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At least 1,441 records · Page 80
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Dy adsorption on and intercalation under graphene on 6 H -SiC(0001) surface from first-principles calculations

Previous experimental observations motivate clarification of configuration stabilities and kinetic processes for intercalation of guest atoms into a layered van der Waals material such as a graphene-SiC system. From our first-principles density functional theory (DFT) calculations, we analyze Dy adsorption and intercalation for graphene on a 6H-SiC(0001) surface, where the system includes two single-atom-thick graphene layers: the top-layer graphene (TLG) and the underling buffer-layer graphene (BLG) above the terminal Si layer. Our chemical potential analysis shows that intercalation of a single Dy atom into the gallery between TLG and BLG is more favorable than adsorption on TLG but that intercalation into the gallery underneath BLG is highly unfavorable. We obtain diffusion barriers of ~0.45 and 0.54 eV for a Dy atom diffusing on and under TLG, respectively. We find that the direct penetration of a Dy atom from the graphene top into the gallery under TLG is almost inhibited below a temperature of ~1400 K due to a large global barrier of at least ~3.5 eV. Instead, we find that a single Dy atom on TLG can easily intercalate by crossing a TLG step (e.g., a zigzag step presaturated by a Dy chain or a reconstructed zigzag step zz57). Additionally, we also perform DFT calculations for different Dy coverages to demonstrate how the favorability of Dy intercalation, as well as the corresponding interlayer spacings, depend on the coverage. Consequently, we can provide general insight and guidance for extensively studied systems involving intercalation of foreign atoms into graphene on a SiC substrate.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Sea ice-atmosphere interaction: Application of multispectral satellite data in polar surface energy flux estimates

The application of multi-spectral satellite data to estimate polar surface energy fluxes is addressed. To what accuracy and over which geographic areas large scale energy budgets can be estimated are investigated based upon a combination of available remote sensing and climatological data sets. The general approach was to: (1) formulate parameterization schemes for the appropriate sea ice energy budget terms based upon the remotely sensed and/or in-situ data sets; (2) conduct sensitivity analyses using as input both natural variability (observed data in regional case studies) and theoretical variability based upon energy flux model concepts; (3) assess the applicability of these parameterization schemes to both regional and basin wide energy balance estimates using remote sensing data sets; and (4) assemble multi-spectral, multi-sensor data sets for at least two regions of the Arctic Basin and possibly one region of the Antarctic. The type of data needed for a basin-wide assessment is described and the temporal coverage of these data sets are determined by data availability and need as defined by parameterization scheme. The titles of the subjects are as follows: (1) Heat flux calculations from SSM/I and LANDSAT data in the Bering Sea; (2) Energy flux estimation using passive microwave data; (3) Fetch and stability sensitivity estimates of turbulent heat flux; and (4) Surface temperature algorithm.

Steffen, K.↗
DOE OSTI2021

Thermodynamics and kinetics of H adsorption and intercalation for graphene on 6 H -SiC(0001) from first-principles calculations

Previous experimental observations for H intercalation under graphene on SiC surfaces motivate the clarification of configuration stabilities and kinetic processes related to intercalation. From first-principles density-functional-theory calculations, we analyze H adsorption and intercalation for graphene on a 6H-SiC(0001) surface, where the system includes two single-atom-thick graphene layers: the top-layer graphene (TLG) and the underling buffer-layer graphene (BLG) above the terminal Si layer. Our chemical potential analysis shows that in the low-H coverage regime (described by a single H atom within a sufficiently large supercell), intercalation into the gallery between TLG and BLG or into the gallery underneath BLG is more favorable thermodynamically than adsorption on top of TLG. However, intercalation into the gallery between TLG and BLG is most favorable. We obtain energy barriers of about 1.3 and 2.3 eV for a H atom diffusing on and under TLG, respectively. From an additional analysis of the energy landscape in the vicinity of a step on the TLG, we assess how readily one guest H atom on the TLG terrace can directly penetrate the TLG into the gallery between TLG and BLG versus crossing a TLG step to access the gallery. Finally, we also perform density functional theory calculations for higher H coverages revealing a shift in favorability to intercalation of H underneath BLG and characterizing the variation with H coverage in interlayer spacings.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Synthesis and Morphological Characterization of Electroless-Deposited Ni-P Coatings on Diamond Abrasives

