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Airborne and Ground-Based Measurements of Aerosol Optical Depth of Freshly Emitted Anthropogenic Plumes in the Athabasca Oil Sands Region

In this work we report the airborne aerosol optical depth (AOD) from measurements within freshly emitted anthropogenic plumes arising from mining and processing operations in the Athabasca Oil Sands Region (AOSR) in the context of ground-based AERONET climatological daily averaged AODs at Fort McMurray (Alberta, Canada). During two flights on 9 and 18 June 2018, the NASA airborne 4STAR (Spectrometers for Sky-Scanning, Sun-Tracking Atmospheric Research) Sun photometer registered high fine-mode (FM, <1 µm) in-plume AODs of up to 0.4 and 0.9, respectively, in the vicinity of the plume source (<20 km). Particle composition shows that the plumes were associated with elevated concentrations of sulfates and ammonium. These high AODs significantly exceed climatological averages for June and were not captured by the nearby AERONET instrument (mean daily AODs of 0.10±0.01 and 0.07±0.02, maximum AOD of 0.12) due possibly to horizontal inhomogeneity of the plumes, plume dilution and winds which in certain cases were carrying the plume away from the ground-based instrument. The average 4STAR out-of-plume (background) AODs deviated only marginally from AERONET daily averaged values. While 4STAR AOD peaks were generally well correlated in time with peaks in the in situ-measured particle concentrations, we show that differences in particle size are the dominant factor in determining the 4STAR-derived AOD. During the two flights of 24 June and 5 July 2018 when plumes likely travelled distances of 60 km or more, the average 4STAR FM AOD increased by 0.01–0.02 over ∼50 km of downwind particle evolution, which was supported by the increases in layer AODs calculated from the in situ extinction measurements. Based on these observations as well as the increases in organic mass, we attribute the observed AOD increase, at least in part, to secondary organic aerosol formation. The in-plume and out-of-plume AODs for this second pair of flights, in contrast to clear differences in in situ optical and other measurements, were practically indistinguishable and compared favourably to AERONET within 0.01–0.02 AOD. This means that AERONET was generally successful in capturing the background AODs, but missed some of the spatially constrained high-AOD plumes with sources as close as 30–50 km, which is important to note since the AERONET measurements are generally thought to be representative of the regional AOD loading. The fact that industrial plumes can be associated with significantly higher AODs in the vicinity of the emission sources than previously reported from AERONET can potentially have an effect on estimating the AOSR radiative impact.

AERONET↗

Retrieving Aerosol Optical Depth and High Spatial Resolution Ocean Surface Wind Speed from CALIPSO: A Neural Network Approach

An innovative neural network retrieval algorithm is developed for retrieving ocean surface wind speed from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) lidar measurements. The neural network is trained with CALIPSO ocean surface and atmospheric backscatter measurements together with collocated Advanced Microwave Scanning Radiometer for EOS(AMSR-E) ocean surface wind speed. Ocean surface wind speeds are derived by applying the neural network algorithm to CALIPSO measurements between 2008 and 2020. CALIPSO wind speed measurement of 2015 also compare with Advanced Microwave Scanning Radiometer 2 (AMSR-2) measurements on the Global Change Observation Mission –Water "Shizuku"(GCOM-W) satellite. Aerosol optical depths are then derived from CALIPSO’s ocean surface backscatter signal and theoretical ocean surface reflectance calculated from CALIPSO wind speed and Cox-Munk wind –surface slope variance relation. This CALIPSO wind speed retrieval technique is an improvement from Hu et al. (2008), as it can be applied to most clear skies with optical depths up to 1.5 without making assumptions about aerosol lidar ratio.

wind aerosols CALIPSO↗

Evaluating Nighttime CALIOP 0.532 micron Aerosol Optical Depth and Extinction Coefficient Retrievals

