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At least 145 records · Page 8

A Novel Freshwater to Marine Evolutionary Transition Revealed within Methylophilaceae Bacteria from the Arctic Ocean

Bacteria inhabiting polar oceans, particularly the Arctic Ocean, are less studied than those at lower latitudes. Discovering bacterial adaptations to Arctic Ocean conditions is essential for understanding responses to the accelerated environmental changes occurring in the North. The Methylophilaceae are emerging as a model for investigating the genomic basis of habitat adaptation, because related lineages are widely distributed across both freshwater and marine ecosystems. Here, we investigated Methylophilaceae diversity in the salinity-stratified surface waters of the Canada Basin, Arctic Ocean. In addition to a diversity of marine OM43 lineages, we report on the genomic characteristics and evolution of a previously undescribed Methylophilaceae clade (BS01) common to polar surface waters yet related to freshwater sediment Methylotenera species. BS01 is restricted to the lower-salinity surface waters, while OM43 is found throughout the halocline. An acidic proteome supports a marine lifestyle for BS01, but gene content shows increased metabolic versatility compared to OM43 and evidence for ongoing genome-streamlining. Phylogenetic reconstruction shows that BS01 colonized the pelagic ocean independently of OM43 via convergent evolution. Salinity adaptation and differences in one-carbon and nitrogen metabolism may play a role in niche differentiation between BS01 and OM43. In particular, urea utilization by BS01 is predicted to provide an ecological advantage over OM43 given the limited amount of inorganic nitrogen in the Canada Basin. These observations provide further evidence that the Arctic Ocean is inhabited by distinct bacterial groups and that at least one group (BS01) evolved via a freshwater to marine environmental transition.

59 BASIC BIOLOGICAL SCIENCES↗

Compensation Between Poleward Energy Transports in the Ocean and Atmosphere. Final report

Equator-to-pole energy transport by the ocean and atmosphere is a fundamental constraint on the Earth's climate. In his 1964 seminal paper, Jacob Bjerknes suggested that if the top-of-the atmosphere fluxes and the ocean heat storage do not vary substantially, which is a reasonable assumption on long time scales, the total energy transport by the climate system would not vary much either. This implies that any large anomalies of oceanic and atmospheric energy transports should be equal and opposite. Despite its fundamental importance in understanding the climate system, this hypothesis, the so-called Bjerknes compensation, has been tested by only a limited number of studies. The goal of our project is to investigate the degree of compensation in poleward energy transports by the atmosphere and ocean and its dependence on the time scale, latitude and background climate primarily based on a large suite of the Community Earth System Model version 1 (CESM1) simulations to test the Bjerknes compensation hypothesis. Our particular emphases are to understand: (1) robustness of the degree of the compensation across the various simulations with differing parameterizations and initial conditions, (2) the competing role of atmosphere-ocean couplings through the momentum flux and buoyancy flux in enabling or deterring the compensation, and (3) the role of compensation in the leading modes of variability in the atmosphere and ocean

54 ENVIRONMENTAL SCIENCES↗

Ice-shelf freshwater triggers for the Filchner–Ronne Ice Shelf melt tipping point in a global ocean–sea-ice model

