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Regional Oil and gas Aerial Methane Synthesis model (Analytica) (ROAMS Analytica) v1.5.2

The Regional Oil and gas Aerial Methane Synthesis model (Analytica) is a tool to convert the results of wide-area, source-resolved aerial methane remote sensing surveys of oil and natural gas infrastructure in a given region into methane emissions inventories (estimates of the magnitude and breakdown of methane emissions from the surveyed infrastructure). This version is written in the Analytica programming language, and this version accompanies a correction in preparation for submission to Sherwin et al. 2024 (Nature). The tool leverages databases of source-resolved methane emissions detected in aerial surveys, aerial survey coverage information (which areas were measured and when), data summarizing surveyed oil and natural gas infrastructure and production (derived from third-party databases), as well as state-of-the-art mechanistic emissions simulation tools to characterize emissions too small for the aerial system to see. The regional methane emissions estimates produced by this tool are much more granular in both space and asset type than common satellite- or flux tower-based regional estimates. Unlike other tools for converting site-level measurements into regional emissions estimates, our unique geostatistical approach integrates aerially measured emissions with limited need for statistical extrapolation, which can be highly sensitive to modeler assumptions. As a result, ROAMS-based estimates of regional methane emissions from oil and gas activity are widely viewed as highly credible, as evidenced by the success of Dr. Sherwin's recent paper in Nature.

Sherwin, Evan [Lawrence Berkeley National Laborato↗

Host-region parameters for an adjustable model for crustal earthquakes to facilitate the implementation of the backbone approach to building ground-motion logic trees in probabilistic seismic hazard analysis

The backbone approach to constructing a ground-motion logic tree for probabilistic seismic hazard analysis (PSHA) can address shortcomings in the traditional approach of populating the branches with multiple existing, or potentially modified, ground-motion models (GMMs) by rendering more transparent the relationship between branch weights and the resulting distribution of predicted accelerations. To capture epistemic uncertainty in a tractable manner, there are benefits in building the logic tree through the application of successive adjustments for differences in source, path, and site characteristics between the host region of the selected backbone GMM and the target region for which the PSHA is being conducted. The implementation of this approach is facilitated by selecting a backbone GMM that is amenable to such host-to-target adjustments for individual source, path, and site characteristics. The NGA-West2 GMM of Chiou and Youngs (CY14) has been identified as a highly adaptable model for crustal seismicity that is well suited to such adjustments. Rather than using generic source, path, and site characteristics assumed appropriate for the host region, the final suite of adjusted GMMs for the target region will be better constrained if the host-region parameters are defined specifically on the basis of their compatibility with the CY14 backbone GMM. To this end, making use of a recently developed crustal shear-wave velocity profile consistent with CY14, we present an inversion of the model to estimate the key source and path parameters, namely the stress parameter and the anelastic attenuation. With these outputs, the effort in constructing a ground-motion logic tree for any PSHA dealing with crustal seismicity can be focused primarily on the estimation of the target-region characteristics and their associated uncertainties. The inversion procedure can also be adapted for any application in which different constraints might be relevant.

Stafford, Peter J.↗

Nutritional markers and proteome in patients undergoing treatment for pulmonary tuberculosis differ by geographic region

Contemporary phase 2 TB disease treatment clinical trials have found that microbiologic treatment responses differ between African versus non-African regions, the reasons for which remain unclear. Understanding host and disease phenotypes that may vary by region is important for optimizing curative treatments. We characterized clinical features and the serum proteome of phase 2 TB clinical trial participants undergoing treatment for smear positive, culture-confirmed TB, comparing host serum protein expression in clinical trial participants enrolled in African and Non-African regions. Serum samples were collected from 289 participants enrolled in the Centers for Disease Control and Prevention TBTC Study 29 (NCT00694629) at time of enrollment and at the end of the intensive phase (after 40 doses of TB treatment). After a peptide level proteome analysis utilizing a unique liquid chromatography IM-MS platform (LC-IM-MS) and subsequent statistical analysis, a total of 183 core proteins demonstrated significant differences at both baseline and at week 8 timepoints between participants enrolled from African and non-African regions. The majority of the differentially expressed proteins were upregulated in participants from the African region, and included acute phase proteins, mediators of inflammation, as well as coagulation and complement pathways. Downregulated proteins in the African population were primarily linked to nutritional status and lipid metabolism pathways. We have identified differentially expressed nutrition and lipid pathway proteins by geographic region in TB patients undergoing treatment for pulmonary tuberculosis, which appear to be associated with differential treatment responses. Future TB clinical trials should collect expanded measures of nutritional status and further evaluate the relationship between nutrition and microbiologic treatment response.

