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At least 145 records · Page 8

Round-robin weathering test of various polymeric back-sheets for PV modules with different ultraviolet irradiation and sample temperatures

Durability assessment of materials exposed to natural weathering with expected service lifetimes of more than 20 years requires accelerated testing of the UV stability, especially for polymeric materials. Fraunhofer ISE organized an interlaboratory comparison for testing different back-sheets in various test laboratories using different UV sources. The five participating test laboratories used three different types of UV sources. The interaction of the UV radiation with the polymers used in PV modules is main subject of this round-robin. Laminates were produced by using solar glass and a suitable EVA encapsulant combined with 10 different back-sheets. The simultaneous usage of different optical filters allowed to investigate roughly the spectral sensitivity and the intensity impact. The degradation was followed by spectral reflectance and transmittance measurements and calculation of the yellowness index as degradation indicator. Clear differences in the degradation behavior of the different products were found.

14 SOLAR ENERGY↗

Proposed acceptance, qualification, and characterization tests for thin-film PV modules

Details of a proposed test program for PV thin-film modules which the Department of Energy has directed the Solar Energy Research Institute (SERI) to prepare are presented. Results of one of the characterization tests that SERI has performed are also presented. The objective is to establish a common approach to testing modules that will be acceptable to both users and manufacturers. The tests include acceptance, qualification, and characterization tests. Acceptance tests verify that randomly selected modules have similar characteristics. Qualification tests are based on accelerated test methods designed to simulate adverse conditions. Characterization tests provide data on performance in a predefined environment.

Waddington, D.↗

Towards 50 Year Lifetime PV Modules: Double Glass vs. Glass/Backsheet

This award aims to increase the lifetime of c-Si modules by lowering the power degradation rate to the goal of 0.2 %/year, while also increasing the harvested irradiance per module using bifacial cells to achieve the 2030 SunShot goal of $0.03/kWh. Increasing the durability and lifetime of modules requires improved module packaging material choices and module architectures to exploit new cell improvements. Bifacial PERC cells (with backside aluminum fingers) are becoming a primary PV technology due to their decreased rear surface recombination and increased light absorption compared to traditional monofacial Al-BSF cells. Bifacial modules with double glass architectures have been deployed to capture the rear-side irradiance thereby increasing the light captured. The choice of a double glass (DG) or glass/backsheet (GB) module leads to two very different chemical (e.g., O 2 , H 2 O) and mechanical environments (e.g., mechanical stress levels) inside the PV module that impact the cell’s operational conditions. The recipient will fabricate 4-cell DG and GB minimodules with various module architectures or constructions (mono- & bifacial cells, transparent & white encapsulants), and conduct stepwise accelerated exposures and characterization.

14 SOLAR ENERGY↗

The Present, Mid-Term, and Long-Term Supply Curves for Tellurium; and Updates in the Results from NREL's CdTe PV Module Manufacturing Cost Model (Presentation)

For those PV technologies that rely upon Te, In, and Ga, first-order observations and calculations hint that there may be resource constraints that could inhibit their successful deployment at a SunShot level. These are only first-order approximations, however, and the possibility for an expansion in global Te, In, and Ga supplies needs to be considered in the event that there are upward revisions in their demand and prices.In this study, we examine the current, mid-term, and long-term prospects of Tellurium (Te) for use in PV. We find that the current global supply base of Te would support <10 GW of annual traditional CdTe PV manufacturing production. But as for the possibility that the supply base for Te might be expanded, after compiling several preliminary cumulative availability curves we find that there may be significant upside potential in the supply base for this element - principally vis a vis increasing demand and higher prices. Primarily by reducing the Tellurium intensity in manufacturing and by increasing the recovery efficiency of Te in Cu refining processes, we calculate that it may prove affordable to PV manufacturers to expand the supply base for Te such that 100 GW, or greater, of annual CdTe PV production is possible in the 2030 - 2050 timeframe.

