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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Planar Thermal Hall Effect from Phonons in Cuprates

A surprising “planar” thermal Hall effect, whereby the field is parallel to the current, has recently been observed in a few magnetic insulators; this effect has been attributed to exotic excitations such as Majorana fermions or chiral magnons. Here, we investigate the possibility of a planar thermal Hall effect in three different cuprate materials, in which the conventional thermal Hall conductivity 𝜅 xy (with an out-of-plane field perpendicular to the current) is dominated by either electrons or phonons. Our measurements show that the planar 𝜅 xy from electrons in cuprates is zero, as expected from the absence of a Lorentz force in the planar configuration. By contrast, we observe a sizable planar 𝜅 xy in those samples where the thermal Hall response is due to phonons, even though it should, in principle, be forbidden by the high crystal symmetry. Our findings call for a careful reexamination of the mechanisms responsible for the phonon thermal Hall effect in insulators.

Cuprates↗
NASA NTRS1998

Analysis of Thermal Radiation Effects on Temperatures in Turbine Engine Thermal Barrier Coatings

Thermal barrier coatings are important, and in some instances a necessity, for high temperature applications such as combustor liners, and turbine vanes and rotating blades for current and advanced turbine engines. Some of the insulating materials used for coatings, such as zirconia that currently has widespread use, are partially transparent to thermal radiation. A translucent coating permits energy to be transported internally by radiation, thereby increasing the total energy transfer and acting like an increase in thermal conductivity. This degrades the insulating ability of the coating. Because of the strong dependence of radiant emission on temperature, internal radiative transfer effects are increased as temperatures are raised. Hence evaluating the significance of internal radiation is of importance as temperatures are increased to obtain higher efficiencies in advanced engines.

Siegel, Robert↗
NASA NTRS1997

Thermal Radiation Effects Analyzed in Translucent Composite and Thermal Barrier Coating

Ceramic parts and coatings are needed to withstand high temperatures in advanced aircraft engines. In hot environments, such as in the combustion chambers of these engines, infrared and visible radiation can penetrate into some ceramics and heat them internally. The internal temperatures depend on radiative effects combined with heat conduction, and on convection and radiation at the material boundaries. Since engine temperatures are high, radiant emission can be large from within translucent parts and coatings, and this must be included in the analysis. Transient and steady-state behavior are both important. During a transient, radiant penetration provides more rapid internal heating than conduction alone, and the temperature distributions are usually considerably different than for steady-state conditions; this can produce transient thermal stresses. Analytical and numerical methods are being used at the NASA Lewis Research Center to predict transient temperatures and heat flows in translucent materials. A transient analysis was done for a composite of two translucent layers. The layer refractive indices were larger than 1, producing internal reflections at the boundaries and at the internal interface. In addition, steady-state results were computed for a two-layer composite with one layer opaque. The results were used to assess the importance of internal radiation in a zirconia thermal barrier coating on a cooled metal wall. Since the radiative transfer equations are rather complex, especially when internal scattering is included, approximate methods are being investigated that might be convenient for computer design programs. An approximate two-flux method was used and verified by comparisons with solutions that used exact radiative transfer relations. The two-flux equations include scattering without increasing solution difficulty.

Siegel, Robert↗
DOE OSTI2024

Impact of Janssen effect on thermal transport in granular flow

Using a modulated photothermal radiometry (MPR) technique capable of measuring thermal transport in particle beds, we find asymptotically increasing effective thermal conductivity and decreasing near-wall thermal resistance along gravity-driven downward granular flows through a 1-meter-long narrow vertical channel owing to the Janssen effect. The Janssen effect is confirmed by similar asymptotic trends from particle bed apparent mass measurements as well as separate MPR heat transfer measurements on stationary particle beds under compression at different heights of the channel with and without pressure screening. Furthermore, local heat transfer coefficient along the 1-meter-long channel was modeled based on measured spatially resolved thermal conductivity and near-wall thermal resistance due to the Janssen effect. This work reveals for the first time the impact of the over century-old Janssen effect on heat transfer in granular media. Furthermore, the results from this work can lead to a better understanding of heat transfer in granular flow.