59 BASIC BIOLOGICAL SCIENCES↗

Compilation of a Comprehensive Earthquake Catalog and Relocations in the Caucasus Region

Instrumental seismic monitoring has a long history in the Caucasus and started in 1899 when the first seismograph was installed in Tbilisi, Georgia. Much of the analog paper records from this time period are preserved in the Tbilisi archives because Georgia served as the regional data center. In the 1990s, due to the collapse of the Soviet Union and the political turmoil in the region, the analog networks and the communication between the newly formed national networks deteriorated. In Georgia, for the next 13 yr, the seismic network coverage was poor until the 2002 Tbilisi earthquake. Following this earthquake, the first permanent digital seismic station in Georgia was established in Tbilisi in 2003. The digital era progressively improved the ability to collect and archive data and today more than a hundred broadband seismic stations (including temporary arrays) are operating in the southern Caucasus. Until recently, the region lacked a coordinated effort to catalog all analog and digital era data collected by different countries into a single repository. As a result of collaboration between Lawrence Livermore National Laboratory, the Ilia State University, and the Republican Seismic Survey Center of Azerbaijan, a comprehensive earthquake catalog was compiled for the Caucasus and neighboring areas as part of a broader probabilistic seismic hazard assessment project. Here this project digitized Soviet-era paper bulletins, compiled a unified earthquake catalog from regional bulletins, developed 1D reference velocity model, and used it to relocate the events. The final catalog contains 16,963 events with magnitudes 3.7 and above, bringing together all the available data sets in the Caucasus region from 1900 to 2015, significantly improving locations, and generating the most complete earthquake catalog in the region, temporally and geographically.

58 GEOSCIENCES↗

Midwestern Regional Carbon Sequestration Partnership (MRCSP) Phase III (Development Phase) (Final Report)

The Midwest Regional Carbon Sequestration Partnership (MRCSP) was founded in 2003 as part of the U.S. Department of Energy’s (DOE’s) Regional Carbon Sequestration Partnership (RCSP) Initiative. The public/private consortium, funded through the MRCSP, brings together nearly 40 industry partners in 10 contiguous states in Mid-West and North-East regions. Battelle, as the project lead, oversees research & development, operations, and coordinates activities among various partners. Since its founding, MRCSP has made significant progress towards advancing CCS and CCUS technologies for participating states in the region. Between 2008 to 2020, Phase III of the MRCSP program focused on the development of large-scale injection tests. This report is part of a series of topical reports prepared under the MRCSP Phase III. The MRCSP Final Technical Report summarizes the research conducted while monitoring large-scale injection tests at a CO 2 -EOR facility in Northern Michigan. The project successfully injected more than one million metric tons of CO 2 into depleted oil fields in the Northern Niagaran Pinnacle Reef Trend (NNPRT) for enhanced oil recovery (EOR). These commercial-scale tests provided valuable real-world knowledge that has been used to refine technologies and methods, reduce uncertainties, and demonstrate safety and effectiveness of CCUS technologies to increase public acceptance. The Final Technical Report provides an overview of Phase III efforts including advancing the understanding of the regional geology, storage capacities, deployment of many monitoring and modeling techniques and its efficacy, and technical demonstration of large-scale CO 2 injection, containment, and associated storage in the NNPRT region. Specific topical reports on the subjects covered in the Final Technical Report are also available through EDX/OSTI.

