Sea urchin-like NiCoO2@C nanocomposites for Li-ion batteries and supercapacitors
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Liang, Jin↗
SEARCH · Engineering Papers
Results for “packing density”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Atomistic and molecular effects in electric double layers at high surface charges
Here, the Poisson–Boltzmann theory for electrolytes near a charged surface is known to be invalid due to unaccounted physics associated with high ion concentration regimes. In order to investigate this regime, fluids density functional theory (f-DFT) and molecular dynamics (MD) simulations were used to determine electric surface potential as a function of surface charge. Based on these detailed computations, for electrolytes with nonpolar solvent, the surface potential is shown to depend quadratically on the surface charge in the high charge limit. We demonstrate that modified Poisson–Boltzmann theories can model this limit if they are augmented with atomic packing densities provided by MD. However, when the solvent is a highly polar molecule water an intermediate regime is identified in which a constant capacitance is realized. Simulation results demonstrate the mechanism underlying this regime, and for the salt water system studied here, it persists throughout the range of physically realistic surface charge densities so the potential’s quadratic surface charge dependence is not obtained.
74 ATOMIC AND MOLECULAR PHYSICS↗
Carbon Nanotube – Polysiloxane Nanocomposites for Ablative Thermal Protection Systems
Ultra-high temperature resins (UHTR) such as polysiloxane possess excellent characteristics for ablation including low thermal conductivity, lightweight composition, high thermal resistance, and the ability to form a durable char layer. To enhance its mechanical strength, the aerospace industry utilizes fiber reinforcement, such as carbon fiber reinforced polysiloxane (CF-polysiloxane), due to its high strength-to-weight ratio. Carbon nanotubes (CNTs) have advantages over microfibers including higher specific strength, lower density, and customizable thermal conductivity. Their nano-scale dimensions allow for a more homogenous material compared to traditional microfibers. Conventional methods of incorporating CNTs into resins often have structural defects such as voids, CNT agglomerations, and randomly dispersed CNTs, resulting in marginal improvements in properties. A novel approach known as bulk nanocomposite laminating (BNL) has been introduced involving CNT densification, resin polymer infiltration, and pressurized curing to achieve a high packing density exceeding 35% by volume. Characterization and testing to simulate re-entry conditions is performed with a sample of CNT-polysiloxane nanocomposite cured onto a CF-polysiloxane backing. These samples are subjected to ablation by an oxyacetylene flame while collecting temperature data to evaluate thermal protection properties.
Palak B Patel↗
Effects of Sample Preparation on the Infrared Reflectance Spectra of Powders
While reflectance spectroscopy is a useful tool in identifying molecular compounds, laboratory measurement of solid (particularly powder) samples often is confounded by sample preparation methods. For example, both the packing density and surface roughness can have an effect on the quantitative reflectance spectra of powdered samples. Recent efforts in our group have focused on developing standard methods for measuring reflectance spectra that accounts for sample preparation, as well as other factors such as particle size and provenance. In this work, the effect of preparation method on sample reflectivity was investigated by measuring the directional-hemispherical spectra of samples that were hand-packed as well as pressed into pellets using an integrating sphere attached to a Fourier transform infrared spectrometer. The results show that the methods used to prepare the sample have a substantial effect on the measured reflectance spectra, as do other factors such as particle size.
