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At least 145 records · Page 8

Marine Toxicity, Biodegradability, and Rolling-Sliding Tribological Performance of Ionic Liquid-Enhanced Environmentally-Acceptable Lubricants for Tidal Turbomachinery

Environmentally acceptable lubricants (EALs) are increasingly being recognized in many fields including waterpower, hydraulics, water transport, agricultural machinery, offshore wind turbines, etc. Specifically, high-performance EALs are demanded for tidal turbomachinery to ensure high efficiency and reliability and avoid the significant risk of direct contamination of the marine ecosystem upon leaks. Here we report a new development of ionic liquid (IL)-enhanced EALs for tidal energy. One short-chain phosphonium phosphate and one short-chain ammonium phosphate ILs were used as the candidate additives and the IL-containing EALs demonstrated significantly improved lubricating performance, much lower toxicity, and increased biodegradability compared with commercial baselines. Specifically, in a rolling-sliding test simulating the operation of a model tidal turbine gearbox bearing, an EAL containing the ILs at a 0.5 wt % concentration demonstrated 40% lower friction, 45% less wear loss, substantially reduced rolling contact fatigue-induced surface damage, and one order of magnitude lower vibration noise compared with a commercial gear oil. In an EPA standard toxicity test, 90 and 70% survival of marine biota was observed when exposed to an EAL containing 5 wt % of the short-chain phosphonium phosphate and ammonium phosphate ILs, respectively, while the selected commercial gear oil and bioderived additive killed all marine biota. In a standard biodegradability test, 2 wt % addition of the phosphonium phosphate IL not only retained the EAL’s ready biodegradability but further boosted the oil decomposition from a range of 60–80% to a higher level of 80–95%. Conversely, adding the commercial bioderived additive downgraded the EAL from readily to inherently biodegradable. Furthermore, this work offers scientific insights for development of ILs as potential EAL additives for marine energy and broader applications.

additives↗

Modal Analysis and Testing of a Cantilever Beam: Results and Guide

This report discusses modal analysis and testing of a cantilever beam including an introduction to modal testing, simulation, analysis, and a comparison of results. An accompanying presentation can be found from the LLNL CASIS website. Modal testing and analysis are essential for characterizing the response of a structure during vibration environments. Determining natural frequencies and mode shapes helps determine whether resonances will be reached during operations and if so, how the structure will respond and how the response can be tuned. The goal of this work is to convey the basics of modal testing and analysis through a simple project. This can be applied later to more complex, applicable structures. This includes a variety of work including data collection, finite element analysis and data processing. For this project a cantilever beam was chosen because it is a simple, well-characterized structure.

42 ENGINEERING↗

Rattlesnake Vibration Controller v.2.0

SAND2021-7300 O The Rattlesnake Vibration Controller is a combined-environments, multiple input/multiple output control system for dynamic excitation of structures under test. It provides capabilities to control multiple responses on the part using multiple exciters and control strategies. Rattlesnake is written in the Python programming language to facilitate multiple input/multiple output vibration research by allowing users to prescribe custom control laws to the controller. Rattlesnake can target multiple hardware devices, or even perform synthetic control to simulate a test virtually. Rattlesnake has been used to execute control problems with up to 200 response channels and 12 drives. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525.

Rohe, Daniel↗

Quench conditioning device. Vibrational quench conditioning

Recently a new type of device, capacitor-based, aiming to eliminate or reduce superconducting magnet training was developed and tested at FNAL. I’ll review its main characteristics and principles of operation, make relevant comparisons and conclusions. Separately, I’ll discuss somewhat similar concepts based on induced vibrations in magnets, but I’ll extend this topic to cover both training reduction and quench protection. Those will be discussed at conceptual level, arguing about feasibility of such an approach and the need for more focused research on the topic, including simulations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Development, Testing, and Validation of Fabry-Pérot Cavity Acoustic Sensors for Microreactor Applications

Nuclear microreactors are a unique reactor design which may allow for the nuclear energy industry to tap into unconventional markets, and their modularity presents some advantages over larger, conventional reactor designs. For nuclear microreactors to be economically viable, on-line structural health monitoring may be necessary to reduce operation and maintenance costs with lower power production. Optical fiber sensors, and specifically optical Fabry-Pérot cavities (FPCs), may present the opportunity to monitor vibrational frequencies of microreactor components during operation, enabling identification of the location and severity of potential damage. In this work, FPCs were designed and fabricated with materials which may be able to survive in the extremely harsh environment of nuclear microreactors. The FPCs were bonded to metal test specimens to monitor their vibrational frequencies, along with a reference piezoelectric accelerometer. Euler-Bernoulli theory was used to calculate the fundamental modes and mode-shapes to compare with experimentally measured frequency spectra. The peak frequencies detected with the FPC and piezoelectric accelerometer, and theoretical modes, all agreed well for the first four fundamental modes (within 5%). Furthermore, when the FPC and accelerometer were co-located on the test specimen, their peak frequencies all agreed within 1%.