01 COAL, LIGNITE, AND PEAT↗

Measurement Acceptance Region (MAR) Assessment Results Based On Sludge Batch 10 Projections from December 2021, February 2022 and August 2022

The Defense Waste Processing Facility (DWPF) is currently preparing to initiate processing of Sludge Batch 10 (SB10), which is comprised of material from Tanks 11H, 13H, 15H, and 26F, Alternate Feed Stock-2 and Sodium Reactor Experiment material from H-Canyon. Frit 473 (8B 2 O 3 -8Li 2 O-5Na 2 O-79SiO 2 , in weight percent) was recommended for sludge-only (SO) and coupled processing with the Salt Waste Processing Facility (SWPF) based on previous assessments of SB10 projections with the DWPF Product Composition Control System (PCCS) glass property models and their associated Measurement Acceptance Region (MAR) constraints. Due to the lower processing rate of Sludge Batch 9 (SB9), the heel in Tank 40 is anticipated to be greater than 40 inches at the projected start of SB10 processing to meet the upcoming Accelerated Basin Deinventory addition dates in Tank 51 for Sludge Batch 11. In December 2021 and February 2022, Savannah River Remediation System Planning provided updated SB10 Tank 40 blend projections based on heels of 74 inches, 84 inches, 94 inches and 103.4 inches. Savannah River Mission Completion (SRMC) subsequently pursued Wash Cycle Y to further reduce the total sulfur in the sludge batch and increase processing flexibility at DWPF. In August 2022, SRMC System Planning provided an updated SB10 Tank 40 blend projection with a 76 inch-heel representing Decant Y2 and 60 kilogallons of bearing water inleakage that is anticipated during the Tank 51 to Tank 40 transfer. The objectives of this task were to: • Determine the impact on the operating windows for SO and coupled processing • Determine whether any composition gaps exist between the already completed SB10 variability study and the reprojected SB10 glass composition region • Compare the SB10 reprojected glass composition region to the DWPF PCCS model development and validation ranges to ensure that compositional gaps do not exist between the data sets. This report documents the results of these evaluations. Calculation-based frit assessments were performed using the DWPF PCCS glass property models and their associated MAR constraints. Evaluated parameters for coupled processing included the following transfer volumes per Sludge Receipt and Adjustment Tank batch: 5700 gallons of Tank 40 sludge, 2400-4500 gallons of the SWPF monosodium titanate (MST) and sludge solids stream, and 15,000 gallons of strip effluent. Based on these MAR assessment results, Frit 473 remains viable for SB10 processing. A target waste loading (WL) of 36% is possible for SO operation and single strike (0.4 g/L MST) coupled processing up to 600 mg/L of SB9 insoluble sludge solids at a nominal transfer volume of ~2800 gallons. Increasing the single strike transfer volume to 4500 gallons may reduce the maximum WL below 40%. Operating windows are 12 percentage points for SO processing and 14-16 percentage points for coupled processing. Frit 625 allows for a target WL of 36% and is acceptable for use during the SB9 to SB10 transition to deplete remaining inventory as needed. Operating windows are 8 percentage points for SO processing and 12-14 percentage points for coupled processing. Predictive PCCS evaluations performed at DWPF will provide insight into batch-specific acceptability at desired WLs for compositions having expected oxide ratios during processing versus the extreme vertices (corner points) evaluated in this study. The reprojected SB10 glass composition region generally overlaps the previously evaluated SB10 variability study composition region. Thus, the minor composition shift of these updated SB10 projections indicates that no additional glasses are necessary to demonstrate acceptability relative to the chemical durability of the Environmental Assessment benchmark glass and predictability using the current PCCS models for durability. Based on a comparison of the PCCS model development and validation data to the reprojected SB10 glass composition region, the viscosity and liquidus temperature models will reliably predict SB10 compositions. No additional glasses are necessary to demonstrate predictability of these models.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Clean Energy Education and Training Resources and Opportunities in New York's Southern Tier Region