FTIR↗
Advanced High-Temperature Flexible TPS for Inflatable Aerodynamic Decelerators
Typical entry vehicle aeroshells are limited in size by the launch vehicle shroud. Inflatable aerodynamic decelerators allow larger aeroshell diameters for entry vehicles because they are not constrained to the launch vehicle shroud diameter. During launch, the hypersonic inflatable aerodynamic decelerator (HIAD) is packed in a stowed configuration. Prior to atmospheric entry, the HIAD is deployed to produce a drag device many times larger than the launch shroud diameter. The large surface area of the inflatable aeroshell provides deceleration of high-mass entry vehicles at relatively low ballistic coefficients. Even for these low ballistic coefficients there is still appreciable heating, requiring the HIAD to employ a thermal protection system (TPS). This TPS must be capable of surviving the heat pulse, and the rigors of fabrication handling, high density packing, deployment, and aerodynamic loading. This paper provides a comprehensive overview of flexible TPS tests and results, conducted over the last three years. This paper also includes an overview of each test facility, the general approach for testing flexible TPS, the thermal analysis methodology and results, and a comparison with 8-foot High Temperature Tunnel, Laser-Hardened Materials Evaluation Laboratory, and Panel Test Facility test data. Results are presented for a baseline TPS layup that can withstand a 20 W/cm2 heat flux, silicon carbide (SiC) based TPS layup, and polyimide insulator TPS layup. Recent work has focused on developing material layups expected to survive heat flux loads up to 50 W/cm2 (which is adequate for many potential applications), future work will consider concepts capable of withstanding more than 100 W/cm2 incident radiant heat flux. This paper provides an overview of the experimental setup, material layup configurations, facility conditions, and planned future flexible TPS activities.
DelCorso, Joseph A.↗
Effects of Rolling Reduction on Critical Current Density and Microstructure of Bi-2212 Wires
Bi-2212 Rutherford cables have been fabricated into flat racetrack coils and canted-cosine-theta dipole magnets. The performance gap between the magnets made with Rutherford cables and the “short-sample-limit” is about 30%. To better understand the influence of Rutherford cable processing on the strand performance, we studied three Bi-2212 wires with filament architectures of 37 × 18 and 55 × 18 and diameters of 0.8 and 1.0 mm. To simulate the deformation caused by cabling process, the three wires were rolled with thickness reductions ranging from 10% to 30%. The aspect ratios of rolled strands are between 1.29 and 2.05. The low aspect-ratio wire is also an interesting form for fabricating solenoid coils with higher packing density. The round and rolled strands were heat-treated under 50 bar and with maximum heat treatment temperatures of 885.5 °C and 890.5 °C. The rolling deformation reduced filament size uniformity, resulting in filament merging in fully heat-treated wires. It was found that rolling reduction reduced wire critical current density (JE) by 16 to 18%, but the JE decrease saturated at 15 to 20% of the thickness reduction. It is believed that the reduced JE results from the filament merging caused by rolling and non-uniform shrinking during overpressure heat treatment.
Bi-2212 wire↗
Thin filament diversity and physiological properties of fast and slow fiber types in astronaut leg muscles
Slow type I fibers in soleus and fast white (IIa/IIx, IIx), fast red (IIa), and slow red (I) fibers in gastrocnemius were examined electron microscopically and physiologically from pre- and postflight biopsies of four astronauts from the 17-day, Life and Microgravity Sciences Spacelab Shuttle Transport System-78 mission. At 2.5-microm sarcomere length, thick filament density is approximately 1,012 filaments/microm(2) in all fiber types and unchanged by spaceflight. In preflight aldehyde-fixed biopsies, gastrocnemius fibers possess higher percentages (approximately 23%) of short thin filaments than soleus (9%). In type I fibers, spaceflight increases short, thin filament content from 9 to 24% in soleus and from 26 to 31% in gastrocnemius. Thick and thin filament spacing is wider at short sarcomere lengths. The Z-band lattice is also expanded, except for soleus type I fibers with presumably stiffer Z bands. Thin filament packing density correlates directly with specific tension for gastrocnemius fibers but not soleus. Thin filament density is inversely related to shortening velocity in all fibers. Thin filament structural variation contributes to the functional diversity of normal and spaceflight-unloaded muscles.