14 SOLAR ENERGY↗

Technology and Climate Trends in PV Module Degradation (Presentation)

To sustain the commercial success of photovoltaic (PV) technology it is vital to know how power output decreases with time. Unfortunately, it can take years to accurately measure the long-term degradation of new products, but past experience on older products can provide a basis for prediction of degradation rates of new products. An extensive search resulted in more than 2000 reported degradation rates with more than 1100 reported rates that include some or all IV parameters. In this presentation we discuss how the details of the degradation data give clues about the degradation mechanisms and how they depend on technology and climate zones as well as how they affect current and voltage differently. The largest contributor to maximum power decline for crystalline Si technologies is short circuit current (or maximum current) degradation and to a lesser degree loss in fill factor. Thin-film technologies are characterized by a much higher contribution from fill factor particularly for humid climates. Crystalline Si technologies in hot & humid climates also display a higher probability to show a mixture of losses (not just short circuit current losses) compared to other climates. The distribution for the module I-V parameters (electrical mismatch) was found to change with field exposure. The distributions not only widened but also developed a tail at the lower end, skewing the distribution.

14 SOLAR ENERGY↗

Technology and Climate Trends in PV Module Degradation: Preprint

To sustain the commercial success of photovoltaic (PV) technology it is vital to know how power output decreases with time. Unfortunately, it can take years to accurately measure the long-term degradation of new products, but past experience on older products can provide a basis for prediction of degradation rates of new products. An extensive search resulted in more than 2000 reported degradation rates with more than 1100 reported rates that include some or all IV parameters. In this paper we discuss how the details of the degradation data give clues about the degradation mechanisms and how they depend on technology and climate zones as well as how they affect current and voltage differently. The largest contributor to maximum power decline for crystalline Si technologies is short circuit current (or maximum current) degradation and to a lesser degree loss in fill factor. Thin-film technologies are characterized by a much higher contribution from fill factor particularly for humid climates. Crystalline Si technologies in hot & humid climates also display a higher probability to show a mixture of losses (not just short circuit current losses) compared to other climates. The distribution for the module I-V parameters (electrical mismatch) was found to change with field exposure. The distributions not only widened but also developed a tail at the lower end, skewing the distribution.

14 SOLAR ENERGY↗

Bottom-Up Cost Analysis of a High Concentration PV Module

We present a bottom-up model of III-V multi-junction cells, as well as a high concentration PV (HCPV) module. We calculate $0.59/W(DC) manufacturing costs for our model HCPV module design with today's capabilities, and find that reducing cell costs and increasing module efficiency offer the most promising paths for future cost reductions. Cell costs could be significantly reduced via substrate reuse and improved manufacturing yields.

14 SOLAR ENERGY↗

Bottom-Up Cost Analysis of a High Concentration PV Module; NREL (National Renewable Energy Laboratory)

We present a bottom-up model of III-V multi-junction cells, as well as a high concentration PV (HCPV) module. We calculate $0.65/Wp(DC) manufacturing costs for our model HCPV module design with today’s capabilities, and find that reducing cell costs and increasing module efficiency offer the promising pathways for future cost reductions. Cell costs could be significantly reduced via an increase in manufacturing scale, substrate reuse, and improved manufacturing yields. We also identify several other significant drivers of HCPV module costs, including the Fresnel lens primary optic, module housing, thermal management, and the receiver board. These costs could potentially be lowered by employing innovative module designs.

$/W↗

Reliable Power Rating of Perovskite PV Modules

As the perovskite technology is ramping up into commercialization, reliable and accurate power rating of large-size perovskite modules becomes a prominent aspect for its future deployment in the PV market. It is known that the performance calibration of perovskite PV devices is very challenging due to its complex dynamic response during a conventional current-voltage (IV) measurement. PV researchers have previously proposed several steady-state performance calibration methods to reliably extract PV efficiencies, but mostly focus on small area research-type cells. In this paper, we emphasize the importance of reliable performance calibration on large-size perovskite modules. Extending the NREL Cell and Module Performance (CMP) group's steady-state performance calibration protocol (i.e., Asymptotic P MAX Scan) for perovskite cells to modules, we justify the necessity of reporting steady-state efficiencies for perovskite cells and discuss the challenges of applying this protocol to modules. We also present our protocol for Maximum Power Point Tracking (MPPT), which is a technique often used for performance calibration of perovskite cells and modules, and show a comparison between MPPT and Asymptotic P MAX . Using MPPT we demonstrate the interplay between metastability and degradation in perovskite modules, and emphasize the necessity to develop preconditioning protocols for stabilizing these devices. Our aim is to promote development of consensus protocols for performance calibration of perovskite modules, and to advance their credible power ratings, which will be beneficial to the growth of perovskite technology in the PV market.

