Measurement of extremely low fluid permeabilities of rocks significant to studies of the origin of life Final report
Permeater for measuring low fluid permeabilities of rocks used to study origin of life
Marsden, S. S., Jr.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The sizes of polymer molecules and the GPC separation
Gel permeation chromatography for polymer molecules size /hydrodynamic volume/ separation
Altgelt, K. H.↗
PH-conditional, ammonia assimilation-deficient mutants of Hydrogenomonas eutropha - Evidence for the nature of the mutation
Hydrogenomonas eutropha mutants deficient amination due to ammonia-nitrogen permeation defect
Decicco, B. T.↗
Long-term aging of elastomers: Chemical stress relaxation of fluorosilicone rubber and other studies
Aerospace applications of elastomers are considered, including: propellant binders, bladder materials for liquid propellant expulsion systems, and fuel tank sealants for high-speed aircraft. A comprehensive molecular theory for mechanical properties of these materials has been developed but has only been tested experimentally in cases where chemical degradation processes are excluded. Hence, a study is being conducted to ascertain the nature, extent, and rate of chemical changes that take place in some elastomers of interest. Chemical changes that may take place in the fluorosilicone elastomer, LS 420, which is regarded as a fuel and high-temperature-resistant rubber are investigated. The kinetic analysis of the chemical stress relaxation and gel permeation chromatography studies comprise the major portion of the report.
Kalfayan, S. H.↗
Study of permeability characteristics of membranes
Pressure-permeation experiments were performed with the concentration-clamp cell. Streaming potentials and hydraulic permeabilities were measured for an AMF C-103 cation-exchange membrane bounded by 0.1 N NaCl solutions. The streaming potential calculated from the slope of the recorded potential differences versus the applied pressure, yields a value of 1.895 millivolt/dekabar. When comparison with other membranes of similar characteristics could be made, good agreement was found. The values of the hydraulic permeability varied somewhat with the applied pressure difference and are between 1.3 x 10 to the minus 8th power and 3.9 x 10 to the minus 8th power sq cm/dekabar-sec. The specific hydraulic permeabilities were also calculated and compared with data from the literature. Fair agreement was found. The diffusion coefficient of the chloride ion in the AMF C-103 membrane was calculated, using Fick's first law of diffusion based on ion concentrations calculated from the Donnan equilibrium concentration of Cl(-).
Spiegler, K. S.↗
Life prediction of expulsion bladders through fatigue test and fold strain analysis
Cycle life data are presented in terms of true maximum strain for four metals, two plastics, and two elastomers. The Coffin-Manson fatigue theory was applied for metals and plastics, and cut-growth fatigue theory for elastomers. The data are based on measurements made at room and elevated temperatures. It was found that double folds give rise to far severer folding strains than do simple folds. It was also found that, except for the elastomers, all the bladder materials develop surface cracks due to double folds after only one cycle. The findings indicate that metals, which are bets for premeation resistance, are worst for fatigue resistance, and vice versa for elastomers. The intermediate plastics were found to be unsatisfactory for both permeation and fatigue resistance for missions of extended duration.
Chu, H. N.↗
Mariner 9 propulsion subsystem performance during interplanetary cruise and Mars orbit insertion
On 14 November 1971 the Mariner 9 1334-N-(300-lbf)-thrust rocket engine was fired for just over 15 min to place the first man-made satellite into orbit about Mars. Propulsion subsystem data gathered during the 5-month interplanetary cruise and orbit insertion are of significance to future missions of this type. Specific results related to performance predictability, zero g heat transfer, and nitrogen permeation, diffusion, and solubility values are presented.
Cork, M. J.↗
The release of energetic particles from the sun.
Development of a model to account for the release of solar cosmic rays from the sun. The solar atmosphere out to 3 to 5 solar radii above the photosphere is permeated with magnetic field lines which trap low-rigidity (less than or equal to 50 MV) flare particles. Plasma heated by the flare process disturbs the trapping field, and not until the disturbance reaches 3 to 5 solar radii can the low-rigidity flare particles have access to interplanetary space. If the plasma is not heated sufficiently to overcome the coronal field, flare particles are trapped efficiently. Subsequent leakage of these particles into interplanetary space forms corotating streams. Reference is made to satellite observations of solar electromagnetic radiation and charged particles.
Simnett, G. M.↗
On the stability of obliquely propagating whistlers.
By means of an energy conservation approach, this paper analyzes the growth rates of whistlers with arbitrary frequency and direction of propagation in a cold plasma permeated by a dilute energetic electron population. Numerical results are obtained for whistler frequencies and plasma characteristics prevailing at the onset of artificially stimulated emissions. It is found that the growth rates do not in general maximize for propagation along the static magnetic field, and a criterion for the existence of maximal growth at this direction is derived. An application to artificially stimulated emissions is discussed.
Brinca, A. L.↗
Rubber composition compatible with hydrazine
Formulation improves compatibility of butyl rubbers with hydrazine while reducing permeation to low levels necessary for prolonged storage in space. This is accomplished by replacing carbon-black filler with inert materials such as hydrated silica or clay. Pressure increases suggest that hydrazine is decomposed only slightly by new type of rubber.