14 SOLAR ENERGY↗
DOE OSTI2024

Quarterly Research Performance Progress Report (Q8)

As part of Task 1, we have started by testing our modeling capabilities by reproducing isothermal DFIT simulations presented in the literature. Once satisfied with the results we have started by targeting the modeling of the DFITs at conducted at well 58-32. We have a identified a specific test (cycle 4 in zone 2) as the most interesting to be model with GEOS hydraulic fracturing module. Thus, we have first produced results with an isothermal model and adjusted model parameters to get a satisfying match with field pressure data. The, we have added thermal effects and compared the modeling results with and without thermal effects to estimate how thermal effects may influence test interpretation. Models seem to suggest that, for small volumes of fluid, thermal effects are moderate. In Task 2, we have adapted GEOS phase-field formulation to be able to simulate near-wellbore hydraulic fracture nucleation and propagation. We have devised a novel formulation that, compared to other existing ones, incorporates rock strengths. We have submitted a journal publication about our work. We are currently employing this phase-field formulation to model the experiments taking place at U Pitt and help us understand the effect of various parameters. In Task 3, we have built a model of the region surround well 16A and have started modeling stage 3 stimulation because of its simpler planar geometry. After calibrating simulation parameters using known analytical solutions, we have simulated the stage 3 stimulation using our isothermal hydraulic fracturing module, varying the permeability field, the stress conditions including different physics to get a better understanding of the numerical challenges and of the effects of varying these parameters on the simulation results. In Task 4 laboratory experimentation, a set of specialized drilling and injection tools has been customized and constructed to accommodate an inclined well with an orientation of up to 30 degrees relative to material anisotropy or principal stress axes. These inclined samples have also undergone thermal stress and hydraulic fracturing at a temperature of 190 degrees Celsius. Furthermore, both vertical and deviated sampling testing setups enable an extended analysis of post-peak pressure behaviors, facilitating post-test pressure analyses such as the G-function, step rate, and fracture reopening measurements. Thus, the key components of in-situ stress estimation can be extracted and validated through our experiment, providing a solid foundation for validating existing in-situ stress estimation theories or proposing new ones. Simultaneously, we are integrating computer vision techniques with traditional experimental fracture observation methods such as multi-overcore/slicing and water-penetration fracture observation. This combination will prove beneficial in populating the hydraulic fracture patterns database, generated under challenging EGS conditions. This approach aims to deepen our understanding of the complexities in EGS reservoirs and pave the way for future data-driven investigations. Additionally, PITT has also equipped the ELE International compression machine, which is now prepared for conducting indirect tensile and fracture toughness tests. These tests will aid in characterizing how rock fabrics influence the resulting fracture patterns. Additionally, we have completed the required personnel training and gained access to Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) for conducting more detailed characterization and analysis of rock fabrics, as well as the examination of thermal and hydraulically induced fracture patterns. Thus, the PITT team has effectively demonstrated the capabilities of our experimental apparatuses in exploring the thermal effects, well deviation angles, material anisotropy, and operational choices (such as circulation rate, injection fluid viscosity, and injection rate) and their impact on pressure responses and fracture trajectories under the Utah FORGE conditions.

15 GEOTHERMAL ENERGY↗
DOE OSTI2025

Intrinsic Thermal Hall Effect in Mott Insulators

Here, in light of recent experimental data indicating a substantial thermal Hall effect in square lattice antiferromagnetic Mott insulators, we investigate whether a simple Mott insulator can sustain a finite thermal Hall effect. We verify that the answer is “no” if one performs calculations within a spin-only low-energy effective spin model with noninteracting magnons. However, by performing determinant quantum Monte Carlo simulations, we show the single-band 𝑡−𝑡′−𝑈 Hubbard model coupled to an orbital magnetic field does support a finite thermal Hall effect when 𝑡′ ≠0 and 𝐵 ≠0 in the Mott insulating phase. We argue that the (carrier agnostic) necessary conditions for observing a finite thermal Hall effect are time-reversal and particle-hole symmetry breaking. By considering magnon-magnon scattering using a semiclassical Boltzmann analysis, we illustrate a physical mechanism by which finite transverse thermal conductivity may arise, consistent with our symmetry argument and numerical results. Our results indicate that square and triangular lattices with SU(2) symmetry can support a finite thermal Hall effect and call for a critical reexamination of thermal Hall effect data in insulating magnets, as the magnon contribution should not be excluded a priori .

