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At least 1,441 records · Page 80
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Efficient Iridium Catalysts for Formic Acid Dehydrogenation: Investigating the Electronic Effect on the Elementary β-Hydride Elimination and Hydrogen Formation Steps

We report herein a series of Cp*Ir complexes containing a rigid 8-aminoquinolinesulfonamide moiety as highly efficient catalysts for the dehydrogenation of formic acid (FA). The complex [Cp*Ir(L)Cl] (HL = N-(quinolin-8-yl)benzenesulfonamide) displayed a high turnover frequency (TOF) of 2.97 × 10 4 h –1 and a good stability (>100 h) at 60 °C. Comparative studies of [Cp*Ir(L)Cl] with the rigid ligand and [Cp*Ir(L')Cl] (HL' = N-propylpypridine-2-sulfonamide) without the rigid aminoquinoline moiety demonstrated that the 8-aminoquinoline moiety could dramatically enhance the stability of the catalyst. The electron-donating ability of the N,N'-chelating ligand was tuned by functionalizing the phenyl group of the L ligand with OMe, Cl, and CF 3 to have a systematical perturbation of the electronic structure of [Cp*Ir(L)Cl]. Experimental kinetic studies and density functional theory (DFT) calculations on this series of Cp*Ir complexes revealed that (i) the electron-donating groups enhance the hydrogen formation step while slowing down the β-hydride elimination and (ii) the electron-withdrawing groups display the opposite effect on these reaction steps, which in turn leads to lower optimum pH for catalytic activity compared to the electron-donating groups.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

Defects clustering and ordering in di- and trivalently doped ceria

Graphical abstract: Display Omitted Highlights: ► Defect structures in trivalently and divalently doped ceria has been elucidated. ► Dumbbell structure is a universal basic vacancy structure in fluorite oxides. ► Electrostatic attraction dominates elastic interaction in doped ceria. ► Provide a physical picture of conductivity behavior in aliovalently doped ceria. -- Abstract: The formation and growth of defect clusters in CeO{sub 2}-M{sub 2}O{sub 3} (M = La{sup 3+}, Pr{sup 3+}, Sm{sup 3+}, Gd{sup 3+}, Dy{sup 3+}, Y{sup 3+}, Yb{sup 3+}) and CeO{sub 2}-DO (N = Cd{sup 2+}, Ca{sup 2+}, Sr{sup 2+}, Ba{sup 2+}) binary solid solutions have been comparatively studied by atomistic simulations based on energy minimization of atomic interactions. The calculation ensemble, including both divalent and trivalent dopants, shows a similar energetic tendency for defect species (dopants and associated oxygen vacancies) to aggregate and grow. The dumbbell structure has been verified as a universal vacancy structure in oxygen deficient fluorite lattice. Nevertheless, it also demonstrates different tendencies of dopant–vacancy associations that depend on dopant valence and radius. The dopant is site-selective in trivalent defect clusters correlated with dopant size. While in divalent solid solutions, clusters adopt similar dopant–vacancy locations. Furthermore, all clusters in divalently doped ceria have stronger dopant–vacancy associations/interactions compared to those in trivalent ones. As a consequence, the correlation of the dopant size as well as valence effects on oxygen-ion conductivity has been illustrated based on an ordered defect cluster model. This study thereby offers insight into the physical picture of ionic conductivity behavior experimentally obtained in aliovalently doped ceria.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Observations of stem water storage in trees of opposing hydraulic strategies

