Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “time resolved spectroscopy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8

Surface Characterization of Carbon Fiber Reinforced Polymers by Picosecond Laser Induced Breakdown Spectroscopy

Adhesive bonding of composite materials requires reliable monitoring and detection of surface contaminants as part of a vigorous quality control process to assure robust and durable bonded structures. Surface treatment and effective monitoring prior to bonding are essential in order to obtain a surface which is free from contaminants that may lead to inferior bond quality. In this study, the focus is to advance the laser induced breakdown spectroscopy (LIBS) technique by using pulse energies below 100 μJ (μLIBS) for the detection of low levels of silicone contaminants in carbon fiber reinforced polymer (CFRP) composites. Various CFRP surface conditions were investigated by LIBS using ∼10 ps, 355 nm laser pulses with pulse energies below 30 μJ. Time-resolved analysis was conducted to optimize the gate delay and gate width for the detection of the C I emission line at 247.9 nm to monitor the epoxy resin matrix of CFRP composites and the Si I emission line at 288.2 nm for detection of silicone contaminants in CFRP. To study the surface sensitivity to silicone contamination, CFRP surfaces were coated with polydimethylsiloxane (PDMS), the active ingredient in many mold release agents. The presence of PDMS was studied by inspecting the Si I emission lines at 251.6 nm and 288.2 nm. The measured PDMS areal densities ranged from 0.15 to 2 μg/cm(sup 2). LIBS measurements were performed before and after laser surface ablation. The results demonstrate the successful detection of PDMS thin layers on CFRP using picosecond μLIBS.

Rodolfo Ledesma↗

Advanced Spectroscopic and Thermal Imaging Instrumentation for Shock Tube and Ballistic Range Facilities

The Electric Arc Shock Tube (EAST) facility and Hypervelocity Free Flight Aerodynamic Facility (HFFAF, an aeroballistic range) at NASA Ames support basic research in aerothermodynamic phenomena of atmospheric entry, specifically shock layer radiation spectroscopy, convective and radiative heat transfer, and transition to turbulence. Innovative optical instrumentation has been developed and implemented to meet the challenges posed from obtaining such data in these impulse facilities. Spatially and spectrally resolved measurements of absolute radiance of a travelling shock wave in EAST are acquired using multiplexed, time-gated imaging spectrographs. Nearly complete spectral coverage from the vacuum ultraviolet to the near infrared is possible in a single experiment. Time-gated thermal imaging of ballistic range models in flight enables quantitative, global measurements of surface temperature. These images can be interpreted to determine convective heat transfer rates and reveal transition to turbulence due to isolated and distributed surface roughness at hypersonic velocities. The focus of this paper is a detailed description of the optical instrumentation currently in use in the EAST and HFFAF.

Grinstead, Jay H.↗

Advanced Spectroscopic and Thermal Imaging Instrumentation for Shock Tube and Ballistic Range Facilities

The Electric Arc Shock Tube (EAST) facility and Hypervelocity Free Flight Aerodynamic Facility (HFFAF, an aeroballistic range) at NASA Ames support basic research in aerothermodynamic phenomena of atmospheric entry, specifically shock layer radiation spectroscopy, convective and radiative heat transfer, and transition to turbulence. Innovative optical instrumentation has been developed and implemented to meet the challenges posed from obtaining such data in these impulse facilities. Spatially and spectrally resolved measurements of absolute radiance of a travelling shock wave in EAST are acquired using multiplexed, time-gated imaging spectrographs. Nearly complete spectral coverage from the vacuum ultraviolet to the near infrared is possible in a single experiment. Time-gated thermal imaging of ballistic range models in flight enables quantitative, global measurements of surface temperature. These images can be interpreted to determine convective heat transfer rates and reveal transition to turbulence due to isolated and distributed surface roughness at hypersonic velocities. The focus of this paper is a detailed description of the optical instrumentation currently in use in the EAST and HFFAF.

