Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Fractionalization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,441 records · Page 80
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Rate constant for the fraction of atomic chlorine with formaldehyde from 200 to 500K

A flash photolysis - resonance fluorescence technique was used to measure rate constant. The results were independent of substantial variations in H2CO, total pressure (Ar), and flash intensity (i.e., initial Cl). The rate constant was shown to be invariant with temperature, the best representation for this temperature range being K = (7.48 + or - 0.50) x 10 to the minus 11 power cu cm molecule-1 s-1 where the error is one standard deviation. The rate constant is theoretically discussed and the potential importance of the reaction in stratospheric chemistry is considered.

Michael, J. V.↗
NASA NTRS1979

Computation of atmospheric attenuation of sound for fractional-octave bands

Correct methods of accounting for atmospheric attenuation in band data requiring consideration of the integrated effect across the bands of the specific distance involved are discussed. Computer programs are provided that are understandable, efficient, and simple to use. It is hoped that this will facilitate more widespread use of correct computational methods, especially where routine computer processing of data is employed.

Montegani, F. J.↗
NASA NTRS1978

Volatile elements in chondrites - Metamorphism or nebular fractionation

Three of the most highly metamorphosed meteorites of their respective classes, Shaw (LL7), Karoonda (C5), and Coolidge (C4), were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Pd, Rb, Re, Sb, Se, Te, Tl, U, and Zn. Comparison with data by Lipschutz and coworkers (1977) on artificially heated primitive meteorites shows that the natural metamorphism of meteorites cannot have taken place in a system open to volatiles. Shaw, metamorphosed at 1300 C for more than 1 million yr, is less depleted in In, Bi, Ag, Te, Zn, and Tl than Krymka heated at 1000 C for 1 week. Karoonda, metamorphosed at 600 C for many millennia, is less depleted in Bi and Tl than Allende heated at 600 C for 1 week. Data on primordial noble gases also show that the volatile-element patterns of ordinary and carbonaceous chondrites were established by nebular condensation and changed little, if at all, during metamorphism. For enstatite chondrites, the evidence is still incomplete but seems to favor a nebular origin of the volatile pattern.

Takahashi, H.↗
NASA NTRS1978

Experimental investigations of trace element fractionation in iron meteorites. I - Early results

Experimental procedures for measuring trace element partitioning among metal and sulfide and silicate phases are described, and solid metal/liquid metal partition coefficients for minor and trace elements in the Fe-Ni system at 5 to 14% Ni are reported. The bulk compositions desired are homogenized at superliquidus temperature for 15-24 hours, held at a temperature in the solid/liquid two phase region for about 24 hours, and quenched to freeze in the equilibrium compositions. Run products are analyzed by electron microprobe. With the exception of Cr, all preliminary partition coefficients obtained are in the same sense as values derived from iron meteorites. The partition coefficients for Cr in solid metal/liquid metal and metal/troilite systems suggest that IIIAB and main group pallasites equilibrated with 9-22% troilite. A second method which makes it possible to place upper and lower limits on the partition coefficient by holding part of the sample at subliquidus and part at superliquidus temperatures, yielded significantly different results for the two metals tested (Au and Pt) from those obtained by the first method, demonstrating the importance of a close approach to equilibrium before using experimentally-determined partition coefficients to test empirical differentiation models for iron meteorites.

Bild, R. W.↗
NASA NTRS1978

An experimental investigation of fractionation by sputter deposition

Artificial glass targets composed of elements varying widely in atomic weight were irradiated at an angle of incidence of 45 deg by 2-keV hydrogen ions at a current density of .33 mA/sq cm, and sputtered atoms were caught on a molybdenum film. Analyses of the sputter-deposited films and unsputtered target glasses were carried out by electron microprobe. The backward-sputtered component was found to be enriched in elements of low atomic weight, while the forward-sputtered component was enriched in heavy atoms. These results indicate that at the lunar surface lighter elements and isotopes would tend to be ejected in backward directions, escaping directly through the openings which admit bombarding ions without first striking an adjacent grain surface; heavy elements and isotopes would be forward-sputtered deeper into the soil and be preferentially retained, contributing to the reported enrichments of heavy elements and isotopes. Additional results show that the binding energy of an element in its oxide form influences the sticking coefficient of a sputtered atom; elements of low binding energy are likely to desorb, while elements of high binding energy tend to stick to the first bounce surface.