NASA Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) Version 3.01 5-km nighttime 0.532 micron aerosol optical depth (AOD) datasets from 2007 are screened, averaged and evaluated at 1 deg X 1 deg resolution versus corresponding/co-incident 0.550 micron AOD derived using the US Navy Aerosol Analysis and Prediction System (NAAPS), featuring two-dimensional variational assimilation of quality-assured NASA Moderate Resolution Imaging Spectroradiometer (MODIS) and Multi-angle Imaging Spectroradiometer (MISR) AOD. In the absence of sunlight, since passive radiometric AOD retrievals rely overwhelmingly on scattered radiances, the model represents one of the few practical global estimates available from which to attempt such a validation. Daytime comparisons, though, provide useful context. Regional-mean CALIOP vertical profiles of night/day 0.532 micron extinction coefficient are compared with 0.523/0.532 micron ground-based lidar measurements to investigate representativeness and diurnal variability. In this analysis, mean nighttime CALIOP AOD are mostly lower than daytime (0.121 vs. 0.126 for all aggregated data points, and 0.099 vs. 0.102 when averaged globally per normalised 1 deg. X 1 deg. bin), though the relationship is reversed over land and coastal regions when the data are averaged per normalised bin (0.134/0.108 vs. 0140/0.112, respectively). Offsets assessed within single bins alone approach +/- 20 %. CALIOP AOD, both day and night, are higher than NAAPS over land (0.137 vs. 0.124) and equal over water (0.082 vs. 0.083) when averaged globally per normalised bin. However, for all data points inclusive, NAAPS exceeds CALIOP over land, coast and ocean, both day and night. Again, differences assessed within single bins approach 50% in extreme cases. Correlation between CALIOP and NAAPS AOD is comparable during both day and night. Higher correlation is found nearest the equator, both as a function of sample size and relative signal magnitudes inherent at these latitudes. Root mean square deviation between CALIOP and NAAPS varies between 0.1 and 0.3 globally during both day/night. Averaging of CALIOP along-track AOD data points within a single NAAPS grid bin improves correlation and RMSD, though day/night and land/ocean biases persist and are believed systematic. Vertical profiles of extinction coefficient derived in the Caribbean compare well with ground-based lidar observations, though potentially anomalous selection of a priori lidar ratios for CALIOP retrievals is likely inducing some discrepancies. Mean effective aerosol layer top heights are stable between day and night, indicating consistent layer-identification diurnally, which is noteworthy considering the potential limiting effects of ambient solar noise during day.

aerosol optical depth↗

Optical Properties of Boreal Region Biomass Burning Aerosols in Central Alaska and Seasonal Variation of Aerosol Optical Depth at an Arctic Coastal Site

Long-term monitoring of aerosol optical properties at a boreal forest AERONET site in interior Alaska was performed from 1994 through 2008 (excluding winter). Large interannual variability was observed, with some years showing near background aerosol optical depth (AOD) levels (<0.1 at 500 nm) while 2004 and 2005 had August monthly means similar in magnitude to peak months at major tropical biomass burning regions. Single scattering albedo (omega (sub 0); 440 nm) at the boreal forest site ranged from approximately 0.91 to 0.99 with an average of approximately 0.96 for observations in 2004 and 2005. This suggests a significant amount of smoldering combustion of woody fuels and peat/soil layers that would result in relatively low black carbon mass fractions for smoke particles. The fine mode particle volume median radius during the heavy burning years was quite large, averaging approximately 0.17 micron at AOD(440 nm) = 0.1 and increasing to approximately 0.25 micron at AOD(440 nm) = 3.0. This large particle size for biomass burning aerosols results in a greater relative scattering component of extinction and, therefore, also contributes to higher omega (sub 0). Additionally, monitoring at an Arctic Ocean coastal site (Barrow, Alaska) suggested transport of smoke to the Arctic in summer resulting in individual events with much higher AOD than that occurring during typical spring Arctic haze. However, the springtime mean AOD(500 nm) is higher during late March through late May (approximately 0.150) than during summer months (approximately 0.085) at Barrow partly due to very few days with low background AOD levels in spring compared with many days with clean background conditions in summer.

