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At least 1,441 records · Page 80
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Neutral but Impactful: Gallium Cluster-Induced Nanopores from Beam-Blanked Gallium Ion Sources

Neutral atoms originating from liquid metal ion sources are an often-overlooked source of contamination and damage in focused ion beam microscopy. Beyond ions and single atoms, these sources also generate atom clusters. While most studies have investigated charged clusters, here we demonstrate that neutral clusters are also formed. These neutral clusters bypass the electrostatic beam blanking system, allowing them to impinge on samples even when the ion beam is blanked. We investigate this phenomenon using thin (≤20 nm) freestanding membranes of hexagonal boron nitride, silicon, and silicon nitride as targets. Randomly dispersed nanopores that form upon neutral cluster exposure are revealed. The average nanopore diameter is ∼2 nm with a narrow size distribution, suggesting that the atom clusters have a preferred size. Various electron microscopy techniques are used to characterize the nanopores, including high-resolution transmission electron microscopy, multislice ptychography, and electron energy-loss spectroscopy. Finally, we show how electron irradiation in the transmission electron microscope can be used to both remove any amorphous material that may clog the pores and to controllably grow the pores to specific sizes. Tunable nanopores such as these are interesting for nanofluidic applications requiring size-selective membranes.

Byrne, Dana O↗
DOE OSTI2023

Orbital-selective metal skin induced by alkali-metal-dosing Mott-insulating Ca2RuO4

Abstract Doped Mott insulators are the starting point for interesting physics such as high temperature superconductivity and quantum spin liquids. For multi-band Mott insulators, orbital selective ground states have been envisioned. However, orbital selective metals and Mott insulators have been difficult to realize experimentally. Here we demonstrate by photoemission spectroscopy how Ca 2 RuO 4 , upon alkali-metal surface doping, develops a single-band metal skin. Our dynamical mean field theory calculations reveal that homogeneous electron doping of Ca 2 RuO 4 results in a multi-band metal. All together, our results provide evidence for an orbital-selective Mott insulator breakdown, which is unachievable via simple electron doping. Supported by a cluster model and cluster perturbation theory calculations, we demonstrate a type of skin metal-insulator transition induced by surface dopants that orbital-selectively hybridize with the bulk Mott state and in turn produce coherent in-gap states.

Physics↗
DOE OSTI2012

NEW ISOLATED PLANETARY-MASS OBJECTS AND THE STELLAR AND SUBSTELLAR MASS FUNCTION OF THE {sigma} ORIONIS CLUSTER

We report on our analysis of the VISTA Orion ZY JHK{sub s} photometric data (completeness magnitudes of Z = 22.6 and J = 21.0 mag) focusing on a circular area of 2798.4 arcmin{sup 2} around the young {sigma} Orionis star cluster ({approx}3 Myr, {approx}352 pc, and solar metallicity). The combination of the VISTA photometry with optical, WISE and Spitzer data allows us to identify a total of 210 {sigma} Orionis member candidates with masses in the interval 0.25-0.004 M{sub Sun }, 23 of which are new planetary-mass object findings. These discoveries double the number of cluster planetary-mass candidates known so far. One object has colors compatible with a T spectral type. The {sigma} Orionis cluster harbors about as many brown dwarfs (69, 0.072-0.012 M{sub Sun }) and planetary-mass objects (37, 0.012-0.004 M{sub Sun }) as very low mass stars (104, 0.25-0.072 M{sub Sun }). Based on Spitzer data, we derive a disk frequency of {approx}40% for very low mass stars, brown dwarfs, and planetary-mass objects in {sigma} Orionis. The radial density distributions of these three mass intervals are alike: all are spatially concentrated within an effective radius of 12' (1.2 pc) around the multiple star {sigma} Ori, and no obvious segregation between disk-bearing and diskless objects is observed. Using the VISTA data and the Mayrit catalog, we derive the cluster mass spectrum ({Delta}N/{Delta}M {approx} M{sup -{alpha}}) from {approx}19 to 0.006 M{sub Sun} (VISTA ZJ completeness), which is reasonably described by two power-law expressions with indices of {alpha} = 1.7 {+-} 0.2 for M > 0.35 M{sub Sun }, and {alpha} = 0.6 {+-} 0.2 for M < 0.35 M{sub Sun }. The {sigma} Orionis mass spectrum smoothly extends into the planetary-mass regime down to 0.004 M{sub Sun }. Our findings of T-type sources (<0.004 M{sub Sun }) in the VISTA {sigma} Orionis exploration appear to be smaller than what is predicted by the extrapolation of the cluster mass spectrum down to the survey J-band completeness.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Merging black hole binaries in galactic nuclei: implications for advanced-ligo detections