Some ocean modeling studies have identified a potential tipping point from a low to a high basal melt regime beneath the Filchner–Ronne Ice Shelf (FRIS), Antarctica, with significant implications for subsequent Antarctic ice sheet mass loss. To date, investigation of the climate drivers and impacts of this possible event have been limited because ice-shelf cavities and ice-shelf melting are only now starting to be included in global climate models. Using a global ocean–sea-ice configuration of the Energy Exascale Earth System Model (E3SM) that represents both ocean circulations and melting within ice-shelf cavities, we explore freshwater triggers (iceberg melt and ice-shelf basal melt) of a transition to a high-melt regime at FRIS in a low-resolution (30 km in the Southern Ocean) global ocean–sea-ice model. We find that a realistic spatial distribution of iceberg melt fluxes is necessary to prevent the FRIS melt regime change from unrealistically occurring under historical-reanalysis-based atmospheric forcing. Further, improvement of the default parameterization for mesoscale eddy mixing significantly reduces a large regional fresh bias and weak Antarctic Slope Front structure, both of which precondition the model to melt regime change. Using two different stable model con figurations, we explore the sensitivity of FRIS melt regime change to regional ice-sheet freshwater fluxes. Through a series of sensitivity experiments prescribing incrementally increasing melt rates from the smaller, neighboring ice shelves in the eastern Weddell Sea, we demonstrate the potential for an ice-shelf melt “domino effect” should the upstream ice shelves experience increased melt rates. The experiments also reveal that modest ice-shelf melt biases in a model, especially at coarse ocean resolution where narrow continental shelf dynamics are not well resolved, can lead to an unrealistic melt regime change at downstream ice shelves. Thus, we find that remote connections between melt fluxes at different ice shelves are sensitive to baseline model conditions. Our results highlight both the potential and the peril of simulating prognostic Antarctic ice-shelf melt rates in a low-resolution global model.

58 GEOSCIENCES↗

Ocean-Powered Oyster Tumbling: A Review of Techniques and Opportunities for Emission Reductions

Oysters perform critical roles in shoreline ecosystems by improving water quality, providing habitat for species, and preventing erosion. These ecosystem functions are present even when oysters are farmed. Because of this, and the lack of need for nutrient inputs, oyster farming is often viewed as environmentally friendly. However, fossil fuels play a large part in oyster farming practices. Fossil fuels are used to power boats, tools, and farming equipment. Oyster tumbling machines, which are used to control biofouling and produce a desirable shape and size, use a significant amount of energy and are often powered by diesel generators. As the oyster farming industry grows and practices such as integrated multi-trophic aquaculture expand, decarbonization of the industry becomes more important. One solution may be “ocean-powered” tumbling, whereby oyster grow-out gear is designed to use a range of ocean movements to tumble oysters gradually as they grow. This solution eliminates the need for fossil fuel-powered tumblers and tends to be less labor intensive. A wide range of ocean-powered gear is used by farms across the United States. New approaches and designs are being explored, making ocean-powered oyster tumbling accessible in different environments. Water movements at oyster farms are primarily driven by tidal exchange, currents, wind waves, or a combination. This paper compares methods of ocean-powered tumbling, explores the transition from standard fossil fuel-powered tumbling techniques to ocean-powered tumbling, and estimates the emission reductions of decarbonizing oyster tumbling practices.

16 TIDAL AND WAVE POWER↗

Observational ozone datasets over the global oceans and polar regions (version 2024)

Studying tropospheric ozone over the remote areas of the planet, such as the open oceans and the polar regions, is crucial to understand the role of ozone as a global climate forcer and regulator of atmospheric oxidative capacity. A focus on the pristine oceanic and polar regions complements the available land-based datasets and provides insights into key photochemical and depositional loss processes that control the concentrations and spatiotemporal variability in ozone as well as the physicochemical mechanisms driving these patterns. However, an assessment of the role of ozone over the oceanic and polar regions has been hampered by a lack of comprehensive observational datasets. Here, we present the first comprehensive collection of ozone data over the oceans and the polar regions. The overall dataset consists of 77 ship cruises/buoy-based observations and 48 aircraft-based campaigns. The dataset, consisting of more than 630 000 independent ozone measurement data points covering the period from 1977 to 2022 and an altitude range from the surface to 5000 m (with a focus on the lowest 2000 m), allows systematic analyses of the spatiotemporal distribution and long-term trends over the 11 defined ocean/polar regions. The datasets from ships, buoys, and aircraft are complemented by ozonesonde data from 29 launch sites or field campaigns and by 21 non-polar and 17 polar ground-based station datasets. The datasets contain information on how long the observed air masses were isolated from land, as estimated by backward trajectories from the individual observation points. To extract observations representative of oceanic conditions, we recommend using a subset of the data with an isolation time of 72 h or longer, from the analysis with coincident radon observations. These filtered oceanic and polar data showed typically flat diurnal cycles at high latitudes, whereas daytime decreases in ozone (11 %–16 %) were observed at lower latitudes. The ship/buoy- and aircraft-based datasets presented here will supplement the land-based ones in the TOAR-II (Tropospheric Ozone Assessment Report Phase II) database to provide a fully global assessment of tropospheric ozone. The described dataset is available at https://doi.org/10.17596/0004044 (Kanaya et al., 2025).