Birri, Tony↗

Development and experimental evaluation of an acoustic flow meter prototype for measuring air flow

Here, this study outlines the development and testing of a flow meter prototype specifically designed for use in nuclear reactor environments. The meter uses flow-induced vibration to measure flow rates and is designed for remote monitoring in harsh environments where radiation can damage electronics. The device generates a vibration signal produced by a feedback system when fluid flows out of an orifice and interacts with a downstream wedge. The frequency of the vibration signal corresponds directly to flow rate and velocity. The study investigates geometric parameters intrinsic to the prototype, such as orifice height, width, edge distance, and chamber length. Different configurations were also tested, including a bypass loop with variable cross-sections around the device. The investigation results reveal the impact of these geometric parameters on the vibration signal output, providing valuable insights for future design improvements and enhancing the effectiveness of flow metering systems used in nuclear reactor applications.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

TRIPWIRE – Deployment and Field-Testing Report

TRIPWIRE is a multi-modal system for containment verification in inaccessible radiological and nuclear waste repositories. The sensing modes are focused on radiation, electromagnetic and vibration. The radiation detection component has been developed over the last three years at Idaho National Laboratory (INL). This development has focused on the fabrication, characterization, and testing of long-length (greater than 10-m) plastic scintillating fibers. This fiscal year, the focus of TRIPWIRE has been on field testing and demonstration of the radiation sensing component in a relevant environment. After reviewing the static storage facilities at INL, the Radioactive Scrap Waste Facility (RSWF) south storage area outside the Materials and Fuels Complex (MFC) was selected due to its periodic changes in configuration and inventory. This report summarizes the research outcomes for the work performed in fiscal year (FY) 2023.

98 - NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL↗

Nonlinear Impact-Echo Test for Quantitative Evaluation of ASR Damage in Concrete

Nonlinear acoustic methods demonstrate high sensitivity for concrete damage evaluation. Among these methods, nonlinear resonance acoustic methods have been widely used in laboratory tests on small scale test samples. In this study, a nonlinear impact-echo (IE) method for concrete damage evaluation was introduced, in which the IE frequency shift was measured at different impact force levels. The nonlinear IE test and the nonlinear impact resonance acoustic spectroscopy (NIRAS) test share similarities in the experimental setup and analysis method. However, the nonlinear IE test excites a local thickness resonance mode of a member instead of the global resonance vibration. Therefore, the analyzed mode is unaffected by member boundary conditions and is applicable to large concrete structural members. To identify the fundamental IE frequencies, multiple impacts were applied along the members. Once the fundamental IE frequencies were determined, the effectiveness of the nonlinear IE method was evaluated by testing seven concrete beam specimens with varying levels of alkali-silica reaction (ASR) damage. In conclusion, the nonlinear IE test demonstrates high sensitivity to concrete damage and allows for quantitative assessment of the damage state of concrete without a baseline measurement.

36 MATERIALS SCIENCE↗

Mounted Accelerometer Frequency Response of Adhesive Products and Aluminum Frame Quick Mounts

An accelerometer mounting technique has large implications on the frequency range and accuracy of the measurement, with stiffness and the mass relative to the monitored structure as the primary concerns. The International Organization for Standardization (ISO) gives an extensive list in 5348:2021, detailing mounting methods, and provides recommendations for testing mounts that are not specifically defined. In the nuclear industry on the laboratory scale, there is a need for vibration measurements for predictive maintenance and process monitoring that are nondestructive and capable of working in high-temperature environments. Commercial adhesive products with easy application and removal were tested as nondestructive methods, while quick mounts to a commonly used aluminum frame were tested as nondestructive and have potential applicability in high-temperature environments. The sinusoidal excitation method was used, measuring frequencies from 50 Hz to 10 kHz in one-third octave band intervals, utilizing three accelerometers and comparing the results to those obtained with the stud-mounting method. Using the lowest ±3 dB threshold across each accelerometer, foam dots and poster strips were not successful, and foam tapes were accurate up to 2000 Hz, hose clamps and zip ties up to 800 Hz, and a custom 3D printed mount up to 1000 Hz. Knowing the limitations of each mounting technique allows for accurate measurements within the appropriate range.