Mott insulators↗
NASA NTRS1977

Thermal environment effects on strength and impact properties of boron-aluminum composites

Thermal effects on fracture strength and impact energy were studied in 50 volume percent unidirectional composites of 143 and 203 micron boron fibers in 6061 and 1100 aluminum matrices. For 6061 matrix composites, strength was maintained to approximately 400 C in the cyclic tests and higher than 400 C in the static tests. For the 1100 matrix composites, strength degradation appeared near 260 C after cycling and higher than 260 C in static heating. This composite strength degradation is explained by a fiber degradation mechanism resulting from a boron-aluminum interface reaction. The impact energy absorption degraded significantly only above 400 C for both matrix alloys. Thus, while impact loss for the 6061 composite correlates with the fiber strength loss, other energy absorption processes appear to extend the impact resistance of the 1100 matrix composites to temperatures beyond where its strength is degraded. Interrupted impact tests on as-received and thermally cycled composites define the range of load over which the fibers break in the impact event.

Grimes, H. H.↗
DOE OSTI2026

Evidence of Chiral Fermion Edge Modes through Geometric Engineering of Thermal Hall Effect in 𝛼−RuCl 3

The experimental observation of half-integer-quantized thermal Hall conductivity in the Kitaev candidate material α-RuCl 3 has served as a signature of non-Abelian anyons through an associated chiral Majorana edge mode. However, both the reproducibility of the quantized thermal Hall conductivity and the fundamental nature of the associated heat carriers, whether bosonic or fermionic, are subjects of ongoing and vigorous debate. In a recent theoretical work, it was proposed that varying the sample geometry through creating constrictions can distinguish between different origins of the thermal Hall effect in magnetic insulators. Here, in this study, we provide experimental evidence of chiral fermion edge modes by comparing the thermal Hall effect of a geometrically constricted α-RuCl 3 sample with that of an unconstricted sample. In contrast to the unconstricted crystals where the thermal Hall signal fades below 5 K, the constricted crystals display a significant thermal Hall signal that remains measurable even at 2 K. This sharp difference agrees well with the theoretical prediction and provides compelling evidence for the contribution of chiral fermion edge modes to the thermal Hall effect in α-RuCl 3 . More broadly, this work confirms that the geometry dependence of the thermal Hall effect can help identify chiral spin liquids in candidate materials like α-RuCl 3 and paves the way for the experimental realization of thermal anyon interferometry.

Zhang, Heda [Oak Ridge National Laboratory (ORNL),↗
DOE OSTI2023

Thermal Hall effect in a van der Waals triangular magnet FeCL 2

Thermal transport is a pivotal probe for studying low-energy, charge-neutral quasiparticles in insulating magnets. In this Letter, we report an observation of large magnetothermal conductivity and thermal Hall effect (THE) in a van der Waals antiferromagnet FeCl 2 . The magnetothermal conductivity reaches over ~700%, indicating strong magnon-phonon coupling. Furthermore, we find an appreciable thermal Hall signal which changes sign concurrently with the spin-flip transition from the antiferromagnetic state to the polarized ferromagnetic state. Our theoretical calculations suggest that, in addition to the Berry curvature induced at the anticrossing points of the hybridized magnon and acoustic phonon modes of FeCl 2 , other mechanisms are needed to account for the magnitude of the observed THE.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Topological Nernst and topological thermal Hall effect in rare-earth kagome ScMn 6 Sn 6

