Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “proton emission”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Anomalous interfacial dynamics of single proton charges in binary aqueous solutions

Our understanding of the dynamics of charge transfer between solid surfaces and liquid electrolytes has been hampered by the difficulties in obtaining interface, charge, and solvent-specific information at both high spatial and temporal resolution. Here, we measure at the single charge scale the dynamics of protons at the interface between an hBN crystal and binary mixtures of water and organic amphiphilic solvents (alcohols and acetone), evidencing a marked influence of solvation on interfacial dynamics. Applying single-molecule localization microscopy to emissive crystal defects, we observe correlated activation between adjacent ionizable surface defects, mediated by the transport of single excess protons along the solid/liquid interface. Solvent content has a nontrivial effect on interfacial dynamics, leading at intermediate water fraction to an increased surface diffusivity, as well as an increased affinity of the proton charges to the solid surface. Our measurements evidence the notable role of solvation on interfacial proton charge transport.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Electron tail suppression and effective collisionality due to synchrotron emission and absorption in mildly relativistic plasmas

Synchrotron radiation losses are a significant cause of concern for high-temperature aneutronic fusion reactions such as proton–Boron 11. The fact that radiation losses occur primarily in the high-energy tail, where the radiation itself has a substantial impact on the electron distribution, necessitates a self-consistent approach to modeling the diffusion and drag induced by synchrotron absorption and emission. Furthermore, an accurate model must account for the fact that the radiation emission spectrum is momentum-dependent, and the plasma opacity is frequency-dependent. Here, we present a simple Fokker–Planck operator, built on a newly solved-for blackbody synchrotron diffusion operator, which captures all relevant features of the synchrotron radiation. Focusing on magnetic mirror fusion plasmas, we show that significant suppression of the electron distribution occurs for relativistic values of the perpendicular electron momentum, which therefore emit much less radiation than predicted under the assumption of a Maxwell–Jüttner distribution.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Early-time γ -ray constraints on cosmic-ray acceleration in the core-collapse SN 2023ixf with the Fermi Large Area Telescope

Context. While supernova remnants (SNRs) have been considered the most relevant Galactic cosmic ray (CR) accelerators for decades, core-collapse supernovae (CCSNe) could accelerate particles during the earliest stages of their evolution and hence contribute to the CR energy budget in the Galaxy. Some SNRs have indeed been associated with TeV γ -rays, yet proton acceleration efficiency during the early stages of an SN expansion remains mostly unconstrained. Aims. The multi-wavelength observation of SN 2023ixf, a Type II supernova (SN) in the nearby galaxy M 101 (at a distance of 6.85 Mpc), opens the possibility to constrain CR acceleration within a few days after the collapse of the red super-giant stellar progenitor. With this work, we intend to provide a phenomenological, quasi-model-independent constraint on the CR acceleration efficiency during this event at photon energies above 100 MeV. Methods. We performed a maximum-likelihood analysis of γ -ray data from the Fermi Large Area Telescope up to one month after the SN explosion. We searched for high-energy, non-thermal emission from its expanding shock, and estimated the underlying hadronic CR energy reservoir assuming a power-law proton distribution consistent with standard diffusive shock acceleration. Results. We do not find significant γ -ray emission from SN 2023ixf. Nonetheless, our non-detection provides the first limit on the energy transferred to the population of hadronic CRs during the very early expansion of a CCSN. Conclusions. Under reasonable assumptions, our limits would imply a maximum efficiency on the CR acceleration of as low as 1%, which is inconsistent with the common estimate of 10% in generic SNe. However, this result is highly dependent on the assumed geometry of the circumstellar medium, and could be relaxed back to 10% by challenging spherical symmetry. Consequently, a more sophisticated, inhomogeneous characterisation of the shock and the progenitor’s environment is required before establishing whether or not Type II SNe are indeed efficient CR accelerators at early times.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Point defects in Ga 2 O 3