Grinstead, Jay H.↗

Supersonic Mass Flux Measurements via Tunable Diode Laser Absorption and Non-Uniform Flow Modeling

Measurements of mass flux are obtained in a vitiated supersonic ground test facility using a sensor based on line-of-sight (LOS) diode laser absorption of water vapor. Mass flux is determined from the product of measured velocity and density. The relative Doppler shift of an absorption transition for beams directed upstream and downstream in the flow is used to measure velocity. Temperature is determined from the ratio of absorption signals of two transitions (lambda(sub 1)=1349 nm and lambda(sub 2)=1341.5 nm) and is coupled with a facility pressure measurement to obtain density. The sensor exploits wavelength-modulation spectroscopy with second-harmonic detection (WMS-2f) for large signal-to-noise ratios and normalization with the 1f signal for rejection of non-absorption related transmission fluctuations. The sensor line-of-sight is translated both vertically and horizontally across the test section for spatially-resolved measurements. Time-resolved measurements of mass flux are used to assess the stability of flow conditions produced by the facility. Measurements of mass flux are within 1.5% of the value obtained using a facility predictive code. The distortion of the WMS lineshape caused by boundary layers along the laser line-of-sight is examined and the subsequent effect on the measured velocity is discussed. A method for correcting measured velocities for flow non-uniformities is introduced and application of this correction brings measured velocities within 4 m/s of the predicted value in a 1630 m/s flow.

Chang, Leyen S.↗

Monitoring Temperature in High Enthalpy Arc-heated Plasma Flows using Tunable Diode Laser Absorption Spectroscopy

A tunable diode laser sensor was designed for in situ monitoring of temperature in the arc heater of the NASA Ames IHF arcjet facility (60 MW). An external cavity diode laser was used to generate light at 777.2 nm and laser absorption used to monitor the population of electronically excited oxygen atoms in an air plasma flow. Under the assumption of thermochemical equilibrium, time-resolved temperature measurements were obtained on four lines-of-sight, which enabled evaluation of the temperature uniformity in the plasma column for different arcjet operating conditions.

Martin, Marcel Nations↗

The Astro-E High Resolution X-Ray Spectrometer

The Astro-E High Resolution X-ray Spectrometer (XRS) was developed jointly by the NASA/Goddard Space Flight Center and the Institute of Space and Astronautical Science in Japan. The instrument is based on a new approach to spectroscopy, the X-ray microcalorimeter. This device senses the energies of individual X-ray photons as heat with extreme precision. A 32 channel array of microcalorimeters is being employed, each with an energy resolution of about 12 eV at 6 keV (the Fe-K region). This will provide spectral resolving power 10 times higher than any other non-dispersive X-ray spectrometer. The instrument incorporates a three stage cooling system capable of operating the array at 60 mK for about two years in orbit. The array sits at the focus of a grazing incidence conical mirror. The quantum efficiency of the microcalorimeters and the reflectivity of the X-ray mirror system combine to give high throughput over the 0.3-12 keV energy band. This new capability will enable the study of a wide range of high-energy astrophysical sources with unprecedented spectral sensitivity. This paper presents the basic design requirements and implementation of the XRS, and also describes the instrument parameters and performance.

Kelley, Richard L.↗

High-resolution Interferometer Sounder (HIS), phase 2

The High-resolution Interferometer Sounder (HIS) was successfully built, tested, and flight proven on the NASA U-2/ER-2 high altitude aircraft. The HIS demonstration has shown that, by using the technology of Fourier Transform Spectroscopy (FTS), it is possible to measure the spectrum of upwelling infrared radiance needed for temperature and humidity sounding with high spectral resolution and high radiometric precision. By resolving individual carbon dioxide lines, the retrieved temperature profiles have vertical resolutions of 1 to 2 km and RMS errors less than 1 C, about 2 to 4 times better than possible with current sounders. Implementing this capability on satellite sounders will greatly enhance the dynamical information content of temperature measurements from space. The aircraft model HIS is now a resource which should be used to support field experiments in mesoscale meteorology, to monitor trace gas concentrations and to better understand their effects on climate, to monitor the surface radiation budget and the radiative effects of clouds, and to collect data for research into retrieval techniques, especially under partially cloudy conditions.