Deposition of a coating on rough surfaces faces unique challenges due to the complexity of substrate morphology. In the present research, electroless deposition of a Ni-P coating was successfully deposited on diamond particles. Microtomography was conducted to study the deposition mechanisms. It revealed that the coating coverage rate on diamond particles was affected by the synergistic action of the deposition time, substrate morphology, and hypophosphite concentration. The best coverage was achieved in a solution with 0.2 mol/L hypophosphite. Two major morphological features of the coating: nodular and smooth, were influenced by the deposition parameters, coating integrity, and substrate morphology. The failure was seen in fractured and peeled off coatings. It was due to residual stress produced by the coalescing of crystallites during the deposition. This failure mechanism explains the tendency of coating fracture at three morphological features of the substrate. This work is beneficial to semiconductor manufacturing where effective cutting in chip fabrication is essential.

36 MATERIALS SCIENCE↗
NASA NTRS1981

The spectral reflectance of water-mineral mixtures at low temperatures

Laboratory reflectance spectra in the 0.325-2.5 micron region of bound water, water-mineral mixtures, mineral grains on frost, and frost on minerals are presented. The materials used in this study are montmorillonite, kaolinite, beryl, Mauna Kea red cinder, and black charcoal. It is found that the wavelengths of bound water and bound OH absorptions do not shift appreciably with temperature and can be detected when large amounts of free water ice are present. The decrease in the visible reflectance seen in many planetary reflectance spectra containing strong water ice absorptions can be explained by water-mineral mixtures, mineral grains on frost, or frost on mineral grains. Mineral grains on frost are detectable in very small quantities (fractional areal coverage less than approximately 0.005) depending on the mineral reflectance features, while it takes a thick layer of frost (greater than approximately 1 mm) to mask a mineral below 1.4 microns, again depending on the mineral reflectance. Frost on a very dark surface (albedo about 6%) is easily seen; however, a dark mineral mixed with water could completely mask the water absorptions (shortward of 2.5 microns).

Clark, R. N.↗
NASA NTRS1992

Infrared imaging of Mars for volatile distribution and seasonal variability between 2.4 and 5.1 microns

Recent advances in ground-based infrared imaging now allow for sub-arc second spectral imaging. Data collected at the NASA Infrared Telescope Facility using protocam, a 62 x 58 InSb array camera with a circular variable filter and a plate scale 0.2 arc-seconds/pixel, are discussed. These images are a first attempt at extended seasonal infrared coverage of Mars to look for seasonal variations. Currently, data collected in Jun. 1990 at Ls = 241 (southern spring) and in Jan. 1991 Ls = 360 (late southern summer) are being reduced and analyzed. The 3 micron bound water band is the strongest surface absorption feature on Mars in the infrared. Infrared spectroscopy can also be useful in the detection of ice and frost deposits, especially in the polar regions. While imaging and spectroscopy at visible wavelengths allows for the detection of condensates, infrared information is needed to distinguish between water and CO2 ice/frost deposits. In the Jun. images, the southern polar cap totally disappears in the 3.4 micron CO2 frost band and is bright in the 3.1 micron water ice band, indicating that water ice is not a detectable component of the southern polar cap at this season. Further investigations are currently under way to look for residual water ice after the disappearance of the seasonal south polar cap in the Jan. images. The Jun. images that were focused on had a sub-earth point located at 184 longitude, and 23.8 S latitude which put the center of the disk in the southern highland region between Elysium and Amazonis. Examination of the Jun. images show that there are four surface units identifiable: a CO2 frost deposit, a northern plains unit, an equatorial unit, and a southern highland unit. At this resolution there does not appear to be any latitudinal variations in the 3 micron band that is independent of the 2.4 micron albedo features. The northern planes unit and the southern highland unit have very similar 'color' in the three micron band as demonstrated by the rise out of the band, but different brightness levels. The equatorial unit has a distinct three micron color implying a compositional difference. The albedo features at 2.4 microns have decreased contrast at longer wavelengths, till they are unrecognizable at 4 microns.

