Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “mixing index”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8

Identification of Absorbing Aerosol Types at a Site in the Northern Edge of Indo-Gangetic Plain and a Polluted Valley in the Foothills of the Central Himalayas

Identification of atmospheric aerosol types and characterization of absorbing aerosols, based on AErosol RObotic NETwork (AERONET) data collected during 2013–2014 over two sites in Nepal: Lumbini in the northernmost part of central Indo-Gangetic Plain (IGP) and Kathmandu Valley in foothills of the central Himalayas, have been conducted in the present study. The relationship between four aerosol parameters; Extinction Angstrom Exponent (EAE), Absorption Angstrom Exponent (AAE), Single Scattering Albedo (SSA) and Real Refractive Index (RRI) was analyzed to study the aerosol types. This resulted in the identification of two types of aerosols concerning their origin: biomass burning and urban/industrial mix. Furthermore, to understand the absorbing aerosol types, the relationship between aerosol size parameters; Fine Mode Fraction (FMF) and Angstrom Exponent (AE), and aerosol absorption characteristics; SSA and AAE were investigated. In regards to the absorbing aerosol types, ‘Mostly BC’ was the dominant absorbing aerosol, over both sites, with comparatively negligible contribution from other absorbing aerosol types such as dust. The aerosol subtypes obtained from satellite-borne CALIPSO instrument supported the results derived from the AERONET data. The CALIPSO images also indicated that the aerosols over the foothills of the Himalayas could extend to the height of >5 km above the ground, which could be transported towards the Himalayan and Tibetan Plateau (HTP) region with sensitive ecosystems. The multi-sites based study of long-term records is required to elucidate the nature and trends of aerosols in the HTP region and any perturbation to the atmospheric environment and other environments in this region.

Aerosol types↗

Exciton effects in the index of refraction of multiple quantum wells and superlattices

Theoretical calculations of the index of refraction of multiple quantum wells and superlattices are presented. The model incorporates both the bound and continuum exciton contributions for the gamma region transitions. In addition, the electronic band structure model has both superlattice and bulk alloy properties. The results indicate that large light-hole masses, i.e., of about 0.23, produced by band mixing effects, are required to account for the experimental data. Furthermore, it is shown that superlattice effects rapidly decrease for energies greater than the confining potential barriers. Overall, the theoretical results are in very good agreement with the experimental data and show the importance of including exciton effects in the index of refraction.

Kahen, K. B.↗

Developing an Energy-Conscious Traffic Signal Control System for Optimized Fuel Consumption in Connected Vehicle Environments

The project titled “Developing an Energy-Conscious Traffic Signal Control System for Optimized Fuel Consumption in Connected Vehicle Environments” addresses energy-related challenges associated with adaptive traffic control systems by integrating connected vehicles (CV) and connected infrastructure (CI). The system developed in this project, a CV-based adaptive traffic control system, aims to improve fuel consumption in mixed traffic environments by capitalizing on emerging CV and CI communication technologies, as well as leveraging recent advances in Artificial Intelligence (AI), optimization, and edge computing. The system was tested at the MLK Smart Corridor, an urban testbed managed by the University of Tennessee at Chattanooga (UTC) and the City of Chattanooga. The system was validated through extensive simulations, both Software-in-the-Loop (SILS) and Hardware-in-the-Loop (HILS), and was further implemented and tested in real-world conditions at several intersections along the corridor. The Fuel Consumption Performance Index (FC-PI) and the Ecological Performance Index (Eco-PI) were developed as the key components for evaluating the system’s impact on fuel consumption and emissions. These metrics provided a comprehensive means of understanding the impact of traffic signal control optimization in mixed traffic environments. The report presents an in-depth analysis of the Eco-PI, FC-PI, adaptive traffic control system integration, and the testing and field implementation of the system. The results demonstrate significant reductions in fuel consumption and emissions, showcasing the system’s capability to contribute to more sustainable urban traffic management. The report also documents the challenges encountered and recommendations for scaling and further improving the system.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Soil fertility and drought interact to determine large variations in wood production for a hyperdominant Amazonian tree species

The productivity of the Amazon Rainforest is related to climate and soil fertility. However, the degrees to which these interactions influence multiannual to decadal variations in tree diameter growth are still poorly explored. To fill this gap, we used radiocarbon measurements to evaluate the variation in tree growth rates over the past decades in an important hyperdominant species, Eschweilera coriacea (Lecythidaceae), from six sites in the Brazilian Amazon that span a range of soil properties and climate. Using linear mixed-effects models, we show that temporal variations in mean annual diameter increment evaluated over a specific time period reflect interactions between soil fertility and the drought index (SPEI-Standardized Precipitation and Evapotranspiration Index). Our results indicate that the growth response of trees to drought is strongly dependent on soil conditions, a facet of forest productivity that is still underexplored, and which has great potential for improving predictions of future tropical tree growth in the face of projected climate change.