Source record↗

SSME Condition Monitoring Using Neural Networks and Plume Spectral Signatures

For a variety of reasons, condition monitoring of the Space Shuttle Main Engine (SSME) has become an important concern for both ground tests and in-flight operation. The complexities of the SSME suggest that active, real-time condition monitoring should be performed to avoid large-scale or catastrophic failure of the engine. In 1986, the SSME became the subject of a plume emission spectroscopy project at NASA's Marshall Space Flight Center (MSFC). Since then, plume emission spectroscopy has recorded many nominal tests and the qualitative spectral features of the SSME plume are now well established. Significant discoveries made with both wide-band and narrow-band plume emission spectroscopy systems led MSFC to develop the Optical Plume Anomaly Detection (OPAD) system. The OPAD system is designed to provide condition monitoring of the SSME during ground-level testing. The operational health of the engine is achieved through the acquisition of spectrally resolved plume emissions and the subsequent identification of abnormal emission levels in the plume indicative of engine erosion or component failure. Eventually, OPAD, or a derivative of the technology, could find its way on to an actual space vehicle and provide in-flight engine condition monitoring. This technology step, however, will require miniaturized hardware capable of processing plume spectral data in real-time. An objective of OPAD condition monitoring is to determine how much of an element is present in the SSME plume. The basic premise is that by knowing the element and its concentration, this could be related back to the health of components within the engine. For example, an abnormal amount of silver in the plume might signify increased wear or deterioration of a particular bearing in the engine. Once an anomaly is identified, the engine could be shut down before catastrophic failure occurs. Currently, element concentrations in the plume are determined iteratively with the help of a non-linear computer code called SPECTRA, developed at the USAF Arnold Engineering Development Center. Ostensibly, the code produces intensity versus wavelength plots (i.e., spectra) when inputs such as element concentrations, reaction temperature, and reaction pressure are provided. However, in order to provide a higher-level analysis, element concentration is not specified explicitly as an input. Instead, two quantum variables, number density and broadening parameter, are used. Past experience with OPAD data analysis has revealed that the region of primary interest in any SSME plume spectrum lies in the wavelength band of 3300 A to 4330 A. Experience has also revealed that some elements, such as iron, cobalt and nickel, cause multiple peaks over the chosen wavelength range whereas other elements (magnesium, for example) have a few, relatively isolated peaks in the chosen wavelength range. Iteration with SPECTRA as a part of OPAD data analysis is an incredibly labor intensive task and not one to be performed by hand. What is really needed is the "inverse" of the computer code but the mathematical model for the inverse mapping is tenuous at best. However, building generalized models based upon known input/output mappings while ignoring details of the governing physical model is possible using neural networks. Thus the objective of the research project described herein was to quickly and accurately predict combustion temperature and element concentrations (i.e., number density and broadening parameter) from a given spectrum using a neural network. In other words, a neural network had to be developed that would provide a generalized "inverse" of the computer code SPECTRA.

Hopkins, Randall↗

Imaging spectroscopy of the solar CO lines at 4.67 microns

We analyze spatially and temporally resolved spectra of the fundamental vibration-rotation transitions of carbon monoxide (CO) in the solar spectrum at 4.67 micrometers. Our observations imply that, in the quiet Sun, spatial variations in CO intensity are largely dynamical in nature, reinforcing the suggestion that dynamical effects play a key role in the formation of the dark CO cores. Time sequences of resolved spectra exhibit mainly 3 minute power in line-core intensity but mainly a 5 minute period in Doppler shift. The weak 7-6 R68 line shows normal Evershed flow in the penumbra of a sunspot; we find evidence for the onset of inverse Evershed flow in the strong 3-2 R14 line. Spectra at the limb indicate that 3-2 R14 emission extends approximately 360 km beyond the continuum limb.

Uitenbroek, Han↗

High-Resolution X-Ray Spectroscopy of the Galactic Supernova Remnant Puppis A with the XMM-Newton RGS

We present high-resolution X-ray spectra of cloud-shock interaction regions in the eastern and northern rims of the Galactic supernova remnant Puppis A, using the Reflection Grating Spectrometer onboard the XMM-Newton satellite. A number of emission lines including K(alpha) triplets of He-like N, O , and Ne are clearly resolved for the first time. Intensity ratios of forbidden to resonance lines in the triplets are found to be higher than predictions by thermal emission models having plausible plasma parameters. The anomalous line ratios cannot be reproduced by effects of resonance scattering, recombination, or inner-shell ionization processes, but could be explained by charge-exchange emission that should arise at interfaces between the cold/warm clouds and the hot plasma. Our observations thus provide observational support for charge-exchange X-ray emission in supernova remnants.

Katsuda, Satoru↗

The WFIRST CGI Integral Field Spectrograph: Requirements and Performance Predictions