Blaney, Diana L.↗
NASA NTRS2001

Global Lidar Measurements of Clouds and Aerosols from Space Using the Geoscience Laser Altimeter System (GLAS)

The Geoscience Laser Altimeter System (GLAS) is scheduled for launch on the ICESat satellite as part of the NASA EOS mission in 2002. GLAS will be used to perform high resolution surface altimetry and will also provide a continuously operating atmospheric lidar to profile clouds, aerosols, and the planetary boundary layer with horizontal and vertical resolution of 175 and 76.8 m, respectively. GLAS is the first active satellite atmospheric profiler to provide global coverage. Data products include direct measurements of the heights of aerosol and cloud layers, and the optical depth of transmissive layers. In this poster we provide an overview of the GLAS atmospheric data products, present a simulated GLAS data set, and show results from the simulated data set using the GLAS data processing algorithm. Optical results from the ER-2 Cloud Physics Lidar (CPL), which uses many of the same processing algorithms as GLAS, show algorithm performance with real atmospheric conditions during the Southern African Regional Science Initiative (SAFARI 2000).

Hlavka, Dennis L.↗
NASA NTRSDate not supplied

Surface Radiation Budget

The Surface Radiation Budget (SRB) data sets contain global 3-hourly, daily and monthly averages of surface longwave and shortwave radiative properties, cloud amount, and meteorological properties computed using models. The main input data for these models include cloud information, top-of-atmosphere radiances and profiles of atmospheric water vapor and temperature. Some of the input data include Earth Radiation Budget Energy (ERBE) top-of-atmosphere clear-sky albedo and International Satellite Cloud Climatology Project (ISCCP) radiances and cloud amount. SRB parameters derived for the renewable energy community are also available from the Surface meteorology and Solar Energy (SSE) data set. Other SRB data are available from Clouds and the Earth's Radiant Energy System (CERES) and Multi-angle Imaging SpectroRadiometer (MISR). [Mission Objectives] The objective of the SRB Project is to produce and archive a global data set of shortwave (SW) and longwave (LW) surface and top of the atmosphere parameters. The data generated in the SRB project may be used in conjunction with other data sets to facilitate the development of renewable energy resources and increase understanding of radiative properties within the meteorological community. [Temporal_Coverage: Start_Date=1983-07-01; Stop_Date=2005-06-30] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180].

Stackhouse, Paul W.↗
NASA NTRS2017

Identifying Stratospheric Air Intrusions and Associated Hurricane-Force Wind Events over the North Pacific Ocean

Motivation: Ocean data is sparse: reliance on satellite imagery for marine forecasting; Ocean Prediction Center (OPC) –“mariner’s weather lifeline”. Responsible for: Pacific, Atlantic, Pacific Alaska surface analyses –24, 48, 96 hrs.; Wind & wave analyses –24, 48, 96 hrs.; Issue warnings, make decisions, Geostationary Operational Environmental Satellite –R Series (now GOES-16), Compared to the old GOES: 3 times spectral resolution, 4 times spatial resolution, 5 times faster coverage; Comparable to Japanese Meteorological Agency’s Himawari-8, used a lot throughout this research. Research Question: How can integrating satellite data imagery and derived products help forecasters improve prognosis of rapid cyclogenesis and hurricane-force wind events? Phase I –Identifying stratospheric air intrusions: Water Vapor –6.2, 6.9, 7.3 micron channels; Airmass RGB Product; AIRS, IASI, NUCAPS total column ozone and ozone anomaly; ASCAT (A/B) and AMSR-2 wind data.

