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At least 145 records · Page 8

Melt State Reinforcement of Polyisoprene by Silica Nanoparticles Grafted with Polyisoprene

Here, we systematically vary the nanoparticle (NP) dispersion state in composites formed by mixing polyisoprene homopolymers with polyisoprene grafted silica particles, and demonstrate how creep measurements allow us to overcome the limitations of small amplitude oscillatory shear (SAOS) experiments. This allows us to access nearly 13 orders in time in the mechanical response of the resulting composites. We find that a specific NP morphology, a percolating particle network achieved at intermediate graft densities, significantly reinforces the system and has a lower NP percolation loading threshold relative to other morphologies. These important effects of morphology only become apparent when we combine creep measurements with SAOS re-emphasizing the role of synergistically combining methods to access the mechanical properties of polymer nanocomposites over broad frequency ranges.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Sonic levitation apparatus

A sonic levitation apparatus is disclosed which includes a sonic transducer which generates acoustical energy responsive to the level of an electrical amplifier. A duct communicates with an acoustical chamber to deliver an oscillatory motion of air to a plenum section which contains a collimated hole structure having a plurality of parallel orifices. The collimated hole structure converts the motion of the air to a pulsed. Unidirectional stream providing enough force to levitate a material specimen. Particular application to the production of microballoons in low gravity environment is discussed.

Dunn, S. A.↗

Finite element or Galerkin type semidiscrete schemes

A finite element of Galerkin type semidiscrete method is proposed for numerical solution of a linear hyperbolic partial differential equation. The question of stability is reduced to the stability of a system of ordinary differential equations for which Dahlquist theory applied. Results of separating the part of numerical solution which causes the spurious oscillation near shock-like response of semidiscrete scheme to a step function initial condition are presented. In general all methods produce such oscillatory overshoots on either side of shocks. This overshoot pathology, which displays a behavior similar to Gibb's phenomena of Fourier series, is explained on the basis of dispersion of separated Fourier components which relies on linearized theory to be satisfactory. Expository results represented.

Durgun, K.↗

Use of Microgravity to Control the Microstructure of Eutectics

This grant began in June of 1996. Its long term goal is to be able to control the microstructure of directionally solidified eutectic alloys, through an improved understanding of the influence of convection. The primary objective of the projects in the present grant is to test hypotheses for the reported influence of microgravity on the microstructure of eutectics. The prior experimental results on the influence of microgravity on the microstructure of eutectics have been contradictory. With lamellar eutectics, microgravity had a negligible effect on the microstructure. Microgravity experiments with fibrous eutectics sometimes showed a finer microstructure and sometimes a coarser microstructure. Most research has been done on the MnBi/Bi rod-like eutectic. Larson and Pirich obtained a two-fold finer microstructure both from microgravity and by use of a magnetic field to quench buoyancy-driven convection. Smith, on the other hand, observed no change in microgravity. Prior theoretical work at Clarkson University showed that buoyancy-driven convection in the vertical Bridgman configuration is not vigorous enough to alter the concentration field in front of a growing eutectic sufficiently to cause a measurable change in microstructure. We assumed that the bulk melt was at the eutectic composition and that freezing occurred at the extremum, i.e. with minimum total undercooling at the freezing interface. There have been four hypotheses attempting to explain the observed changes in microstructure of fibrous eutectics caused by convection: I .A fluctuating freezing rate, combined with unequal kinetics for fiber termination and branching. 2. Off-eutectic composition, either in the bulk melt due to an off-eutectic feed or at the freezing interface because of departure from the extremum condition. 3. Presence of a strong habit modifying impurity whose concentration at the freezing interface would be altered by convection. At the beginning of the present grant, we favored the first of these hypotheses and set out to test it both experimentally and theoretically. We planned the following approaches: I .Pass electric current pulses through the MnBi/Bi eutectic during directional solidification in order to produce an oscillatory freezing rate. 2. Directionally solidify the MnBi/Bi eutectic on Mir using the QUELD II gradient freeze furnace developed by Professor Smith at Queen's University. 3. Select another fibrous eutectic system for investigation using the Accelerated Crucible Rotation Technique to introduce convection. 4. Develop theoretical models for eutectic solidification with an oscillatory freezing rate. Because of the problems with Mir, we substituted ground-based experiments at Queen's University with QUELD II vertical and horizontal, with and without vibration of the furnace. The Al-Si system was chosen for the ACRT experiments. Three related approaches were used to model eutectic solidification with an oscillatory freezing rate. A sharp interface model was used to calculate composition oscillations at the freezing interface in response to imposed freezing rate oscillations.

