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At least 1,441 records · Page 80

Co{sup 2+} Substituted ZnCuFe{sub 2}O{sub 4} (0.0 ≤ x ≤ 0.5) Ferrites: Synthesis, Magneto-structural and Optical Properties for Their Photocatalytic Performance

The cobalt (Co{sup 2+}) has been successively substituted in ZnCuFe{sub 2}O{sub 4} to obtain Zn{sub 0.5−x}Co{sub x}Cu{sub 0.5}Fe{sub 2}O{sub 4} (0.0 ≤ x ≤ 0.5) ferrites by auto-combustion technique. Prior to photocatalytic degradation, all as-synthesized ferrites were characterized to study their structure, composition, morphology, magnetic and optical behavior. The shifting of tetrahedral as well as octahedral stretching peaks towards higher frequencies observed in the Fourier transform infrared spectroscopy indicates that Co{sup 2+} ion is substituted in ZnCuFe{sub 2}O{sub 4}. X-ray diffraction pattern confirms the formation of single-phase cubic spinel with decrease in average lattice constant from 8.3915 to 8.3224 Å with increase in Co{sup 2+} substitution. The photocatalytic performance of obtained ferrite catalyst was determined using methylene blue (MB) as model dye under visible light and direct sunlight. The degradation of MB with as-obtained photocatalyst under sunlight improves (91%) which proves the effective utilization of visible light active magnetic photocatalyst.

36 MATERIALS SCIENCE↗

57 Fe Mössbauer study of Lu 2 Fe 3 Si 5 iron silicide superconductor

With the advent of Fe–As based superconductivity it has become important to study how superconductivity manifests itself in details of 57 Fe Mössbauer spectroscopy of conventional, Fe-bearing superconductors. The iron-based superconductor Lu 2 Fe 3 Si 5 has been studied by 57 Fe Mössbauer spectroscopy over the temperature range from 4.4 K to room temperature with particular attention to the region close to the superconducting transition temperature (T c =6.1 K). Consistent with the two crystallographic sites for Fe in this structure, the observed spectra appear to have a pattern consisting of two doublets over the whole temperature range. Furthermore, the value of Debye temperature was estimated from temperature dependence of the isomer shift and the total spectral area and compared with the specific heat capacity data. Neither abnormal behavior of the hyperfine parameters at or near T c , nor phonon softening were observed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Preparation and characterization of biodegradable Mg-Zn-Ca/MgO nanocomposites for biomedical applications

Highlights: • Novel biodegradable Mg-Zn-Ca/MgO matrix composites, were devised and prepared using high shear melt conditioning. • The excellent interfacial bonding between MgO particles and α-Mg matrix was observed via HRTEM and FFT pattern analysis. • The optimum solution treatment and the addition of MgO nanoparticles hugely enhanced corrosion resistance of nanocomposites. • The yield tensile strength (YTS) increased by 22.81% with 0.5% MgO addition, while the ductility did not mainly deteriorate. - Abstract: In order to improve the corrosion resistance and mechanical properties of magnesium alloys for biomedical implant applications, novel biodegradable Mg-3Zn-0.2Ca (wt%) matrix composites, reinforced by adding various contents of MgO nanoparticles (0.1, 0.2, 0.3, 0.5 wt%), were devised and prepared using high shear melt conditioning. An optimum solution treatment (450 °C, 48 h) and subsequent hot extrusion was carried out to produce the Mg-3Zn-0.2Ca/MgO composites. It was found that the as-extruded composite exhibited a fine grain structure with relatively uniformly distributed MgO particles. The orientation relationships (ORs) of (1 1 1){sub MgO} ~ 2.62° from (0 0 0 2){sub α-Mg} and [0 −1 1]{sub MgO} // [2 −1 −1 0]{sub α-Mg}, were observed between the MgO particles and the α-Mg matrix via high resolution transmission electron microscopy (HRTEM) investigation and fast Fourier transform (FFT) pattern analysis, verifying the excellent interfacial bonding between the phases. Additionally, a substantial reduction in the secondary phase content was found in the solution treated sample. In vitro immersion, electrochemical, and mechanical tensile tests were used to characterize the corrosion behavior and mechanical properties. The ultimate tensile strength (UTS) increased to 329.03 ± 2.01 MPa and the yield tensile strength (YTS) increased by 22.81% with 0.5 wt% MgO loading, while the ductility did not substantially deteriorate. The polarization resistance (R{sub p}) of the composite was shown to increase from 0.95 kΩ cm{sup 2} to 2.02 kΩ cm{sup 2} with the addition of 0.2 wt% MgO. With increasing MgO content, agglomeration of the MgO particles was detected in the analyzed composite, resulting in decreased ductility and the occurrence of pitting corrosion.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Electrical properties and conduction mechanism study by OLPT model of NaZnPO4 compound