New York's Southern Tier Region is experiencing high growth and investment in the clean energy sector and is anticipating more jobs to come in energy efficiency, renewable energy, and manufacturing in the coming years. The Network for a Sustainable Tomorrow (NEST) is a nonprofit network of programs working to develop a regional backbone system for education and training programs as well as curricula to support the workforce needed for the region's growing industries to succeed. Through its participation in the US Department of Energy's Better Buildings Workforce Accelerator, NEST requested technical assistance in conducting a landscape and needs assessment of the region's existing clean energy education and workforce development assets. This report supports NEST's efforts by providing a baseline of clean energy employment data, an inventory and gap analysis of the education and workforce development assets currently available and serving the Southern Tier Region, and case studies of innovative and successful regional clean energy education and workforce coalitions from around the county.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

MRCI Subtask 2.1: Defining Sub-Regional Carbon Storage Systems Final Technical Summary Report

In order to assess the regional and subregional geologic framework of the MRCI area and expand carbon dioxide (CO2) storage characterization efforts in this larger region, the current state of geologic knowledge relative to carbon storage (CS) has been summarized by compiling available geologic data and interpretive results into a centralized resource under Subtask 2.1. The MRCI region is a large area, which includes (1) part of the Forest City Basin and Western Arches, (2) Illinois Basin, (3) Upper Mississippi Embayment, (4) Michigan Basin, (5) Central Arches, (6) Appalachian Basin, and (7) Atlantic Coastal Plain and West Atlantic basins. Basins and arches are subdivided into areas of similar geology based on geologic structures and state-specific stratigraphic nomenclature. A concerted effort was made to present the current understanding of rock-unit stratigraphy in the subsurface of each basin and arch region (and subdivisions therein). Rock units are characterized based on their relative CS potential (saline reservoirs, confining intervals, etc.) within CS systems. CS systems are defined by regional confining units (usually thick, widespread shales), and contain all reservoirs and strata between the regional confining units. Report Authors – Steve Greb and Tom Sparks (Kentucky Geological Survey), Mark Kelley, Sanjay Mawalkar, John Hershberger, Priya Ravi Ganesh, Derrick James, and Stuart Skopec (Battelle), Charles Bopp, Yaghoob Lasemi and Hannes Leetaru (deceased) (Illinois State Geological Survey), Kristin Carter (Pennsylvania Geological Survey), William Harrison (Michigan Geological Repository for Research and Education – Michigan Geological Survey), Susan Pool (West Virginia Geological and Economic Survey), James McDonald (Ohio Geological Survey), John Schmelz (Rutgers University), Ryan Clark (Iowa Geological Survey). Other Technical Contributors – Seth Carpenter and John Hickman (Kentucky Geological Survey), Jessica Moore, Eric Lewis, Philip Dinterman, Timothy Vance, and Gary Daft (West Virginia Geological and Economic Survey), Michele Cooney, Robin Anthony, Cheyenne Woodward, and Katherine Schmid (Pennsylvania Geological Survey), Autumn Haagsma and Amber Conner (Michigan Geological Repository for Research and Education – Michigan Geological Survey), Kenneth Miller (Rutgers University), Ashley Douds and Valerie Beckham-Feller (Indiana Geological & Water Survey), Michael Solis (Ohio Geological Survey).

Appalachian,Arches,Forest City,Illinois,MRCI,Michi↗

Identifying a regional aerosol baseline in the eastern North Atlantic using collocated measurements and a mathematical algorithm to mask high-submicron-number-concentration aerosol events