54 ENVIRONMENTAL SCIENCES↗

On the growth of Hg2Cl(1-x)2Br(x2) single crystals

Single crystals of mixed mercurous halides Hg2X2 (where X = Cl and Br) were grown by the physical vapor transport process. Structural parameters and optical properties were determined to examine the suitability of mixed crystals for acoustooptic devices. Mixed crystals grown in the low concentration region did not show striations or banding. Crystals grown in the high concentration region showed considerable inhomogeneity in the refractive index. Since we had used identical thermal conditions, inhomogeneity was attributed to the solutal convection caused by the difference in densities of mercurous chloride and bromide vapors. A low concentration of dopant did not change the acoustic velocity of the parent components.

Singh, N. B.↗

Seasonal Variability of Saturn's Tropospheric Temperatures, Winds and Para-H2 from Cassini Far-IR Spectroscopy

Far-IR 16-1000 micrometer spectra of Saturn's hydrogen-helium continuum measured by Cassini's Composite Infrared Spectrometer (CIRS) are inverted to construct a near-continuous record of upper tropospheric (70-700 mbar) temperatures and para-H2 fraction as a function of latitude, pressure and time for a third of a saturnian year (2004-2014, from northern winter to northern spring). The thermal field reveals evidence of reversing summertime asymmetries superimposed onto the belt/zone structure. The temperature structure is almost symmetric about the equator by 2014, with seasonal lag times that increase with depth and are qualitatively consistent with radiative climate models. Localised heating of the tropospheric hazes (100-250 mbar) create a distinct perturbation to the temperature profile that shifts in magnitude and location, declining in the autumn hemisphere and growing in the spring. Changes in the para-H2 (f(sub p)) distribution are subtle, with a 0.02-0.03 rise over the spring hemisphere (200-500 mbar) perturbed by (i) low-f(sub p) air advected by both the springtime storm of 2010 and equatorial upwelling; and (ii) subsidence of high-f(sub p) air at northern high latitudes, responsible for a developing north-south asymmetry in f(sub p). Conversely, the shifting asymmetry in the para-H2 disequilibrium primarily reflects the changing temperature structure (and hence the equilibrium distribution of f(sub p)), rather than actual changes in f(sub p) induced by chemical conversion or transport. CIRS results interpolated to the same point in the seasonal cycle as re-analysed Voyager-1 observations (early northern spring) show qualitative consistency from year to year (i.e., the same tropospheric asymmetries in temperature and f(sub p)), with the exception of the tropical tropopause near the equatorial zones and belts, where downward propagation of a cool temperature anomaly associated with Saturn's stratospheric oscillation could potentially perturb tropopause temperatures, para-H2 and winds. Quantitative differences between the Cassini and Voyager epochs suggest that the oscillation is not in phase with the seasonal cycle at these tropospheric depths (i.e., it should be described as quasi-periodic rather than 'semi annual'). Variability in the zonal wind field derived from latitudinal thermal gradients is small (less than 10 m/s per scale height near the tropopause) and mostly affects the broad retrograde jets, with the notable exception of large variability on the northern flank of the equatorial jet. The meridional potential vorticity (PV) gradient, and hence the 'staircase of PV' associated with spatial variations in the vigour of vertical mixing, has varied over the course of the mission but maintained its overall shape. PV gradients in latitude and altitude are used to estimate the atmospheric refractive index for the propagation of stationary planetary (Rossby) waves, predicting that such wave activity would be confined to regions of real refractivity (tropical regions plus bands at 35-45 in both hemispheres). The penetration depth of these regions into the upper troposphere is temporally variable (potentially associated with stratification changes), whereas the latitudinal structure is largely unchanged over time (associated with the zonal jet system).

Fletcher, Leigh N.↗

"We Burn to Learn" About Fuel-Air Mixing Within Aircraft Powerplants

I am working with my branch s advanced diagnostics team to investigate fuel-air mixing in jet-fueled gas turbine combustors and jet-fuel reformers. Our data acquisition begins with bench-top experiments which will help with calibration of equipment for facility testing. While conducting the bench-top experiments I learned to align laser and optical equipment to collect data, to use the data acquisition software, and to process the data into graphs and images. which jet he1 is to be reformed into hydrogen. Testing will commence shortly, after which we will obtain and analyze data and meet a critical milestone for the end of September. I am also designing the layout for a Schlieren system that will be used during that time frame. A Schlieren instrument records changes in the refractive index distribution of transparent media like air flows. The refractive index distribution can then be related to density, temperature, or pressure distributions within the flow. I am working on a scheme to quantify this information and add to the knowledge of the fuel-air mixing process.

