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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Zero-gap microbial electrolysis cells for efficient hydrogen production from real liquid waste streams

Zero-gap microbial electrolysis cells (MECs) have demonstrated large current and hydrogen production rates from defined substrates in synthetic media, but operation with real waste streams has yet to be proved. This study evaluated the performance and 30-days stability of zero-gap MECs operated with effluent from a single-stage anaerobic digester. The system achieved a maximum current density of 8.8 ± 0.3 A/m 2 with a hydrogen production rate of 32 ± 6 L/L-d, and during 30 days of continuous operation, sustained an average current density of 7 ± 2 A/m 2 and a hydrogen production rate of 20.8 ± 0.2 L/L-d. Carbonate precipitation was identified as a major challenge to long-term stability, and mild acid washing effectively mitigated its adverse effects. The low buffer capacity of the effluent was primarily limiting performance. Furthermore, these findings underscore the significant impact of wastewater chemistry on MEC operation and validate the feasibility of utilizing real waste streams as viable feedstocks for biohydrogen production in zero-gap configurations.

Acid wash↗
DOE OSTI2021

Atomic Layer Deposition with TiO2 for Enhanced Reactivity and Stability of Aromatic Hydrogenation Catalysts

Hydrogenation of aromatic molecules in fossil- and bio-derived fuels is essential for decreasing emissions of harmful combustion products and addressing growing concerns around urban air pollution. In this work, we used atomic layer deposition to significantly enhance the hydrogenation performance of a conventional supported Pd catalyst by applying an ultrathin coating of TiO2 in a scalable powder coating process. The TiO2-coated catalyst showed substantial gains in the conversion of multiple aromatic molecules, including a 5-fold improvement in turnover frequency versus the uncoated catalyst in the hydrogenation of naphthalene. This activity enhancement was maintained upon scaling the coating synthesis process from 3 to 100 g. Based on the results from Xray photoelectron spectroscopy, X-ray absorption spectroscopy, and computational modeling, the activity enhancement was attributed to ensemble effects resulting from partial TiO2 coverage of the Pd surface rather than fundamental changes to the Pd electronic structure. Additional durability testing confirmed that the TiO2 coating improved the thermal and hydrothermal stability of the catalyst as well as tolerance toward sulfur impurities in the reactant stream. Using an economic model of an industrial deep hydrogenation process, we found that an increase in catalyst activity or lifetime of 2× would justify even a relatively high estimate for the cost of TiO2 atomic layer deposition coatings at scale

atomic layer↗
DOE OSTI2019

Iodine Capture and Mechanical Stability of Modified Silver-Functionalized Silica Aerogel

Silver-functionalized silica aerogel (AgAero) is a material proposed for use in the removal of iodine from the off-gas streams arising from nuclear fuel reprocessing. This material was developed by Pacific Northwest National Laboratory and has been shown to adsorb up to 300 mg of iodine per gram of AgAero. One of the challenges noted for AgAero as an iodine sorbent is its mechanical stability. Its initial particle size is >0.85 mm, but previous testing has shown that extended exposure to heated gas streams results in the degradation of the material such that the sorbent bed is compacted with a substantial amount of fines produced. The observed mechanical degradation prompted an effort to reengineer the silica aerogel to improve the mechanical stability of the material without compromising its iodine capture characteristics. Pacific Northwest National Laboratory has modified the material with the intention of strengthening the aerogel backbone and improving mechanical durability. This reengineered material was transferred to Oak Ridge National Laboratory for extended testing to assess its mechanical durability. Modified AgAero was continuously exposed to a CH 3 I-bearing humid gas stream for 84 days. Testing was performed at 150°C with a superficial gas velocity of 10 m/min., a CH 3 I concentration of 554 ppb, and an inlet dew point of 10°C. The density of the AgAero increased by 16% during testing, and the height of the column was observed to decrease by 11%. The fines produced by the material were comparable to that of previously supplied material. Additionally, iodine loading of a thin bed of modified AgAero was performed at 150°C with a superficial gas velocity of 10 m/min. and a CH 3 I concentration of 50 ppm (balance dry air) with a total test duration of 1 week. The CH 3 I capture capacity of the reengineered material was 225 mg iodine per gram AgAero, as compared to a CH 3 I capacity of 250 mg iodine per gram AgAero for the original material. The primary data collected were visual observations, density measurements before and after testing, and the extent of column compaction during testing. Additionally, the material was tested to ensure that the iodine capacity of the material was not adversely impacted by the alternative methods used in the production of the reengineered material. Based on these criteria, no distinguishable improvements were observed between the material produced in fiscal years 2017 and 2019 and the mechanical stability of the aerogel in prototypic off-gas conditions remains a challenge to large-scale deployment.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Selective Oxidative Cracking of n –Butane to Light Olefins over Hexagonal Boron Nitride with Limited Formation of CO x