Thermal and thermoelectric measurements are known as powerful tools to uncover the physical properties of quantum materials due to their sensitivity towards the scattering and chirality of heat carriers. We use these techniques to confirm the presence of momentum and real-space topology in ScMn 6 Sn 6 . There is an unconventional dramatic increase in the Seebeck coefficient on entering the transverse conical spiral (TCS) state below $T$ = 200 K, suggesting an unusual scattering of heat carriers. In addition, the observed anomalous thermal Hall effect and the anomalous Nernst effect indicate nonzero Berry curvature in k space. Furthermore, we identify a significant topological contribution to the thermal Hall and Nernst signals in the TCS phase revealing the impacts of real-space Berry curvature. We discuss the presence of the topological thermal Hall effect and topological Nernst effect in the diverse HfFe 6 Ge 6 family. In conclusion, this study illustrates the importance of transverse thermal and thermoelectric measurements to investigate the origin of topological transport in the noncoplanar magnetic phases in this family of kagome metals.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Thermal Hall effect in the Kitaev-Heisenberg system with spin-phonon coupling

Motivated by the giant phonon anomalies in α-RuCl3 reported by H. Li et al. [Nat. Commun. 12, 3513 (2021)], we investigate the thermal Hall effect in a Kitaev-Heisenberg system in the presence of the coupling between spins and phonons arising from chlorine atoms' vibration. We observe that the coupling modifies the relative stability between different magnetic states under a magnetic field, especially stabilizing a canted zigzag antiferromagnetic state. Remarkably, the spin-phonon interaction has distinct effects on the thermal Hall conductivity in different magnetically ordered states. For a canted zigzag state, which is relevant to α-RuCl3, the spin-phonon interaction enhances the magnon excitation gap induced by a magnetic field and suppresses the thermal Hall conductivity at low temperatures. For the Kitaev spin liquid state, we find that the spin-phonon interaction reduces the excitation gap of Majorana fermions and destabilizes the quantized thermal Hall effect. Our results demonstrate a crucial role of phonon degrees of freedom in the thermal Hall effect in Kitaev materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2000

Curved Thermopiezoelectric Shell Structures Modeled by Finite Element Analysis

"Smart" structures composed of piezoelectric materials may significantly improve the performance of aeropropulsion systems through a variety of vibration, noise, and shape-control applications. The development of analytical models for piezoelectric smart structures is an ongoing, in-house activity at the NASA Glenn Research Center at Lewis Field focused toward the experimental characterization of these materials. Research efforts have been directed toward developing analytical models that account for the coupled mechanical, electrical, and thermal response of piezoelectric composite materials. Current work revolves around implementing thermal effects into a curvilinear-shell finite element code. This enhances capabilities to analyze curved structures and to account for coupling effects arising from thermal effects and the curved geometry. The current analytical model implements a unique mixed multi-field laminate theory to improve computational efficiency without sacrificing accuracy. The mechanics can model both the sensory and active behavior of piezoelectric composite shell structures. Finite element equations are being implemented for an eight-node curvilinear shell element, and numerical studies are being conducted to demonstrate capabilities to model the response of curved piezoelectric composite structures (see the figure).

Lee, Ho-Jun↗
NASA NTRS1979

The effects of thermal cycling on the thermal deformation of graphite-polyimide

The effects of repetitive thermal cycling on the thermal deformation of graphite-fiber-reinforced polyimide laminates are investigated. Unsymmetric and unidirectional laminate specimens were cycled in an oven between room temperature and 180 or 315 C five times, and temperature and deformation were recorded as a function of time in order to measure thermal deformation. The results of the lower temperature cycling reveal a hysteresis-like effect in the temperature-thermal deformation relation for a single cycle, while no differences are detected from one cycle to the next. The response of an eight-layer curved specimen is found to agree well with predictions based on a piecewise-linear lamination theory, however, four-layer laminate response could not be explained. The results of the high-temperature tests also indicate a dependence of the strain on whether the specimen was being heated or cooled, however quantitative results are considered unreliable, due to strain gage difficulties.

Hyer, M. W.↗