Abstract. High-time-resolution measurements of in situ aerosol and cloud properties provide the ability to study regional atmospheric processes that occur on timescales of minutes to hours. However, one limitation to this approach is that continuous measurements often include periods when the data collected are not representative of the regional aerosol. Even at remote locations, submicron aerosols are pervasive in the ambient atmosphere with many sources. Therefore, periods dominated by local aerosol should be identified before conducting subsequent analyses to understand aerosol regional processes and aerosol–cloud interactions. Here, we present a novel method to validate the identification of regional baseline aerosol data by applying a mathematical algorithm to the data collected at the U.S. Department of Energy's (DOE) Atmospheric Radiation Measurement (ARM) user facility in the eastern North Atlantic (ENA). The ENA central facility (C1) includes an aerosol observing system (AOS) for the measurement of aerosol physical, optical, and chemical properties at time resolutions from seconds to minutes. A second temporary supplementary facility (S1), located ∼0.75 km from C1, was deployed for ∼1 year during the Aerosol and Cloud Experiments (ACE-ENA) campaign in 2017. First, we investigate the local aerosol at both locations. We associate periods of high submicron number concentration (Ntot) in the fine-mode condensation particle counter (CPC) and size distributions from the Ultra-High Sensitivity Aerosol Spectrometer (UHSAS) as a function of wind direction using a meteorology sensor with local sources. Elevated concentrations of Aitken-mode (< 100 nm diameter) particles were observed in correspondence with the wind directions associated with airport operations. At ENA, the Graciosa Airport and its associated activities were found to be the main sources of high-concentration aerosol events at ENA, causing peaks in 1 min Ntot that exceeded 8000 and 10 000 cm−3 at C1, in summer and winter, respectively, and 5000 cm−3 at S1 in summer. Periods with high Ntot not associated with these wind directions were also observed. As a result, the diverse local sources at ENA yielded a poor relationship between Ntot measurements collected at C1 and S1 (R2=0.03 with a slope =0.05±0.001). As a first approach to mask these events, the time periods when the wind direction was associated with the airport operations (west to northwest and southeast to south at C1 and east to south at S1) were applied. The meteorological masks removed 38.9 % of the data at C1 and 43.4 % at S1, and they did not significantly improve the relationship between the two sites (R2=0.18 with a slope =0.06±0.001). Due to the complexity of high-Ntot events observed at ENA, we develop and validate a mathematical ENA Aerosol Mask (ENA-AM) to identify high-Ntot events using 1 min resolution data from the AOS CPC at C1 and S1. After its parameterization and application, ENA-AM generated a high correlation between Ntot in the summer at C1 and S1 (R2=0.87 with a slope =0.84±0.001). We identified the regional baseline at ENA to be 428±228 cm−3 in the summer and 346±223 cm−3 in the winter. Lastly, we compared masked measurements from the AOS with the ARM Aerial Facility (AAF) during flights over C1 in the summer to understand submicron aerosol vertical mixing over C1. The high correlation (R2=0.71 with a slope of 1.04±0.01) observed between C1 and the AAF Ntot collected within an area of 10 km surrounding ENA and at altitudes < 500 m indicated that the submicron aerosol at ENA was well mixed within the first 500 m of the marine boundary layer during the month of July during ACE-ENA. Our novel method for determining a regional aerosol baseline at ENA can be applied to other time periods and at other locations with validation by a secondary site or additional collocated measurements.

54 ENVIRONMENTAL SCIENCES↗

Quantification of regional net CO 2 flux errors in the Orbiting Carbon Observatory-2 (OCO-2) v10 model intercomparison project (MIP) ensemble using airborne measurements

Inverse model intercomparison projects (MIPs) provide a chance to assess the uncertainties in inversion estimates arising from various sources. However, accurately quantifying ensemble CO 2 flux errors remains challenging and often relies on the ensemble spread. This study proposes a method for quantifying the errors in regional net surface–atmosphere CO 2 flux estimates from models taken from the Orbiting Carbon Observatory-2 (OCO-2) v10 MIP by using independent airborne CO 2 measurements for the period 2015–2017. We first calculate the root mean square error (RMSE) between the ensemble mean of posterior CO 2 concentrations and airborne observations and then isolate the CO 2 concentration errors caused solely by the ensemble mean of posterior net fluxes by subtracting the observation, representation, and transport errors from seven regions. Our analysis reveals that the flux errors projected onto CO 2 space account for 55 %–85 % of the regional average RMSE over the 3 years, ranging from 0.88 to 1.91 ppm. In five regions, the error estimates based on observations exceed those computed from the ensemble spread of posterior fluxes by a factor of 1.33–1.93, implying an underestimation of the actual flux errors, while their magnitudes are comparable in two regions. The adjoint sensitivity analysis identifies that the underestimation of flux errors is prominent where the magnitudes of fossil fuel emissions exceed those of terrestrial-biosphere fluxes by a factor of 3–31 over the 3 years. This suggests the presence of systematic biases in the inversion estimates associated with errors in the prescribed fossil fuel emissions common to all models. Our study emphasizes the value of airborne measurements for quantifying regional errors in ensemble net CO 2 flux estimates.