Highlights: • The crystal structure was resolved using Fullproof program. • The conduction in NaZn PO{sub 4} is insured by OLPT model. • Ac conductivity of NaZn PO{sub 4} compound obeys the Joncher’s law. - Abstract: A polycrystalline sample with NaZnPO{sub 4} stoichiometry was synthesized by the conventional solid-state reaction and then identified and characterized by X-ray powder diffraction, Raman spectroscopy and impedance spectroscopy. The X-ray diffraction pattern revealed that the composite represents a single phase that crystallizes in the monoclinic system with a P2{sub 1}/n space group. All vibration modes of tetrahedral PO{sub 4} appeared in the Raman spectrum. Besides, the electrical conductivity behavior of the title compound was analysed as a function of frequency ranging from 209 Hz to 1 MHz and at a temperature interval ranging from 578 K to 728 K by means of impedance spectroscopy to elucidate the conduction mechanism in this compound. The temperature dependence of frequency exponent ′s′ showed that the conduction in NaZnPO{sub 4} is insured by the overlapping large polaron tunneling (OLPT) model. A correlation between electrical and structural properties was also depicted.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Linking Stream Chemistry to Subsurface Redox Architecture

As drinking-water scarcity grows worldwide, we need to improve predictions of the quantity and quality of our water resources. An overarching problem for model improvement is that we do not know the geological structure of aquifers in sufficient detail. In this work, we demonstrate that mineral-water reactions imprint structure in the subsurface that impacts the flow and transport of some chemical species. Specifically, pyrite, a ubiquitous mineral, commonly oxidizes and depletes in the upper layers of the weathering profile in most humid watersheds, only remaining at depths of meters. We hypothesize that variations in concentrations (C) of pyrite-derived sulfate released into rivers as a function of discharge (q) reflect the rate-limiting step and depth of pyrite-oxidizing layers. We found that log C - log q behaviors thus differ in small and large watersheds in the Susquehanna River Basin as well as in selected watersheds in the Western United States. Although coal mining changes pyrite oxidation from closed to open system with respect to O 2 , patterns in stream chemistry as a function of discharge are consistent with deep and shallow pyrite oxidation zones in small and large watersheds respectively. Therefore, understanding the subsurface patterns of mineral reactions and how they affect the architecture of aquifers will elucidate patterns of changing river chemistry and our ability to manage water resources in the future under accelerated land use and climate change.

54 ENVIRONMENTAL SCIENCES↗

Robust observations of land-to-atmosphere feedbacks using the information flows of FLUXNET

Feedbacks between atmospheric processes like precipitation and land surface fluxes including evapotranspiration are difficult to observe, but critical for understanding the role of the land surface in the Earth System. To quantify global surface-atmosphere feedbacks we use results of a process network (PN) applied to 251 eddy covariance sites from the LaThuile database to train a neural network across the global terrestrial surface. There is a strong land–atmosphere coupling between latent (LE) and sensible heat flux (H) and precipitation (P) during summer months in temperate regions, and between H and P during winter, whereas tropical rainforests show little coupling seasonality. Savanna, shrubland, and other semi-arid ecosystems exhibit strong responses in their coupling behavior based on water availability. Feedback couplings from surface fluxes to P peaks at aridity (P/potential evapotranspiration ET p ) values near unity, whereas coupling with respect to clouds, inferred from reduced global radiation, increases as P/ET p approaches zero. Spatial patterns in feedback coupling strength are related to climatic zone and biome type. Information flow statistics highlight hotspots of (1) persistent land–atmosphere coupling in sub-Saharan Africa, (2) boreal summer coupling in the central and southwestern US, Brazil, and the Congo basin and (3) in the southern Andes, South Africa and Australia during austral summer. Our data-driven approach to quantifying land atmosphere coupling strength that leverages the global FLUXNET database and information flow statistics provides a basis for verification of feedback interactions in general circulation models and for predicting locations where land cover change will feedback to climate or weather.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A magnon scattering platform

Significance This work describes a general scattering platform that uses magnons to explore the underlying properties of target materials. In this work we show how both phase and amplitude of magnons can be imaged using a nitrogen vacancy center magnetometer and how the scattered pattern of waves can be used to infer geometric and magnetic properties of a target material. To demonstrate this new experimental methodology we use a permalloy disk as our target and show that even with such a simple target unexpected behavior is observed. In addition, we provide a theoretical framework to reconstruct the properties of the target.