Wilcox. William R.↗

Resistive decay of Alfven waves in a non-uniform plasma

The effect of resistive dissipation on the propagation of an MHD disturbance in a nonuniform plasma is examined. The present analysis, based on a boundary-layer technique, shows the existence of resistive normal modes with complex eigenfrequencies. The real part of the eigenfrequency is associated with an oscillatory behavior and defines the location in space of the layer where resistivity is important. The dissipation mechanism is responsible for the damping of the wave, in contrast with previous works in which the ideal MHD theory was used.

Mok, Y.↗

Attosecond response of molecules to impulsive ionization

When matter interacts with energetic radiation it can undergo sudden, or impulsive, ionization. This process can drive chemical change and occurs widely in space and planetary atmospheres, yet its comprehensive description challenges our current theoretical and computational capabilities as it requires advanced treatment of electron correlation and nonadiabatic dynamics beyond the Born–Oppenheimer approximation. Here, in this study, we measure the response of the para-aminophenol molecule to sudden ionization. Using attosecond X-ray absorption spectroscopy, we resolve the ultrafast dynamics of the ionized molecule with atomic precision. A subfemtosecond decay corresponds to states undergoing non-radiative decay, whereas few-femtosecond oscillatory signatures are associated with electronic wavepacket motion in stable cation states that later couple to nuclear motion. We compare our measurement with state-of-the-art computational modelling, qualitatively reproducing the observed response across multiple timescales. These results provide a benchmark for computational models of sudden ionization and ultrafast charge motion in matter.

Driver, Taran [SLAC National Accelerator Laborator↗

Dynamic pair-breaking current, critical superfluid velocity, and nonlinear electromagnetic response of nonequilibrium superconductors

Here, we report numerical calculations of a dynamic pair-breaking current density $J_d$ and a critical superfluid velocity $v_d$ in a nonequilibrium superconductor carrying a uniform, large-amplitude AC current density $J(t) = J_a$sinΩ$\textit{t}$ with Ω well below the gap frequency Ω $\ll Δ_0/ℏ$. The dependencies $J_d$(Ω, $\textit{T}$) and $v_d$(Ω, $\textit{T}$) near the critical temperature $T_c$ were calculated from either the full time-dependent nonequilibrium equations for a dirty $\textit{s}$-wave superconductor or the time-dependent Ginzburg-Landau (TDGL) equations for a gapped superconductor, taking into account the GL relaxation time of the order parameter $τ_{\text{GL}}$ and the inelastic electron-phonon relaxation time of quasiparticles $τ_E$. We show that both approaches give similar frequency dependencies of $J_d$(Ω) and $v_d$(Ω) which gradually increase from their static pair-breaking GL values $J_c$ and $v_c$ at Ω$τ_E \ll$1 to $\sqrt{2}J_c$ and $\sqrt{2}v_c$ at Ω$τ_E \gg$ 1. Here $J_d, v_d$ and a dynamic superheating field at which the Meissner state becomes unstable were calculated in two different regimes of a fixed AC current and a fixed AC superfluid velocity induced by the applied AC magnetic field $H = H_a$ sinΩ$\textit{t}$ in a thin superconducting filament or a type-II superconductor with a large GL parameter. We also calculated a nonlinear electromagnetic response of a nonequilibrium superconducting state, particularly a dynamic kinetic inductance and a dissipative quasiparticle conductivity, taking into account the oscillatory dynamics of superconducting condensate and the kinetics of quasiparticles driven by a strong AC current. It is shown that an AC current density produces multiple harmonics of the electric field, the amplitudes of the higher-order harmonics diminishing as $τ_E$ increases.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A new method for analysis of limit cycle behavior of the NASA/JPL 70-meter antenna axis servos

A piecewise linear method of analyzing the effects of discontinuous nonlinearities on control system performance is described. The limit cycle oscillatory behavior of the system resulting from the nonlinearities is described in terms of a sequence of linear system transient responses. The equations are derived which relate the initial and the terminal conditions of successive transients and the boundary conditions imposed by the non-linearities. The method leads to a convenient computation algorithm for prediction of limit cycle characteristics resulting from discontinuous nonlinearities such as friction, deadzones, and hysteresis.