Non-NASA Center↗
Demonstration of a Pilot-Scale Plant for Biomass Torrefaction and Briquetting
Abstract. A semi-mobile torrefaction and densification pilot plant was constructed in order to determine ideal operating conditions and evaluate briquette quality and throughput rate using forest residuals as the input feedstock. Experiments were conducted at various conditions with feedstock moisture content ranging from 4% to 25% (wet basis), reactor residence times of 10 and 20 min, and final product temperatures between 214°C and 324°C. Optimal operating conditions, evaluated based on throughput rate, specific electricity demand, torrefied briquette grindability, briquette volumetric energy density, and briquette durability, were identified to occur with a short residence time (10 min), low feedstock moisture content (<11% wet basis), and high final product temperature between 267°C and 275°C. These conditions were able to process 510 to 680 kg h -1 (wet basis) feedstock with a dry mass yield of 79% to 84% to produce torrefied biomass with a higher heating value of 21.2 to 23.0 MJ kg -1 (dry basis) compared to 19.6 MJ kg -1 for the original biomass. Torrefied briquettes produced at these conditions had a neatly stacked packing density of 990 kg m -3 and a volumetric energy density of 21,800 MJ m -3 . Their specific grinding energy was an average 37% of the energy required to grind a raw biomass briquette. These torrefied briquettes were more durable (94% DU) than raw briquettes (85% DU) directly following production, but were less durable after undergoing temperature and humidity fluctuations associated with long distance transportation (74% DU for torrefied and 84% DU for raw biomass briquettes). Results from this pilot plant are promising for commercial scale production of high quality torrefied briquettes and should lead to additional research and development of a torrefaction system optimized for a higher throughput rate at these conditions. Keywords: Biomass, Biomass conversion technology, Bioenergy, Briquetting, Densification, Forest residuals, Pyrolysis, Torrefaction.
Agriculture↗
Spacelab high density digital recorders
The design and performance of the high-density digital recorder (HDDR) developed for use at the NASA centers (KSC, JSC, and GSFC) and at the JPL to store and retrieve 50-Mb/s PCM data streams from the Spacelab experiments are reported. The recording reproduction, and transport requirements are reviewed; and the design solutions adopted in the final version of the HDDR are described, incuding three-position-modulation and Y-phase encoding, microprocessor-controlled automatic bit synchronization and equalization, cyclic-redundancy-check error detection and correction, clock regeneration, data and clock variations, tape-speed control, and EEE-488 remote control. Reliable performance, with bit error rates 1 in 10 to the 10th forward and 1 in 10 to the 9th reverse or better and packing density up to 50 percent greater than that obtainable using conventional codes, is reported after 1.5 years of service.
Blais, R. A.↗
Hollow Fibers Structured Packings in Olefin/Paraffin Distillation: Apparatus Scale-Up and Long-Term Stability
Following the conceptual demonstration of high separation efficiency and column capacity obtained in olefin/paraffin distillation using hollow fiber structured packings (HFSPs) in a bench scale (J. Membr. Sci.2006, 2007, and 2010), we scaled-up this process with a 10-fold increase in the internal flow rate and a 3-fold increase in the module length. We confirmed that the HFSPs technology gives high separation efficiency and column capacity in iso-/n-butane distillation for 18 months. We systematically investigated the effects of packing density, concentration of light component, reflux ratio, and module age on the separation efficiency and operating stability. The comprehensive characterizations using scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA) were carried out to probe the changes in the morphological, thermal, and mechanical properties of polypropylene (PP) hollow fibers over the aging process. Our results suggest that after a long-term exposure to light hydrocarbon environments at ≤70 °C the morphological and mechanical properties of the PP polymer do not degrade significantly in a propane/propylene and iso-/n-butane environment.