Eck, T. F.↗

Inference of the optical depth to reionization τ from Planck CMB maps with convolutional neural networks

The optical depth to reionization, τ, is the least constrained parameter of the cosmological Λ cold dark matter (ΛCDM) model. To date, its most precise value is inferred from large-scale polarized cosmic microwave background (CMB) power spectra from the High Frequency Instrument (HFI) aboard the Planck satellite. These maps are known to contain significant contamination by residual non-Gaussian systematic effects, which are hard to model analytically. Therefore, robust constraints on τ are currently obtained through an empirical cross-spectrum likelihood built from simulations. In this paper, we present a likelihood-free inference of τ from polarized Planck HFI maps which, for the first time, is fully based on neural networks (NNs). NNs have the advantage of not requiring an analytical description of the data and can be trained on state-of-the-art simulations, combining the information from multiple channels. By using Gaussian sky simulations and Planck SRoll2 simulations, including CMB, noise, and residual instrumental systematic effects, we trained, tested, and validated NN models considering different setups. We inferred the value of τ directly from Stokes Q and U maps at ~4° pixel resolution, without computing angular power spectra. On Planck data, we obtained τ NN = 0.0579 ± 0.0082, which is compatible with current EE cross-spectrum results but with a ~30% larger uncertainty, which can be assigned to the inherent nonoptimality of our estimator and to the retraining procedure applied to avoid biases. While this paper does not improve on current cosmological constraints on τ, our analysis represents a first robust application of NN-based inference on real data, and highlights its potential as a promising tool for complementary analysis of near-future CMB experiments, also in view of the ongoing challenge to achieve the first detection of primordial gravitational waves.

79 ASTRONOMY AND ASTROPHYSICS↗

On the Rayleigh-scattering optical depth of the atmosphere

It is pointed out that revised Rayleigh-scattering optical depths published by Hoyt (1977) are not correct, because King's (1923) formula, which was used by Hoyt, requires that the rotational lines be included in the polarization measurement. To exclude them is to exclude the contribution of the Raman-shifted photons to the total molecular extinction. Hoyt's error was repeated by Froehlich and Shaw (1980), who also confused the depolarization for natural light with that for (polarized) laser light. In an effort to clarify basic concepts, attention is given to the origin of the depolarization correction, depolarization ratios, vibrational Raman effects, and extinction measurements.

Young, A. T.↗

How Do A-train Sensors Intercompare in the Retrieval of Above-cloud Aerosol Optical Depth? A Case Study-based Assessment

We intercompare the above-cloud aerosol optical depth (ACAOD) of biomass burning plumes retrieved from A-train sensors, i.e., Moderate Resolution Imaging Spectroradiometer (MODIS), Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP), Polarization and Directionality of Earth Reflectances (POLDER), and Ozone Monitoring Instrument (OMI). These sensors have shown independent capabilities to retrieve aerosol loading above marine boundary layer clouds-a kind of situation often found over the southeast Atlantic Ocean during dry burning season. A systematic comparison reveals that all passive sensors and CALIOP-based research methods derive comparable ACAOD with differences mostly within 0.2 over homogeneous cloud fields. The 532 nm ACAOD retrieved by CALIOP operational algorithm is underestimated. The retrieved 1064 nm AOD however shows closer agreement with passive sensors. Given the different types of measurements processed with different algorithms, the reported close agreement between them is encouraging. Due to unavailability of direct measurements above cloud, the validation of satellite-based ACAOD remains an open challenge. The intersatellite comparison however can be useful for the relative evaluation and consistency check

Aerosol↗

What is the Uncertainty in MODIS Aerosol Optical Depth in the Vicinity of Clouds?