Kanaya, Yugo [Japan Agency for Marine-Earth Scienc↗

An evaluation of the E3SMv1 Arctic ocean and sea-ice regionally refined model

The Energy Exascale Earth System Model (E3SM) is a state-of-the-science Earth system model (ESM) with the ability to focus horizontal resolution of its multiple components in specific areas. Regionally refined global ESMs are motivated by the need to explicitly resolve, rather than parameterize, relevant physics within the regions of refined resolution, while offering significant computational cost savings relative to the respective cost of configurations with high-resolution (HR) everywhere on the globe. In this paper, we document results from the first Arctic regionally refined E3SM configuration for the ocean and sea-ice components (E3SM-Arctic-OSI), while employing data-based atmosphere, land, and hydrology components. Our aim is an improved representation of the Arctic coupled ocean and sea-ice state, its variability and trends, and the exchanges of mass and property fluxes between the Arctic and the sub-Arctic. We find that E3SM-Arctic-OSI increases the realism of simulated Arctic ocean and sea-ice conditions compared to a similar low-resolution E3SM simulation without the Arctic regional refinement in ocean and sea-ice components (E3SM-LR-OSI). In particular, exchanges through the main Arctic gateways are greatly improved with respect to E3SM-LR-OSI. Other aspects, such as the Arctic freshwater content variability and sea-ice trends, are also satisfactorily simulated. Yet, other features, such as the upper-ocean stratification and the sea-ice thickness distribution, need further improvements, involving either more advanced parameterizations, model tuning, or additional grid refinements. Overall, E3SM-Arctic-OSI offers an improved representation of the Arctic system relative to E3SM-LR-OSI, at a fraction (15 %) of the computational cost of comparable global high-resolution configurations, while permitting exchanges with the lower-latitude oceans that cannot be directly accounted for in Arctic regional models.

54 ENVIRONMENTAL SCIENCES↗

FEOTS v0.0.0: a new offline code for the fast equilibration of tracers in the ocean

Abstract. In this paper we introduce a new software framework for the offline calculation of tracer transport in the ocean. The Fast Equilibration of Ocean Tracers Software (FEOTS) is an end-to-end set of tools to efficiently calculate tracer distributions on a global or regional sub-domain using transport operators diagnosed from a comprehensive ocean model. To the best of our knowledge, this is the first application of a transport matrix model to an eddying ocean state. While a Newton–Krylov-based equilibration capability is still under development and not presented here, we demonstrate in this paper the transient modeling capabilities of FEOTS in an application focused on the Argentine Basin, where intense eddy activity and the Zapiola Anticyclone lead to strong mixing of water masses. The demonstration illustrates progress in developing offline passive tracer simulation capabilities, while highlighting the challenges of the impulse response functions approach in capturing tracer transports by a non-linear advection scheme. Our future work will focus on improving the computational efficiency of the code to reduce time-to-solution, using different basis functions to better represent non-linear advection operators, applying FEOTS to a parent model with unstructured grids (Ocean Model for Prediction Across Scales, MPAS-Ocean), and fully implementing a Newton–Krylov steady-state solver.