Motivated by the recent detection of gravitational waves from the black hole binary merger GW150914, we study the dynamical evolution of (stellar-mass) black holes in galactic nuclei, where massive star clusters reside. With masses of ∼10{sup 7} M{sub ⊙} and sizes of only a few parsecs, nuclear star clusters (NSCs) are the densest stellar systems observed in the local universe and represent a robust environment where black hole binaries can dynamically form, harden, and merge. We show that due to their large escape speeds, NSCs can retain a large fraction of their merger remnants. Successive mergers can then lead to significant growth and produce black hole mergers of several tens of solar masses similar to GW150914 and up to a few hundreds of solar masses, without the need to invoke extremely low metallicity environments. We use a semi-analytical approach to describe the dynamics of black holes in massive star clusters. Our models give a black hole binary merger rate of ≈1.5 Gpc{sup −3} yr{sup −1} from NSCs, implying up to a few tens of possible detections per year with Advanced LIGO. Moreover, we find a local merger rate of ∼1 Gpc{sup −3} yr{sup −1} for high mass black hole binaries similar to GW150914; a merger rate comparable to or higher than that of similar binaries assembled dynamically in globular clusters (GCs). Finally, we show that if all black holes receive high natal kicks, ≳50 km s{sup −1}, then NSCs will dominate the local merger rate of binary black holes compared to either GCs or isolated binary evolution.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1978

Early stages of the oxidation of metal surfaces

Photoemission cross sections were calculated for the ZnO4(-6) cluster using the self consistent-chi alpha- scattered wave theory to display the main features of the ultraviolet and X-ray photoemission data from ZnO. A solid model is suggested for an absolute photoemission intensity comparison resulting in chi alpha intensities which are roughly 70% of the experimental values. Together with the experimental data, the calculations allow a complete determination of the electronic structure of a ZnO surface.

Gatos, H. C.↗
DOE OSTI2012

ON THE ORIGIN OF THE METALLICITY DEPENDENCE IN DYNAMICALLY FORMED EXTRAGALACTIC LOW-MASS X-RAY BINARIES

Globular clusters (GCs) effectively produce dynamically formed low-mass X-ray binaries (LMXBs). Observers detect {approx}100 times more LMXBs per stellar mass in GCs compared to stars in the fields of galaxies. Observationally, metal-rich GCs are about three times more likely to contain an X-ray source than their metal-poor counterparts. Recent observations have shown that this ratio holds in extragalactic GCs for all bright X-ray sources with L{sub X} between 2 Multiplication-Sign 10{sup 37} and 5 Multiplication-Sign 10{sup 38} erg s{sup -1}. In this Letter, we propose that the observed metallicity dependence of LMXBs in extragalactic GCs can be explained by the differences in the number densities and average masses of red giants in populations of different metallicities. Red giants serve as seeds for the dynamical production of bright LMXBs via two channels-binary exchanges and physical collisions-and the increase of the number densities and masses of red giants boost LMXB production, leading to the observed difference. We also discuss a possible effect of the age difference in stellar populations of different metallicities.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1996

A liquid drop model for embedded atom method cluster energies

Minimum energy configurations for homonuclear clusters containing from two to twenty-two atoms of six metals, Ag, Au, Cu, Ni, Pd, and Pt have been calculated using the Embedded Atom Method (EAM). The average energy per atom as a function of cluster size has been fit to a liquid drop model, giving estimates of the surface and curvature energies. The liquid drop model gives a good representation of the relationship between average energy and cluster size. As a test the resulting surface energies are compared to EAM surface energy calculations for various low-index crystal faces with reasonable agreement.