In the field of high-power electronics, gallium oxide (Ga 2 O 3 ) is attracting attention due to its wide band gap and ability to be doped n-type. Point defects, including vacancies, impurities, and dopants, play important roles in optimizing device performance. This tutorial discusses the fundamental properties of point defects in monoclinic β-Ga 2 O 3 and the methods employed to study them. Oxygen vacancies are deep donors that do not cause n-type conductivity but may compensate acceptors. Gallium vacancies are deep acceptors that can be partially passivated by hydrogen. Substitutional magnesium is a promising acceptor that produces semi-insulating material and also forms a complex with hydrogen. Calcium and iron also have deep acceptor levels. Iridium deep donors are introduced into crystals grown from a melt in an Ir crucible. Here, other defects are introduced by irradiation with energetic particles such as neutrons or protons. In addition to altering the electronic properties, defects give rise to UV/visible emission bands in photoluminescence and cathodoluminescence spectra.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Resolution of a discrepancy in the γ-ray emission probability from the β decay of 137 Ce g

We have deduced the emission probability of the 447-keV γ ray from the ε + β + decay of Ce g 137 (9.0 h) relative to that of the 254-keV γ ray from the Ce m 137 (34.4 h) decay in transient equilibrium. The time-dependent factor in transient equilibrium was applied following the Bateman equation for a radioactive decay chain. The isotope was produced via the La 139 ( p , 3 n ) Ce m , g 137 reaction by bombarding nat La with a proton beam from the 88-in. cyclotron at Lawrence Berkeley National Laboratory. γ -ray intensities were measured using an HPGe detector. The emission probability for the 447-keV γ ray deduced in this work is 1.21(3) (that is 1.21 ± 0.03) per hundred parent decays, which differs significantly from an earlier published value of 2.24(10). We identify the source of this discrepancy to be an incorrect use of the time-dependent factor. Additionally, we have deduced the emission probability of the 504-keV γ ray from the decay of Y g 85 (2.68 h) relative to that of the 232-keV γ ray from the Sr m 85 (1.127 h) decay in transient equilibrium. The isotope was produced via the Sr 86 ( p , 2 n ) Y g 85 reaction by bombarding SrCO 3 86 with a proton beam at the same facility. Overall, the study confirms the assumption of the time-dependent correction for recommending the emission probability of the 504-keV γ ray in the literature. Our work highlights the importance of explicit description by authors of any time-dependent correction they have made when reporting γ -ray intensities for nuclides in transient equilibrium. The need and significance of accurate and precise decay data of Ce g 137 and Y g 85 in basic science and medicine is briefly outlined.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Regulation of Absorption and Emission in a Protein/Fluorophore Complex

Human cellular retinol binding protein II (hCRBPII) was used as a protein engineering platform to rationally regulate absorptive and emissive properties of a covalently bound fluorogenic dye. We demonstrate the binding of a thio-dapoxyl analog via formation of a protonated imine between an active site lysine residue and the chromophore’s aldehyde. Rational manipulation of the electrostatics of the binding pocket results in a 204 nm shift in absorption and a 131 nm shift in emission. The protein is readily expressed in mammalian systems and binds with exogenously delivered fluorophore as demonstrated by live-cell imaging experiments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Fast Muon Capture Monitoring in Mu2e with the CAPHRI Detector

The Mu2e experiment at Fermilab will search for the charged lepton flavor violating (CLFV) process of a neutrinoless muon-to-electron conversion in the field of an aluminum nucleus. Reaching the experiment’s target sensitivity requires precise normalization of the physics signal through accurate monitoring of the muon capture rate on the stopping target. For this purpose, the Calorimeter Precise High-Resolution Intensity detector (CAPHRI) has been developed. The detector is composed of four LYSO crystals installed in the upstream disk of the Mu2e calorimeter and read out with the standard calorimeter readout. CAPHRI measures the muon capture rate by detecting the characteristic 1.8~MeV gamma emission line of the $^{27}Al(\mu^−, \nu n \gamma) ^{26}Mg$ nuclear reaction. The fast, precise response enables injection-by-injection monitoring of proton beam intensity fluctuations. We report on the commissioning and performance characterization of CAPHRI. The response of each channel is calibrated at two SiPM overvoltages using both the intrinsic self-emission of the LYSO crystals and cosmic ray signals. In parallel, Monte Carlo simulations are used to evaluate the detector acceptance and the expected signal-to-background ratio under realistic running conditions. Preliminary results show a crystal light yield consistent with expectations and a channel inter-calibration at the 2--4% level. Simulation studies indicate that the detector acceptance and background rejection satisfy the requirements for physics operations, with about 1000 detected events per beam injection at a beam power of 1.5~kW. These results demonstrate that CAPHRI is an effective tool for beam monitoring and signal normalization in Mu2e.