54 ENVIRONMENTAL SCIENCES↗

Exploring ice sheet model sensitivity to ocean thermal forcing and basal sliding using the Community Ice Sheet Model (CISM)

Abstract. Multi-meter sea level rise (SLR) is thought to be possible within the next few centuries, with most of the uncertainty originating from the Antarctic land ice contribution. One source of uncertainty relates to the ice sheet model initialization. Since ice sheets have a long response time (compared to other Earth system components such as the atmosphere), ice sheet model initialization methods can have significant impacts on how the ice sheet responds to future forcings. To assess this, we generated 25 different ice sheet spin-ups, using the Community Ice Sheet Model (CISM) at a 4 km resolution. During each spin-up, we varied two key parameters known to impact the sensitivity of the ice sheet to future forcing: one related to the sensitivity of the ice shelf melt rate to ocean thermal forcing (TF) and the other related to the basal friction. The spin-ups all nudge toward observed thickness and enforce a no-advance calving criterion, such that all final spin-up states resemble observations but differ in their melt and friction parameter settings. Each spin-up was then forced with future ocean thermal forcings from 13 different CMIP6 models under the Shared Socioeconomic Pathway (SSP)5-8.5 emissions scenario and modern climatological surface mass balance data. Our results show that the effects of the ice sheet and ocean parameter settings used during the spin-up are capable of impacting multi-century future SLR predictions by as much as 2 m. By the end of this century, the effects of these choices are more modest, but still significant, with differences of up to 0.2 m of SLR. We have identified a combined ocean and ice parameter space that leads to widespread mass loss within 500 years (low friction and high melt rate sensitivity). To explore temperature thresholds, we also ran a synthetically forced CISM ensemble that is focused on the Amundsen region only. Given certain ocean and ice parameter choices, Amundsen mass loss can be triggered with thermal forcing anomalies between 1.5 and 2 ∘C relative to the spin-up. Our results emphasize the critical importance of considering ice sheet and ocean parameter choices during spin-up for SLR predictions and suggest the importance of including glacial isostatic adjustment in ice sheet simulations.

54 ENVIRONMENTAL SCIENCES↗

Ice-shelf freshwater triggers for the Filchner–Ronne Ice Shelf melt tipping point in a global ocean–sea-ice model

Abstract. Some ocean modeling studies have identified a potential tipping point from a low to a high basal melt regime beneath the Filchner–Ronne Ice Shelf (FRIS), Antarctica, with significant implications for subsequent Antarctic ice sheet mass loss. To date, investigation of the climate drivers and impacts of this possible event have been limited because ice-shelf cavities and ice-shelf melting are only now starting to be included in global climate models. Using a global ocean–sea-ice configuration of the Energy Exascale Earth System Model (E3SM) that represents both ocean circulations and melting within ice-shelf cavities, we explore freshwater triggers (iceberg melt and ice-shelf basal melt) of a transition to a high-melt regime at FRIS in a low-resolution (30 km in the Southern Ocean) global ocean–sea-ice model. We find that a realistic spatial distribution of iceberg melt fluxes is necessary to prevent the FRIS melt regime change from unrealistically occurring under historical-reanalysis-based atmospheric forcing. Further, improvement of the default parameterization for mesoscale eddy mixing significantly reduces a large regional fresh bias and weak Antarctic Slope Front structure, both of which precondition the model to melt regime change. Using two different stable model configurations, we explore the sensitivity of FRIS melt regime change to regional ice-sheet freshwater fluxes. Through a series of sensitivity experiments prescribing incrementally increasing melt rates from the smaller, neighboring ice shelves in the eastern Weddell Sea, we demonstrate the potential for an ice-shelf melt “domino effect” should the upstream ice shelves experience increased melt rates. The experiments also reveal that modest ice-shelf melt biases in a model, especially at coarse ocean resolution where narrow continental shelf dynamics are not well resolved, can lead to an unrealistic melt regime change at downstream ice shelves. Thus, we find that remote connections between melt fluxes at different ice shelves are sensitive to baseline model conditions. Our results highlight both the potential and the peril of simulating prognostic Antarctic ice-shelf melt rates in a low-resolution global model.

