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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,441 records · Page 80

Human life support during interplanetary travel and domicile. IV - Mars expedition technology trade study

Results of trading processing technologies in a closed-loop configuration, in terms of power and weight for the Mars Expedition Mission, are presented. The technologies were traded and compared to a baseline set for functional elements that include CO2 removal, H2O electrolysis, potable H2O cleanup, and hygiene H2O cleanup. These technologies were selected from those being considered for Space Station Freedom and represent only chemical/physical technologies. Attention is given to the technology trade calculation scheme, technology data and selection, the generic modular flow schematic, and life support system specifications.

Rohatgi, Naresh K.↗

Total Organic Carbon Analyzer

The development and testing of a breadboard version of a highly sensitive total-organic-carbon (TOC) analyzer are reported. Attention is given to the system components including the CO2 sensor, oxidation reactor, acidification module, and the sample-inlet system. Research is reported for an experimental reagentless oxidation reactor, and good results are reported for linearity, sensitivity, and selectivity in the CO2 sensor. The TOC analyzer is developed with gravity-independent components and is designed for minimal additions of chemical reagents. The reagentless oxidation reactor is based on electrolysis and UV photolysis and is shown to be potentially useful. The stability of the breadboard instrument is shown to be good on a day-to-day basis, and the analyzer is capable of 5 sample analyses per day for a period of about 80 days. The instrument can provide accurate TOC and TIC measurements over a concentration range of 20 ppb to 50 ppm C.

Godec, Richard G.↗

NASA's Office of Aeronautics and Exploration Technology space power flight projects

NASA created a program called In-STEP (in-space technology experiments program) to give the aerospace community an opportunity to validate advanced technologies in space. In-STEP has funded feasibility studies for the following experiments in the power technology arena: a microsphere insulation investigation, a utilized regenerative fuel cell experiment, an inflatable solar collector experiment, a moving belt radiator experiment, and a liquid drop radiator experiment. The following experiments are currently in the experiment definition phase: an integrated two-phase thermal experiment, an electrolysis performance experiment, and a sodium sulfur battery experiment. Three In-STEP experiments are entering the hardware fabrication phase: thermal energy storage technology, solar array module plasma interaction, and heat pipe performance experiments. Each of these experiments is described, with an emphasis on the benefits of technology validation.

Chmielewski, Art B.↗

Vapor-Exposure Cell For Testing Thin-Film Electrodes

Vapor-exposure test cell (VETC) designed to be used in testing thin-film electrodes on solid electrolytes electrochemically at high temperature. Use of VETC much simpler and less expensive than testing alkali-metal thermal-to-electric converter (AMTEC) fuel cell, electrolysis cell, or other entire device containing solid electrolyte and electrodes of material and configuration to be characterized.

Ryan, Margaret A.↗

Preventing Growth Of Barnacles On Propellers

Possible to prevent barnacles and other marine life from obtaining firm bonds on propellers and other metal parts by coating parts with NEDOX (or equivalent) cavitation-resistant material. Available in several forms; one that works best is mold-release coating. Also provides improved surface hardness, protection against electrolysis, better resistance to abrasion, and less friction between propellers and water.

Parrish, Kemp L.↗

Lunar mining of oxygen using fluorine

An important aspect of lunar mining will be the extraction of volatiles, particularly oxygen, from lunar rocks. Thermodynamic data show that oxygen could readily be recovered by fluorination of abundant lunar anorthite, CaAl2Si2O8. Fluorine is the most reactive element, and the only reagent able to extract 100 percent of the oxygen from any mineral, yet it can safely be stored or reacted in nickel or iron containers. The general fluorination reaction, mineral + 2F2 = mixed fluorides = O2, has been used for more than 30 years at a laboratory scale by stable-isotope geochemists. For anorthite, metallic Al and Si may be recovered from the mixed fluorides by Na-reduction, and CaO via exchange with Na2O; the resulting NaF may be recycled into F2 and Na by electrolysis, using lanthanide-doped CaF2 as the inert anode.

Burt, Donald M.↗

SPE propulsion electrolyzer for NASA's integrated propulsion test article

Hamilton Standard has delivered a 3000 PSI SPE Propulsion Electrolyzer Stack and Special Test Fixture to the NASA Lyndon B. Johnson Space Center (JSC) Integrated Propulsion Test Article (IPTA) program in June 1990, per contract NAS9-18030. This prototype unit demonstrates the feasibility of SPE-high pressure water electrolysis for future space applications such as Space Station propulsion and Lunar/Mars energy storage. The SPE-Propulsion Electrolyzer has met or exceeded all IPTA program goals. It continues to function as the primary hydrogen and oxygen source for the IPTA test bed at the NASA/JSC Propulsion and Power Division Thermochemical Test Branch.