perovskite↗

Reliable Power Rating of Perovskite PV Modules: Preprint

As the perovskite technology is ramping up into commercialization, reliable and accurate power rating of large-size perovskite modules becomes a prominent aspect for its future deployment in the PV market. It is known that the performance calibration of perovskite PV devices is very challenging due to its complex dynamic response during a conventional current-voltage (IV) measurement. PV researchers have previously proposed several steady-state performance calibration methods to reliably extract PV efficiencies, but mostly focus on small area research-type cells. In this paper, we emphasize the importance of reliable performance calibration on large-size perovskite modules. Extending the NREL Cell and Module Performance (CMP) group’s steady-state performance calibration protocol (i.e., Asymptotic PMAX Scan) for perovskite cells to modules, we justify the necessity of reporting steady-state efficiencies for perovskite cells and discuss the challenges of applying this protocol to modules. We also present our protocol for Maximum Power Point Tracking (MPPT), which is a technique often used for performance calibration of perovskite cells and modules, and show a comparison between MPPT and Asymptotic PMAX. Using MPPT we demonstrate the interplay between metastability and degradation in perovskite modules, and emphasize the necessity to develop preconditioning protocols for stabilizing these devices. Our aim is to promote development of consensus protocols for performance calibration of perovskite modules, and to advance their credible power ratings, which will be beneficial to the growth of perovskite technology in the PV market.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Nondestructive Characterization and Accelerated UV Testing of Browned Field-Aged PV Modules

Encapsulant browning is one of the most common degradation modes found in crystalline silicon field-aged photovoltaic modules. Browning, usually undetected unless severe, reduces the short-circuit current (Isc) produced by a module. Therefore, field-aged browned modules have been subjected to accelerated UV testing to obtain true end-of-life activation energy for the encapsulant browning mechanism. A novel time- and resource-saving accelerated UV exposure testing method simultaneously allowing multiple module temperatures to be maintained in a single chamber run is presented. Six field-aged crystalline silicon modules of glass/backsheet construction (three each from BP Solar/Solarex MSX 60 and Siemens M55) with similar glass and encapsulant formulation were exposed to a UV dosage of 450 kWh/m2 . Through passive heating, the average module temperatures for the BP Solar/Solarex modules were 60 degrees C, 77 degrees C, and 85 degrees C and those of Siemens M55 were 75 degrees C, 80 degrees C, and 837 degrees C. To study UV browning, the modules were intermittently characterized through visual imaging, UV fluorescence imaging, electroluminescence imaging, quantum efficiency measurements, module, and cell-level light I-V measurements. An Isc decrease corroborated the increased extent of browning with increased module temperature. For the BP Solar/Solarex modules, the Low T, Mid T, and the High T modules showed a 1.37%, 2.48%, and 3.26% Isc drop, respectively. The Siemens modules showed a 4.11%, 5.65%, and 6.95% Isc drop. The multiple cell-level Isc data points obtained for each module temperature increased provided statistical significance. Activation energy for encapsulant browning was calculated as 0.44 and 0.72 eV for MSX 60 and M55 modules, respectively.

14 SOLAR ENERGY↗

Application of the NREL Test-to-Failure Protocol for PV Modules

Initial results of application of the NREL Test-to-Failure Protocol are presented and discussed. Six commercially available multicrystalline Si-cell flat-plate modules were subjected to the protocol with controls. The samples were divided among three test sequences, (1) 1000 hours of 85C/85% relative humidity with positive or negative 600 V bias to the active layers with respect to the grounded frame, (2) -40/85C thermal cycling with electrical load at the rated module power, and (3) an alternating sequence between tests (1) and (2). Application of the protocol manifested in the acceleration of degradation mechanisms seen in the field including backsheet delamination, corrosion, bubble formation within the laminate, discoloration of the antireflective coating, and localized heating with degradation of the backsheet as a result of moisture ingress, corrosion, and concentrated current flow. Significant differences in performance after one round of the protocol are seen in damp heat depending on the polarity of the bias applied to the active layer (the short-circuited power leads of the module). The protocol is found to successfully accelerate module degradation mechanisms that have been observed in the field and will help to differentiate the performance and reliability of various module technologies.

14 SOLAR ENERGY↗