54 ENVIRONMENTAL SCIENCES↗

PMEL Passive Acoustics Research: Quantifying the Ocean Soundscape from Whales to Wave Energy

Passive acoustic monitoring of the global ocean has increased dramatically over the last decade, providing insights into seasonal sea ice and wind/wave variability, biodiversity, geophysical hazards, and anthropogenic noise impacts. All of these phenomena are sentinels of marine ecosystem health and ocean climate change. Recognizing the utility of underwater sound, the Pacific Marine Environmental Laboratory (PMEL) formed a passive acoustic research program with the goal of quantifying deep-ocean and coastal soundscapes in support of NOAA’s mission to conserve and manage marine ecosystems. PMEL Acoustics Program researchers have built a stable of novel ocean technologies, including autonomous stationary hydrophones, mobile platforms, and near-real-time surface buoys with satellite communication capability. These passive acoustic monitoring systems have been deployed in every major ocean basin on Earth, enabling significant advancements in understanding of natural and anthropogenic sounds. This progress includes evaluation of human-made sound levels across US waters, observations of ship noise fluctuations during the COVID-19 pandemic, and evaluation of noise levels from offshore wave-energy devices. Progress in natural sound research includes assessment of seasonal variability in the presence of endangered cetacean species due to population recovery and/or changing ocean temperatures as well as early detection of the collapse of an Antarctic ice shelf.

54 ENVIRONMENTAL SCIENCES↗

Atmosphere–Ocean Coupled Energy Budgets of Tropical Convective Discharge–Recharge Cycles

An energy budget combining atmospheric moist static energy (MSE) and upper ocean heat content (OHC) is used to examine the processes impacting day-to-day convective variability in the tropical Indian and western Pacific Oceans. Feedbacks arising from atmospheric and oceanic transport processes, surface fluxes, and radiation drive the cyclical amplification and decay of convection around suppressed and enhanced convective equilibrium states, referred to as shallow and deep convective discharge–recharge (D–R) cycles, respectively. The shallow convective D–R cycle is characterized by alternating enhancements of shallow cumulus and stratocumulus, often in the presence of extensive cirrus clouds. The deep convective D–R cycle is characterized by sequential increases in shallow cumulus, congestus, narrow deep precipitation, wide deep precipitation, a mix of detached anvil and altostratus and altocumulus, and once again shallow cumulus cloud types. Transitions from the shallow to deep D–R cycle are favored by a positive “column process” feedback, while discharge of convective instability and OHC by mesoscale convective systems (MCSs) contributes to transitions from the deep to shallow D–R cycle. Variability in the processes impacting MSE is comparable in magnitude to, but considerably more balanced than, variability in the processes impacting OHC. Variations in the quantity of atmosphere–ocean coupled static energy (MSE + OHC) result primarily from atmospheric and oceanic transport processes, but are mainly realized as changes in OHC. MCSs are unique in their ability to rapidly discharge both lower-tropospheric convective instability and OHC.

54 ENVIRONMENTAL SCIENCES↗

Ocean surface radiation measurement best practices

Ocean surface radiation measurement best practices have been developed as a first step to support the interoperability of radiation measurements across multiple ocean platforms and between land and ocean networks. This document describes the consensus by a working group of radiation measurement experts from land, ocean, and aircraft communities. The scope was limited to broadband shortwave (solar) and longwave (terrestrial infrared) surface irradiance measurements for quantification of the surface radiation budget. Best practices for spectral measurements for biological purposes like photosynthetically active radiation and ocean color are only mentioned briefly to motivate future interactions between the physical surface flux and biological radiation measurement communities. Topics discussed in these best practices include instrument selection, handling of sensors and installation, data quality monitoring, data processing, and calibration. It is recognized that platform and resource limitations may prohibit incorporating all best practices into all measurements and that spatial coverage is also an important motivator for expanding current networks. Thus, one of the key recommendations is to perform interoperability experiments that can help quantify the uncertainty of different practices and lay the groundwork for a multi-tiered global network with a mix of high-accuracy reference stations and lower-cost platforms and practices that can fill in spatial gaps.