Source record↗

The onsite manufacture of propellant oxygen from lunar resources

The Aerojet carbothermal process for the manufacture of oxygen from lunar materials has three essential steps: the reduction of silicate with methane to form carbon monoxide and hydrogen; the reduction of carbon monoxide with hydrogen to form methane and water; and the electrolysis of water to form hydrogen and oxygen. The reactions and the overall process are shown. It is shown with laboratory experimentation that the carbothermal process is feasible. Natural silicates can be reduced with carbon or methane. The important products are carbon monoxide, metal, and slag. The carbon monoxide can be completely reduced to form methane and water. The water can be electrolyzed to produce hydrogen and oxygen. A preliminary engineering study shows that the operation of plants using this process for the manufacture of propellant oxygen has a large economic advantage when the cost of the plant and its operation is compared to the cost of delivering oxygen from Earth.

Rosenberg, Sanders D.↗

NASA Space Engineering Research Center for utilization of local planetary resources

Because of a change in the NASA funding cycle, the present reporting period covers only the six months from March to September 1991. Nevertheless, remarkable progress was made in a number of areas, some of the most noteworthy of which are: (1) Engineering operation of a breadboard CO2 yields O2 demonstration plant that produced over 10 grams of oxygen per day during several runs of over 100 hours each with a single electrolytic cell. Complete automation of controls, monitoring of various inputs/outputs and critical internal variables, diagnostics, and emergency shutdown in an orderly manner were also included. Moreover, 4-cell and 16-cell units, capable of much higher rates of production, were assembled and tested. (2) Demonstration of a 200 percent increase in the carbothermal reduction of ilmenite through vapor deposition of carbon layers on particles of that material. (3) Demonstration of the deposition of strong iron films from carbonyl chemical vapor deposition, establishing the crucial role of additive gases in governing the process. (4) Discovery of an apparent 800 percent increase in the conversion rates of a modified ilmenite simulant in a plasma-augmented reactor, including direct enhancement by solar radiation absorption. (5) Proof that test specimens of lunar soil with small amounts of metallic additives, recrystallized at moderate temperatures, exhibit an improvement of several orders of magnitude in ductility/tensile strength. (6) Experiments establishing the feasibility of producing silicon-based polymers from indigenous lunar materials. (7) Application of CCD technology to the production of maps of TiO2 abundance, defining primary ilmenite deposits, on the disk of the full moon. (8) Attainment of a discovery rate of approximately 3 new near-Earth asteroids per month by Spacewatch, more than doubling the previous global rate. (9) Coordination of industry and university magma electrolysis investigations in a workshop designed to define remaining problem areas and propose critical experiments.

Ramohalli, Kumar↗

Integrated oxygen recovery system

Life Systems has conceptualized an innovative Integrated Oxygen Recovery System (IORS) applicable to advanced mission air revitalization. The IORS provides the capability to electrochemically generate metabolic oxygen (O2) and recover O2 from the space habitat atmosphere via a carbon dioxide (CO2) reduction process within a single assembly. To achieve this capability, the IORS utilizes a Solid Metal Cathode (SMC) water electrolysis unit that simultaneously serves as the Sabatier CO2 reduction reactor. The IORS enables two major life support systems currently baselined in closed loop air revitalization systems to be combined into one smaller, less complex system. This concept reduces fluidic and electrical interface requirements and eliminates a hydrogen (H2) interface. Life Systems is performing an evaluation of the IORS process directed at demonstrating performance and quantifying key physical characteristics including power, weight, and volume. Technical progress achieved during the first two months of the program is summarized.

Lee, M. Gene↗

Integrated oxygen recovery system

Life Systems has conceptualized an innovative Integrated Oxygen Recovery System (IORS) applicable to advanced mission air revitalization. The IORS provides the capability to electrochemically generate metabolic oxygen (O2) and recover O2 from the space habitat atmosphere via a carbon dioxide (CO2) reduction process within a single assembly. To achieve this capability, the IORS utilizes a Solid Metal Cathode (SMC) water electrolysis unit that simultaneously serves as the Sabatier CO2 reduction reactor. The IORS enables two major life support systems currently baselined in closed loop air revitalization systems to be combined into one smaller, less complex system. This concept reduces fluidic and electrical interface requirements and eliminates a hydrogen (H2) interface. Life Systems is performing an evaluation of the IORS process directed at demonstrating performance and quantifying key physical characteristics including power, weight, and volume. The results of the checkout, shakedown, and initial parametric tests are summarized.