Finley, C. W.↗
DOE OSTI2012

THE GLOBULAR CLUSTER POPULATIONS OF GIANT GALAXIES: MOSAIC IMAGING OF FIVE MODERATE-LUMINOSITY EARLY-TYPE GALAXIES

This paper presents results from wide-field imaging of the globular cluster (GC) systems of five intermediate-luminosity (M{sub V} {approx} -21 to -22) early-type galaxies. The aim is to accurately quantify the global properties of the GC systems by measuring them out to large radii. We obtained BVR imaging of four lenticular galaxies (NGC 5866, NGC 4762, NGC 4754, NGC 3384) and one elliptical galaxy (NGC 5813) using the KPNO 4 m telescope and Mosaic imager and traced the GC population to projected galactocentric radii ranging from {approx}20 kpc to 120 kpc. We combine our imaging with Hubble Space Telescope data to measure the GC surface density close to the galaxy center. We calculate the total number of GCs (N{sub GC}) from the integrated radial profile and find N{sub GC} = 340 {+-} 80 for NGC 5866, N{sub GC} = 2900 {+-} 400 for NGC 5813, N{sub GC} = 270 {+-} 30 for NGC 4762, N{sub GC} = 115 {+-} 15 for NGC 4754, and N{sub GC} = 120 {+-} 30 for NGC 3384. The measured GC specific frequencies are S{sub N} between 0.6 and 3.6 and T in the range 0.9-4.2. These values are consistent with the mean specific frequencies for the galaxies' morphological types found by our survey and other published data. Three galaxies (NGC 5866, NGC 5813, and NGC 4762) had sufficient numbers of GC candidates to investigate color bimodality and color gradients in the GC systems. NGC 5813 shows strong evidence (>3{sigma}) for bimodality and a B - R color gradient resulting from a more centrally concentrated red (metal-rich) GC subpopulation. We find no evidence for statistically significant color gradients in the other two galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Quasars probing quasars. VII. The pinnacle of the cool circumgalactic medium surrounds massive z ∼ 2 galaxies

We survey the incidence and absorption strength of the metal-line transitions C II 1334 and C IV 1548 from the circumgalactic medium (CGM) surrounding z ∼ 2 quasars, which act as signposts for massive dark matter halos M {sub halo} ≈ 10{sup 12.5} M {sub ☉}. On scales of the virial radius (r {sub vir} ≈ 160 kpc), we measure a high covering fraction f{sub C} = 0.73 ± 0.10 to strong C II 1334 absorption (rest equivalent width W {sub 1334} ≥ 0.2 Å), implying a massive reservoir of cool (T ∼ 10{sup 4} K) metal enriched gas. We conservatively estimate a metal mass exceeding 10{sup 8} M {sub ☉}. We propose that these metals trace enrichment of the incipient intragroup/intracluster medium that these halos eventually inhabit. This cool CGM around quasars is the pinnacle among galaxies observed at all epochs, as regards covering the fraction and average equivalent width of H I Lyα and low-ion metal absorption. We argue that the properties of this cool CGM primarily reflect the halo mass, and that other factors such as feedback, star-formation rate, and accretion from the intergalactic medium are secondary. We further estimate that the CGM of massive, z ∼ 2 galaxies accounts for the majority of strong Mg II absorption along random quasar sightlines. Last, we detect an excess of strong C IV 1548 absorption (W {sub 1548} ≥ 0.3 Å) over random incidence to the 1 Mpc physical impact parameter and measure the quasar-C IV cross-correlation function: ξ{sub C} {sub IV-Q}(r)=(r/r{sub 0}){sup −γ} with r{sub 0}=7.5{sub −1.4}{sup +2.8} h{sup −1} Mpc and γ=1.7{sub −0.2}{sup +0.1}. Consistent with previous work on larger scales, we infer that this highly ionized C IV gas traces massive (10{sup 12} M {sub ☉}) halos.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