Ozone↗
DOE OSTI2025

Long-term hydro-economic analysis tool for evaluating global groundwater cost and supply: Superwell v1.1

Abstract. Groundwater plays a key role in meeting water demands, supplying over 40 % of irrigation water globally, with this role likely to grow as water demands and surface water variability increase. A better understanding of the future role of groundwater in meeting sectoral demands requires an integrated hydro-economic evaluation of its cost and availability. Yet substantial gaps remain in our knowledge and modeling capabilities related to groundwater availability, recharge, feasible locations for extraction, extractable volumes, and associated extraction costs, which are essential for large-scale analyses of integrated human–water system scenarios, particularly at the global scale. To address these needs, we developed Superwell, a physics-based groundwater extraction and cost accounting model that operates at sub-annual temporal and at the coarsest 0.5° (≈50 km × 50 km) gridded spatial resolution with global coverage. The model produces location-specific groundwater supply–cost curves that provide the levelized cost to access different quantities of available groundwater. The inputs to Superwell include recent high-resolution hydrogeologic datasets of permeability, porosity, aquifer thickness, depth to water table, recharge, and hydrogeological complexity zones. It also accounts for well capital and maintenance costs, as well as the energy costs required to lift water to the surface. The model employs a Theis-based scheme coupled with an amortization-based cost accounting formulation to simulate groundwater extraction and quantify the cost of groundwater pumping. The result is a spatiotemporally flexible, physically realistic, economics-based model that produces groundwater supply–cost curves. We show examples of these supply–cost curves and the insights that can be derived from them across a set of scenarios designed to explore model outcomes. The supply–cost curves produced by the model show that most (90 %) nonrenewable groundwater in storage globally is extractable at costs lower than USD 0.57 m−3, while half of the volume remains extractable at under USD 0.108 m−3. The global unit cost is estimated to range from a minimum of USD 0.004 m−3 to a maximum of USD 3.971 m−3. We also demonstrate and discuss examples of how these cost curves could be used by linking Superwell's outputs with other models to explore coupled human–environmental system challenges, such as water resources planning and management, or broader analyses of multisectoral feedbacks.

Global Change Analysis Model (GCAM)↗
NASA NTRS1989

A study of oceanic surface heat fluxes in the Greenland, Norwegian, and Barents Seas

This study examines oceanic surface heat fluxes in the Norwegian, Greenland, and Barents seas using the gridded Navy Fleet Numerical Oceanography Central surface analysis and the First GARP Global Experiment (FGGE) IIc cloudiness data bases. Monthly and annual means of net and turbulent heat fluxes are computed for the FGGE year 1979. The FGGE IIb data base consisting of individual observations provides particularly good data coverage in this region for a comparison with the gridded Navy winds and air temperatures. The standard errors of estimate between the Navy and FGGE IIb winds and air temperatures are 3.6 m/s and 2.5 C, respectively. The computations for the latent and sensible heat fluxes are based on bulk formulas with the same constant heat exchange coefficient of 0.0015. The results show extremely strong wintertime heat fluxes in the northern Greenland Sea and especially in the Barents Sea in contrast to previous studies.

Hakkinen, Sirpa↗
NASA NTRS1995

Unoccupied electronic resonances of Sc adsorbed on W(001) by k-resolved inverse photoemission

Scandium adsorbed on the (001) face of tungsten has been studied using Auger-electron spectroscopy, low-energy electron diffraction, k-resolved inverse photoelectron spectroscopy, work-function measurements, and relativistic-electronic-structure calculations. We find that the work function of W(001) does not decrease monotonically as a function of scandium adsorption but reaches a minimum value of Phi = 3.25 eV at 50% coverage. For a complete monolayer, an order 1 X 1 Sc overlayer is formed. Inverse photoemission in the isochromat mode was used to map the unoccupied energy levels of this overlayer along the bar-Gamma(bar-Mu) symmetry direction of the surface Brillouin zone. Local-density-functional calculations using the muffin-tin orbital method were performed for a 1 X 1 Sc overlayer on W and are compared with the experimental two-dimensional band structure.