In recent years, hexagonal boron nitride (hBN) has emerged as an unexpected catalyst for the oxidative dehydrogenation of alkanes. Here, the versatility of hBN was extended to alkane oxidative cracking chemistry by investigating the production of ethylene and propylene from n-butane. Cracking selectivity was primarily controlled by the ratio of n-butane to O 2 within the reactant feed. Under O 2 -lean conditions, increasing temperature led to increased selectivity to ethylene and propylene and decreased selectivity to CO x . In addition to surface-mediated chemistry, homogeneous gas-phase reactions likely contributed to the observed product distribution, and a reaction mechanism was proposed based on these observations. Here, the catalyst showed good stability under oxidative cracking conditions for 100 h time-on-stream while maintaining high selectivity to ethylene and propylene.

03 NATURAL GAS↗
DOE OSTI2020

Engineering the Composition of Bimetallic Nanocrystals to Improve Hydrodeoxygenation Selectivity for 2-Acetylfuran

Hydrodeoxygenation (HDO) of 2-acetylfuran (2-AF) was examined at 473 K and 33 bar over carbon-supported, bimetallic catalysts. Monodispersed, Pt-based (PtNi, PtCo, and PtCu) and Ni-based (NiCu) nanocrystals (NCs) with well-defined sizes and compositions were prepared via colloidal synthesis. Steady-state, flow-reactor measurements demonstrate that selectivities for the HDO reaction to 2-ethylfuran (2-EF) are strongly dependent on the alloy compositions. The HDO of 2-AF is shown to be sequential, where 2-EF can react further to form over-hydrogenated products. The NiCu 3 /C nanocatalyst was superior to the other bimetallics; with the optimal residence time, it was possible to achieve a selectivity of 75% 2-EF with 80% conversion of 2-AF, with good stability for up to at least 5 hours time-on-stream. Deactivation due to coking became an issue when the NCs were deposited on oxide supports with weak acidity (SiO 2 and γ-Al 2 O 3 ). Furthermore, this work provides insights into which bimetallic catalytic systems might be useful for HDO of 2-AF reaction.

2-acetylfuran↗
DOE OSTI2022

Waste Control Specialists Technical Review Team Report

1. Modeling of Drum 68660 and the WCS Drums: A calibrated model of Los Alamos National Laboratory (LANL) Drum 68660 indicates that pressurization of the drum by restriction of drum venting could have led to the thermal runaway reaction at the Waste Isolation Pilot Plant (WIPP) in 2014, supporting the hypothesis that the contents of the drum were not fundamentally different from the overall remediated nitrate salt (RNS) waste stream. 2. Nitric Acid Reactions and Aging of the Waste: The stability of the WCS RNS waste with respect to autocatalytic thermal runaway due to nitric acid chemistry should increase over time as the nitric acid is depleted from chemical reactions in the drum. However, this cannot be confirmed because of the lack of long-term experimental data on the impact of aging on the reactivity of RNS waste. The calibrated model indicates that the waste drums retain most of their reactive components, metal nitrate salts and sWheat Scoop ® , even after eight years. 3. Pressure Effects and Runaway Reactions: The calibrated model indicates that if the drums and standard waste boxes (SWBs) are not allowed to pressurize during transport or storage and they are stored at historical WIPP repository temperatures, then an autocatalytic thermal runaway event is not expected to occur. Since the cause of Drum 68660 pressurization is not known, decision makers are not able to tailor mitigating strategies to the initiating event. Consequently, mitigating strategies must consider all feasible internal and external events that could lead to the pressurization of the drums. 4. Temperature Effects and Runaway Reactions: Temperature also has a strong influence on the stability of the waste. The calibrated model indicates that cooling the drums or SWBs can reduce the possibility of autocatalytic thermal runaway reactions. Simulations suggest that for a drum with a plugged vent, the probability of thermal runaway may be reduced or eliminated if wastes are maintained at or below 43 °F through active cooling measures from the initiation of transport until emplacement at WIPP.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS2011

An Analysis of Database Replication Technologies with Regard to Deep Space Network Application Requirements