36 MATERIALS SCIENCE↗
Modeling and Simulation of Porosity in Spray Deposition
Numerical models, consisting of interstitial porosity model and gas porosity model, have been developed to predict the porosity in the spray deposition process. The interstitial porosity model is based on the assumption of liquid feeding in the porous mushy layer of the deposit. The porosity fraction is related to the particle packing density and the amount of the feeding flow during solidification. The gas porosity model is based on the diffusion kinetics of gas pore formation. A numerical simulation of spray deposition for a billet was carried out by coupling the porosity model with the shape and heat-transfer models. The volume fraction and distribution of the porosity were investigated. As a result of the experimental verification, the simulation results showed good agreement with the experimental data. As applications, the models were used to investigate the influence of spray process parameters on porosity formation. The investigation demonstrated that the porosity is substantially influenced by the temperature of the impinging layer and the preheating of the substrate.
36 MATERIALS SCIENCE↗
An assessment of the effect on Olkiluoto repository capacity achievable with advanced fuel cycles
Previously a few scenarios have been simulated for transition from thermal to fast reactor fleet in Finland in order to determine how much the transuranic inventory could be reduced with the partitioning and transmutation (P-T) technologies. Those calculations, performed with COSI6 code developed by CEA, are extended in the present study, in which the effect of P-T on the capacity of the planned final disposal repository at Olkiluoto (Finland) is evaluated by taking into account the created fission products and transuranic residuals from the reprocessing operations. The decay heat is assumed to be the most restrictive factor in defining the waste disposal packing density. The repository capacity evaluation of this study is based on the comparison of the decay heats produced by the deposited waste in various scenarios. The reference scenario of this article involves only Light Water Reactors (LWR) in an open fuel cycle. The capacity requirement of the geological repository is estimated in a few closed fuel cycle scenarios, all including actinide transmutation with Fast Reactors (FR). The comparison between the P-T scenarios and reference is based on the decay heat production of the deposited waste. The COSI6 code is used for simulations to provide the repository decay heat curves. Applying the closed fuel cycle would change the disposal concept and schedule, because of which it is not quite straightforward to assess the impact of P-T on the capacity. However, it can be concluded that recycling the transuranic nuclides probably decreases the required volume for the disposal, but thermal dimensioning analysis is needed for more specific conclusions.
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
Stiff and Transparent Multilayer Thin Films Prepared Through Hydrogen-Bonding Layer-by-Layer Assembly of Graphene and Polymer [Super Stiff and Highly Transparent Multilayer Thin Films Prepared through Hydrogen-Bonding Layer-by-Layer Assembly of Graphene and Polymer]
Due to their exceptional orientation of 2D nanofillers, layer–by–layer (LbL) assembled polymer/graphene oxide thin films exhibit unmatched mechanical performance relative to any conventionally produced counterparts with similar composition. Unprecedented mechanical property improvement, by replacing graphene oxide with pristine graphene, is demonstrated in this work. Polyvinylpyrrolidone–stabilized graphene platelets are alternately deposited with poly(acrylic acid) using hydrogen bonding assisted LbL assembly. Transmission electron microscopy imaging and the Halpin–Tsai model are used to demonstrate, for the first time, that intact graphene can be processed from water to generate polymer nanocomposite thin films with simultaneous parallel–alignment, high packing density, and exfoliation. A multilayer thin film with only 3.9 vol% of highly exfoliated, and structurally intact graphene, increases the elastic modulus (E) of a polymer multilayer thin film by 322% (from 1.41 to 4.81 GPa), while maintaining visible light transmittance of ≈90%. This is one of the greatest improvements in elastic modulus ever reported for a graphene–filled polymer nanocomposite with a glassy (E > 1 GPa) matrix. In conclusion, the technique described here provides a powerful new tool to improve nanocomposite properties (mechanical, gas transport, etc.) that can be universally applied to a variety of polymer matrices and 2D nanoplatelets.