THREE DISCRETE GROUPS WITH HOMOGENEOUS CHEMISTRY ALONG THE RED GIANT BRANCH IN THE GLOBULAR CLUSTER NGC 2808

We present the homogeneous reanalysis of Mg and Al abundances from high resolution UVES/FLAMES spectra for 31 red giants in the globular cluster NGC 2808. We found a well defined Mg-Al anticorrelation reaching a regime of subsolar Mg abundance ratios, with a spread of about 1.4 dex in [Al/Fe]. The main result from the improved statistics of our sample is that the distribution of stars is not continuous along the anticorrelation because they are neatly clustered into three distinct clumps, each with different chemical compositions. One group (P) shows a primordial composition of field stars of similar metallicity, and the other two (I and E) have increasing abundances of Al and decreasing abundances of Mg. The fraction of stars we found in the three components (P: 68%, I: 19%, E: 13%) is in excellent agreement with the ratios computed for the three distinct main sequences in NGC 2808: for the first time there is a clear correspondence between discrete photometric sequences of dwarfs and distinct groups of giants with homogeneous chemistry. The composition of the I group cannot be reproduced by mixing of matter with extreme processing in hot H-burning and gas with pristine, unprocessed composition, as also found in the recent analysis of three discrete groups in NGC 6752. This finding suggests that different classes of polluters were probably at work in NGC 2808 as well.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

HST-COS SPECTROSCOPY OF THE COOLING FLOW IN A1795—EVIDENCE FOR INEFFICIENT STAR FORMATION IN CONDENSING INTRACLUSTER GAS

We present far-UV spectroscopy from the Cosmic Origins Spectrograph on the Hubble Space Telescope of a cool, star-forming filament in the core of A1795. These data, which span 1025 Å < λ{sub rest} < 1700 Å, allow for the simultaneous modeling of the young stellar populations and the intermediate-temperature (10{sup 5.5} K) gas in this filament, which is far removed (∼30 kpc) from the direct influence of the central active galactic nucleus. Using a combination of UV absorption line indices and stellar population synthesis modeling, we find evidence for ongoing star formation, with the youngest stars having ages of 7.5{sub −2.0}{sup +2.5} Myr and metallicities of 0.4{sub −0.1}{sup +0.2} Z {sub ☉}. The latter is consistent with the local metallicity of the intracluster medium. We detect the O VI λ1038 line, measuring a flux of f {sub O} {sub VI,} {sub 1038} = 4.0 ± 0.9 × 10{sup –17} erg s{sup –1} cm{sup –2}. The O VI λ1032 line is redshifted such that it is coincident with a strong Galactic H{sub 2} absorption feature, and is not detected. The measured O VI λ1038 flux corresponds to a cooling rate of 0.85 ± 0.2 (stat) ± 0.15 (sys) M {sub ☉} yr{sup –1} at ∼10{sup 5.5} K, assuming that the cooling proceeds isochorically, which is consistent with the classical X-ray luminosity-derived cooling rate in the same region. We measure a star formation rate of 0.11 ± 0.02 M {sub ☉} yr{sup –1} from the UV continuum, suggesting that star formation is proceeding at 13{sub −2}{sup +3}% efficiency in this filament. We propose that this inefficient star formation represents a significant contribution to the larger-scale cooling flow problem.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

DISCOVERY OF A CLOSE PAIR OF FAINT DWARF GALAXIES IN THE HALO OF CENTAURUS A

As part of the Panoramic Imaging Survey of Centaurus and Sculptor (PISCeS), we report the discovery of a pair of faint dwarf galaxies (CenA-MM-Dw1 and CenA-MM-Dw2) at a projected distance of ∼90 kpc from the nearby elliptical galaxy NGC 5128 (CenA). We measure a tip of the red giant branch distance to each dwarf, finding D = 3.63 ± 0.41 Mpc for CenA-MM-Dw1 and D = 3.60 ± 0.41 Mpc for CenA-MM-Dw2, both of which are consistent with the distance to NGC 5128. A qualitative analysis of the color-magnitude diagrams indicates stellar populations consisting of an old, metal-poor red giant branch (≳12 Gyr, [Fe/H] ∼ –1.7 to –1.9). In addition, CenA-MM-Dw1 seems to host an intermediate-age population as indicated by its candidate asymptotic giant branch stars. The derived luminosities (M{sub V} = –10.9 ± 0.3 for CenA-MM-Dw1 and –8.4 ± 0.6 for CenA-MM-Dw2) and half-light radii (r{sub h} = 1.4 ± 0.04 kpc for CenA-MM-Dw1 and 0.36 ± 0.08 kpc for CenA-MM-Dw2) are consistent with those of Local Group dwarfs. CenA-MM-Dw1's low central surface brightness (μ {sub V,} {sub 0} = 27.3 ± 0.1 mag arcsec{sup –2}) places it among the faintest and most extended M31 satellites. Most intriguingly, CenA-MM-Dw1 and CenA-MM-Dw2 have a projected separation of only 3 arcmin (∼3 kpc): we are possibly observing the first, faint satellite of a satellite in an external group of galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Structural Changes in Metal Chalcogenide Nanoclusters Associated with Single Heteroatom Incorporation