The Deep Space Network (DSN) has three communication facilities which handle telemetry, commands, and other data relating to spacecraft missions. The network requires these three sites to share data with each other and with the Jet Propulsion Laboratory for processing and distribution. Many database management systems have replication capabilities built in, which means that data updates made at one location will be automatically propagated to other locations. This project examines multiple replication solutions, looking for stability, automation, flexibility, performance, and cost. After comparing these features, Oracle Streams is chosen for closer analysis. Two Streams environments are configured - one with a Master/Slave architecture, in which a single server is the source for all data updates, and the second with a Multi-Master architecture, in which updates originating from any of the servers will be propagated to all of the others. These environments are tested for data type support, conflict resolution, performance, changes to the data structure, and behavior during and after network or server outages. Through this experimentation, it is determined which requirements of the DSN can be met by Oracle Streams and which cannot.

Oracle Database File System↗
NASA NTRS1994

Receptivity of flat-plate boundary layer in a non-uniform free stream (vorticity normal to the plate)

Recent progress in both the linear and nonlinear aspects of stability theory has highlighted the importance of the receptivity problem. One of the most unclear aspects of receptivity study is the receptivity of boundary-layer flow normal to vortical disturbances. Some experimental and theoretical results permit the proposition that quasi-steady outer-flow vortical disturbances may trigger by-pass transition. In present work such interaction is investigated for vorticity normal to a leading edge. The interest in these types of vortical disturbances arise from theoretical work, where it was shown that small sinusoidal variations of upstream velocity along the spanwise direction can produce significant variations in the boundary-layer profile. In the experimental part of this work, such non-uniform flow was created and the laminar-turbulent transition in this flow was investigated. The experiment was carried out in a low-turbulence direct-flow wind tunnel T-361 at the Central Aerohydrodynamic Institute (TsAGI). The non-uniform flow was produced by laminar or turbulent wakes behind a wire placed normal to the plate upstream of the leading edge. The theoretical part of the work is devoted to studying the unstable disturbance evolution in a boundary layer with strongly non-uniform velocity profiles similar to that produced by outer-flow vorticity. Specifically, the Tollmien-Schlichting wave development in the boundary layer flow with spanwise variations of velocity is investigated.

Kogan, M. N.↗
NASA NTRS1972

Boundary layer stability on a yawed spinning body of revolution and its effect on the magnus force and moment

The parameters are established which are important to the stability of a boundary layer flow over a yawed spinning cylinder in a uniform stream. It is shown that transition occurs asymmetrically in general and this asymmetry can be important for the prediction of aerodynamic forces and moments (e.g., the Magnus effect). Instability of the steady-state boundary layer flow is determined using small disturbance theory. Although the approach is strictly valid only for the calculation of the conditions for stability in the small, experimental data indicate that in many problems, it provides a good estimate for the transition to turbulence.

Jacobson, I. D.↗
NASA NTRS1986

Spatially growing disturbances in a two-stream, coplanar jet

The influence of the outer stream on the instability of a two-stream, coplanar jet with only the primary (central) stream heated for a nominal outer-to-primary velocity ratio of 0.3 was investigated by means of inviscid linearized stability theory. The instability properties of spatially growing axisymmetric and first order azimuthal disturbances were studied. It was found that the instability characteristics of the two stream jet are very different from those of a single stream jet. The presence of the outer stream enhanced the instability of the jet and increased the unstable frequency range for the first order azimuthal mode.

Miles, Jeffrey H.↗
NASA NTRS1978

Effect of winglets on a first-generation jet transport wing. 4: Stability characteristics for a full-span model at Mach 0.30

The static longitudinal and lateral directional characteristics of a 0.035 scale model of a first generation jet transport were obtained with and without upper winglets. The data were obtained for take off and landing configurations at a free stream Mach number of 0.30. The results generally indicated that upper winglets had favorable effects on the stability characteristics of the aircraft.

Meyer, R. R., Jr.↗
NASA NTRS1959

Effect of Flow Incidence and Reynolds Number on Low-Speed Aerodynamic Characteristics of Several Noncircular Cylinders with Applications to Directional Stability and Spinning

The aerodynamic characteristics of several noncircular two-dimensional cylinders with axes normal to the stream at various flow incidences (analogous to angles of attack of a two-dimensional airfoil and obtained by rotating the cylinders about their axes) for a range of Reynolds numbers have been determined from low-speed wind-tunnel tests. The results indicate that these parameters have rather large effects on the drag and side force developed on these cylinders. The side force is especially critical and very often undergoes a change in sign with a change in Reynolds number. Since the flow incidences correspond to combined angles of attack and sideslip in the crossflow plane of three-dimensional bodies, these two-dimensional results appear to have strong implications with regard to directional stability of fuselages at high angles of attack. These implications, along with those associated with the spin-recovery characteristics of aircraft, are briefly discussed.