36 MATERIALS SCIENCE↗
Deep-Learning-Enabled Crack Detection and Analysis in Commercial Lithium-Ion Battery Cathodes
We report in Li-ion batteries, the mechanical degradation initiated by micro cracks is one of the bottlenecks for enhancing the performance. Quantifying the crack formation and evolution in complex composite electrodes can provide important insights into electrochemical behaviors under prolonged and/or aggressive cycling. However, observation and interpretation of the complicated crack patterns in battery electrodes through imaging experiments are often time-consuming, labor intensive, and subjective. Herein, a deep learning-based approach is developed to extract the crack patterns from nanoscale hard X-ray holo-tomography data of a commercial 18650-type battery cathode. Efficient and effective quantification of the damage heterogeneity with automation and statistical significance is demonstrated. The crack characteristics are further associated with the active particles’ packing densities and a potentially viable architectural design is discussed for suppressing the structural degradation in an industry-relevant battery configuration.
25 ENERGY STORAGE↗
Quantitative Principles for Precise Engineering of Sensitivity in Graphene Electrochemical Sensors
Abstract A major difficulty in implementing carbon‐based electrode arrays with high device‐packing density is to ensure homogeneous and high sensitivities across the array. Overcoming this obstacle requires quantitative microscopic models that can accurately predict electrode sensitivity from its material structure. Such models are currently lacking. Here, it is shown that the sensitivity of graphene electrodes to dopamine and serotonin neurochemicals in fast‐scan cyclic voltammetry measurements is strongly linked to point defects, whereas it is unaffected by line defects. Using the physics of point defects in graphene, a microscopic model is introduced that explains how point defects determine sensitivity. The predictions of this model match the empirical observation that sensitivity linearly increases with the density of point defects. This model is used to guide the nanoengineering of graphene structures for optimum sensitivity. This approach achieves reproducible fabrication of miniaturized sensors with extraordinarily higher sensitivity than conventional materials. These results lay the foundation for new integrated electrochemical sensor arrays based on nanoengineered graphene.
Wu, Ting↗
Low Thermal Conductivity and Diffusivity at High Temperatures Using Stable High–Entropy Spinel Oxide Nanoparticles
The realization of low thermal conductivity at high temperatures (0.11 W m –1 K –1 800 °C) in ambient air in a porous solid thermal insulation material, using stable packed nanoparticles of high-entropy spinel oxide with 8 cations (HESO-8 NPs) with a relatively high packing density of ≈50%, is reported. The high-density HESO-8 NP pellets possess around 1000-fold lower thermal diffusivity than that of air, resulting in much slower heat propagation when subjected to a transient heat flux. The low thermal conductivity and diffusivity are realized by suppressing all three modes of heat transfer, namely solid conduction, gas conduction, and thermal radiation, via stable nanoconstriction and infrared-absorbing nature of the HESO-8 NPs, which are enabled by remarkable microstructural stability against coarsening at high temperatures due to the high entropy. Furthermore, this work can elucidate the design of the next-generation high-temperature thermal insulation materials using high-entropy ceramic nanostructures.
thermal insulation↗
Anisotropic Optical and Frictional Properties of Langmuir–Blodgett Film Consisting of Uniaxially-Aligned Rod-Shaped Cellulose Nanocrystals
Langmuir–Blodgett (LB) film deposition gives an opportunity to control the packing density and orientation of anisotropic nanoparticles at a monolayer level, allowing accurate characterization of their anisotropic material properties. Additionally, the uniaxial deposition of rod-shaped cellulose nanocrystals (CNCs) over a macroscopically large area is achieved by aligning the long axis of CNCs on the LB trough with the direction of the maximum drag force within the meniscus during the vertical pulling of the substrate from the LB trough. On the uniaxially-aligned LB films, anisotropic linear and non-linear optical properties of CNCs are obtained using Mueller matrix spectroscopy and sum frequency generation spectroscopy, respectively, and explained with time-dependent density functional theory calculations. Also, the frictional anisotropy of the LB film is measured using atomic force microscopy and explained theoretically. The findings of this study will be valuable for preparation of anisotropic nanoparticle thin films with uniform arrangements and utilization of their anisotropic material properties.
36 MATERIALS SCIENCE↗