Robinson, Heidi N.↗

Streaming Instability with Multiple Dust Species – II. Turbulence and Dust–Gas Dynamics at Non-Linear Saturation

The streaming instability is a fundamental process that can drive dust–gas dynamics and ultimately planetesimal formation inprotoplanetary discs. As a linear instability, it has been shown that its growth with a distribution of dust sizes can be classifiedinto two distinct regimes, fast- and slow-growth, depending on the dust-size distribution and the total dust-to-gas density ratio. Using numerical simulations of an unstratified disc, we bring three cases in different regimes into non-linear saturation. Wefind that the saturation states of the two fast-growth cases are similar to its single-species counterparts. The one with maximumdimensionless stopping timeτs,max=0.1 and=2 drives turbulent vertical dust–gas vortices, while the other withτs,max=2and=0.2 leads to radial traffic jams and filamentary structures of dust particles. The dust density distribution for the former isflat in low densities, while the one for the latter has a low-end cut-off. By contrast, the one slow-growth case results in a virtuallyquiescent state. Moreover, we find that in the fast-growth regime, significant dust segregation by size occurs, with large particlesmoving towards dense regions while small particles remain in the diffuse regions, and the mean radial drift of each dust speciesis appreciably altered from the (initial) drag-force equilibrium. The former effect may skew the spectral index derived frommultiwavelength observations and change the initial size distribution of a pebble cloud for planetesimal formation. The latteralong with turbulent diffusion may influence the radial transport and mixing of solid materials in young protoplanetary discs.

Chao-chin Yang↗

Direct Optical Lithography of Colloidal Metal Oxide Nanomaterials for Diffractive Optical Elements with 2π Phase Control

Spatially patterned dielectric materials are ubiquitous in electronic, photonic, and optoelectronic devices. These patterns are typically made by subtractive or additive approaches utilizing vapor-phase reagents. On the other hand, recent advances in solution-phase synthesis of oxide nanomaterials have unlocked a materials library with greater compositional, microstructural, and interfacial tunability. However, methods to pattern and integrate these nanomaterials in real-world devices are less established. In this work, we directly optically pattern oxide nanoparticles (NPs) by mixing them with photosensitive diazo-2-naphthol-4-sulfonic acid and irradiating with widely available 405 nm light. We demonstrate the direct optical lithography of ZrO 2 , TiO 2 , HfO 2 , and ITO NPs and investigate the chemical and physical changes responsible for this photoinduced decrease in solubility. Micron-thick layers of amorphous ZrO 2 NPs were patterned with micron resolution and shown to allow 2 pi phase control of visible light. We also show multilayer patterning and use it to fabricate features with different thicknesses and distinct structural colors. Upon annealing at 400 degrees C, the deposited ZrO 2 structures have excellent optical transparency across a wide wavelength range (0.3-10 mu m), a high refractive index (n = 1.84 at 633 nm), and are optically smooth. We then fabricate diffractive optical elements, such as binary phase diffraction gratings, that show efficient diffractive behavior and good thermal stability. Different oxide NPs can also be mixed prior to patterning, providing a high level of material tunability. This work demonstrates a general patterning approach that harnesses the processability and diversity of colloidal oxide nanomaterials for use in photonic applications.

2𝜋 phase shift↗

RSP Data Status, Updates and Plans from the Team

•All radiance (L1C), aerosol and cloud (L2) products are in the archive. •Revised calibration performed at GSFC in July 2021 applied to reprocessing. •Clouds have smaller drops and higher optical depths (larger droplet number concentrations) in winter than in summer. Cloud top droplet size distributions tend to be narrow with roughly 80% having an effective variance of less than 0.07. This is relevant to how well bulk auto-conversion parameterizations are likely to work at cloud top (order of magnitude effects) and also to assumptions used in the remote sensing of droplet number (~ 10% effect). Real refractive index and effective radius retrievals are consistent with hygroscopic growth of aerosols Real refractive index and effective variance retrievals imply the presence of an insoluble fraction of aerosols Future work on clouds will look at differences in cloud top drizzle formation and auto-conversion rates between the different campaigns and at how well mixed phase clouds can be detected (if at all) from sensors such as VIIRS and PACE OCI.