MODIS dark-target (DT) algorithm retrieves aerosol optical depth (AOD) using a Look Up Table (LUT) approach. Global comparison of AOD (Collection 6 ) with ground-based sun photometer gives an Estimated Error (EE) of +/-(0.04 + 10%) over ocean. However, EE does not represent per-retrieval uncertainty. For retrievals that are biased high compared to AERONET, here we aim to closely examine the contribution of biases due to presence of clouds and per-pixel retrieval uncertainty. We have characterized AOD uncertainty at 550 nm, due to standard deviation of reflectance in 10 km retrieval region, uncertainty related to gas (H2O, O3) absorption, surface albedo, and aerosol models. The uncertainty in retrieved AOD seems to lie within the estimated over ocean error envelope of +/-(0.03+10%). Regions between broken clouds tend to have higher uncertainty. Compared to C6 AOD, a retrieval omitting observations in the vicinity of clouds (< or = 1 km) is biased by about +/- 0.05. For homogeneous aerosol distribution, clear sky retrievals show near zero bias. Close look at per-pixel reflectance histograms suggests retrieval possibility using median reflectance values.

Patadia, Falguni↗

Aerosol Optical Depth Value-Added Product Report

This document describes the process applied to retrieve aerosol optical depth (AOD) from multifilter rotating shadowband radiometers (MFRSR) and normal incidence multifilter radiometers (NIMFR) operated at the ARM Climate Research Facility’s ground-based facilities.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric optical depth effects on angular anisotropy of plant canopy reflectance

The effects of varying atmospheric aerosol optical depth on the bidirectional reflectance distribution of vegetation canopies is investigated. The reflectance distributions of two pasture grass canopies and one soya bean canopy under different sky irradiance distributions were measured, and the data were analyzed in the visible and IR spectral bands. It is observed that, for the pasture grass canopies, the change in reflectance is due to the percentage of shadowed area viewed by the sensor, and for the soya bean, the specular reflection effect and increased diffuse irradiance penetration into the canopy cause reflectance changes. It is detected that the reflectivity for the soya bean canopy on a hazy day is lower than on a clear day; however, the opposite change is observed for the pasture grass. It is also detected that the normalized difference vegetation index values differ under clear and hazy conditions for the same vegetation canopy conditions.

Deering, Donald W.↗

Climatology of the Aerosol Optical Depth by Components from the Multi-Angle Imaging Spectroradiometer (MISR) and Chemistry Transport Models

The Multi-angle Imaging Spectroradiometer (MISR) Joint Aerosol (JOINT_AS) Level 3 product has provided a global, descriptive summary of MISR Level 2 aerosol optical depth (AOD) and aerosol type information for each month over 16+ years since March 2000. Using Version 1 of JOINT_AS, which is based on the operational (Version 22) MISR Level 2 aerosol product, this study analyzes, for the first time, characteristics of observed and simulated distributions of AOD for three broad classes of aerosols: spherical nonabsorbing, spherical absorbing, and nonspherical - near or downwind of their major source regions. The statistical moments (means, standard deviations, and skew-nesses) and distributions of AOD by components derived from the JOINT_AS are compared with results from two chemistry transport models (CTMs), the Goddard Chemistry Aerosol Radiation and Transport (GOCART) and SPectral RadIatioN-TrAnSport (SPRINTARS). Overall, the AOD distributions retrieved from MISR and modeled by GOCART and SPRINTARS agree with each other in a qualitative sense. Marginal distributions of AOD for each aerosol type in both MISR and models show considerable high positive skewness, which indicates the importance of including extreme AOD events when comparing satellite retrievals with models. The MISR JOINT_AS product will greatly facilitate comparisons between satellite observations and model simulations of aerosols by type.

