Process for applying black coating to metals Patent
High thermal emittance black surface coatings and process for applying to metal and metal alloy surfaces used in radiative cooling of spacecraft
Lewis, B. W.↗
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Optical properties of thermal control coating contaminated by MMH/N2O4 5-pound thruster in a vacuum environment with solar simulation
Cat-a-lac Black, and S13G thermal control coatings were exposed to the exhaust of a thruster in a simulated space environment. Vacuum was maintained at less than 10 to the minus 5th power torr during thruster firing in the liquid helium cooled facility. The thruster was fired in a 50-millisecond pulse mode and the accumulated firing time was 224 seconds. Solar absorptance (alpha sub s) and thermal emittance (sigma) of the coatings were measured in-situ at intervals of 300 pulses. A calorimetric technique was used to measure alpha sub s and sigma. The tests, technique, and test results are presented. The Cat-a-lac Black coatings showed no change in alpha sub s or sigma. The S13G showed up to 25 percent increase in alpha sub s but no change in sigma.
Sommers, R. D.↗
Results of a comprehensive program for analysis of thermal radiative properties.
An extensive program has been developed to identify, collect, extract, analyze, and disseminate thermal radiative property data on materials of use to the aerospace endeavors under conditions likely to exist in their application. The properties examined include thermal emittance, reflectance, absorptance, and transmittance. Reference is made to the coverage of the results which is organized in three major volumes, representing the most comprehensive treatment on this subject matter.
Dewitt, D. P.↗
Effects of simulated space environment on Skylab parasol material
A material consisting of ripstop nylon bonded to the Mylar side of aluminized Mylar film was used to construct the first Skylab parasol. The mechanical properties of elongation and tensile strength and the radiative properties of solar absorptance and thermal emittance were measured before and after exposure to simulated solar radiation at intensities of 1.0 and 3.5 solar constants for exposure times as long as 947 hours or 3316 equivalent solar hours. The accelerated testing indicated more severe degradation than was experienced in the real-time test (1 solar constant). The results predicted that this material could have given satisfactory performance throughout the planned lifetime of the Skylab workshop.
Slemp, W. S.↗
Airborne thermography of temperature patterns in sugar beet piles
An investigation was conducted to evaluate the use of thermography for locating spoilage areas (chimneys) within storage piles and to subsequently use the information for the scheduling of their processing. Thermal-infrared quantitative scanner data were acquired initially on January 16, 1975, over the storage piles at Moorhead, Minnesota, both during the day and predawn. Photographic data were acquired during the day mission to evaluate the effect of uneven snow cover on the thermal emittance, and the predawn thermography was used to locate potential chimneys. The piles were examined the day prior for indications of spoilage areas, and the ground crew indicated that no spoilage areas were located using their existing methods. Nine spoilage areas were interpreted from the thermography. The piles were rechecked by ground methods three days following the flights. Six of the nine areas delineated by thermography were actual spoilage areas.
Moore, D. G.↗
Electrically conductive thermal control coatings
A coating characterized by low thermal absorption, high thermal emittance and high electrical conductivity comprises: (1) a fired oxide pigment comprising a minor amount of aluminum oxide and a major amount of zinc oxide; (2) sufficient water to provide a mixture suitable for application to a substrate, is presented. The fired oxide pigment may further include a minor amount of cobalt oxide. The resulting coating is particularly useful for coating the surfaces of spacecraft and similar objects.
Shai, M. C.↗
User chooses coating properties
Anodizing technique allows independent selection of coating thermal emittance and solar absorption. Process has three phases: initial material processing, which prepares material and establishes initial values of emittance and absorption; anodizing with chromic acid solution, which determines final values; and material postprocessing. Stability tests show less than 15 percent coating degradation over 2,000 hour solar exposure.