54 ENVIRONMENTAL SCIENCES↗

Hybrid Energy-Powered Electrochemical Direct Ocean Capture Model

Offshore synthetic fuel production and marine carbon dioxide removal can be enabled by direct ocean capture, which extracts carbon dioxide from the ocean that then can be used as a feedstock for fuel production or sequestered underground. To maximize carbon capture, plants require a variety of low-carbon energy sources to operate, such as variable renewable energy. However, the impacts of variable power on direct ocean capture have not yet been thoroughly investigated. To facilitate future deployments, a generalizable model for electrodialysis-based direct ocean capture plants is created to evaluate plant performance and electricity costs under intermittent power availability. This open-source Python-based model captures key aspects of the electrochemistry, ocean chemistry, post-processing, and operation scenarios under various conditions. To incorporate realistic energy supply dynamics and cost estimates, the model is coupled with the National Renewable Energy Laboratory’s H2Integrate tool, which simulates hybrid energy system performance profiles and costs. This integrated framework is designed to provide system-level insights while maintaining computational efficiency and flexibility for scenario exploration. Initial evaluations show similar results to those predicted by the industry, and demonstrate how a given plant could function with variable power in different deployment locations, such as with wind energy off the coast of Texas and with wind and wave energy off the coast of Oregon. The results suggest that electrochemical systems with greater tolerances for power variability and low minimum power requirements may offer operational advantages in variable-energy contexts. However, further research is needed to quantify these benefits and evaluate their implications across different deployment scenarios.

16 TIDAL AND WAVE POWER↗

Advancing an integrated understanding of land–ocean connections in shaping the marine ecosystems of coastal temperate rainforest ecoregions

Land and ocean ecosystems are strongly connected and mutually interactive. As climate changes and other anthropogenic stressors intensify, the complex pathways that link these systems will strengthen or weaken in ways that are currently beyond reliable prediction. In this review we offer a framework of land–ocean couplings and their role in shaping marine ecosystems in coastal temperate rainforest (CTR) ecoregions, where high freshwater and materials flux result in particularly strong land–ocean connections. Using the largest contiguous expanse of CTR on Earth—the Northeast Pacific CTR (NPCTR)—as a case study, we integrate current understanding of the spatial and temporal scales of interacting processes across the land–ocean continuum, and examine how these processes structure and are defining features of marine ecosystems from nearshore to offshore domains. We look ahead to the potential effects of climate and other anthropogenic changes on the coupled land–ocean meta-ecosystem. Finally, we review key data gaps and provide research recommendations for an integrated, transdisciplinary approach with the intent to guide future evaluations of and management recommendations for ongoing impacts to marine ecosystems of the NPCTR and other CTRs globally. In the light of extreme events including heatwaves, fire, and flooding, which are occurring almost annually, this integrative agenda is not only necessary but urgent.

54 ENVIRONMENTAL SCIENCES↗

Ocean circulation and climate variability in the northern South China Sea during the Greek Minimum derived from coral Δ 14 C and Sr/Ca records

Ocean circulation transports heat, salt and nutrients, and has profound impacts on the marine environment and climate change. However, the seasonal to centennial variations of the paleocirculation of the South China Sea (SCS) and their driving forces are still unclear due to limited records. Here we reconstructed a high-resolution Δ 14 C record of a coral from Sanya to investigate the seasonal variations of the SCS ocean circulation around 2300 cal yr BP during a grand solar minimum (GSM) period. The seasonal Δ 14 C variability shows the influence of coastal upwelling caused by the East Asian Summer Monsoon (EASM) in summer and the effect of water intrusion from the western Pacific Ocean driven by the Kuroshio Intrusion (KI) in winter. Here we compiled the marine radiocarbon reservoir correction (ΔR) records since 2500 cal yr BP, which indicate a gradual decrease of upwelling significantly correlated with the EASM. Comparisons with other climate records suggest that both the EASM and KI may regulate the ocean circulation variability on centennial time scales. As a good index of the sea surface temperature (SST), our Sr/Ca record and spectral analysis results show a low temperature and a low frequency of El Niño-Southern Oscillation (ENSO) events around 2300 cal yr BP. Moreover, the composite coral Sr/Ca-SST and ENSO index records since 2500 cal yr BP show relatively low SST and weak ENSO during GSMs, supporting the modulation of tropical SST and ENSO by solar activity. Our study has provided high-resolution proxy data and revealed the driving forces of ocean circulation and climate change in the SCS at multiple time scales, which should be considered in further modeling work.