Ciccarella, V. [Frascati; U. Rome La Sapienza (mai↗
DOE OSTI2022

Roll to Roll (R2R) Manufacturing of Electrolysis Electrodes for Low Cost Hydrogen Production: Cooperative Research and Development Final Report, CRADA Number CRD-18-00780

NREL, Argonne National Laboratory (ANL) and Oak Ridge National Laboratory (ORNL), which are also referred to collectively herein as the "Contractors" will perform electrode ink development and characterization, focusing on 1) inks with appropriate properties for R2R (gravure and slot-die) coating onto PFSA membrane and 2) catalysts suitable for electrolysis. Participant will develop acceptance criteria and characterization methods for direct coating on the membrane. The purpose of this project is to show feasibility for cost reduction of the electrode through increased throughput and improved material utilization. Successful completion of this project will result in more affordable hydrogen production via proton exchange membrane (PEM) electrolysis by substantially reducing the anode precious metal content and catalyst-coated membrane processing costs. Assists laboratory in achieving programmatic scope, adds new capability to the laboratory's core competencies. This project uses and enhances the laboratory's core competencies, and enhances U.S. competitiveness by utilizing DOE developed intellectual property and/or capabilities. This project will benefit the Fuel Cell subprogram within the EERE Fuel Cell Technologies Office (FCTO) by actively developing materials, formulations, components, and processes for PEM electrolyzer stacks for overcoming critical technical barriers to widespread hydrogen production for zero-emission transportation applications. Through this JWS, NREL, ANL and ORNL are assisting a key domestic industry partner, Proton Energy Systems, Inc., in the area of low-cost electrolyzer electrode formulation and coating technology. After completion of this project, NREL, ANL and ORNL will be able to verify whether the direct deposit coating processes investigated are suitable for producing CCMs for PEM electrolyzers, which is of great interest and benefit to the DOE EERE Fuel Cell Technologies Office (FCTO) and H2@Scale missions.

08 HYDROGEN↗
DOE OSTI2021

High performance protonic ceramic fuel cell systems for distributed power generation

The technology landscape around distributed generation continues to evolve in response to increasing demand for high-efficiency, low-emission, low-cost power generation. While emerging distributed power technologies, such as solid oxide fuel cells (SOFCs), continue to advance, they still face challenges due to their high capital costs, and shorter lifetimes that typically arise from electrochemical stack performance degradation at high operating temperatures (>750 °C). Recent advancements in protonic ceramic fuel cells (PCFCs) offer the potential to mitigate drawbacks of their higher temperature SOFC counterparts by enabling lower operating temperatures (550 °C–600 °C) with acceptable power densities. Here the present work leverages the recent progress in protonic ceramic cell and stack technology development to generate viable system configurations and evaluate the energetic performance potential of PCFC-based systems for stationary power generation. Process system engineering of two water-neutral system concepts, which provide 25 kW of electric power and process hot water, are presented and evaluated through sensitivity studies. Stack design parameters are altered and used to gauge the effect on system performance characteristics, including fuel cell stack and balance-of-plant sizing requirements, and electric and cogeneration efficiencies. The study finds that the potentially high per-pass fuel utilization capability of PCFC stacks could enable unprecedented electric efficiencies approaching 70% without hybridization with other prime movers.