Lee, M. Gene↗

Lunar mining of oxygen using fluorine

Experiments during the first year of the project were directed towards generating elemental fluorine via the electrolysis of anhydrous molten fluorides. Na2SiF6 was dissolved in either molten NaBF4 or a eutectic (minimum-melting) mixture of KF-LiF-NaF and electrolyzed between 450 and 600 C to Si metal at the cathode and F2 gas at the anode. Ar gas was continuously passed through the system and F2 was trapped in a KBr furnace. Various anode and cathode materials were investigated. Despite many experimental difficulties, the capability of the process to produce elemental fluorine was demonstrated.

Burt, Donald M.↗

Space Station propulsion integrated propulsion test article

Viewgraphs on space station propulsion integrated propulsion test articles are presented. Topics covered include: integrated propulsion test article; phase 1 configuration description; phase 2 testing; and electrolysis unit development contracts.

Henderson, J.↗

Propulsion technology discipline

Viewgraphs on propulsion technology discipline for Space Station Freedom are presented. Topics covered include: water electrolysis O2/H2 system; hydrazine system advancements; common technology; fluids disposal; and storable bipropellant system.

Jones, Lee W.↗

Propellant production and useful materials: Hardware data from components and the systems

Research activities at the University of Arizona/NASA Space Engineering Research Center are described; the primary emphasis is on hardware development and operation. The research activities are all aimed toward introducing significant cost reductions through the utilization of resources locally available at extraterrestrial sites. The four logical aspects include lunar, Martian, support, and common technologies. These are described in turn. The hardware realizations are based upon sound scientific principles which are used to screen a host of interesting and novel concepts. Small scale feasibility studies are used as the screen to allow only the most promising concepts to proceed. Specific examples include: kg/day-class oxygen plant that uses CO2 as the feed stock, spent stream utilization to produce methane and 'higher' compounds (using hydrogen from a water electrolysis plant), separation of CO from the CO2, reduction of any iron bearing silicate (lunar soils), production of structural components, smart sensors and autonomous controls, and quantitative computer simulation of extraterrestrial plants. The most important feature of all this research continues to be the training of high-quality students for our future in space.

Ramohalli, Kumar↗

On-site manufacture of propellant oxygen from lunar resources

The Aerojet Carbothermal Process for the manufacture of oxygen from lunar resources has three essential steps: the reduction of silicate with methane to form carbon monoxide and hydrogen; the reduction of carbon monoxide with hydrogen to form methane and water; and the electrolysis of water to form oxygen and hydrogen. This cyclic process does not depend upon the presence of water or water precursors in the lunar materials; it will produce oxygen from silicates regardless of their precise composition and fine structure. Research on the first step of the process was initiated by determining some of the operating conditions required to reduce igneous rock with carbon and silicon carbide. The initial phase of research on the second step is completed; quantitative conversion of carbon monoxide and hydrogen to methane and water was achieved with a nickel-on-kieselguhr catalyst. The equipment used in and the results obtained from these process studies are reported in detail.

Rosenberg, Sanders D.↗

Current-Collecting Grids For AMTEC Electrodes

Photodeposition or sputter deposition of refractory metal in grid pattern on solid electrolyte of alkali-metal thermoelectric converter (AMTEC) prior to deposition of electrode decreases electronic resistance and increases current and peak power of converter significantly. Concept also applicable to other devices that include electrically conductive, porous electrodes; such as solid-state fuel cells and solid-state electrolysis cells.

Ryan, Margaret A.↗

Primary and secondary electrical space power based on advanced PEM systems

For new space ventures, power continues to be a pacing function for mission planning and experiment endurance. Although electrochemical power is a well demonstrated space power technology, current hardware limitations impact future mission viability. In order to document and augment electrochemical technology, a series of experiments for the National Aeronautics and Space Administration Lewis Research Center (NASA LeRC) are underway at the Los Alamos National Laboratory that define operational parameters on contemporary proton exchange membrane (PEM) hardware operating with hydrogen and oxygen reactants. Because of the high efficiency possible for water electrolysis, this hardware is also thought part of a secondary battery design built around stored reactants - the so-called regenerative fuel cell. An overview of stack testing at Los Alamos and of analyses related to regenerative fuel cell systems are provided in this paper. Finally, this paper describes work looking at innovative concepts that remove complexity from stack hardware with the specific intent of higher system reliability. This new concept offers the potential for unprecedented electrochemical power system energy densities.

Vanderborgh, N. E.↗