The WFIRST coronagraphic instrument (CGI) will demonstrate exoplanet spectroscopy using an integral field spectrograph (IFS). The CGI IFS, being designed and built at Goddard Space Flight Center, has a spectral resolution of R50 and is designed to accommodate a 20% bandpass spanning 600- 970 nm. The IFS is principally targeting the abundance of Methane features, with the primary coronagraph band being centered around 770nm. Key to the performance estimates are the achievable signal-to-noise (SNR) ratios and the stability of the microspectra over the course of tens and hundreds of hours. As a technology demonstration for CGI, the ability to close a wavefront control loop around the IFS, maintain a stable dark hole, and provide time resolved data that simultaneously spans spatial and spectral dimensions are crucial demonstrations for future observatories. The IFS is optimized both for coronagraphs and science observations with a potential future starshade. We highlight how the long duration observations, and requirements for both starshades and coronagraphs drive the IFS requirements and the calibrations required both onorbit and on the ground. We also provide further detail on the optomechanical design, its stability based on thermal and structural predictions, anticipated performance, and operations concept of the CGI IFS. The impact of these performance metrics are projected into simulated data products, demonstrating cube extraction of noisy images and the subsequent planet spectrum that can be extracted from them. These demonstrations and performance predictions are key to future missions such as LUVOIR and HabEx, whose principal science case relies on efficient spectroscopy of exoplanets.

Tyler Groff↗

Microwave spectroscopy of the active sun

In studies of solar active regions and bursts, the ability to obtain spatially resolved radio spectra (brightness temperature spectra) opens a whole new range of possibilities for study of the solar corona. For active regions, two-dimensional maps of brightness temperature over a wide range of frequencies allows one to determine temperature, column density, and magnetic field strength over the entire region in a straightforward, unambiguous way. For flares, the time-dependent electron energy distribution, number of accelerated electrons, and magnetic field strength and direction can be found. In practice, obtaining complete radio images at a large number of frequencies is a significant technical challenge, especially while keeping costs down. Our instrument at Owens Valley Radio Observatory provided the starting point for a modest attempt at meeting this goal. We proposed to build three additional, very low-cost 2-m antennas which, when combined with our existing two 27-m dishes, expands the array to 5 elements. This modest increase in number of solar dedicated antennas, from 2 to 5, increases our maximum number of physical baselines from 1 to 10 and allows the instrument to do true imaging of solar microwave sources, both bursts and active regions. Combined with the technique of frequency synthesis, the new array has up to 450 effective baselines, giving imaging capability that approaches that of a sub-arrayed VLA. The prototype antenna design was finalized and the antenna was put into operation in Nov. 1989.

Hurford, Gordon↗

The Need for X-Ray Spectroscopy

For over four decades, X-ray, EUV, and UV spectral observations have been used to measure physical properties of the solar atmosphere. During this time, there has been substantial improvement in the spectral, spatial, and temporal resolution of the observations for the EUV and UV wavelength ranges. At wavelengths below 100 Angstroms, however, observations of the solar corona with simultaneous spatial and spectral resolution are limited, and not since the late 1970's have spatially resolved solar X-ray spectra been measured. The soft-X-ray wavelength range is dominated by emission lines formed at high temperatures and provides diagnostics unavailable in any other wavelength range. In this presentation, we will discuss the important science questions that can be answered using spatially and spectrally resolved X-ray spectra.

Winebarger, Amy R.↗

Ground Based Observation of Isotopic Oxygen in the Martian Atmosphere Using Infrared Heterodyne Spectroscopy

Infrared heterodyne spectra of isotopic CO2 in the Martian atmosphere were obtained using the Goddard Heterodyne Instrument for Planetary Wind and Composition, HIPWAC, which was interfaced with the 3-meter telescope at the NASA Infrared Telescope Facility- Spectra were colle cted at a resolution of lambda/delta lambda=10(exp 7). Absorption fea tures of the CO2 isotopologues have been identified from which isotop ic ratios of oxygen have been determined. The isotopic ratios O-17/O -16 and O-18/O-16 in the Martian atmosphere can be related to Martian atmospheric evolution and can be compared to isotopic ratios of oxyg en in the Earth's atmosphere. Isotopic carbon and oxygen are importa nt constraints on any theory for the erosion of the Martian primordia l atmosphere and the interaction between the atmosphere and surface o r subsurface chemical reservoirs. This investigation explored the pr esent abundance of the stable isotopes of oxygen in Mars' atmospheric carbon dioxide by measuring rovibrational line absorption in isotop ic species of CO2 using groundbased infrared heterodyne spectroscopy in the vicinity of the 9.6 micron and 10.6 micron CO2 lasing bands. T he target transitions during this observation were O-18 C-12 O-16 as well as O-178 C-12 O-16 and O-16 C-113 O-16 at higher resolving power of lambda/delta lambda=10(exp 7) and with high signal-to-noise ratio (longer integration time) in order to fully characterize the absorpt ion line profiles. The fully-resolved lineshape of both the strong n ormal-isotope and the weak isotopic CO2 lines were measured simultane ously in a single spectrum.