36 MATERIALS SCIENCE↗

Travel Patterns and Characteristics of the Population from Zero Vehicle Households in New York State

This study explores how zero vehicle and vehicle deficit (i.e., fewer cars than licensed drivers) households manage their daily travel needs and overall mobility decisions. Using the 2009, 2017, and 2022 National Household Travel Survey, the research team investigates key patterns such as trip rates, trip distances, travel modes, and trip purposes, as well as evaluates the impact of information and communication technologies like online shopping and telework. Additionally, the team evaluates how the COVID-19 pandemic has influenced travel behavior, with a focus on New York State, where a significant number of zero vehicle and vehicle deficit households offer unique perspectives on the challenges and opportunities associated with limited vehicle access.

99 GENERAL AND MISCELLANEOUS↗

Heat transfer to a full-coverage film-cooled surface with 30 degree slant-hole injection

Heat transfer behavior was studied in a turbulent boundary layer with full coverage film cooling through an array of discrete holes and with injection 30 deg to the wall surface in the downstream direction. Stanton numbers were measured for a staggered hole pattern with pitch-to-diameter ratios of 5 and 10, an injection mass flux ratio range of 0.1 to 1.3, and a range of Reynolds number Re sub x of 150,000 to 5 million. Air was used as the working fluid, and the mainstream velocity varied from 9.8 to 34.2 m/sec (32 to 112 ft/sec). The data were taken for secondary injection temperature equal to the wall temperature and also equal to the mainstream temperature. The data may be used to obtain Stanton number as a continuous function of the injectant temperature by use of linear superposition theory. The heat transfer coefficient is defined on the basis of a mainstream-to-wall temperature difference. This definition permits direct comparison of performance between film cooling and transpiration cooling. A differential prediction method was developed to predict the film cooling data base. The method utilizes a two-dimensional boundary layer program with routines to model the injection process and turbulence augmentation. The program marches in the streamwise direction, and when a row of holes is encountered, it stops and injects fluid into the boundary layer. The turbulence level is modeled by algebraically augmenting the mixing length, with the augmentation keyed to a penetration distance for the injected fluid.

Crawford, M. E.↗

Feature Extraction of Event-Related Potentials Using Wavelets: An Application to Human Performance Monitoring

This report describes the development and evaluation of mathematical models for predicting human performance from discrete wavelet transforms (DWT) of event-related potentials (ERP) elicited by task-relevant stimuli. The DWT was compared to principal components analysis (PCA) for representation of ERPs in linear regression and neural network models developed to predict a composite measure of human signal detection performance. Linear regression models based on coefficients of the decimated DWT predicted signal detection performance with half as many f ree parameters as comparable models based on PCA scores. In addition, the DWT-based models were more resistant to model degradation due to over-fitting than PCA-based models. Feed-forward neural networks were trained using the backpropagation,-, algorithm to predict signal detection performance based on raw ERPs, PCA scores, or high-power coefficients of the DWT. Neural networks based on high-power DWT coefficients trained with fewer iterations, generalized to new data better, and were more resistant to overfitting than networks based on raw ERPs. Networks based on PCA scores did not generalize to new data as well as either the DWT network or the raw ERP network. The results show that wavelet expansions represent the ERP efficiently and extract behaviorally important features for use in linear regression or neural network models of human performance. The efficiency of the DWT is discussed in terms of its decorrelation and energy compaction properties. In addition, the DWT models provided evidence that a pattern of low-frequency activity (1 to 3.5 Hz) occurring at specific times and scalp locations is a reliable correlate of human signal detection performance.