Hill, R. E.↗

Local Communication in Populations of Thermostatically Controlled Loads

Thermostatically controlled loads (TCLs) have shown great potential for demand response (DR) in electric grid operations. However, it has been commonly seen that DR events using TCLs may cause load synchronization and unwanted oscillatory effects, especially in homogeneous populations. In an attempt to mitigate the negative impacts of DR events, a decentralized method is proposed that modifies each thermostat behavior based on the activity of a small number of nearby TCLs. This feedback introduces the possibility of instability in the aggregate behavior. A stability analysis is performed on a linearized model of the aggregate system and the results of that analysis compared to simulation results. The proposed modification of thermostat behavior results in fourfold reduction in the post-DR peak while suppressing ensuing oscillations at the expense of a modest increase in compressor cycling. Further, the linearized model also provides insight into the aggregate behavior of the population.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Carrier density oscillation in the photoexcited semiconductor

Abstract The perturbation of a semiconductor from the thermodynamic equilibrium often leads to the display of non-linear dynamics and formation of spatiotemporal patterns due to the spontaneous generation of competing processes. Here, we use scanning ultrafast electron microscopy to show that the transport of hot carriers in the strongly excited semiconductor slows down by turning into an oscillatory process; this is evidenced by the expansions and contractions in the second moment of the distribution. We attribute such a response to the electric field generated by the spatial separation of photo-excited electrons and holes under intrinsic and photo-induced fields; we then introduce a transport model that mimics the experimental observation. Our finding provides a direct imaging evidence for the electrostatic oscillation of hot carriers in the highly excited semiconductor and offers new insights into their dynamics in space and time.

Physics↗

Prospects for gravitational wave and ultra-light dark matter detection with binary resonances beyond the secular approximation

Precision observations of orbital systems have recently emerged as a promising new means of detecting gravitational waves and ultra-light dark matter, offering sensitivity in new regimes with significant discovery potential. These searches rely critically on precise modeling of the dynamical effects of these signals on the observed system; however, previous analyses have mainly only relied on the secularly-averaged part of the response. We introduce here a fundamentally different approach that allows for a fully time-resolved description of the effects of oscillatory metric perturbations on orbital dynamics. We find that gravitational waves and ultra-light dark matter can induce large oscillations in the orbital parameters of realistic binaries, enhancing the sensitivity to such signals by orders of magnitude compared to previous estimates.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The effects of time-dependent excitation on the oscillatory motion of viscously damped laminated composite flat panels

Analytical estimates are used to describe the effects of transverse shear deformation, transverse normal stress, damping, and heterogeneity on the dynamic responses of laminated composite structures. The higher-order plate model is delineated with attention given to applications for viscously damped cross-ply symmetrically laminated plates subject to different time-history excitations. These effects are considered in the context of sonic-boom and blast loadings, and comparisons are made between the results of higher-order plate theory, first-order transverse-shear deformation, and classical theory. The results of the present higher-order model are found to be immune to the changes incurred by adding transverse viscous into the analysis. The responses of pulse-loadings due to symmetrical sonic boom and a triangular blast are found to be similar for certain times and pressure fields. It is shown that only the higher-order plate theory permits the accurate evaluation of frequency spectrum and time-history structural response of composite laminates.