Gilliland, C. S.↗
Analysis of differential and active charging phenomena on ATS-5 and ATS-6
Spacecraft charging on the differential charging and artificial particle emission experiments on ATS 5 and ATS 6 were studied. Differential charging of spacecraft surfaces generated large electrostatic barriers to spacecraft generated electrons, from photoemission, secondary emission, and thermal emitters. The electron emitter could partially or totally discharge the satellite, but the mainframe recharged negatively in a few 10's of seconds. The time dependence of the charging behavior was explained by the relatively large capacitance for differential charging in comparison to the small spacecraft to space capacitance. A daylight charging event on ATS 6 was shown to have a charging behavior suggesting the dominance of differential charging on the absolute potential of the mainframe. Ion engine operations and plasma emission experiments on ATS 6 were shown to be an effective means of controlling the spacecraft potential in eclipse and sunlight. Elimination of barrier effects around the detectors and improving the quality of the particle data are discussed.
Olsen, R. C.↗
Effects of High Temperature on Collector Coatings
Report reveals electroplated black chrome is good coating for concentrating collectors in which temperatures are in the 650 degrees-800 degrees F (340 degrees - 430 degrees C) range. Black chrome thermal emittance is low and solar-absorption properties are not seriously degraded at high temperatures. Black coatings are used to increase absorption of solar energy by base metal while decreasing emission of infrared energy. Coatings are intended to improve efficiency of solar collectors.
Lowery, J. R.↗
Geologic remote sensing
Remote-sensing techniques based on the analysis of spectral reflectance, spectral emittance, thermal inertia, and radar measurements are reviewed. Specific applications of Landsat multispectral scanner are examined with emphasis on mineral exploration. The potential of satellite systems for detailed lithologic mapping is pointed out.
Goetz, A. F. H.↗
Variable anodic thermal control coating
A process for providing a thermal control solar stable surface coating for aluminum surfaces adapted to be exposed to solar radiation wherein selected values within the range of 0.10 to 0.72 thermal emittance (epsilon sub tau) and 0.2 to 0.4 solar absorptance (alpha subs) are reproducibly obtained by anodizing the surface area in a chromic acid solution for a selected period of time. The rate voltage and time, along with the parameters of initial epsilon sub tau and alpha subs, temperature of the chromic acid solution, acid concentration of the solution and the material anodized determines the final values of epsilon/tau sub and alpha sub S. 9 Claims, 5 Drawing Figures.
Gilliland, C. S.↗
Estimation of total above-ground phytomass production using remotely sensed data
Remote sensing potentially offers a quick and nondestructive method for monitoring plant canopy condition and development. In this study, multispectral reflectance and thermal emittance data were used in conjunction with micrometeorological data in a simple model to estimate above-ground total dry phytomass production of several spring wheat canopies. The fraction of absorbed photosynthetic radiation (PAR) by plants was estimated from measurements of visible and near-infrared canopy reflectance. Canopy radiation temperature was used as a crop stress indicator in the model. Estimated above-ground phytomass values based on this model were strongly correlated with the measured phytomass values for a wide range of climate and plant-canopy conditions.
Asrar, G.↗
TIMS data applications in Nebraska
A total of 172 flight-line miles of Thermal Infrared Multispectral Scanner (TIMS) data were acquired in the state of Nebraska; and an additional mission is planned for August of this year. Data collected by the scanner were generally applied to investigations in four general areas: hydrology, geology, soils, and vegetation analysis. Relatively simple manipulations of these thermal-emittance data led to excellent classifications of vegetation communities established along topographic gradients in the Nebraska Sandhills. Similar procedures were used to study variations in soil parameters along those same routes. Proposed geologic applications include mapping of the surficial geology along a portion of the Platte River and the delineation of a segment of the Cambridge Arch, a structural feature in central Nebraska.