25 ENERGY STORAGE↗
DOE OSTI2026

VERITAS Observations Contemporaneous with the LHAASO Detection of NGC 4278

Significant gamma-ray emission between 1 TeV and 20 TeV from a point source, 1LHAASO J1219+2915, consistent with the location of the LINER/LLAGN galaxy NGC 4278 was recently reported by the Large High Altitude Air Shower Observatory (LHAASO) collaboration. These data were later split into active and quasi-quiet states, with most of the LHAASO significance coming from the active state (MJD 59449-59589). Subsequent analysis of Fermi-LAT and Swift-XRT observations have been used to explore the double-peaked broadband emission. Models of the spectral energy distribution (SED) are currently unconstrained due to the lack of contemporaneous multiwavelength data at either peak. Here, we report serendipitous observations of NGC 4278 with the Very Energetic Radiation Imaging Telescope Array System (VERITAS), made possible by the contemporaneous observations of the nearby blazars 1ES 1218+304, 1ES 1215+303, and W Comae, each of which are located within 2° of NGC 4278. VERITAS did not detect any gamma-ray emission, and a flux upper limit was calculated. The flux upper limits constrain the photon spectrum of the quasi-quiet period, and together with Fermi-LAT, indicate a peak in the SED between 100 GeV and 2 TeV. We present an interpretation of the broadband SED that is based on acceleration of protons in the corona of the active galactic nuclei, followed by p–γ interactions and optically thin γ-ray emission. Within this framework, the implied neutrino signal is slightly below the current sensitivity of IceCube.

Archer, A. [DePauw University, Greencastle, IN (Un↗
DOE OSTI2026

Cost Analysis of Heavy-Duty Vehicle Proton Exchange Membrane Fuel Cell Stationary Power Plants

Heavy-duty PEM fuel cells could be a low-cost, low emission alternative to combustion turbines for re-electrifying hydrogen if used as part of a long duration grid energy storage systems. Many studies expect heavy duty PEM fuel cell production costs to reduce as manufacturing volumes ramp up and their expected durability of 25,000-30,000 hours aligns well with a 30-year life for hydrogen seasonal energy storage plants that would likely operate less than 10% of the year. The labor, material, and equipment costs associated with installing PEM fuel cells and their required balance of plant for stationary applications have not been thoroughly explored, however. This study performs a detailed design and cost analysis of a 100 MW stationary PEM fuel cell power plant, capturing costs such as cooling, power electronics, pipes, valves, fittings, cabling, conduit, concrete foundations, buildings, and land. It employs methods consistent with NLR's solar PV benchmarking cost analysis and annual technology baseline to derive the total installed costs of stationary PEM fuel cell plants that utilize heavy duty PEM fuel cells.

08 HYDROGEN↗
DOE OSTI2020

Validation of neutron emission and neutron energy spectrum calculations on a Mega Ampere Spherical Tokamak with directional relativistic spectrum simulator

The recently developed directional relativistic spectrum simulator (DRESS) code has been validated for the first time against numerical calculations and experimental measurements performed on the Mega Ampere Spherical Tokamak . In this validation, the neutron emissivities and rates computed by DRESS are benchmarked against TRANSP/NUBEAM predictions while the neutron energy spectra provided by DRESS taking as input TRANSP/NUBEAM and ASCOT/BBNBI in Gyro-Orbit mode fast ion distributions are validated against proton pulse height spectra measured by the neutron flux monitor. Finally, excellent agreement was found between DRESS and TRANSP/NUBEAM predictions of local and total neutron emission.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Nanostructured carbon as highly efficient and stable anodes for ethylene production and power generation in protonic ceramic electrochemical cells

Protonic ceramic electrochemical cells (PCECs) have the potential in reducing the energy input and carbon emissions in ethylene production from ethane dehydrogenation. The performance of conventional perovskite-based anode materials for ethane conversion in PCECs is limited by their low active surface area and proneness to coke deposition. In this work, for the first time, we demonstrate the use of aligned carbon nanotube forests (CNTFs) as a novel anode material for an ethane fueled PCEC to co-produce ethylene and electricity. The CNTF electrode was grown on the electrolyte by the chemical vapor deposition (CVD) method. Highly dispersed iron carbide nanoparticles are formed in situ on the CNTFs during the CVD process, acting as highly active catalysts for ethane dehydrogenation. The novel PCECs show superior catalytic and electrochemical performances to that using conventional perovskite-based anodes. The cell also exhibits excellent durability and anti-coking abilities within 100 h test. This work showcases the promising application of nanostructured carbon, a new class of non-perovskite materials, as the multifunctional electrode materials for PCECs.

