DOE OSTI2013
In tetragonal SrCo 2 As 2 single crystals, inelastic neutron scattering measurements demonstrated that strong stripe-type antiferromagnetic (AFM) correlations occur at a temperature T = 5 K [W. Jayasekara et al., arXiv:1306.5174] that are the same as in the isostructural AFe 2 As 2 (A = Ca, Sr, Ba) parent compounds of high-T c superconductors. This surprising discovery suggests that SrCo 2 As 2 may also be a good parent compound for high-T c superconductivity. Here, structural and thermal expansion, electrical resistivity ρ, angle-resolved photoemission spectroscopy (ARPES), heat capacity C p , magnetic susceptibility χ, 75 As NMR and neutron diffraction measurements of SrCo 2 As 2 crystals are reported together with LDA band structure calculations that shed further light on this fascinating material. The c-axis thermal expansion coefficient α c is negative from 7 to 300 K, whereas α a is positive over this T range. The ρ(T) shows metallic character. The ARPES measurements and band theory confirm the metallic character and in addition show the presence of a flat band near the Fermi energy E F . The band calculations exhibit an extremely sharp peak in the density of states D(E F ) arising from a flat d x 2 -y 2 band. A comparison of the Sommerfeld coefficient of the electronic specific heat with χ(T → 0) suggests the presence of strong ferromagnetic itinerant spin correlations which on the basis of the Stoner criterion predicts that SrCo 2 As 2 should be an itinerant ferromagnet, in conflict with the magnetization data. The χ(T) does have a large magnitude, but also exhibits a broad maximum at 115 K suggestive of dynamic short-range AFM spin correlations, in agreement with the neutron scattering data. The measurements show no evidence for any type of phase transition between 1.3 and 300 K and we propose that metallic SrCo 2 As 2 has a gapless quantum spin-liquid ground state.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