47 - OTHER INSTRUMENTATION↗

Pilot-Scale Validation of Distributed Optical Fiber Sensors for Underground Pipeline Monitoring

Monitoring parameters such as hoop strain, pressure, and acoustic vibrations is key to detecting potential leaks, intrusions, or structural issues. Distributed optical fiber sensor (DOFS) systems provide a compelling solution for continuous, real-time monitoring over long distances. This paper details the development and pilot-scale implementation of DOFS systems for underground pipeline monitoring, evolving from a proof-of-concept stage. Multiple custom-designed DOFS interrogator units—such as optical frequency-domain reflectometry (OFDR), Brillouin optical time-domain analysis (BOTDA), and multimodal interferometer-based fiber acoustic sensor systems were tested to measure the key parameters, such as hoop strain, pipe pressure, surrounding soil temperature, and acoustic vibrations. The underground product pipeline’s outer diameter is 30 inches, the wall thickness is 1.28 inches, and 3 feet deep from the surface. The fiber deployment strategies and sensing data acquisition methods for these systems are discussed. The results demonstrate the effectiveness of DOFS in detecting hoop strain, temperature changes, and acoustic vibrations, showcasing their potential for real-time monitoring and enhancing pipeline safety. These findings from pilot-scale testing offer valuable insights into advancing pipeline monitoring technologies and improving the reliability of underground pipeline systems.

fiber optic sensors↗

Flexible machine-learning interatomic potential for simulating structural disordering behavior of Li 7 La 3 Zr 2 O 12 solid electrolytes

Batteries based on solid-state electrolytes, including Li 7 La 3 Zr 2 O 12 (LLZO), promise improved safety and increased energy density; however, atomic disorder at grain boundaries and phase boundaries can severely deteriorate their performance. Machine-learning (ML) interatomic potentials offer a uniquely compelling solution for simulating chemical processes, rare events, and phase transitions associated with these complex interfaces by mixing high scalability with quantum-level accuracy, provided that they can be trained to properly address atomic disorder. To this end, we report the construction and validation of an ML potential that is specifically designed to simulate crystalline, disordered, and amorphous LLZO systems across a wide range of conditions. The ML model is based on a neural network algorithm and is trained using ab initio data. Performance tests prove that the developed ML potential can predict accurate structural and vibrational characteristics, elastic properties, and Li diffusivity of LLZO comparable to ab initio simulations. As a demonstration of its applicability to larger systems, we show that the potential can correctly capture grain boundary effects on diffusivity, as well as the thermal transition behavior of LLZO. Here these examples show that the ML potential enables simulations of transitions between well-defined and disordered structures with quantum-level accuracy at speeds thousands of times faster than ab initio methods.

25 ENERGY STORAGE↗

Numerical Analysis and Flow Induced Vibration Studies in Pressurized Helium Gas Cooling Channels

Los Alamos National Laboratory (LANL) is working with NorthStar Medical Radioisotopes (NMR) on their efforts to produce Mo-99 from the irradiation of Mo-100 targets. The NMR target consists of an Inconel window that allows the electron beam to penetrate and irradiate a stack of Mo-100 discs. The irradiation process generates large amounts of heat and is cooled using pressurized helium gas flowing at 400 g/s. LANL provides both numerical analysis support and experimental support. Computational fluid dynamics (CFD) simulations for both 300 g/s and 400 g/s are performed on the NMR target to analyze the helium flow through the NMR system. The pressure drop, the mass flow rate through each of the disc and window channels and the force applied on the first disc are some of the quantities estimated using CFD. These results will be combined with Monte Carlo N-Particle (MCNP) estimates of heat flux into the system from the electron beam to perform conjugate heat transfer analysis (CHT). The experiments presented in this report focus on the effect of the flow induced vibrations from helium flowing through the coolant gaps between the discs. There is concern that the flow induced vibrations may lead to excessive mass loss of the enriched Mo-100 discs, and the goal would be to mitigate the mass loss. This work presents benchtop tests of flow through a subset of the target stack which involves high speed imaging and displacement measurements used to estimate disc vibration, as well as mass loss.