54 ENVIRONMENTAL SCIENCES↗

Predicting Missing Regions in Charged Particle Tracks Using a Sparse 3D Convolutional Neural Network

The 2x2 Demonstrator is a prototype of ND-LAr, the liquid argon time-projection chamber of the Deep Underground Neutrino Experiment’s Near Detector complex. Both the 2x2 Demonstrator and ND-LAr are modular detectors that will have pixelated charge readouts and inactive regions wherein there is no sensitivity to charge deposition and light signals that arise from charged particle interactions with liquid argon. In the 2x2, these inactive regions are located in between the active detector modules, which introduces the challenge of inferring what charge signals ought to look like in these regions. This study explores the use of a Sparse 3D Convolutional Neural Network (ConvNet) to infer missing regions in charged particle tracks. Hits corresponding to energy depositions are voxelized into a three-dimensional grid for each track. Voxels that fall into predefined inactive regions are removed to simulate the lack of detector output. The model is trained to infer the topology of the missing track voxels, with the ultimate goal of inferring the missing charge or energy values in these voxels as well. Results indicate that this approach shows promise in prediction of missing track regions with some accuracy.

Utaegbulam, Hilary↗

Newton trust-region methods with primary variable switching for simulating high temperature multiphase porous media flow

Coupling multiphase flow with energy transport due to high temperature heat sources introduces significant new challenges since boiling and condensation processes can lead to dry-out conditions with subsequent re-wetting. The transition between two-phase and single-phase behavior can require changes to the primary dependent variables adding discontinuities as well as extending constitutive nonlinear relations to extreme physical conditions. Practical simulations of large-scale engineered domains lead to Jacobian systems with a very large number of unknowns that must be solved efficiently using iterative methods in parallel on high-performance computers. Performance assessment of potential nuclear repositories, carbon sequestration sites and geothermal reservoirs can require numerous Monte-Carlo simulations to explore uncertainty in material properties, boundary conditions, and failure scenarios. Due to the numerical challenges, standard NR iteration may not converge over the range of required simulations and require more sophisticated optimization method like trust-region. In this study, we use the open-source simulator PFLOTRAN for the important practical problem of the safety assessment of future nuclear waste repositories in the U.S. DOE geologic disposal safety assessment Framework. The simulator applies the PETSc parallel framework and a backward Euler, finite volume discretization. We demonstrate failure of the conventional NR method and the success of trust-region modifications to Newton’s method for a series of test problems of increasing complexity. Trust-region methods essentially modify the Newton step size and direction under some circumstances where the standard NR iteration can cause the solution to diverge or oscillate. Furthermore, we show how the Newton Trust-Region method can be adapted for Primary Variable Switching (PVS) when the multiphase state changes due to boiling or condensation. The simulations with high-temperature heat sources which led to extreme nonlinear processes with many state changes in the domain did not converge with NR, but they do complete successfully with the trust-region methods modified for PVS. This implementation effectively decreased weeks of simulation time needing manual adjustments to complete a simulation down to a day. Finally, we show the strong scalability of the methods on a single node and multiple nodes in an HPC cluster.