Nosier, A.↗

Low-frequency oscillations in radiative-convective systems

Although eastward propagation has long been considered one of the essential features of the Madden-Julian waves, recent observations have revealed a stationary or quasi-stationary component in the oscillations, particularly in measures of the diabatic heating rate. Wave-CISK theories of the low-frequency oscillations have struggled to explain the observed period and vertical structure of the waves. On the other hand, theoretical and numerical studies have shown that low-frequency waves strongly resembling the observed oscillations can be excited by specified low-frequency oscillations of the convective heating. A problem with the latter set of theories is that the cause of the oscillatory heating has not been satisfactorily explained. It is proposed here that the observed low-frequency wave motions are the response to forcing by an essentially stationary, self-excited oscillating heat source that is produced by nonlinear interactions among radiation, cumulus convection, and the surface fluxes of sensible heat and moisture. Feedback of the large-scale motions on the latent heating is not required. Results from two very different one-dimensional models are presented to support this hypothesis. The physical processes included in the models are essentially the same, that is, radiation, cumulus convection, and the surface fluxes of sensible heat and moisture; the first model is highly simplified, however, while the second includes relatively sophisticated parameterizations of all the relevant physical processes. Results from both models show low-frequency oscillations of the latent heating, temperature, and moisture. Experiments show that the oscillations are favored by a warm sea surface and weak surface wind speeds, consistent with the observed conditions over the Indian Ocean and the tropical western Pacific Ocean.

Hu, QI↗

Inflight Treadmill Exercise Can Serve as Multi-Disciplinary Countermeasure System

The goals of the Functional Task Test (FTT) study were to determine the effects of space flight on functional tests that are representative of high priority exploration mission tasks and to identify the key underlying physiological factors that contribute to decrements in performance. Ultimately this information will be used to assess performance risks and inform the design of countermeasures for exploration class missions. We have previously shown that for Shuttle, ISS and bed rest subjects, functional tasks requiring a greater demand for dynamic control of postural equilibrium (i.e. fall recovery, seat egress/obstacle avoidance during walking, object translation, jump down) showed the greatest decrement in performance. Functional tests with reduced requirements for postural stability (i.e. hatch opening, ladder climb, manual manipulation of objects and tool use) showed little reduction in performance. These changes in functional performance were paralleled by similar decrements in sensorimotor tests designed to specifically assess postural equilibrium and dynamic gait control. The bed rest analog allows us to investigate the impact of axial body unloading in isolation on both functional tasks and on the underlying physiological factors that lead to decrements in performance and then compare them with the results obtained in our space flight study. These results indicate that body support unloading experienced during space flight plays a central role in postflight alteration of functional task performance. These data also support the concept that space flight may cause central adaptation of converging body-load somatosensory and vestibular input during gravitational transitions [1]. Therefore, we conclude that providing significant body-support loading during inflight treadmill along with balance training is necessary to mitigate decrements in critical mission tasks that require dynamic postural stability and mobility. Data obtained from space flight and bed rest support the notion that in-flight treadmill exercise, in addition to providing aerobic exercise and mechanical stimuli to the bone, also has a number of sensorimotor benefits by providing: 1) A balance challenge during locomotion requiring segmental coordination in response to a downward force. 2) Body-support loading during performance of a full-body active motor task. 3) Oscillatory stimulation of the otoliths and synchronized periodic foot impacts that facilitate the coordination of gait motions and tune the full-body gaze control system. 4) Appropriate sensory input (foot tactile input, muscle and tendon stretch input) to spinal locomotor central pattern generators required for the control of locomotion. Forward work will focus on a follow-up bed rest study that incorporates aerobic and resistance exercise with a treadmill balance and gait training system that can serve as an integrated interdisciplinary countermeasure system for future exploration class missions.

Bloomberg, J. J.↗

Surface oxygenation of multicomponent nanoparticles toward active and stable oxidation catalysts

Abstract The need for active and stable oxidation catalysts is driven by the demands in production of valuable chemicals, remediation of hydrocarbon pollutants and energy sustainability. Traditional approaches focus on oxygen-activating oxides as support which provides the oxygen activation at the catalyst-support peripheral interface. Here we report a new approach to oxidation catalysts for total oxidation of hydrocarbons (e.g., propane) by surface oxygenation of platinum (Pt)-alloyed multicomponent nanoparticles (e.g., platinum-nickel cobalt (Pt–NiCo)). The in-situ/operando time-resolved studies, including high-energy synchrotron X-ray diffraction and diffuse reflectance infrared Fourier transform spectroscopy, demonstrate the formation of oxygenated Pt–NiOCoO surface layer and disordered ternary alloy core. The results reveal largely-irregular oscillatory kinetics associated with the dynamic lattice expansion/shrinking, ordering/disordering, and formation of surface-oxygenated sites and intermediates. The catalytic synergy is responsible for reduction of the oxidation temperature by ~100 °C and the high stability under 800 °C hydrothermal aging in comparison with Pt, and may represent a paradigm shift in the design of self-supported catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Application of two-dimensional unsteady aerodynamic to a free-tip rotor response analysis