42 ENGINEERING↗

Design and Manufacturing of High Performance, Reduced Charge Heat Exchangers

Air-to-fluid heat exchangers (HXs) play a critical role as the main heat transfer component in Heating, Ventilation, Air-Conditioning, and Refrigeration (HVAC&R) systems. However, their airside thermal resistance significantly inhibits their overall performance. Furthermore, these HXs must be continually more compact to meet the latest refrigerant charge limits to reduce emissions. Recent literature suggests that traditional HX geometries (e.g., round or flat tubes with fins), have reached their limits, and more sophisticated shape- and topology-optimized designs are required to achieve the next jump in performance. This research sheds light on the next generation of air-to-refrigerant HXs and aims to address several practical issues to commercialization such as novelty challenges (improved performance for significant charge reduction; modeling expertise & time investment), manufacturing challenges (non-round tube manufacturing; tube-header integration; product qualification, e.g., burst pressure testing, extreme operational environment, etc.), and operational challenges (flow maldistribution, fouling & wetting, noise & vibration). For example, a >20% improvement on one (or more) HX-level performance metrics (e.g., envelope volume, airside pressure drop, face area, capacity, refrigerant charge, weight, cost, etc.) must be achieved before a HX design is considered for commercialization. We present a new, comprehensive and experimentally validated air-to-refrigerant HX optimization framework with simultaneous thermal-hydraulic performance and mechanical strength considerations for novel, non-round, shape- and topology-optimized tubes capable of optimizing single and two-phase HX designs for any refrigerant choice and performance requirement with significant engineering time savings compared to conventional design practices. The framework was exercised for a wide range of applications and refrigerants, resulting in HXs which achieved greater than 20% improved performance, 20% reductions in size, and 25% reductions in refrigerant charge. To enable non-round tube bundle use in next generation HVAC&R equipment, novel manufacturing techniques were investigated, including the development of conventional manufacturing methods for small diameter, non-round tubes and novel tube-header integration strategies. In total, ten HX prototypes were manufactured, nine using conventional methods directly attributed to this project and one using advanced additive manufacturing methods. The five-year manufacturing feasibility of the proposed HXs was found to have a good outlook. The non-round tube HX simulated performance was validated through comprehensive experimental testing, including nine in-house component-level tests, one independent component-level test at an industry partner laboratory, and in-house system-level tests of using a commercially-available, residential packaged A/C unit which was retrofitted with a non-round tube prototype HX. It was found that HX designs proposed by the new framework can successfully predict experimental thermal-hydraulic performance within ±10-20% the first time with no manual design changes, eliminating the need for time-consuming and expensive prototyping efforts. This work will accelerate design and time to market for next generation HXs while simultaneously facilitating industry transition to new refrigerants at lower charge.

42 ENGINEERING↗

Coupled Aero-Hydro-Mechanical Hybrid Simulation Testing of Offshore Wind Turbines Subjected to Operational and Extreme Loading Conditions

Understanding the response of the Offshore Wind Turbine (OWT) subjected to realistic applied loads requires modeling the whole structure including its soil-foundation system. This requires unique and innovative testing facilities. OWT systems experience cyclic and dynamic loading due to wind, wave, current, rotor vibrations (i.e., 1P load) and vibrations caused by the blade shadowing effects (2P/3P loads). These loads are complicated in nature and have varying amplitudes, frequencies, and directions. Investigating the response of the entire OWT system including the soil-foundation system under these complex loading conditions, requires: (1) full understanding of the loading characteristics including: the power take-off mechanical load (1P and 3P), and areo- and hydrodynamic loads that the OWT system is subjected to; (2) testing facility with unique multidirectional loading capabilities that allows for simultaneous application of realistic wind, wave and machine loads, axial gravity loads, and induced overturning moments; and (3) unique and cost-effective testing techniques that allow for accurate analysis of the overall response of the OWT system under realistic conditions such as: Real-Time Hybrid Simulation (RTHS).