Hydraulic capacitance and water storage form a critical buffer against cavitation and loss of conductivity within the xylem system. Withdrawal from water storage in leaves, branches, stems, and roots significantly impacts sap flow, stomatal conductance, and transpiration. Storage quantities differ based on soil water availability, tree size, wood anatomy and density, drought tolerance, and hydraulic strategy (anisohydric or isohydric). However, the majority of studies focus on the measurement of storage in conifers or tropical tree species. We demonstrate a novel methodology using frequency domain reflectometry (FDR) to make continuous, direct measurements of wood water content in two hardwood species in a forest in Michigan. We present results of a two month study comparing the water storage dynamics between a mature red oak and red maple, two species with differing wood densities, hydraulic architecture, and hydraulic strategy. We also include results pertaining to the use of different probe lengths to sample water content only within the active sapwood and over the entire conductive sapwood and the outer portion of heartwood in red oak. Both species studied exhibited diurnal cycles of storage that aligned well with the dynamics of sap flux. Red maple, a diffuse porous, relatively isohydric species showed a strong dependence on stored water during both wet and dry periods. Red oak, a ring porous relatively anisohydric species, was less reliant on storage, and did not demonstrate a dependence on soil water potential. Comparison between long and short FDR probes in the oak revealed that oaks may utilize water stored in the innermost layers of the xylem when soil moisture conditions are limiting. We found the FDR probes to be a reliable, functional means for continuous automated measurement of wood water content in hardwoods at a fast time scale. Application of FDR technology for the measurement of tree water storage will benefit forest ecologists as well as the modeling community as we improve our understanding and simulations of plant hydrodynamic processes on a large scale.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Scoping Analysis of Sodium Cooled Fast Spectrum Test Reactor Cores

A team from the national laboratories conducted a study that assessed advanced reactor technology options and the irradiation needs of a broad group of stakeholders. This identified a gap in the fast neutron irradiation capability - the need for a test reactor that can deliver high neutron fluxes of fast neutrons. The study compared fast and thermal neutron irradiation technology options based on technology maturity and the ability to meet strategic objectives, along with pathways to deployment and tradeoffs in mission. It also provided a recommendation on specific technology options to address the current gap in fast neutron irradiation capabilities. In this context, a detailed scope of work was prepared that pertains to a trade study focusing on the core of a fast neutron spectrum test reactor. This report presents the main results obtained by a team of Argonne National Laboratory (ANL) and Idaho National Laboratory (INL) scientists. It aims at developing an overall understanding of how the various areas important to the design and successful operation of such a facility interact with one another. Developing a sense of the relevant sensitivities at a systems level creates an understanding of where and how margins may be available to improve performances (e.g., flux level, capacity factor, and thermal hydraulic limits). Emphasis is given to the reactor (core design options and safety) and its fuel cycle (fuel supply and fabrication, as well as spent fuel management).

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS1988

Model of Jovian F region ionosphere

To date, seven electron density profiles of the Jovian ionosphere have been furnished by the radio occultation experiments aboard the Pioneer and Voyager space probes. The data correspond to various localities (latitudes and longitudes) and times (dawn and dusk) and phases of sunspot cycle (high and low). This renders comparative studies difficult. Nevertheless, the possibility of existence of diurnal variation, equatorial anomaly, and auroral particle precipitation in the Jovian ionosphere have been put forth. The grand magnitude and depth of the equatorial anomaly, in particular, is a matter of great interest and speculation. Correct interpretations of the data and the physical processes in the complex Jovian atmospheric environment will remain a major task for the Aeronomer for decades to come. Model studies of a Jovian ionosphere created by solar EUV radiation and subjected to model ExB drifts showed that equatorial anomaly similar to that in the terrestrial ionosphere can indeed be produced in the Jovian ionosphere. However, owing to the difference in size and rotation period of the two planets and the ionic compositions, much larger drift velocities are required to produce a comparable anomaly in the Jovian atmosphere.

Tan, A.↗
DOE OSTI2016

On the evolution of secondary hardening carbides during continuous versus isothermal heat treatment of high speed steel HS 6-5-2