Lamouri, A.↗
NASA NTRS2002

Evaluation of Improvements to the TRMM Microwave Rain Algorithm

Improvements made to the Version 5 TRMM passive microwave rain retrieval algorithm (2A-12) are evaluated using independent data. Surface rain rate estimates from the Version 5 TRMM TMI (2A-12), PR (2A-25) and TMI/PR Combined (2B-31) algorithms and ground-based radar estimates for selected coincident subset datasets in 1998 over Melbourne and Kwajalein show varying degrees of agreement. The surface rain rates are then classified into convective and stratiform rain types over ocean, land, and coastal areas for more detailed comparisons to the ground radar measurements. These comparisons lead to a better understanding of the relative performances of the current TRMM rain algorithms. For example, at Melbourne more than 80% of the radar-derived rainfall is classified as convective rain. Convective rain from the TRMM rain algorithms is less than that from ground radar measurements, while TRMM stratiform rain is much greater. Rain area coverage from 2A-12 is also in reasonable agreement with ground radar measurements, with about 25% more over ocean and 25% less over land and coastal areas. Retrieved rain rates from the improved (Version 6) 2A-12 algorithm will be compared to 2A-25, 2B-31, and ground-based radar measurements to evaluate the impact of improvements to 2A-12 in Version 6. An important improvement to the Version 6 2A-12 algorithm is the retrieval of Q1/Q2 (latent heating/drying) profiles in addition to the surface rain rate and hydrometeor profiles. In order to ascertain the credibility of the new products, retrieved Q1/Q2 profiles are compared to independent ground-based estimates. Analyses of dual-Doppler radar data in conjunction with coincident rawinsonde data yield estimates of the vertical distributions of diabatic heating/drying at high horizontal resolution for selected cases over the Kwajalein and LBA field sites. The estimated vertical heating/drying structures appear to be reasonable. Comparisons of Q1/Q2 profiles from Version 6 2A-12 and the ground-based estimates are in progress. Retrieved Q1/Q2 structures will also be compared to MM5 hurricane simulations for selected cases. The results of these intercomparisons will be presented at the conference.

Yang, Song↗
NASA NTRS2024

Solar System Science With the Single Aperture Large Telescope for Universe Studies Space Observatory

Single Aperture Large Telescope for Universe Studies (SALTUS) is a NASA Astrophysics Probe Explorer (APEX)-class mission concept employing a robust far-infrared pointed space observatory. SALTUS comprises a 14-m inflatable reflector that provides 16× the sensitivity and 4× the angular resolution of Herschel, with a sunshield that radiatively cools the primary to 45 K, along with cryogenic detectors that collectively span the 34 to 660 μm far-infrared spectral range at high and moderate spectral resolutions. The high sensitivity and high spectral resolving power of the SALTUS heterodyne receivers enable both submillimeter and far-infrared observations of trace compounds comprising water and its isotopologues, hydrogen deuteride (HD), and a plethora of molecular species containing carbon, hydrogen, nitrogen, oxygen, phosphorus, or sulfur (CHNOPS), all of which are obscured by the Earth’s atmosphere. The high sensitivity and broadband spectral coverage of the SALTUS far-infrared grating spectrometer enables far-infrared observations of the lattice vibrational spectral signatures of ices and mineral grains contained within a wide variety of solar system targets, including comets, planetary atmospheres, near Enceladus’ plumes, and on the surfaces of icy moons, Jupiter trojans, centaurs, and Kuiper Belt objects. A key objective of SALTUS is to measure HDO∕H 2 O in both Jupiter family and Oort cloud comets. Additional observations will allow us to characterize the water torus around Saturn generated by its icy moon Enceladus, determine the source of stratospheric water in the giant planets, ascertain the time evolution of water on Venus, and search for H 2 O plumes on Europa, Ganymede, and Callisto. SALTUS will measure HD∕H 2 in all four giant planets to constrain models of their origin. SALTUS can also measure the abundance of CHNOPS-containing molecules and halides in the atmosphere of Venus and in the comae of comets. We review the extensive amount of solar system science achievable with SALTUS for both the Guaranteed Time Observation and the Guest Observer APEX mission observing programs.