03 NATURAL GAS↗
DOE OSTI2022

Radiation and Polarization Signatures from Magnetic Reconnection in Relativistic Jets. II. Connection with γ-Rays

Abstract It is commonly believed that blazar jets are relativistic magnetized plasma outflows from supermassive black holes. One key question is how the jets dissipate magnetic energy to accelerate particles and drive powerful multiwavelength flares. Relativistic magnetic reconnection has been proposed as the primary plasma physical process in the blazar emission region. Recent numerical simulations have shown strong acceleration of nonthermal particles that may lead to multiwavelength flares. Nevertheless, previous works have not directly evaluated γ -ray signatures from first-principles simulations. In this paper, we employ combined particle-in-cell and polarized radiation transfer simulations to study multiwavelength radiation and optical polarization signatures under the leptonic scenario from relativistic magnetic reconnection. We find harder-when-brighter trends in optical and Fermi-LAT γ -ray bands as well as closely correlated optical and γ -ray flares. The swings in optical polarization angle are also accompanied by γ -ray flares with trivial time delays. Intriguingly, we find highly variable synchrotron self-Compton signatures due to inhomogeneous particle distributions during plasmoid mergers. This feature may result in fast γ -ray flares or orphan γ -ray flares under the leptonic scenario, complementary to the frequently considered minijet scenario. It may also imply neutrino emission with low secondary synchrotron flux under the hadronic scenario, if plasmoid mergers can accelerate protons to very high energy.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Triple Emission of 5'-( para -R-Phenylene)vinylene-2-(2'-hydroxyphenyl)benzoxazole (PVHBO). Part II: Emission from Anions

This paper is the second part of a study on the effects of a substituted 5'-phenylenevinylene (PV) functionality on the emission properties of 2-(2'-hydroxyphenyl)benzoxazole (HBO)-a dye that is known for excited-state intramolecular proton transfer. The topical compounds are referred to as PVHBOs, each of which is a structural fusion of HBO and a 4-hydroxy-4'-R-stilbene fluorophore that occurs at the hydroxyphenyl moiety. Therefore, the resulting fusion fluorophore manifests the properties of one component or the other, as governed by its interactions with the environment. In part I (the preceding paper), PVHBOs are divided into two groups depending on whether the R substituent is electron-donating/neutral (group I) or electron-withdrawing (group II). The difference in absorption and emission properties between groups I and II is explained based on observations from spectroscopic experiments (both steady-state and time-resolved) and quantum chemical calculations. In the current paper, the same set of tools is applied to characterize the photophysical properties of the conjugate bases-that is, the anions-of PVHBOs. The emission energy of the anion of any group I compound, where the R substituent is either electron-donating or neutral, is situated between those of the neutral enol and keto forms. The emission of the anion of any given group II compound, on the other hand, has a lower energy than both the enol and keto emissions. In this work, the frontier molecular orbitals (i.e., HOMO, LUMO, and LUMO + 1) of a PVHBO localized on either HBO or stilbenoid are impacted by the substituent R and the solvent/additive differently, which leads to the differences in the optical properties of group I and II PVHBOs in both neutral and anion forms.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