The continuous heat treatment of high speed steels reduces the process times from several hours to a few minutes. The resulting cost savings as well as lower decarburisation and distortion make the continuous heat treatment favourable over an isothermal heat treatment. However, the microstructure-property relationship during continuous heat treatments is far from being well understood. In order to identify the key microstructural features for the future optimisation of continuous heat treatments of high speed steels this study compares a current industrial continuous and an isothermal heat treatment of steel HS 6-5-2 by means of light optical microscopy, scanning electron microscopy, X-ray diffraction, atom probe tomography, and red hardness. After continuous hardening the content of primary carbides is higher and the amount of retained austenite is lower compared to isothermal hardening. Due to the reduced time for dissolution of primary carbides a lower content of alloying elements is present in the martensitic matrix for subsequent tempering. Therefore, the chemical composition of the secondary hardening carbides after tempering is different for a continuous heat treatment. Although the difference in chemistry is quite pronounced, the deterioration of the hardness at elevated temperatures, which strongly influences the performance characteristics of the finished parts, is not altered. - Highlights: •We studied the continuous and isothermal heat treatment of the steel HS 6-5-2. •The amount of primary carbides is higher in a continuously heat treated steel. •The chemistry of secondary hardening carbides changes during tempering. •Continuously heat treated steels exhibit the same performance characteristics.

36 MATERIALS SCIENCE↗
NASA NTRS1975

Remote sensing applications in water resources management by the California Department of Water Resources

The possibility of applying imagery from high altitude aircraft and satellites sensors to water management in California was evaluated. Results from seven applications studies comparing the costs of using high altitude imagery for various purposes to the costs of using conventional data sources, reveal the high altitude imagery to be more cost effective in six cases and equal to conventional data sources in one case. These results also reveal that the imagery provides a level of quality not generally achievable with uncorrected conventional imagery. Although satellite application studies are not yet complete, preliminary results indicate that some definite possibilities exist for employing satellite imagery on an operational basis within the next few years.

Brown, B.↗
NASA NTRS1991

WetNet: Using SSM/I data interactively for global distribution of rainfall and precipitable water

By completing hardware installation, preparing for comparative studies of SSM/I, radar, and lightning data, it is believed that this will be a powerful combination for evaluating the global distribution of tropical rainfall, and the vertical distribution of latent heating, with strong application to algorithms for use on TRMM, EOS-A, and future GOES spacecraft. Potential data bases will be surveyed, about 5 case studies with surface rainfall, radar, lightning, and sounding data will be identified. SSM/I algorithms will be used to identify convective regions of MCSs. A catalog will be developed of the global profile of heavy tropical rainfall, and how these zones are organized within larger tropical weather systems. Beginning with the first few months of SSM/I data distributed over WetNet, SSM/I radiances will be compared with TOVS radiance (moisture and thermal) and OLR observations. The purpose is to improve understanding of how real world water vapor profiles in the tropical atmosphere are perceived by SSM/I precipitable water algorithm and, at the same time, by the TOVS water vapor channel.

Zipser, Edward J.↗
NASA NTRS2017

Climatological Study of the Short-Term Variation of the 0 C, -10 C, and -20 C Altitude Levels over the Florida Spaceport

For evaluation of the potential of cloud electrification, it is necessary to know the altitude of the 0, -10 and -20 degree Celsius levels. Cape Canaveral Air Force Station has recorded balloon launch data back to 1989. In support of rocket launches, often multiple balloons are launched within minutes of each other in the 4-6 hours leading up to launch. In the past, temperature data from sondes was typically available every hour or so through the launch countdown, allowing for frequent updates of these critical temperature thresholds. Recently, launch customers are relying on Jimsphere and wind profiler data that do not have a thermodynamic component in the latter 4-6 hours of a countdown. This study compares the altitude differences of the 0, -10 and -20 degree Celsius levels from consecutive balloon pairs not to exceed 6 hours apart. The analysis uses 9685 soundings from 1989 to 2013. Approximately 5 of the time the altitude of the temperature level in question (0, -10, -20 degrees C), varies by more than 500 feet (operationally significant threshold) within 6 hours. This study analyzes the altitude variability as a function of several meteorological parameters, such as change in sonde type, dew point depression, and solar zenith angle. Additionally, the study concludes with impacts to launch operations.