Carrie M. Anderson↗
NASA NTRS2012

An Assessment of the Surface Longwave Direct Radiative Effect of Airborne Dust in Zhangye China During the Asian Monsoon Year Field Experiment (2008)

Tiny suspensions of solid particles or liquid droplets, called aerosols, hover in earth's atmosphere and can be found over just about anywhere including oceans, deserts, vegetated areas, and other global regions. Aerosols come in a variety of sizes, shapes, and compositions which depend on such factors as their origin and how long they have been in the atmosphere (i.e., their residence time). Some of the more common types of aerosols include mineral dust and sea salt which get lifted from the desert and ocean surfaces, respectively by mechanical forces such as strong winds. Depending on their size, aerosols will either fall out gravitationally, as in the case of larger particles, or will remain resident in the atmosphere where they can undergo further change through interactions with other aerosols and cloud particles. Not only do aerosols affect air quality where they pose a health risk, they can also perturb the distribution of radiation in the earth-atmosphere system which can inevitably lead to changes in our climate. One aerosol that has been in the forefront of many recent studies, particularly those examining its radiative effects, is mineral dust. The large spatial coverage of desert source regions and the fact that dust can radiatively interact with such a large part of the electromagnetic spectrum due to its range in particle size, makes it an important aerosol to study. Dust can directly scatter and absorb solar and infrared radiation which can subsequently alter the amount of radiation that would otherwise be present in the absence of dust at any level of the atmosphere like the surface. This is known as radiative forcing. At the surface dust can block incoming solar energy, however at infrared wavelengths, dust acts to partially compensate the solar losses. Evaluating the solar radiative effect of dust aerosols is relatively straightforward due in part to the relatively large signal-to-noise ratio in the measurements. At infrared wavelengths, on the other hand, the effect is rather difficult to ascertain since the measured dust signal level is on the same order as the instrumental uncertainties. Although the radiative impact of dust is much smaller in the infrared, it can still have a noticeable influence on the distribution of energy in the Earth-atmosphere system. This is mainly attributed to the strong light-absorptive properties commonly found in many earth minerals.

Hansell, Richard A.↗
NASA NTRS1993

Analysis of the tropospheric water distribution during FIRE 2

The Penn State/NCAR mesoscale model, as adapted for use at ARC, was used as a testbed for the development and validation of cloud models for use in General Circulation Models (GCM's). This modeling approach also allows us to intercompare the predictions of the various cloud schemes within the same dynamical framework. The use of the PSU/NCAR mesoscale model also allows us to compare our results with FIRE-II (First International Satellite Cloud Climatology Project Regional Experiment) observations, instead of climate statistics. Though a promising approach, our work to date revealed several difficulties. First, the model by design is limited in spatial coverage and is only run for 12 to 48 hours at a time. Hence the quality of the simulation will depend heavily on the initial conditions. The poor quality of upper-tropospheric measurements of water vapor is well known and the situation is particularly bad for mid-latitude winter since the coupling with the surface is less direct than in summer so that relying on the model to spin-up a reasonable moisture field is not always successful. Though one of the most common atmospheric constituents, water vapor is relatively difficult to measure accurately, especially operationally over large areas. The standard NWS sondes have little sensitivity at the low temperatures where cirrus form and the data from the GOES 6.7 micron channel is difficult to quantify. For this reason, the goals of FIRE Cirrus II included characterizing the three-dimensional distribution of water vapor and clouds. In studying the data from FIRE Cirrus II, it was found that no single special observation technique provides accurate regional distributions of water vapor. The Raman lidar provides accurate measurements, but only at the Hub, for levels up to 10 km, and during nighttime hours. The CLASS sondes are more sensitive to moisture at low temperatures than are the NWS sondes, but the four stations only cover an area of two hundred kilometers on a side. The aircraft give the most accurate measurements of water vapor, but are limited in spatial and temporal coverage. This problem is partly alleviated by the use of the MAPS analyses, a four-dimensional data assimilation system that combines the previous 3-hour forecast with the available observations, but its upper-level moisture analyses are sometimes deficient because of the vapor measurement problem. An attempt was made to create a consistent four-dimensional description of the water vapor distribution during the second IFO by subjectively combining data from a variety of sources, including MAPS analyses, CLASS sondes, SPECTRE sondes, NWS sondes, GOES satellite analyses, radars, lidars, and microwave radiometers.

Westphal, Douglas L.↗