Trejo, Leonard J.↗

Feature extraction of event-related potentials using wavelets: an application to human performance monitoring

This report describes the development and evaluation of mathematical models for predicting human performance from discrete wavelet transforms (DWT) of event-related potentials (ERP) elicited by task-relevant stimuli. The DWT was compared to principal components analysis (PCA) for representation of ERPs in linear regression and neural network models developed to predict a composite measure of human signal detection performance. Linear regression models based on coefficients of the decimated DWT predicted signal detection performance with half as many free parameters as comparable models based on PCA scores. In addition, the DWT-based models were more resistant to model degradation due to over-fitting than PCA-based models. Feed-forward neural networks were trained using the backpropagation algorithm to predict signal detection performance based on raw ERPs, PCA scores, or high-power coefficients of the DWT. Neural networks based on high-power DWT coefficients trained with fewer iterations, generalized to new data better, and were more resistant to overfitting than networks based on raw ERPs. Networks based on PCA scores did not generalize to new data as well as either the DWT network or the raw ERP network. The results show that wavelet expansions represent the ERP efficiently and extract behaviorally important features for use in linear regression or neural network models of human performance. The efficiency of the DWT is discussed in terms of its decorrelation and energy compaction properties. In addition, the DWT models provided evidence that a pattern of low-frequency activity (1 to 3.5 Hz) occurring at specific times and scalp locations is a reliable correlate of human signal detection performance. Copyright 1999 Academic Press.

Evoked Potentials↗

Time Matters: A Survival Analysis of Public Electric Vehicle Charging Infrastructure Utilization

The rapid adoption of plug-in electric vehicles (PEVs) places significant demands on public charging infrastructure, making it critical to understand and optimize charger utilization. This study provides one of the most comprehensive analyses of charging behavior to date by applying a survival analysis to a dataset of nearly 16 million level 2 (L2) and direct current (DC) fast charger sessions across the United States from 2017 to 2022. Using Kaplan-Meier curves and log rank tests, our analysis reveals statistically significant and distinct duration patterns influenced by charger type, time of day, and day of the week. We find that L2 charging sessions exhibit high variability tied to venue type, whereas DC sessions are more uniform, typically lasting 30-45 min. This study introduces the operational efficiency score (OES), a metric for standardizing the performance evaluation of charging stations. Our findings offer actionable insights for optimizing charger deployment, developing dynamic pricing strategies to reduce vehicle dwell time, and improving load management for grid operators, ultimately enhancing the efficiency and availability of public charging infrastructure.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Detection of Cervical Cancer Biomarker Patterns in Blood Plasma and Urine by Differential Scanning Calorimetry and Mass Spectrometry

Improved methods for the accurate identification of both the presence and severity of cervical intraepithelial neoplasia (CIN) and extent of spread of invasive carcinomas of the cervix (IC) are needed. Differential scanning calorimetry (DSC) has recently been shown to detect specific changes in the thermal behavior of blood plasma proteins in several diseases. This methodology is being explored to provide a complementary approach for screening of cervical disease. The present study evaluated the utility of DSC in differentiating between healthy controls, increasing severity of CIN and early and advanced IC. Significant discrimination was apparent relative to the extent of disease with no clear effect of demographic factors such as age, ethnicity, smoking status and parity. Of most clinical relevance, there was strong differentiation of CIN from healthy controls and IC, and amongst patients with IC between FIGO Stage I and advanced cancer. The observed disease-specific changes in DSC profiles (thermograms) were hypothesized to reflect differential expression of disease biomarkers that subsequently bound to and affected the thermal behavior of the most abundant plasma proteins. The effect of interacting biomarkers can be inferred from the modulation of thermograms but cannot be directly identified by DSC. To investigate the nature of the proposed interactions, mass spectrometry (MS) analyses were employed. Quantitative assessment of the low molecular weight protein fragments of plasma and urine samples revealed a small list of peptides whose abundance was correlated with the extent of cervical disease, with the most striking plasma peptidome data supporting the interactome theory of peptide portioning to abundant plasma proteins. The combined DSC and MS approach in this study was successful in identifying unique biomarker signatures for cervical cancer and demonstrated the utility of DSC plasma profiles as a complementary diagnostic tool to evaluate cervical cancer health.