Polhamus, Edward C.↗
NASA NTRS1996

Hypersonic Boundary Layer Stability Experiments in a Quiet Wind Tunnel with Bluntness Effects

Hypersonic boundary layer measurements over a flared cone were conducted in a Mach 6 quiet wind tunnel at a freestream unit Reynolds number of 2.82 million/ft. This Reynolds number provided laminar-to-transitional flow over the cone model in a low-disturbance environment. Four interchangeable nose-tips, including a sharp-tip, were tested. Point measurements with a single hot-wire using a novel constant voltage anemometer were used to measure the boundary layer disturbances. Surface temperature and schlieren measurements were also conducted to characterize the transitional state of the boundary layer and to identify instability modes. Results suggest that second mode disturbances were the most unstable and scaled with the boundary layer thickness. The second mode integrated growth rates compared well with linear stability theory in the linear stability regime. The second mode is responsible for transition onset despite the existence of a second mode subharmonic. The subharmonic disturbance wavelength also scales with the boundary layer thickness. Furthermore, the existence of higher harmonics of the fundamental suggests that nonlinear disturbances are not associated with 'high' free stream disturbance levels. Nose-tip radii greater than 2.7% of the base radius completely stabilized the second mode.

Lachowicz, Jason T.↗
NASA NTRS1980

Non-Synchronous Whirling Due to Fluid-Dynamic Forces in Axial Turbo-Machinery Rotors

The role of fluid forces acting on the blades of an axial turborotor with regards to whirling was analyzed. The dynamic equations were formulated for the coning mode of an overhung rotor. The exciting forces due to the motion were defined through a set of rotor stability derivatives, and analytical expressions of the aerodynamic contributions were found for the case of small mean stream deflection, high solidity and equivalent flat plate cascade. For a typical case, only backward whirl was indicated when the phase shifting of the rotor wake effect was ignored. A parametric study of the dynamic stability boundary reveals that a reduction in blade stagger angle, mass flow rate, fluid density and an increase in stiffness and external damping are all inductive for improved stability.

Shen, S. F.↗
DOE OSTI2025

Frontiers of Ionic Liquids in Carbon Dioxide Separation and Valorization

Ionic liquids (ILs) have emerged as highly tunable sorbents and membranes for gas separation, especially in the purification of CO 2 -containing gas streams such as air, natural gas, biogas, and syngas. Their negligible volatility, high thermal stability, and chemical versatility position them as promising alternatives to conventional amine and alkaline metal derivative-based systems, effectively addressing key challenges such as volatility, stability, and high regeneration energy. Here, this Review explores IL-derived systems for CO 2 -related gas separation across dense, porous, and supported categories. At the dense liquid level, we discuss strategies for tailoring IL properties to optimize CO 2 sorption, focusing on the correlation between IL-CO 2 interaction strength, uptake capacity, and regeneration energy. Key advancements in carbon capture, including amino-functionalized (AILs) and superbase-derived ILs (SILs), are highlighted, along with strategies such as chemical structure engineering, multiple binding site integration, alternative driving force exploration, and stability enhancement. Then, the porous liquids (PLs) scale focuses on the emerging field integrating IL properties with permanent porosity engineering, spanning ultramicropores (<5 Å) to macropores (around 100 nm). These innovations improve gas uptake capacity, accelerate transport kinetics, introduce the gating effect, and enable the coexistence of active sites with antagonistic properties within a single IL medium. At the supported IL scale, the discussion shifts to IL- and ionic pair-modified sorbents and membranes, emphasizing the modulation of cations and anions, confinement effects from porous supports, and the IL–interface interaction to enhance CO 2 separation performance, particularly in diluted gas streams. Beyond separation, this Review highlights IL-based integrated processes for CO 2 capture and conversion into value-added chemicals via thermocatalytic, electrocatalytic, and photocatalytic pathways. At each scale, advanced computational and experimental tools for IL design are also discussed, providing insights into stability enhancement, sorption efficiency, and process integration. The Review concludes by addressing existing challenges and outlining future directions for IL-driven innovations in gas separation technologies.

Qiu, Liqi [Univ. of Tennessee, Knoxville, TN (Unit↗