Smith, R. L.↗

Simultaneous soft and hard X-ray spectroscopy of AM Herculis with EXOSAT: Discovery of photospheric absorption features

We present 0.1-10 keV spectroscopic observations of AM Herculis obtained with the Transmission Grating Spectrometers and Medium Energy experiments on EXOSAT, taken when the object was in its 'reversed X-ray mode.' The observation covers over six binary orbits without interruption, enabling us to analyze the phase and intensity dependence of both the hard and the soft spectrum simultaneously. We resolve the optically thick soft X-ray spectrum, and find definite evidence for time- and phase-dependent photospheric absorption structure arising in the white dwarf atmosphere. We present a simple empirical analysis of the combined soft and hard X-ray spectra, to examine whether the effect of a better determination of the column density of neutral absorbing material, afforded by our data, would solve the problem of the large relative soft X-ray overluminosity previously observed in AM Her. We find that a single absorbing column fits the entire spectrum, and that the column densities implied are indeed substantially lower than previously estimated. However, during half the binary orbit we still determine a strong lower limit to the soft-to-hard luminosity ratio of L(sub soft)/L(sub hard) is greater than or approximately equal to 10, in conflict with the simple radiative shock models for the accretion region. We argue that this indicates the need to reexamine the luminosity problem using explicit models for the emission spectrum based on a full solution of the atmospheric radiative transfer problem.

Paerels, Frits↗

Steps toward determination of the size and structure of the broad-line region in active nuclei. 7: Variability of the optical spectrum of NGC 5548 over years

We report on the results of a continuation of a large monitoring program of optical spectroscopy of the Seyfert 1 galaxy NGC 5548. The new observations presented here were obtained between 1990 December and 1992 October, and extend the existing database to nearly 1400 days, dating back to 1988 December. The continuum variations are generally smooth and well-resolved, except during the third year of this 4 year project, when the variations were apparently more rapid and of lower amplitude than observed at other times. The broad H(beta) emission line is found to vary in response to the continuum variations with a lag of about 18 days, but with some changes from year to year. The H(beta) transfer functions for each of the 4 yr and for the entire 4 yr database are derived by using a maximum entropy method.

Peterson, B. M.↗

Herschel Observations of Gas and Dust in the Unusual 49 Ceti Debris Disk

We present far-IR/sub-mm imaging and spectroscopy of 49 Ceti, an unusual circumstellar disk around a nearby young A1V star. The system is famous for showing the dust properties of a debris disk, but the gas properties of a low-mass protoplanetary disk. The data were acquired with the Herschel Space Observatory PACS and SPIRE instruments, largely as part of the “Gas in Protoplanetary Systems” (GASPS) Open Time Key Programme. Disk dust emission is detected in images at 70, 160, 250, 350, and 500 micron; 49 Cet is significantly extended in the 70 micron image, spatially resolving the outer dust disk for the first time. Spectra covering small wavelength ranges centered on eight atomic and molecular emission lines were obtained, including [O i] 63 micron and [C ii] 158 micron. The C ii line was detected at the 5 sigma level—the first detection of atomic emission from the disk. No other emission lines were seen, despite the fact that the Oi line is the brightest one observed in Herschel protoplanetary disk spectra. We present an estimate of the amount of circumstellar atomic gas implied by the C ii emission. The new far-IR/sub-mm data fills in a large gap in the previous spectral energy distribution (SED) of 49 Cet. A simple model of the new SED confirms the two-component structure of the disk: warm inner dust and cold outer dust that produces most of the observed excess. Finally, we discuss preliminary thermochemical modeling of the 49 Cet gas/dust disk and our attempts to match several observational results simultaneously. Although we are not yet successful in doing so, our investigations shed light on the evolutionary status of the 49 Cet gas, which might not be primordial gas but rather secondary gas coming from comets.

thermochemical modeling↗

Accurate quantum yields by laser gain vs absorption spectroscopy - Investigation of Br/Br(asterisk) channels in photofragmentation of Br2 and IBr

Various techniques have been used to study photodissociation dynamics of the halogens and interhalogens. The quantum yields obtained by these techniques differ widely. The present investigation is concerned with a qualitatively new approach for obtaining highly accurate quantum yields for electronically excited states. This approach makes it possible to obtain an accuracy of 1 percent to 3 percent. It is shown that measurement of the initial transient gain/absorption vs the final absorption in a single time-resolved signal is a very accurate technique in the study of absolute branching fractions in photodissociation. The new technique is found to be insensitive to pulse and probe laser characteristics, molecular absorption cross sections, and absolute precursor density.

Haugen, H. K.↗