17 WIND ENERGY↗

Predicting System Response at Unmeasured Locations

Traditional techniques to derive dynamic specification for components have a great deal of uncertainty. One of the major sources of uncertainty is that the number of response measurements in the operational system environment is insufficient to determine the component motion. This inadequacy is due to logistical limitations for data recording in field testing and space limitations for accelerometers, strain gages and associated wiring. Available measurements are often some distance from the component and therefore do not represent component motion. Typical straight-line envelopes of these unrepresentative measurements guarantee an increase in the uncertainty. In this paper multiple methods are attempted to expand a sparse set of field test measurements on a system to responses of interest that cannot be measured in the field due to the limitations. Proof of concept is demonstrated on the Modal Analysis Test Vehicle (MATV). The responses of interest, known as “truth responses”, are measured in a system vibration environment along with an optimized sparse set of 30 field responses. Methods to expand the field responses to the truth responses are demonstrated by comparing the acceleration spectral density of the expanded response to the measured response. Two methods utilize a validated finite element model of the MATV. One is developed from purely experiment based frequency response functions of a laboratory pre-test. Finally, these approaches are designed to drastically reduce the uncertainty of the component in-service motion as a basis for developing specifications that are guaranteed to be conservative with a known (instead of unknown) conservatism.

42 ENGINEERING↗

Charge Delocalization and Vibronic Couplings in Quadrupolar Squaraine Dyes

Squaraines are prototypical quadrupolar charge-transfer chromophores that have recently attracted much attention as building blocks for solution-processed photovoltaics, fluorescent probes with large two-photon absorption cross sections, and aggregates with large circular dichroism. Their optical properties are often rationalized in terms of phenomenological essential state models, considering the coupling of two zwitterionic excited states to a neutral ground state. As a result, optical transitions to the lowest S 1 excited state are one-photon allowed, whereas the next higher S 2 state can only be accessed by two-photon transitions. A further implication of these models is a substantial reduction of vibronic coupling to the ubiquitous high-frequency vinyl-stretching modes of organic materials. Here, in this study, we combine time-resolved vibrational spectroscopy, two-dimensional electronic spectroscopy, and quantum-chemical simulations to test and rationalize these predictions for nonaggregated molecules. We find small Huang–Rhys factors below 0.01 for the high-frequency, 1500 cm –1 modes in particular, as well as a noticeable reduction for those of lower frequency modes in general for the electronic S 0 → S 1 transition. The two-photon allowed state S 2 is well separated energetically from S 1 and has weak vibronic signatures as well. Thus, the resulting pronounced concentration of the oscillator strength in a narrow region relevant to the lowest electronic transition makes squaraines and their aggregates exceptionally interesting for strong and ultrastrong coupling of excitons to localized light modes in external resonators with chiral properties that can largely be controlled by the molecular architecture.

36 MATERIALS SCIENCE↗

Nonlinear Characterization of a Joint Exhibiting a Reduction in Damping at High Energy

Even with the advent of additive manufacturing, the vast majority of complex structures are comprised of individual components held together with bolted joints. However, bolted joints present a challenge for mechanical design as they are a source of nonlinearity and increase the uncertainty in the overall behavior of the system in a dynamic environment. While many advances have been made in the ability to accurately model and test bolted joints, it is still an open area of research. Modes of vibration that exercise bolted joints typically exhibit nonlinear behavior where, with increased excitation level, the natural frequency decreases (i.e. softens) and the damping increases. However, the system under study for this work has an axial mode which does not follow this trend; it does soften as expected, but, after an initial increase, the apparent damping decreases with excitation amplitude. At the highest excitation level, the frequency of the mode decreases to that of a nearby bending mode and the response is amplified nearly 500% above that at lower levels. It is unclear whether the decrease in damping is due to the coupling of the two modes or if it is a characteristic of the axial mode. Therefore, the objective of this project is to investigate the coupling between the axial and bending modes and the dynamics leading to the decrease in damping.

42 ENGINEERING↗

Optimization of an Impedance-Matched Test Fixture with the Modal Projection Error

Across many industries and engineering disciplines, components and systems are designed and deployed into their operational environment of intended use. It is the desire of the design agency to be able to predict whether their component or system will function in its shock and vibration environments or if it will fail due to mechanical stresses. One method to determine if the component will survive the shock and vibration environments is to expose the component to the operational environment in a laboratory. One difficulty in executing a representative laboratory test is that the component may not have the same boundary condition in the laboratory as in the operational configuration. This paper examines the use of parameterized optimization to design the test fixture in order to better match the operational configuration. Several frequency and modal-based objective functions are examined for the optimization. The study shows that the Modal Projection Error objective function performs the best of the functions studied. The efficacy of the Modal Projection Error is demonstrated with respect to dynamic test fixture design on several analytical and experimental exemplars.

dynamic↗