Queen, Lloyd↗
Observations of the galactic plane by the zodiacal infrared project
The two rocket flights of the Zodiacal Infrared Project (ZIP), flown 18 August 1980 and 31 July 1981, were intended to provide data on the near-infrared thermal emission of the interplanetary dust cloud over a broad range of ecliptic coordinates (latitudes -60 to +85 degrees, solar elongation angles 22 to 90 degrees and 140 to 180 degrees). In addition, their multiple crossings of the Galactic plane provided low resolution spectral data (delta lambda/lambda ranging from 1. to 0.1, for effective wavelengths from 3 to 30 microns) for most of the first quadrant (longitudes 30 to 100 degrees). Examples are displayed. Having made a thorough reanalysis of the calibration of the ZIP database, researchers present the salient features of the Galactic plane as observed by ZIP. The binned, in-plane data, corrected for zodiacal emission, generally show an exponential decrease with increasing longitude. The fitted exponential scale-length is 0.038/degree, and can be inverted to derive a radial density profile. Channel ratios are converted to temperatures by using model spectra in which thermal emitters with emissivity approx. 1/lambda are convolved with the filter responses. The results for channels 5 (11 microns) and 12 (21 microns) are shown, along with similarly derived temperatures from Infrared Astronomy Satellite (IRAS) 12 microns and 25 microns data. The ZIP data show little variation with longitude, consistent with IRAS results. A narrow spectral feature at 13 microns appears consistently in data for the plane (uncorrected for zodiacal emission). However, this is strongly contaminated by calibration problems for channel 8. Researchers suggest that residual emission at 13 microns arises from the (NeII) line at 12.8 microns.
Rickard, L. J.↗
Effects of LDEF flight exposure on selected polymeric films and thermal control coatings
The characterization of polymeric films and thermal control coatings which were exposed for five years and ten months to the low-Earth environment is reported. Changes in solar absorptance, thermal emittance, and transmission are compared to laboratory control specimens. Sputter-deposited metallic coatings are shown to eliminate atomic oxygen erosion of resin matrix composite materials. The effects of long-term atomic oxygen exposure to metallized FEP Teflon film is characterized. Chemical characterization of polymeric films indicates that although surface erosion occurs, the molecular structure of the basic polymeric film has not changed significantly in response to this exposure.
Slemp, Wayne S.↗
Condition of chromic acid anodized aluminum clamps flown
A survey of the condition of the chromic acid anodized (CAA) coating on selected LDEF tray clamps was carried out. Measurements of solar absorptance and thermal emittance were carried out at multiple locations on both the space exposed and spacecraft facing sides of the clamps. Multiple clamps from each available angle relative to the ram direction were examined. The diffuse component of the reflectance spectrum was measured for a selected subset of the clamps. The thickness of the CAA was determined for a small set of clamps. Examples of variation in integrity of the coatings from leading to trailing edge will be shown.
Plagemann, W. L.↗
Video System Highlights Hydrogen Fires
Video system combines images from visible spectrum and from three bands in infrared spectrum to produce color-coded display in which hydrogen fires distinguished from other sources of heat. Includes linear array of 64 discrete lead selenide mid-infrared detectors operating at room temperature. Images overlaid on black and white image of same scene from standard commercial video camera. In final image, hydrogen fires appear red; carbon-based fires, blue; and other hot objects, mainly green and combinations of green and red. Where no thermal source present, image remains in black and white. System enables high degree of discrimination between hydrogen flames and other thermal emitters.
Youngquist, Robert C.↗
Optical Measurements on Solid Specimens of Solid Rocket Motor Exhaust and Solid Rocket Motor Slag
Samples of aluminum slag were investigated to aid the Earth Science and Applications Division at the Marshall Space Flight Center (MSFC). Alumina from space motor propellant exhaust and space motor propellant slag was examined as a component of space refuse. Thermal emittance and solar absorptivity measurements were taken to support their comparison with reflectance measurements derived from actual debris. To determine the similarity between the samples and space motor exhaust or space motor slag, emittance and absorbance results were correlated with an examination of specimen morphology.
Roberts, F. E., III↗