The free-tip rotor utilizes a rotor blade tip which is structurally decoupled from the blade inboard section. The tip is free to pitch about its own pitch axis to respond to the local flow angularity changes. The tip also experiences the heaving motion due to the flapping of the rotor blade. For an airfoil in any pitching and heaving motion which can be expanded into a Fourier series, the lift and moment calculated by Theodoren's theory is simply the linear combination of the lift and moment calculated for each harmonic. These lift and moment are then used to determine the response of the free-tip rotor. A parametric study is performed to determine the effect of mechanical damping, mechanical spring, sweep, friction, and a constant control moment on the free-tip rotor response characteristics and the resulting azimuthal lift distributions. The results showed that the free-tip has the capability to suppress the oscillatory lift distribution around the azimuth and to eliminate a significant negative life peak on the advancing tip. This result agrees with the result of the previous analysis based on the steady aerodynamics.

Yates, L.↗

Sensitivity of the Tropical Ocean-Atmosphere to Seasonal and Long-Term Climate Forcing

Since the pioneer works of Bjerknes (1966,1969) many studies have been conducted to understand the El Nino and Southern Oscillation (ENSO) phenomenon. These studies have led to a basic understanding of the dynamics of El Nino. Central to the couple dynamics of ENSO is the delayed action oscillator theory (Suarez and Schopf 1988), which successfully describes the cyclic feature of El Nino. While the oscillatory feature of El Nino is reasonably well understood, the irregularity of El Nino, the effect of monsoon on ENSO, and the response of coupled system to the global warming are still under debate. In the present study, we attempt to provide some theoretical understanding of possible impacts of seasonal cycle, monsoon, and climate changes on ENSO using intermediate coupled model.

Kim, K.-M.↗

Electrophysiology of the mammillary complex in vitro. II. Medial mammillary neurons

1. The electrophysiological properties of guinea pig medial mammillary body (MMB) neurons were studied using an in vitro slice preparation. 2. The neurons (n = 80) had an average resting potential of -57 +/- 5.5 (SD) mV, an input resistance of 176 +/- 83 M omega, and a spike amplitude of 58 +/- 15.7 mV. Most of the neurons were silent at rest (n = 52), but some fired spontaneous single spikes (n = 16) or spike bursts (n = 14). 3. The main electrophysiological characteristic of MMB neurons was the ability to generate Ca(2+)-dependent regenerative events, which resulted in very robust burst responses. However, this regenerative event was not the same for all neurons, ranging from typical low-threshold Ca2+ spikes (LTSs) to intermediate-threshold plateau potentials (ITPs). 4. The ITPs were distinct from the LTSs in that they lasted > or = 100 ms and were not inactivated at membrane potentials at or positive to -55 mV. 5. Some cells with a prominent ITP and no LTS (n = 36) displayed repetitive, usually rhythmic, bursting (n = 14). This ITP could be powerful enough to maintain rhythmic membrane potential oscillations after pharmacological block of Na+ conductances. 6. A group of 32 MMB neurons displayed complex bursting that was generated by activation of both LTSs and ITPs. This was established on the basis of their distinct time- and voltage-dependent characteristics. In a group of neurons (n = 14), the burst responses were exclusively generated by an LTS; however, a Ca(2+)-dependent plateau potential contributed to the generation of rebound-triggered oscillatory firing. 7. In addition to the Ca(2+)-dependent LTS and/or ITP, MMB neurons always displayed high-threshold Ca2+ spikes after reduction of K+ conductances with tetraethylammonium. 8. MMB neurons display one of the richer varieties of voltage-dependent Ca2+ conductances so far encountered in mammalian CNS. We propose that the very prominent endogenous bursting and oscillatory properties of MB neurons allow this nuclear complex to function as an oscillatory relay for the transmission of low-frequency rhythmic activities throughout the limbic circuit.

NASA Discipline Neuroscience↗