Huddleston, Lisa L.↗
DOE OSTI2013

Nonlinear evolution of the magnetized Kelvin-Helmholtz instability: From fluid to kinetic modeling

The nonlinear evolution of collisionless plasmas is typically a multi-scale process, where the energy is injected at large, fluid scales and dissipated at small, kinetic scales. Accurately modelling the global evolution requires to take into account the main micro-scale physical processes of interest. This is why comparison of different plasma models is today an imperative task aiming at understanding cross-scale processes in plasmas. We report here the first comparative study of the evolution of a magnetized shear flow, through a variety of different plasma models by using magnetohydrodynamic (MHD), Hall-MHD, two-fluid, hybrid kinetic, and full kinetic codes. Kinetic relaxation effects are discussed to emphasize the need for kinetic equilibriums to study the dynamics of collisionless plasmas in non trivial configurations. Discrepancies between models are studied both in the linear and in the nonlinear regime of the magnetized Kelvin-Helmholtz instability, to highlight the effects of small scale processes on the nonlinear evolution of collisionless plasmas. We illustrate how the evolution of a magnetized shear flow depends on the relative orientation of the fluid vorticity with respect to the magnetic field direction during the linear evolution when kinetic effects are taken into account. Even if we found that small scale processes differ between the different models, we show that the feedback from small, kinetic scales to large, fluid scales is negligible in the nonlinear regime. This study shows that the kinetic modeling validates the use of a fluid approach at large scales, which encourages the development and use of fluid codes to study the nonlinear evolution of magnetized fluid flows, even in the collisionless regime.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2024

The Analogs for VENus’ GEologically Recent Surfaces (AVENGERS) Initiative: Updates and New Target Areas

Several missions to Venus have been recently selected for launch, opening a new era for the exploration of the planet. One of the key questions that future missions need to address is the rate and style of present-day volcanic activity on Venus. To this regard, an important target on Venus is certainly represented by the young topographic rises, which can be interpreted as the surface expression of underlying mantle plumes. These areas can be considered as the geologically youngest regions of Venus, being characterized by recent volcanic and tectonic activity. Studying areas of active volcanism and tectonism on Venus is crucial as it can reveal clues to the geologic past of the planet, as well as provide information about the volatile content of its interior and about the formation of its dense atmosphere. The “Analogs for VENus’ GEologically Recent Surfaces” (AVENGERS) initiative aims to select and analyze a number of terrestrial analog sites for the comparative study of recent and possibly ongoing volcanic activity on Venus. In addition to its scientific importance, the AVENGERS initiative acts as a bridge for international scientific collaboration, including selected mission teams.

P D'Incecco↗
NASA NTRS2015

Comparing and Contrasting Detectors: JWST NIR vs HST WFC3

In many ways, WFC3s IR channel is a good indicator for what to expect with JWST. There are some differences, most of which should be beneficial in JWST- JWSTs lower operating temperature will freeze out charge traps that would affect WFC3. Benefits should include lower dark current, lower persistence, and better reciprocity- JWSTs more recent HgCdTe process has lower defect density. The benefits are as described above- JWST uses better indium barriers. The benefits should include fewer RC type pixels. One area where more study might be beneficial is stability. The detector electronics play a significant role in determining how stable a detector system is(v.s. bias drifts and photometry). JWSTs SIDECARs are completely WFC3s Ball electronics- Studies comparing the bias and photometric stability of WFC3 and JWST might be useful to informing data acquisition and calibration strategies for JWST.

NIR↗
DOE OSTI2014

Ce–O Covalence in Silicate Oxyapatites and Its Influence on Luminescence Dynamics