SPRINTARS↗

The Diurnal Variation of the Aerosol Optical Depth at the ARM SGP Site

Abstract This study examines the diurnal variation of the aerosol optical depth (AOD) at 355 nm observed by Raman lidar (RL) at the Atmospheric Radiation Measurement Program Southern Great Plains (SGP) site under both clear and cloudy‐sky conditions. Here only cloudy‐skies when the lidar signal is not fully attenuated are considered. The daytime AOD and its variation from the RL showed an excellent agreement with the Aerosol Robotic Network, demonstrating that the RL‐retrieved AOD is not affected by solar background contamination. The climatological annual‐mean daytime‐mean AOD is only slightly larger than the nighttime‐mean AOD (by 1%–3%). However, day‐to‐day variations are observed such that the daytime‐ and nighttime‐mean AOD difference for a given day can be large (about 95% of days have differences within 0.2). The seasonal AOD diurnal range (i.e., the difference between the maximum and minimum values) relative to the mean was 10%–15% except in the winter when it was 44%. The seasonal‐mean cloudy‐sky AOD diurnal variation is similar to that for clear‐sky, except that the AODs are larger (the annual‐mean cloudy‐sky AOD is larger than the clear‐sky by 24%). The aerosol lidar ratio diurnal variations are also examined, which are 10%–20% for all seasons with a minimum near 9 a.m. to 15 p.m. for all seasons except winter. Also presented is the annual‐mean AOD from the Cloud‐Aerosol Lidar and Infrared Pathfinder Satellite at SGP site: its daytime AOD is about 0.1 smaller than nighttime AOD because of daytime solar background contamination.

54 ENVIRONMENTAL SCIENCES↗

Determining optical depth in different parts of the Fraunhofer line contour

The method of approximate determination of the optical depth tau in the profile of the Fraunhofer line is considered. In the method the observed profile and allocation of tau to the temperature in the photosphere must be known. If the source function B prime (tau) in the line seems not to be equal to the Planck function, the dependence B prime (tau) on tau is needed. The method for the determination of B prime (tau) using the center-to-limb observations of the central intensities of the line is suggested.

Gurtovenko, E. A.↗

Improvement of Aerosol Optical Depth Retrieval from MODIS Spectral Reflectance over the Global Ocean Using New Aerosol Models Archived from AERONET Inversion Data and Tri-axial Ellipsoidal Dust Database

New over-ocean aerosol models are developed by integrating the inversion data from the Aerosol Robotic Network (AERONET) sun/sky radiometers with a database for the optical properties of tri-axial ellipsoid particles. The new aerosol models allow more accurate retrieval of aerosol optical depth (AOD) from the Moderate Resolution Imaging Spectroradiometer (MODIS) in the case of high AOD (AOD greater than 0.3). The aerosol models are categorized by using the fine-mode fraction (FMF) at 550 nm and the singlescattering albedo (SSA) at 440 nm from the AERONET inversion data to include a variety of aerosol types found around the globe. For each aerosol model, the changes in the aerosol optical properties (AOPs) as functions of AOD are considered to better represent aerosol characteristics. Comparisons of AODs between AERONET and MODIS for the period from 2003 to 2010 show that the use of the new aerosol models enhances the AOD accuracy with a Pearson coefficient of 0.93 and a regression slope of 0.99 compared to 0.92 and 0.85 calculated using the MODIS Collection 5 data. Moreover, the percentage of data within an expected error of +/-(0.03 + 0.05xAOD) is increased from 62 percent to 64 percent for overall data and from 39 percent to 51 percent for AOD greater than 0.3. Errors in the retrieved AOD are further characterized with respect to the Angstrom exponent (AE), scattering angle, SSA, and air mass factor (AMF). Due to more realistic AOPs assumptions, the new algorithm generally reduces systematic errors in the retrieved AODs compared with the current operational algorithm. In particular, the underestimation of fine-dominated AOD and the scattering angle dependence of dust-dominated AOD are significantly mitigated as results of the new algorithm's improved treatment of aerosol size distribution and dust particle nonsphericity.

aerosol optical depth↗

Refined Use of Satellite Aerosol Optical Depth Snapshots to Constrain Biomass Burning Emissions in the GOCART Model