Research Scanning Polarimeter↗

Chemical mixture exposure patterns and obesity among U.S. adults in NHANES 2005–2012

The effect of chemical exposure on obesity has raised great concerns. Real-world chemical exposure always imposes mixture impacts, however their exposure patterns and the corresponding associations with obesity have not been fully evaluated. To discover obesity-related mixed chemical exposure patterns in the general U.S. population. Sparse Decompositional Regression (SDR), a model adapted from sparse representation learning technique, was developed to identify exposure patterns of chemical mixtures with exclusion (non-targeted model) and inclusion (targeted model) of health outcomes. We assessed the relationships between the identified chemical mixture patterns and obesity-related indexes. We also conducted a comprehensive evaluation of this SDR model by comparing to the existing models, including generalized linear regression model (GLM), principal component analysis (PCA), and Bayesian kernel machine regression (BKMR). Eight core exposure patterns were identified using the non-targeted SDR model. Patterns of high levels of MEP, high levels of naphthalene metabolites (ΣOH-Nap), and a pattern of high exposure levels of MCOP, MCNP, and MCPP were positively associated with obesity. Patterns of high levels of BP3, and a pattern of higher mixed levels of MPB, PPB, and MEP were found to have negative associations. Associations were strengthened using the targeted SDR model. In the single chemical analysis by GLM, BP3, MBP, PPB, MCOP, and MCNP showed significant associations with obesity or body indexes. The SDR model exceeded the performance of PCA in pattern identification. Both SDR and BKMR identified a positive contribution of ΣOH-Nap and MCOP, as well as a negative contribution of BP3 and PPB to obesity. Our study identified five core exposure patterns of chemical mixtures significantly associated with obesity using the newly developed SDR model. The SDR model could open a new avenue for assessing health effects of environmental mixture contaminants.

54 ENVIRONMENTAL SCIENCES↗

An efficient explicit implementation of a near-optimal quantum algorithm for simulating linear dissipative differential equations

We propose an efficient block-encoding technique for the implementation of the Linear Combination of Hamiltonian Simulations (LCHS) for simulating dissipative initial-value problems. This algorithm approximates a target nonunitary operator as a weighted sum of Hamiltonian evolutions, thereby emulating a dissipative problem by mixing various time scales. We introduce an efficient encoding of the LCHS into a quantum circuit based on a simple coordinate transformation that turns the dependence on the summation index into a trigonometric function. Classically, this method is equivalent to the use of a highly accurate Fejér-Clenshaw-Curtis quadrature formula. Quantumly, this significantly simplifies block-encoding of a dissipative problem and allows one to perform an exponential number of Hamiltonian simulations by a single Quantum Signal Processing (QSP) circuit. The resulting LCHS circuit has high success probability and the selector scales logarithmically with the number of terms in the LCHS sum and linearly with time. Careful analysis of error convergence proves that this method is more efficient than other LCHS circuits that have recently appeared in the literature. We verify the quantum circuit and its scaling by simulating it on a digital emulator of fault-tolerant quantum computers and, as a test problem, solve the advection-diffusion equation. The proposed algorithm can be used for simulating a wide class of nonunitary initial-value problems including the Liouville equation with added dissipation and linear embeddings of nonlinear systems, such as the Koopman-von Neumann and Carleman embeddings.

Novikau, I [Lawrence Livermore National Laboratory↗

Navigating thermal stability intricacies of high-nickel cathodes for high-energy lithium batteries

High-nickel oxide cathodes, LiNi x M 1−x O 2 (x ≥ 0.8), are preferred in automotive lithium batteries, but they face thermal instability challenges. Inconsistent literature reports and unstandardized testing protocols further complicate quantitative assessments of the thermal stability of these cathodes. Here, we present here a statistical thermal analysis based on the differential scanning calorimetry measurements of 15 representative cathode materials with different compositions, morphologies and states of charge. The findings reveal that each cathode has a critical state of charge that defines its safe operating limit, which is affected by the metal–oxygen bond strength and surface reactivity. The thermal runaway temperature is dictated by the layered Li 1−x NiO 2 to LiNi 2 O 4 spinel-like phase transition, which is thermodynamically determined by the metal–oxygen bond covalency and kinetically influenced by the cation mixing and particle size. Raman spectroscopy is used to predict the thermal runaway temperature on the basis of the linear relationship between them. Finally, we propose a thermal stability index to quantify cathode thermal stability as a guide for developing safer high-nickel cathodes.

batteries↗

Infrared fiber optic focal plane dispersers

Far infrared transmissive fiber optics as a component in the design of integrated far infrared focal plane array utilization is discussed. A tightly packed bundle of fibers is placed at the focal plane, where an array of infrared detectors would normally reside, and then fanned out in two or three dimensions to individual detectors. Subsequently, the detectors are multiplexed by cryogenic electronics for relay of the data. A second possible application is frequency up-conversion (v sub 1 + v sub 2 = v sub 3), which takes advantage of the nonlinear optical index of refraction of certain infrared transmissive materials in fiber form. Again, a fiber bundle is utilized as above, but now a laser of frequency v sub 1 is mixed with the incoming radiation of frequency v sub 1 within the nonlinear fiber material. The sum, v sub 2 is then detected by near infrared or visible detectors which are more sensitive than those available at v sub 2. Due to the geometrical size limitations of detectors such as photomultipliers, the focal plane dispersal technique is advantageous for imaging up-conversion.