Cerium substituting gadolinium in Ca2Gd8(SiO4)6O2 occupies two intrinsic sites of distinct coordination. The coexistence of an ionic bonding at a 4F site and an ionic–covalent mixed bonding at a 6H site in the same crystalline compound provides an ideal system for comparative studies of ion–ligand interactions. Experimentally, the spectroscopic properties and photoluminescence dynamics of this white-phosphor are investigated. An anomalous thermal quenching of the photoluminescence of Ce3+ at the 6H site is analyzed. Theoretically, ab initio calculations are conducted to reveal the distinctive properties of the Ce–O coordination at the two Ce3+ sites. The calculated eigenstates of Ce3+ at the 6H site suggest a weak Ce–O covalent bond formed between Ce3+ and one of the coordinated oxygen ions not bonded with Si4+. The electronic energy levels and frequencies of local vibrational modes are correlated with specific Ce–O pairs to provide a comparative understanding of the site-resolved experimental results. On the basis of the calculated results, we propose a model of charge transfer and vibronic coupling for interpretation of the anomalous thermal quenching of the Ce3+ luminescence. The combination of experimental and theoretical studies in the present work provides a comprehensive understanding of the spectroscopy and luminescence dynamics of Ce3+ in crystals of ionic–covalent coordination.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1923

A Study of Taking off and Landing an Airplane

This report covers the results of an investigation carried on at the Langley Memorial Aeronautical Laboratory of the National Advisory Committee for Aeronautics for the purpose of discussing the various methods of effecting the take-off and the landing of an airplane, and to make a direct analysis of the control movements, the accelerations, and air speeds during these the maneuvers. The recording instruments developed at the laboratory were used in this test and the records obtained by them were made the basis for a comparative study of the two extreme methods of taking off (the tail-high and tail-low methods) and of various types of landings. The records should be of considerable value to a student pilot in enabling him to visualize the movements of the controls and the consequent effect upon the air speed and acceleration.

Carroll, T↗
DOE OSTI2015

Recent Arctic tundra fire initiates widespread thermokarst development

Fire-induced permafrost degradation is well documented in boreal forests, but the role of fires in initiating thermokarst development in Arctic tundra is less well understood. Here we show that Arctic tundra fires may induce widespread thaw subsidence of permafrost terrain in the first seven years following the disturbance. Quantitative analysis of airborne LiDAR data acquired two and seven years post-fire, detected permafrost thaw subsidence across 34% of the burned tundra area studied, compared to less than 1% in similar undisturbed, ice-rich tundra terrain units. The variability in thermokarst development appears to be influenced by the interaction of tundra fire burn severity and near-surface, ground-ice content. Subsidence was greatest in severely burned, ice-rich upland terrain (yedoma), accounting for -50% of the detected subsidence, despite representing only 30% of the fire disturbed study area. Microtopography increased by 340% in this terrain unit as a result of ice wedge degradation. Increases in the frequency, magnitude, and severity of tundra fires will contribute to future thermokarst development and associated landscape change in Arctic tundra regions.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2018

Experimental Thermal Performance Testing of Cryogenic Tank Systems and Materials

A comparative study was conducted to collect and analyze thermal conductivity data on a wide variety of low density materials, as well as thermal performance data on a number of vacuum-jacketed cryogenic tank systems. Although a vast number of these types of materials and cryogenic tank systems exist, the thermal conductivity of insulation materials and the thermal performance of cryogenic tank systems is often difficult to compare because many industrial methods and experimental conditions are available and utilized. The availability of a new thermal conductivity measurement device, the Macroflash Cup Cryostat, which is applicable for assessing a variety of materials, is accessible at NASA's Cryogenic Test Laboratory (CTL) at the Kennedy Space Center (KSC). The convenience of this device has resulted in the ability to rapidly measure the thermal conductivity properties of these materials by using a flat-plate liquid nitrogen (LN2) boiloff technique that employs a guarded heat flow test methodology in order to determine the effective thermal conductivity (ke) of a test specimen. As the thermal conductivities are measured at cryogenic temperatures, materials suitable for both future space missions and cryogenic tank systems can be identified and experimentally analyzed. Also recognizable are materials which may help increase energy efficiency by limiting the thermal losses encountered under various environmental conditions. The overall focus of this work consisted of two parts. One part, was to produce and analyze thermal conductivity data on a wide variety of materials with suitable properties conducive to those needed to aid in the production of a calibration curve for the "low end" of the Macroflash instrument. (Low end meaning materials with a thermal conductivity rating below 100 milliwatts per meter-Kelvin). The second part was to collect and analyze heat transfer data for a variety of small vacuum-jacketed vessels (cryogenic tank systems) in order to compare the thermal performance between them.