Simulations of biomass burning (BB) emissions in global chemistry and aerosol transport models depend on external inventories, which provide location and strength of burning aerosol sources. Our previous work (Petrenko et al., 2012) shows that satellite snapshots of aerosol optical depth (AOD) near the emitted smoke plume can be used to constrain model-simulated AOD, and effectively, the assumed source strength. We now refine the satellite-snapshot method and investigate applying simple multiplicative emission correction factors for the widely used Global Fire Emission Database version 3 (GFEDv3) emission inventory can achieve regional-scale consistency between MODIS AOD snapshots and the Goddard Chemistry Aerosol Radiation and Transport (GOCART) model. The model and satellite AOD are compared over a set of more than 900 BB cases observed by the MODIS instrument during the 2004, and 2006-2008 biomass burning seasons. The AOD comparison presented here shows that regional discrepancies between the model and satellite are diverse around the globe yet quite consistent within most ecosystems. Additional analysis of including small fire emission correction shows the complimentary nature of correcting for source strength and adding missing sources, and also indicates that in some regions other factors may be significant in explaining model-satellite discrepancies. This work sets the stage for a larger intercomparison within the Aerosol Inter-comparisons between Observations and Models (AeroCom) multi-model biomass burning experiment. We discuss here some of the other possible factors affecting the remaining discrepancies between model simulations and observations, but await comparisons with other AeroCom models to draw further conclusions.

aerosol optical depth↗

Cirrus optical depth retrieval from satellite-measured bidirectional reflectance

In the framework of investigating the relationship between the visible optical depth and microphysics of cirrus clouds, the doubling scheme for radiative transfer in cirrus cloudy atmospheres, as developed by Takano and Liou (1988), has been used to compute the bidirectional reflectances at the top of the atmosphere. Reflectance data taken at about the same time from GOES and AVHRR over Waussau, as well as particle distributions observed during the FIRE IFO carried out in Wisconsin (1986) were the basis of the experiment. For the cirrus microphysical model, hexagonal ice crystals and area-equivalent ice spheres are considered. The single scattering phase functions for randomly oriented hexagonal columns and area-equivalent ice spheres are computed from geometric optics and Mie theory, respectively.

Takano, Y.↗

Thermal Infrared Dust Optical Depth and Coarse-Mode Effective Diameter Over Oceans Retrieved From Collocated MODIS and CALIOP Observations

In this study, we developed a novel algorithm based on the collocated Moderate Resolution Imaging Spectroradiometer (MODIS) thermal infrared (TIR) observations and dust vertical profiles from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) to simultaneously retrieve dust aerosol optical depth at 10 µm (DAOD10μm) and the coarse-mode dust effective diameter (Deff) over global oceans. The accuracy of the Deff retrieval is assessed by comparing the dust lognormal volume particle size distribution (PSD) corresponding to retrieved Deff with the in-situ measured dust PSDs from the AER-D, SAMUM-2 and SALTRACE field campaigns through case studies. The new DAOD10μm retrievals were evaluated first through comparisons with the collocated DAOD10.6μm retrieved from the combined Imaging Infrared Radiometer (IIR) and CALIOP observations from our previous study (Zheng et al. 2022). The pixel-to-pixel comparison of the two DAOD retrievals indicates a good agreement (R~0.7) and a significant reduction of (~50%) retrieval uncertainties largely thanks to the better constraint on dust size. In a climatological comparison, the seasonal and regional (5°×2°) mean DAOD10um retrievals based on our combined MODIS and CALIOP method are in good agreement with the two independent Infrared Atmospheric Sounding Interferometer (IASI) products over three dust transport regions (i.e., North Atlantic (NA; R = 0.9), Indian Ocean (IO; R = 0.8) and North Pacific (NP; R = 0.7)). Using the new retrievals from 2013 to 2017, we performed a climatological analysis of coarse mode dust Deff over global oceans. We found that dust Deff over IO and NP are up to 20% smaller than that over NA. Over NA in summer, we found a ~50% reduction of the number of retrievals with Deff > 5 μm from 15°W to 35°W and a stable trend of Deff average at 4.4 μm from 35°W throughout the Caribbean Sea (90°W). Over NP in spring, only ~5% of retrieved pixels with Deff > 5 μm are found from 150°E to 180°, while the mean Deff remains stable at 4.0 μm throughout eastern NP. To our best knowledge, this study is the first to retrieve both DAOD and coarse-mode dust particle size over global oceans for multiple years. This retrieval dataset provides insightful information for evaluating dust long-wave radiative effects and coarse mode dust particle size in models.

dust optical depth↗