59 BASIC BIOLOGICAL SCIENCES↗

Effect of gamma irradiation on dielectric properties of manganese zinc nanoferrites

Naocrystalline ferrites Mn{sub 1−x}Zn{sub x}Fe{sub 2}O{sub 4} (x = 0.00, 0.25, 0.50, 0.75 and 1.00) were prepared by combustion method. The samples were characterized by XRD technique. The dielectric measurements were carried out in the frequency range 40 Hz to 100 MHz at room temperature. All the measurements were performed before and after gamma {sup 60}Co irradiation. The X-ray diffraction patterns revealed the formation of nanocrystalline and single-phase spinel structure. The lattice parameter decrease with zinc ion concentration and increased after the irradiation due to ferric ions of smaller radius converted to ferrous ions of larger radius. The dielectric behavior is attributed to the Maxwell-Wagner type interfacial polarization. The dielctric contant, dielectric loss and AC conductivity enhanced after the irradiation.

36 MATERIALS SCIENCE↗

Facile fabrication of highly ordered poly(vinylidene fluoride-trifluoroethylene) nanodot arrays for organic ferroelectric memory

Nano-patterned ferroelectric materials have attracted significant attention as the presence of two or more thermodynamically equivalent switchable polarization states can be employed in many applications such as non-volatile memory. In this work, a simple and effective approach for fabrication of highly ordered poly(vinylidene fluoride–trifluoroethylene) P(VDF-TrFE) nanodot arrays is demonstrated. By using a soft polydimethylsiloxane mold, we successfully transferred the 2D array pattern from the initial monolayer of colloidal polystyrene nanospheres to the imprinted P(VDF-TrFE) films via nanoimprinting. The existence of a preferred orientation of the copolymer chain after nanoimprinting was confirmed by Fourier transform infrared spectra. Local polarization switching behavior was measured by piezoresponse force microscopy, and each nanodot showed well-formed hysteresis curve and butterfly loop with a coercive field of ∼62.5 MV/m. To illustrate the potential application of these ordered P(VDF-TrFE) nanodot arrays, the writing and reading process as non-volatile memory was demonstrated at a relatively low voltage. As such, our results offer a facile and promising route to produce arrays of ferroelectric polymer nanodots with improved piezoelectric functionality.

36 MATERIALS SCIENCE↗

1990 CATS Household Travel Survey

The Chicago Area Transportation Study (CATS) 1990 Household Travel Survey was a self-administered mail-out mail-back survey. The purpose of the study was to update existing data on travel patterns and characteristics of Chicago residents. CATS surveyed the region on a county-by-county basis with the Chicago Central Business District in collaboration with the Urban Transportation Center of the University of Illinois. The study gathered demographic and travel behavior data from residents of northeastern Illinois who were 14 years old or older. 19,314 households participated in the survey. The study focused on non-work travel by motorized vehicle and by foot, and residents recorded their trips on a single travel day. Transportation-related variables include trip origin and destination, trip purpose, travel time, mode of travel used, vehicle occupancy, and walking distance (if that transit mode was involved).

1Hz data↗

Dynamics of solid lubrication as observed by optical microscopy

A bench metallograph was converted into a micro contact imager by the addition of a tribometer employing a steel ball in sliding contact with a glass disk. The sliding contact was viewed in real time by means of projection microscope optics. The dynamics of abrasive particles and of solid lubricant particles within the contact were observed in detail. The contact was characterized by a constantly changing pattern of elastic strain with the passage of surface discontinuities and solid particles. Abrasive particles fragmented upon entering the contact, embedded in one surface and scratched the other; in contrast, the solid lubricant particles flowed plastically into thin films. The rheological behavior of the lubricating solids gave every appearance of a paste-like consistency within the Hertzian contact.

Sliney, H. E.↗

Dynamics of solid lubrication as observed by optical microscopy

A bench metallograph was converted into a 'micro contact imager' by the addition of a tribometer employing a steel ball in sliding contact with a glass disk. The sliding contact was viewed in real time by means of projection microscope optics. The dynamics of abrasive particles and of solid lubricant particles within the contact were observed in detail. The contact was characterized by a constantly changing pattern of elastic strain with the passage of surface discontinuities and solid particles. Abrasive particles fragmented upon entering the contact, embedded in one surface and scratched the other; in contrast, the solid lubricant particles flowed plastically into thin films. The rheological behavior of the lubricating solids gave every appearance of a paste-like consistency within the Hertzian contact.

Sliney, H. E.↗