54 ENVIRONMENTAL SCIENCES↗

Non-Synchronous Rotation on Europa Driven by Ocean Currents

It has been suggested that the ice shell of Jupiter's moon Europa may drift non-synchronously due to tidal torques. Here we argue that torques applied by the underlying ocean are also important and can result in non-synchronous rotation. The resulting spin rate can be slightly slower than the synchronous angular rate that would have kept the same point of the ice shell facing Jupiter. We develop an ice shell rotation model, driven by ocean stress calculated using a high-resolution state-of-the-art ocean general circulation model, and take into account the viscoelastic deformation of the ice shell. We use the ice shell model results together with observed limits on the ice shell drift speed to constrain ice shell parameters such as effective viscosity, which is currently uncertain by at least four orders of magnitude. Our results suggest, at best, sluggish ice shell convection. Depending on the relaxation time scale of the ice shell and on the ocean currents, the ice shell may exhibit negligible drift, constant drift, or oscillatory drift superimposed on random fluctuations. The expected rotation rate exceeds ~30 m/yr; future spacecraft observations can be used to test these predictions and yield insight into the properties of the ice shell and underlying ocean.

15 GEOTHERMAL ENERGY↗

The Association Between Cloud Droplet Number over the Summer Southern Ocean and Air Mass History

The cloud properties and governing processes in Southern Ocean marine boundary layer clouds have emerged as a central issue in understanding the Earth's climate sensitivity. While our understanding of Southern Ocean cloud feedbacks have evolved in the most recent climate model intercomparison, the background properties of simulated summertime clouds in the Southern Ocean are not consistent with measurements due to known biases in simulating cloud condensation nuclei concentrations. This paper presents several case studies collected during the Capricorn 2 and Marcus campaigns held aboard Australian research vessels in the Austral Summer of 2018. Combining the surface–observed cases with MODIS data along forward and backward air mass trajectories, we demonstrate the evolution of cloud properties with time. These cases are consistent with multi–year statistics showing that long trajectories of air masses over the Antarctic ice sheet are critical to creating high droplet number clouds in the high latitude summer Southern Ocean. We speculate that secondary aerosol production via the oxidation of biogenically derived aerosol precursor gasses over the high actinic flux region of the high latitude ice sheets is fundamental to maintaining relatively high droplet numbers in Southern Ocean clouds during Summer.

54 ENVIRONMENTAL SCIENCES↗

Observed declines in upper ocean phosphate-to-nitrate availability

Climate warming is increasing ocean stratification, which in turn should decrease the nutrient flux to the upper ocean. This may slow marine primary productivity, causing cascading effects throughout food webs. However, observing changes in upper ocean nutrients is challenging because surface concentrations are often below detection limits. We show that the nutricline depth, where nutrient concentrations reach well-detected levels, is tied to productivity and upper ocean nutrient availability. Next, we quantify nutricline depths from a global database of observed vertical nitrate and phosphate profiles to assess contemporary trends in global nutrient availability (1972–2022). We find strong evidence that the P-nutricline (phosphacline) is mostly deepening, especially throughout the southern hemisphere, but the N-nutricline (nitracline) remains mostly stable. Earth System Model (ESM) simulations support the hypothesis that reduced iron stress and increased nitrogen fixation buffer the nitracline, but not phosphacline, against increasing stratification. These contemporary trends are expected to continue in the coming decades, leading to increasing phosphorus but not nitrogen stress for marine phytoplankton, with important ramifications for ocean biogeochemistry and food web dynamics.

54 ENVIRONMENTAL SCIENCES↗