Myers, Wesley C.↗
NASA NTRS1998

Enhanced Sea Ice Concentration and Ice Temperature Algorithms for AMSR

Accurate quantification of sea ice concentration and ice temperature from satellite passive microwave data is important because they provide the only long term, spatially detailed and consistent data set needed to study the climatology of the polar regions. Sea ice concentration data are used to derive large-scale daily ice extents that are utilized in trend analysis of the global sea ice cover. They are also used to quantify the amount of open water and thin ice in polynya and divergence regions which together with ice temperatures are in turn needed to estimate vertical heat and salinity fluxes in these regions. Sea ice concentrations have been derived from the NASA Team and Bootstrap algorithms while a separate technique for deriving ice temperature has been reported. An integrated technique that will utilizes most of the channels of AMSR (Advanced Microwave Scanning Radiometer) has been developed. The technique uses data from the 6 GHz and 37 GHz channels at vertical polarization obtain an initial estimate of sea ice concentration and ice temperature. The derived ice temperature is then utilized to estimate the emissivities for the corresponding observations at all the other channels. A procedure for calculating the ice concentration similar to the Bootstrap technique is then used but with variables being emissivities instead of brightness temperatures to minimizes errors associated with spatial changes in ice temperatures within the ice pack. Comparative studies of ice concentration results with those from other algorithms, including the original Bootstrap algorithm and those from high resolution satellite visible and infrared data will be presented. Also, results from a simulation study that demonstrates the effectiveness of the technique in correcting for spatial variations in ice temperatures will be shown. The ice temperature results are likewise compared with satellite infrared and buoy data with the latter adjusted to account for the effects of the snow cover.

Comiso, Josefino C.↗
DOE OSTI2020

Transmural Remodeling of Cardiac Microstructure in Aged Spontaneously Hypertensive Rats by Diffusion Tensor MRI

The long-standing high blood pressure (also known as hypertension) overworks the heart. Microstructural remodeling is a key factor of hypertensive heart disease progression. Diffusion tensor magnetic resonance imaging (DT-MRI) is a powerful tool for the rapid noninvasive nondestructive delineation of the cardiomyocyte organization. The spontaneously hypertensive rat (SHR) is a well-established model of genetic hypertension. The goal of this study was to employ high-resolution DT-MRI and the SHR animal model to assess the transmural layer-specific remodeling of myocardial microstructure associated with hypertension. Ex vivo experiments were performed on excised formalin-fixed hearts of aged SHRs (n = 4) and age-matched controls (n = 4). The DT-MRI-derived fractional anisotropy (FA), longitudinal diffusivity (λ L ), transversal diffusivity (λ T ), and mean diffusivity (MD) served as the readout parameters investigated at three transmural zones (i.e., endocardium, mesocardium, and epicardium). The helix angles (HAs) of the aggregated cardiomyocytes and the orientation of laminar sheetlets were also studied. Compared with controls, the SHRs exhibited decreased epicardial FA, while FA changes in the other two transmural regions were insignificant. No substantial differences were observed in the diffusivity parameters and the transmural course of HAs between the two groups. A consistent distribution pattern of laminar sheetlet orientation was not identified for either group. Our findings are in line with the known cellular microstructure from early painstaking histological studies. Biophysical explanations of the study outcomes are provided. In conclusion, our experimental findings indicate that the epicardial microstructure is more vulnerable to high blood pressure leading to more pronounced changes in this region during remodeling. DT-MRI is well-suited for elucidating these alterations. The revealed transmural nonuniformity of myocardial reorganization may shed light on the mechanisms of the microstructure-function relationship in hypertension progression. Our results provide insights into the management of patients with systemic arterial hypertension, thus prevent the progression toward heart failure. The findings of this study should be acknowledged by electromechanical models of the heart that simulate the specific cardiac pathology.

60 APPLIED LIFE SCIENCES↗