EPCAPE-PT-LANL Measurements: Proton Transfer Reaction Mass Spectrometer

Coastal cities offer a unique environment for studying aerosol-cloud interactions and the effects of urban emissions on cloud properties. As part of the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE), the Partitioning Thrust by Los Alamos National Laboratory (EPCAPE-PT-LANL) was conducted. Our campaign focused on measuring the optical and chemical properties of aerosols and their interactions within marine stratocumulus clouds in La Jolla, California. EPCAPE-PT-LANL enhances the primary goals of EPCAPE through innovative observations of vapor-phase transitions between aerosols and cloud droplets, the impact of black carbon on aerosol-cloud dynamics, and the effects of cloud processing on aerosol optical properties. Instrument: IONICON High-Resolution PTR-TOF-MS - Trace VOC Analyzer. Concentrations were calculated based on theoretical reaction rates of each species with H3O+. Details of the calculation are found in the PTR-MS Ionicon Manual. Data Notes: It is a high-resolution PTR-TOF-MS we have sub-selected relevant species. Contact us if you want additional data products from this instrument. Header: - CalculatedAcetonitrile[ppbv]: The concentration of acetonitrile expressed in parts per billion by volume (ppbv). - CalculatedAcetaldehyde[ppbv]: The concentration of acetaldehyde expressed in parts per billion by volume (ppbv). - CalculatedAcetone[ppbv]: The concentration of acetone expressed in parts per billion by volume (ppbv). - CalculatedAceticAcid[ppbv]: The concentration of acetic acid expressed in parts per billion by volume (ppbv). - CalculatedIsoprene[ppbv]: The concentration of isoprene expressed in parts per billion by volume (ppbv). - CalculatedMVK[ppbv]: The concentration of methyl vinyl ketone (MVK) and methacrolein (MACR) expressed in parts per billion by volume (ppbv). - CalculatedMEK[ppbv]: The concentration of methyl ethyl ketone (MEK) expressed in parts per billion by volume (ppbv). - CalculatedBenzene[ppbv]: The concentration of benzene expressed in parts per billion by volume (ppbv). - CalculatedToluene[ppbv]: The concentration of toluene expressed in parts per billion by volume (ppbv).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Coupling of high-resolution mass spectrometer and photosynthesis system for comprehensive leaf volatile metabolite profiling

Background Leaf-level biogenic volatile organic compounds (BVOCs) emissions represent a major source of organic gases in the atmosphere, influencing both climate and air quality. These emissions are strongly driven by environmental perturbations, which affect individual plant- to ecosystem-level processes. Uncovering all the BVOCs and understanding how their emissions respond to altered environmental conditions provide critical insights into vegetation-driven changes in atmospheric chemistry. We developed a tandem instrumentation setup that integrates a proton transfer reaction time-of-flight mass spectrometer (PTR-ToF-MS) with parts-per-trillion detection limits and a photosynthetic infrared gas exchange system for the untargeted survey of all the BVOCs. This novel system enables simultaneous, real-time monitoring of BVOC emissions and photosynthetic parameters at the leaf level, offering new opportunities to disentangle the physiological and environmental drivers of VOC release. Furthermore, we established the VOC Analysis and Processing Optimization Resource (VAPOR), an open-access software tool designed for rapid data post-processing and the analysis of the variability of hundreds of BVOCs. We assessed the performance of the tandem system under varying background conditions, using standard gas mixtures and a range of environmental factors. Results Blank emissions were substantially lower for major BVOCs (e.g., isoprene) compared to those observed in plant emissions. Despite this, the observation of background-level VOCs highlights the importance of routinely acquiring and accounting for blank measurements in analyses using the coupled instrumentation. Introduction of known VOC concentrations to the system demonstrated a linear response across different compounds with varying molecular compositions, indicating minimal gas loss regardless of chemical moieties within the coupled instrumentation. We applied the optimized system to investigate the physiological mechanisms driving BVOC emissions across different genotypes of poplar and pennycress. The high mass resolution capabilities of the PTR-ToF-MS, coupled with comprehensive VAPOR-driven data analysis, enabled the identification of several important BVOCs, including methanol and methanethiol; these BVOCs displayed substantial variation across pennycress genotypes and showed concentrations ~ 100–350% higher than the blank. Moreover, isoprene emissions varied significantly among poplar genotypes grown in different potting media. Conclusions Tandem instrumentation offers a powerful tool for profiling volatile molecular markers and elucidating their genetic and environmental underpinnings. This approach enhances our ability to predict BVOC emissions in response to genotype by environmental interactions and contributes to a deeper understanding of vegetation responses to environmental changes.

Biogenic volatile organic compounds↗