54 ENVIRONMENTAL SCIENCES↗

Exploring the Potential of Rainwater Harvesting for Cooling Towers: A Systematic Review and Regional Feasibility Assessment

Water scarcity has driven interest in rainwater harvesting, especially for U.S. industries like power and manufacturing, which dedicate a large percentage of their water needs to cooling towers. This paper provides a comprehensive systematic review of studies on the use of rainwater in cooling tower applications, along with an assessment of the regional feasibility of integrating RWH in U.S. manufacturing cooling towers. The systematic review examines the technical, economic, environmental, and policy feasibility of utilizing harvested rainwater, and the regional feasibility analysis evaluates the practical implementation of RWH in manufacturing cooling towers, considering factors such as regional RWH potential, water costs, state policies, and the industrial water use of manufacturing facilities per state. This study supports the hypothesis that RWH for cooling towers is technically feasible, economically viable, and environmentally beneficial. Harvested rainwater is naturally less conductive and soft, and rainwater reuse minimizes the ecological footprint. Supportive state policies, regional RWH potential, and rising water costs across the U.S. are important variables that may impact RWH adoption. The review highlights rooftop RWH as the most studied method and notes that implementing RWH requires infrastructure changes and filtration techniques. While initial investment costs may be high, operational and maintenance costs are low, making RWHS economically feasible over time. Regions with higher water costs and supportive policies are more likely to benefit from RWH adoption. The study provides a foundation for understanding the potential for using RWH in industrial cooling towers.

Cooling towers↗

An Evaluation of Dynamical Downscaling Methods Used to Project Regional Climate Change

In the past decade, dynamical downscaling using “pseudo-global-warming” (PGW) techniques has been applied frequently to project regional climate change. Such techniques generate signals by adding mean global climate model (GCM)-simulated climate change signals in temperature, moisture, and circulation to lateral and surface boundary conditions derived from reanalysis. An alternative to PGW is to downscale GCM data directly. This technique should be advantageous, especially for simulation of extremes, since it incorporates the GCM's full spectrum of changing synoptic-scale dynamics in the regional solution. Here, we test this assumption, by comparing simulations in Europe and Western North America. We find that for warming and changes in temperature extremes, PGW often produces similar results to direct downscaling in both regions. For mean and extreme precipitation changes, PGW generally also performs surprisingly well in many cases. Moisture budget analysis in the Western North America domain reveals why. Large fractions of the downscaled hydroclimate changes arise from mean changes in large-scale thermodynamics and circulation, that is, increases in temperature, moisture, and winds, included in PGW by design. The one component PGW may have difficulty with is the contribution from changes in synoptic-scale variability. When this component is large, PGW performance could be degraded. Global analysis of GCM data shows there are regions where it is large or dominant. Hence, our results provide a road map to identify, through GCM analyses, the circumstances when PGW would not be expected to accurately regionalize GCM climate signals.

54 ENVIRONMENTAL SCIENCES↗

Transboundary effects from idealized regional geoengineering

Regional geoengineering, by reflecting sunlight over a very limited spatial domain, might be considered as a means to target specific regional impacts of climate change. One of the obvious concerns raised by such approaches is the extent to which the resulting effects would be detectable well beyond the targeted region (e.g. in neighbouring countries). A few studies have explored this question for targeted regions that are still comparatively large. We consider idealized simulations with increased ocean albedo over relatively small domains; the Gulf of Mexico (0.23% of Earth's surface) and over the Australian Great Barrier Reef (0.07%), both with negligible global radiative forcing. Applied over these very small domains, the only statistically significant non-local changes we find are some limited reduction on summer precipitation in Florida in the Gulf of Mexico case (adjacent to the targeted region). The lack of transboundary effects suggests that governance needs for such targeted interventions are quite distinct from those for more global sunlight reflection.