Paruso, D. M.↗
NASA NTRS1980

Hazards of high altitude decompression sickness during falls in barometric pressure from 1 atm to a fraction thereof

Various tests related to studies concerning the effects of decompression sicknesses at varying pressure levels and physical activity are described. The tests indicate that there are no guarantees of freedom from decompression sicknesses when man transitions from a normally oxygenated normobaric nitrogen-oxygen atmosphere into an environment having a 0.4 atm or lower pressure and he is performing physical work.

Genin, A. M.↗
NASA NTRS1980

Chemical fractionations in meteorites. XI - C2 chondrites

Measurements of the compositions of 20 trace elements in the representative C2 chondrites Boriskino, Cold Bokkeveld, Erakot, Essebi, Haripura, Santa Cruz and Al Rais are reported. The contents of Ag, Au, Bi, Cd, Cs, Ge, In, Ir, Ni, Os, Pd, Rb, Re, Sb, Se, Sn, Te, Tl, U, and Zn were determined by radiochemical neutron activation analysis. The siderophile abundances of the C2 chondrites are found to be less uniform than those of other carbonaceous chondrites, while the C2R chondrite Al Rais is systematically lower in 12 volatiles than the C2M chondrites. Enrichment of Bi and Tl found in Erakot and Haripura indicate the possible presence of the late condensate mysterite. Volatile abundances are shown to agree with matrix contents for meteorites that have suffered little aqueous alteration, however to be 20-30% lower for the more altered meteorites. Finally, the decline of element abundance with volatility is shown to be consistent with the sigmoid curve explained by the two-component model.

Wolf, R.↗
NASA NTRS1980

The combined effects of ionizing radiation and weightlessness on calcium and phosphorus content in the mineral fraction of the calcified tissues in the rat skeleton

Phosphorus and calcium content in the ash from skeletal bones (ribs, scapula, vertebra, and crus) of 30 rats exposed to ionizing radiation (800 rads) on the flight of the Kosmos 690 biosatellite was studied. A 10 percent decrease in ash content coefficient and 29 percent decrease in phosphorus content was found immediately after the flight, and a 9 percent decrease in phosphorus content persisted after 26 days of readaptation to terrestrial conditions.

Prokhonchukov, A. A.↗
NASA NTRS1980

A comparison of fractionation trends in the lunar crust and the Stillwater complex

Trends analogous to those of lunar highland samples are found in a plot of Mg/(Mg+Fe) in mafic minerals against the anorthosite content of coexisting plagioclase for the Stillwater complex. By applying the model derived from such data to lunar highland rocks, major element variations in the 'ferroan anorthosite' suite can be explained. It is concluded that the anorthositic suite may represent the original lunar crust, whereas the Mg-rich suite may have been derived from later high level intrusions.

Raedeke, L. D.↗
NASA NTRS1981

Fractional-frequency rotor motion due to nonsymmetric clearance effects

Analysis based on the Jeffcott model is presented to explain 1/2 speed and 1/3 speed whirling motion occurring in rotors which are subject to periodic normal-loose or normal-tight radial stiffness variations. The normal-loose stiffness variation results due to bearing-clearance effects, while normal-tight stiffness variations result from rubbing over a portion of a rotor's orbit. The results demonstrate that 1/2 speed subharmonic motion can be explained as either a linear parametric-excitation phenomenon or as a stable nonlinear subharmonic motion. The 1/3 speed motion is shown to be possible due to the radial stiffness nonlinearity. A linear parametric-excitation analysis demonstrates that during a normal-tight rubbing condition, Coulomb damping significantly widens the potential range of unstable speeds.

Childs, D. W.↗
NASA NTRS1983

Refractory precursor components of Semarkona chondrules and the fractionation of refractory elements among chondrites

Instrumental neutron activation analysis has been used to measure about 20 of the lithophile elements in 30 chondrules from the Semarkona chondrite. The amounts of oxidized iron were calculated from other compositional parameters, and Si concentrations are estimated from mass-balance considerations. It is suggested that the refractory component probably forms from fine grained materials that were able to equilibrate down to lower nebular temperatures. The chondrite matrix may have had an origin similar to that of the nonrefractory material. The low abundance of refractories and Mg in ordinary and enstatite chondrites was produced by the loss of materials having a higher refractory element/Mg ratio than that of the refractory element of the chondrules.

Grossman, J. N.↗