Repar, J.↗
Long Term Aging of Elastomers: Chemorheology of Viton B Fluorocarbon Elastomer
The continuation of a study to ascertain the nature, extent, and the rate of chemical changes that take place in certain selected elastomers is reported. Under discussion is Viton B, regarded as a temperature and fuel resistant fluorocarbon rubber. The kinetic analysis of the chemical stress relaxation, and infrared and gel permeation chromatography analysis results are discussed.
Kalfayan, S. H.↗
Preparation and properties of polytetrafluoroethylene impregnated with rhenium oxides
The results of tests carried out to determine the properties of polytetrafluorethylene (PTFE) impregnated with rhenium oxides are presented. The tests included measurement of physical properties of the impregnated material and investigation of the effects of preparation process variables. Based on the latter tests a mechanism to describe the permeation process is postulated which identifies the rate controlling step to be diffusion of ReF6 molecules into the solid during the initial ReF6 soak. Physical property tests indicated that the electronic conductance is increased by many orders of magnitude while the desirable properties of the PTFE remain virtually unchanged.
Leibecki, H. F.↗
Evaluation of an electrochemical N2/H2 gas separator
A program was successfully completed to evaluate an electrochemical nitrogen/hydrogen (N2/H2) separator for use in a spacecraft nitrogen (N2) generator. Based on the technical data obtained a N2/H2 separator subsystem consisting of an organic polymer gas permeator first stage and an electrochemical second and third stage was estimated to have the lowest total spared equivalent weight, 257 kg (566 lb), for a 15 lb/day N2 generation rate. A pre-design analysis of the electrochemical N2/H2 separator revealed that its use as a first stage resulted in too high a power requirement to be competitive with the organic polymer membrane and the palladium-silver membrane separation methods. As a result, program emphasis was placed on evaluating the electrochemical. A parametric test program characterized cell performance and established second- and third-stage electrochemical N2/H2 separator operating conditions. A design verification test was completed on the second and third stages. The second stage was then successfully endurance tested for 200 hours.
Marshall, R. D.↗
Hydrocarbon polymeric binder for advanced solid propellant
A series of DEAB initiated isoprene polymerizations were run in the 5-gallon stirred autoclave reactor. Polymerization run parameters such as initiator concentration and feed rate were correlated with the molecular weight to provide a basis for molecular weight control in future runs. Synthetic methods were developed for the preparation of n-1,3-alkadienes. By these methods, 1,3-nonadiene was polymerized using DEAB initiator to give an ester-telechelic polynonadiene. This was subsequently hydrogenated with copper chromite catalyst to give a hydroxyl terminated saturated liquid hydrocarbon prepolymer having greatly improved viscosity characteristics and a Tg 18 degrees lower than that of the hydrogenated polyisoprenes. The hydroxyl-telechelic saturated polymers prepared by the hydrogenolysis of ester-telechelic polyisoprene were reached with diisocyanates under conditions favoring linear chain extension gel permeation chromatography was used to monitor this condensation polymerization. Fractions having molecular weights above one million were produced.
Potts, J. E.↗
Hydrogen gas embrittlement and the disc pressure test
A disc pressure test has been used to study the influenced of a hydrogen gas environment on the mechanical properties of three high strength superalloys, Inconel 718, L-605 and A-286, in static and dynamic conditions. The influence of the hydrogen pressure, loading rate, temperature, mechanical and thermal fatigue has investigated. The permeation characteristics of Inconel 718 have been determined in collaboration with the French AEC. The results complemented by a fractographic study are consistent either with a stress-sorption or with an internal embrittlement type of mechanism.
Bachelet, E. J.↗
Poly/diphenylsiloxy/arylazines. I - Synthesis and characterization
A detailed description is presented for the synthesis of poly(diphenylsiloxy)arylazines by the melt polymerization of hydroxyarylazines and bis(anilino)diphenylsilane. The resulting polymers have been characterized by elemental analysis, gel-permeation chromatography, vapor-phase osmometry, and UV-VIS-IR optical spectroscopy.
Goldsberry, R. E.↗
Quantum crystals in neutron stars
Using the many-body techniques appropriate for quantum crystals it is shown that the deep interior of a neutron star is most likely an orderly arrangement of neutrons, protons and hyperons forming a solid. It is shown that a liquid or gas arrangement would produce higher energy. If so, a neutron star can be viewed as two solids (crust and core) permeated by a layer of ordinary or (perhaps) superfluid liquid. Astronomical evidence is in favor of such a structure: the sudden jumps in the periods of the Crab and Vela pulsars that differ by a factor of about 100 can be easily explained by the star-quake model. If the Crab is less massive than Vela (i.e., if it is not dense enough to have a solid core), the star-quakes take place in the crust whereas for Vela they occur in the core.
Canuto, V.↗
Polymer-lined filament-wound pressure vessels for nitrogen containment
A program has been started to develop fatigue-resistant polymeric liners for a filament-wound pressure vessel to contain nitrogen gas at room temperature. First, nitrogen permeation of butyl rubber sheet coated with Saran and Parylene C was studied in flat specimens. Then four 10-cm-diam cylindrical pressure vessels were prepared with chlorobutyl rubber liners coated with the same materials. These vessels were valved off after nitrogen gas pressurization to approximately 65% (approximately 11.7 MPa or 1700 psig) of their expected failure pressure. One vessel leaked. The other three vessels showed an average pressure loss of less than 1% per month. These pressure vessels have an average performance factor of approximately 370 kPa-cu m/kg (1,500,000 in.) based on composite mass.
Hamstad, M. A.↗