sample surface alter its dielectric response. The assumed volatile influence disappear after evacuation. A comparison of the dielectric properties of lunar and terrestrial materials as a function of density, temperature, and frequency indicates that if the lunar simulator analyzed were completely devoid of atmospheric moisture it would present dielectric losses smaller than those of the lunar sample. It is concluded that density prevails over temperature as the controlling factor of dielectric permittivity in the lunar regolith and that dielectric losses vary slowly with depth.

Morrison, H. F.↗

Observational features of field line resonances excited by solar wind pressure variations on 4 September 1984

The purpose of the study is to establish the most probable excitation mechanism of the magnetic storm occurred after an inverse sudden impulse on September 4, 1984. Geomagnetic pulsations in the Pc5-frequency range observed at magnetometer stations are evaluated. Attention is focused on two events of the enhanced activity: for the first one, conjugate observations on the ground are assessed and then compared with satellite-based observations on adjacent field lines; for the second event two hours later, data from an extended azimuthal range is employed. It is pointed out that the observations are consistent with the theory of filed-line resonance, and may be interpreted as excitations caused by pressure variations in the solar wind. Both magnetopause-surface waves and cavity resonances are excited; the cavity mode drives toroidal field-line oscillations at locations where its frequency matches the resonance frequency of the field lines.

Warnecke, J.↗

Acoustical evaluation of the NASA Lewis 9 by 15 foot low speed wind tunnel

The test section of the NASA Lewis 9- by 15-Foot Low Speed Wind Tunnel was acoustically treated to allow the measurement of acoustic sources located within the tunnel test section under simulated free field conditions. The treatment was designed for high sound absorption at frequencies above 250 Hz and to withstand tunnel airflow velocities up to 0.2 Mach. Evaluation tests with no tunnel airflow were conducted in the test section to assess the performance of the installed treatment. This performance would not be significantly affected by low speed airflow. Time delay spectrometry tests showed that interference ripples in the incident signal resulting from reflections occurring within the test section average from 1.7 dB to 3.2 dB wide over a 500 to 5150 Hz frequency range. Late reflections, from upstream and downstream of the test section, were found to be insignificant at the microphone measuring points. For acoustic sources with low directivity characteristics, decay with distance measurements in the test section showed that incident free field behavior can be measured on average with an accuracy of +/- 1.5 dB or better at source frequencies from 400 Hz to 10 kHz. The free field variations are typically much smaller with an omnidirectional source.

Dahl, Milo D.↗

The submillimeter-wave spectrum of propionitrile (C2H5CN)

The laboratory millimeter-wave and submillimeter-wave rotational spectrum of propionitrile (ethyl cyanide, C2H5CN) in its ground vibrational state has been extended through J = 70 and K(sub a) = 36. Transitions measured in this study are in the frequency range 250-610 GHz. A fit of 952 transitions including 732 new measurements to a Watson A-reduced Hamiltonian has yielded a complete set of quartic and sextic distortion constants, in addition to six octic distortion constants. Internal rotation and hyperfine splittings have not been resolved, so they are not included in the analysis. Predicted transition frequencies for a large number of additional transitions of interest to radioastronomers are provided.

Pearson, J. C.↗

Inlet Noise Reduction by Shielding for the Blended-Wing-Body Airplane

Noise shielding benefits associated with an advanced unconventional subsonic transport concept, the Blended-Wing-Body, were studied using a 4- percent scale, 3-engine nacelle model. The study was conducted in the Anechoic Noise Research Facility at NASA Langley Research Center. A high- frequency, wideband point source was placed inside the nacelles of the center engine and one of the side engines in order to simulate broadband engine noise. The sound field of the model was measured with a rotating microphone array that was moved to various stations along the model axis and with a fixed array of microphones that was erected behind the model. Ten rotating microphones were traversed a total of 22 degrees in 2-degree increments. Seven fixed microphones covered an arc that extended from a point in the exhaust exit plane of the center engine (and directly below its centerline) to a point 30 degrees above the jet centerline. While no attempt was made to simulate the noise emission characteristics of an aircraft engine, the model source was intended to radiate sound in a frequency range encompassing 1, 2, and 3 times the blade passage of a typical full-scale engine. In this study, the Blended-Wing-Body model was found to provide significant shielding of inlet noise. In particular, noise radiated downward into the forward sector was reduced by 20 to 25 dB overall in the full-scale frequencies from 2000 to 4000 Hz, decreasing to 10 dB or less at the lower frequencies. Also, it was observed that noise associated with the exhaust radiates into the sector directly below the model downstream to reduce shielding efficiency.

Clark, Lorenzo R.↗