Atomically precise nanoclusters (NCs) are promising building blocks for designing materials and interfaces with unique properties. By incorporating heteroatoms into the core, the electronic and magnetic properties of NCs can be precisely tuned. To accurately predict these properties, density functional theory (DFT) is often employed, making the rigorous benchmarking of DFT results particularly important. In this study, we present a benchmarking approach based on metal chalcogenide NCs as a model system. We synthesized a series of bimetallic, iron-cobalt chalcogenide NCs [Co 6-x Fe x S 8 (PEt 3 ) 6 ] + (x = 0-6) (PEt = triethyl phosphine) and investigated the effect of heteroatoms in the octahedral metal chalcogenide core on their size and electronic properties. Using ion mobility-mass spectrometry (IM-MS), we observed a gradual increase in the collision cross section (CCS) with an increase in the number of Fe atoms in the core. DFT calculations combined with trajectory method CCS simulations successfully reproduced this trend, revealing that the increase in cluster size is primarily due to changes in metal-ligand bond lengths, while the electronic properties of the core remain largely unchanged. Moreover, this method allowed us to exclude certain multiplicity states of the NCs, as their CCS values were significantly different from those predicted for the lowest-energy structures. Here, this study demonstrates that gas-phase IM-MS is a powerful technique for detecting subtle size differences in atomically precise NCs, which are often challenging to observe using conventional NC characterization methods. Accurate CCS measurements are established as a benchmark for comparison with theoretical calculations. The excellent correspondence between experimental data and theoretical predictions establishes a robust foundation for investigating structural changes of transition metal NCs of interest to a broad range of applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

THE AGE-METALLICITY RELATIONSHIP OF THE LARGE MAGELLANIC CLOUD FIELD STAR POPULATION FROM WIDE-FIELD WASHINGTON PHOTOMETRY

We analyze age and metallicity estimates for an unprecedented database of some 5.5 million stars distributed throughout the Large Magellanic Cloud (LMC) main body, obtained from CCD Washington CT{sub 1} photometry, reported on in Piatti et al. We produce a comprehensive field star age-metallicity relationship (AMR) from the earliest epoch until {approx}1 Gyr ago. This AMR reveals that the LMC has not evolved chemically as either a closed-box or bursting system, exclusively, but as a combination of both scenarios that have varied in relative strength over the lifetime of the galaxy, although the bursting model falls closer to the data in general. Furthermore, while old and metal-poor field stars have been preferentially formed in the outer disk, younger and more metal-rich stars have mostly been formed in the inner disk, confirming an outside-in formation. We provide evidence for the formation of stars between 5 and 12 Gyr, during the cluster age gap, although chemical enrichment during this period was minimal. We find no significant metallicity gradient in the LMC. We also find that the range in the metallicity of an LMC field has varied during the lifetime of the LMC. In particular, we find only a small range of the metal abundance in the outer disk fields, whereas an average range of {Delta}[Fe/H] = +0.3 {+-} 0.1 dex appears in the inner disk fields. Finally, the cluster and field AMRs show a satisfactory match only for the last 3 Gyr, while for the oldest ages (>11 Gyr), the cluster AMR is a remarkable lower envelope to the field AMR. Such a difference may be due to the very rapid early chemical evolution and lack of observed field stars in this regime, whereas the globular clusters are easily studied. This large difference is not easy to explain as coming from stripped ancient Small Magellanic Cloud (SMC) clusters, although the field SMC AMR is on average {approx}0.4 dex more metal-poor at all ages than that of the LMC but otherwise very similar.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Computing the cross sections of nuclear reactions with nuclear clusters emission for proton energies between 30 MeV and 2.6 GeV

The cross sections of nuclear reactions involving emission of clusters of light nuclei in proton collisions with a heavy-metal target are computed for incident-proton energies between 30 MeV and 2.6 GeV. The calculation relies on the ALICE/ASH and CASCADE/INPE computer codes. The parameters determining the pre-equilibrium cluster emission are varied in the computation.

74 ATOMIC AND MOLECULAR PHYSICS↗