Goebel, J. H.↗

A geometric nonlinear degenerated shell element using a mixed formulation with independently assumed strain fields

A mixed formulation is chosen to overcome deficiencies of the standard displacement-based shell model. Element development is traced from the incremental variational principle on through to the final set of equilibrium equations. Particular attention is paid to developing specific guidelines for selecting the optimal set of strain parameters. A discussion of constraint index concepts and their predictive capability related to locking is included. Performance characteristics of the elements are assessed in a wide variety of linear and nonlinear plate/shell problems. Despite limiting the study to geometric nonlinear analysis, a substantial amount of additional insight concerning the finite element modeling of thin plate/shell structures is provided. For example, in nonlinear analysis, given the same mesh and load step size, mixed elements converge in fewer iterations than equivalent displacement-based models. It is also demonstrated that, in mixed formulations, lower order elements are preferred. Additionally, meshes used to obtain accurate linear solutions do not necessarily converge to the correct nonlinear solution. Finally, a new form of locking was identified associated with employing elements designed for biaxial bending in uniaxial bending applications.

Graf, Wiley E.↗

The ultrafast Kerr effect in anisotropic and dispersive media

The ultrafast optical Kerr effect (OKE) is widely used to investigate the structural dynamics and interactions of liquids, solutions, and solids by observing their intrinsic nonlinear temporal responses through nearly collinear four-wave mixing. Non-degenerate mixing schemes allow for background free detection and can provide information on the interplay between a material’s internal degrees of freedom. Here, we show a source of temporal dynamics in the OKE signal that is not reflective of the internal degrees of freedom but arises from a group index and momentum mismatch. It is observed in two-color experiments on condensed media with sizable spectral dispersion, a common property near an optical resonance. In particular, birefringence in crystalline solids is able to entirely change the character of the OKE signal via the off-diagonal tensor elements of the nonlinear susceptibility. We develop a detailed description of the phase-mismatched ultrafast OKE and show how to extract quantitative information on the spectrally resolved birefringence and group index from time-resolved experiments in one and two dimensions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Microwave boundary conditions on the atmosphere and clouds of Venus

The dielectric properties of H2O/H2SO4 mixtures are deduced from the Debye equations and, for a well-mixed atmosphere, the structure of H2O and H2O/H2SO4 clouds is calculated. Various data on the planet together set an upper limit on the mixing ratio by number for H2O of about 0.001 in the lower Venus atmosphere, and for H2SO4 of about 0.00001. The polarization value of the real part of the refractive index of the clouds, the spectroscopic limits on the abundance of water vapor above the clouds, and the microwave data together set corresponding upper limits on H2O of approximately 0.0002 and on H2SO4 of approximately 0.000009. Upper limits on the surface density of total cloud constituents and of cloud liquid water are, respectively, about 0.1 g/sq cm and about 0.01 g/sq cm. The infrared opacities of 90 bars of CO2, together with the derived upper limits to the amounts of water vapor and liquid H2O/H2SO4, may be sufficient to explain the high surface temperatures through the greenhouse effect.

Rossow, W. B.↗

Shock experiments on maskelynite-bearing anorthosite

A series of shock recovery experiments over 9.9-60.4 GPa have been carried out on naturally shocked anorthosite from the Mistastin impact structure in Labrador consisting primarily of diaplectic plagioclase glass or maskelynite, An(50), and pyroxene. Petrographic observations of the experimental products indicate that the component minerals and diaplectic glasses generally retained their initial character throughout, the only exception being the increase in fracturing which occurred in the 9.9 GPa shot. Reshocking at pressures higher than the initial shock tends to lower the refractive index of maskelynite. The increase in refractive index of maskelynite reshocked to pressures lower than the initial pressure is interpreted as due to shock densification of the diaplectic glass above the Hugoniot elastic limit and below the mixed phase regime. The data suggest that the low-high-low density transition of maskelynite occurs about 8 GPa below that of the crystal of corresponding composition.

Lambert, P.↗