54 ENVIRONMENTAL SCIENCES↗

Regional trends and drivers of the global methane budget

Abstract The ongoing development of the Global Carbon Project (GCP) global methane (CH 4 ) budget shows a continuation of increasing CH 4 emissions and CH 4 accumulation in the atmosphere during 2000–2017. Here, we decompose the global budget into 19 regions (18 land and 1 oceanic) and five key source sectors to spatially attribute the observed global trends. A comparison of top‐down (TD) (atmospheric and transport model‐based) and bottom‐up (BU) (inventory‐ and process model‐based) CH 4 emission estimates demonstrates robust temporal trends with CH 4 emissions increasing in 16 of the 19 regions. Five regions—China, Southeast Asia, USA, South Asia, and Brazil—account for >40% of the global total emissions (their anthropogenic and natural sources together totaling >270 Tg CH 4 yr −1 in 2008–2017). Two of these regions, China and South Asia, emit predominantly anthropogenic emissions (>75%) and together emit more than 25% of global anthropogenic emissions. China and the Middle East show the largest increases in total emission rates over the 2000 to 2017 period with regional emissions increasing by >20%. In contrast, Europe and Korea and Japan show a steady decline in CH 4 emission rates, with total emissions decreasing by ~10% between 2000 and 2017. Coal mining, waste (predominantly solid waste disposal) and livestock (especially enteric fermentation) are dominant drivers of observed emissions increases while declines appear driven by a combination of waste and fossil emission reductions. As such, together these sectors present the greatest risks of further increasing the atmospheric CH 4 burden and the greatest opportunities for greenhouse gas abatement.

59 BASIC BIOLOGICAL SCIENCES↗

Regional analysis of aluminum and steel flows into the American automotive industry

Aluminum and steel represent the two most dominant metals in light duty vehicles, yet the flows of these materials into the American automotive industry have not been well characterized. This study proposes and implements a method for analyzing the flow of these metals into the automotive industry. We create a framework for performing regionally linked, sector specific material flow analyses and use this framework to trace flows of aluminum and steel entering the American automotive industry, focusing on flows downstream from raw material production. We show that automotive aluminum sheet and extrusions are sourced primarily from the NPCC (23%), SERC (20%), MRO (18%), and RFC (13%) NERC regions and a spatially unresolved Local region within the U.S. and Canada (18%). We determine that primary aluminum is largely from Canada (70%), nearly all from Quebec (69%). Further upstream, alumina and bauxite originate mostly from Brazil, Australia, and Jamaica. We also show that finished automotive steel is sourced primarily from the RFC (63%) and SERC (20%) regions. The crude steel supply similarly originates mainly from the RFC (69%) and SERC (7%) regions. Upstream raw materials including coke, coking coal, iron ore, lime, and steel scrap are primarily sourced from the U.S. with only direct reduced iron and pig iron used in electric arc furnace steel production coming mostly from outside the U.S. The framework developed here allows for increased spatial resolution of material flows, which can be used to develop more specific life cycle impact factors for life cycle assessments.

aluminum↗

Use-Inspired, Process-Oriented GCM Selection: Prioritizing Models for Regional Dynamical Downscaling

Dynamical downscaling is a crucial process for providing regional climate information for broad uses, using coarser-resolution global models to drive higher-resolution regional climate simulations. The pool of global climate models (GCMs) providing the fields needed for dynamical downscaling has increased from the previous generations of the Coupled Model Intercomparison Project (CMIP). However, with limited computational resources, the need for prioritizing the GCMs for subsequent downscaling studies remains. GCM selection for dynamical downscaling should focus on evaluating processes relevant for providing boundary conditions to the regional models and be inspired by regional uses such as the response of extremes to changes in the boundary conditions. This leads to the need for metrics representing processes of relevance to diverse stakeholders and subregions of a domain. Procedures to account for metric redundancy and the statistical distinguishability of GCM rankings are required. Further, procedures for selecting realizations from ensembles of top-performing GCM simulations can be used to span the range of climate change signals in multiple ways. As a result, distinct weighting of metrics and prioritization of particular realizations may depend on user needs. We provide high-level guidelines for such region-specific evaluations and address how CMIP7 might enable dynamical downscaling of a representative sample of high-quality models across representative shared socioeconomic pathways (SSPs).

54 ENVIRONMENTAL SCIENCES↗