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At least 145 records · Page 8

Cyclic and isothermal oxidation behavior on some Ni-Cr alloys

It is shown experimentally that 3 wt.% Si and 3 wt.% Mn additions can substantially improve the oxidation resistance of Ni-20Cr under both isothermal and cyclic conditions at 1100 and 1200 C. This is especially true in cyclic oxidation. In all cases, Si offers a greater improvement than Mn; however, the advantage of Si is substantial only during cyclic oxidation at 1200 C. The Si additions which lead to alloys of improved oxidation resistance suppress the formation of NiO and NiCr2O4 even under the most severe test conditions. The mechanism of improvement afforded by Mn appears to be the formation of MnCr2O4 at the expense of NiO and NiCr2O4.

Lowell, C. E.↗

Isothermal elastohydrodynamic lubrication of point contacts. 1: Theoretical formulation

The isothermal elastohydrodynamic lubrication (EHL) of a point contact was analyzed numerically by simultaneously solving the elasticity and Reynolds equations. In the elasticity analysis the contact zone was divided into equal rectangular areas, and it was assumed that a uniform pressure was applied over each area. In the numerical analysis of the Reynolds equation, a phi analysis (where phi is equal to the pressure times the film thickness of the 3/2 power) was used to help the relaxation process. The EHL point contact analysis is applicable for the entire range of elliptical parameters and is valid for any combination of rolling and sliding within the contact.

Hamrock, B. J.↗

Comparison of sonic boom minimization results in real and isothermal atmospheres

The method of Seebass and George (1972, 1974) for minimizing certain features of the pressure signature and yielding the corresponding F function and equivalent area distribution A in an isothermal atmosphere is modified to provide the same capability for a real atmosphere. The appropriate equations of George and Plotkin (1969) describing horizontal advance, ray tube area, and signature propagation are used.

Darden, C. M.↗

Comparison of isothermal and cyclic oxidation behavior of twenty-five commercial sheet alloys at 1150 C

Twenty-five commercial nickel-, iron-, and cobalt-base sheet alloys incorporating chromium or chromium and aluminum additions for oxidation resistance were tested at 1150 C in air for 100 hr in both isothermal and 1-hr cyclic furnace exposures. The alloys were evaluated by sample specific weight change, by type of scale formed, by amount and type of spall, and by sample thickness change and microstructure.-

Barrett, C. A.↗

Isothermal elastohydrodynamic lubrication of point contacts. 2: Ellipticity parameter results

A numerical solution of the isothermal elastohydrodynamic problem for point contacts is presented which reproduces all the essential features of experimental observations based upon optical interferometry. In particular, the two side lobes, in which minimum film thickness regions occur, emerge in the theoretical solutions. The influence of the ellipticity parameter on solutions to the point contact problem is explored. The ellipticity parameter k was varied from 1 (a ball on a plate) to 8 (a configuration approaching line contact). It is shown that the minimum film thickness can be related to the well known line contact solutions by a remarkably simple expression involving either k or the effective radius of curvature ratio R sub y/R sub x.

Hamrock, B. J.↗

Isothermal elastohydrodynamic lubrication of point contacts. II - Ellipticity parameter results

A numerical solution of the isothermal elastohydrodynamic problem for point contacts has been presented which reproduces all the essential features of the previously reported experimental observations based upon optical interferometry. In particular, the two 'side lobes' in which minimum film thickness regions occur are shown to emerge in the theoretical solutions. The influence of the ellipticity parameter upon solutions to the point contact problem has been explored in the present paper. The ellipticity parameter (k) was varied from one (a ball on a plate) to eight (a configuration approaching line contact), and it has been shown that both the central and minimum film thicknesses can be related to the well known line contact solutions by remarkably simple expressions involving either (k) or the effective radius of curvature ratio (Ry/Rx).

Hamrock, B. J.↗

Isothermal elastohydrodynamic lubrication of point contacts. I - Theoretical formulation

The analysis of an isothermal elastohydrodynamic lubrication (EHL) point contact was evaluated numerically. This required the simultaneous solution of the elasticity and Reynolds equations. In the elasticity analysis the contact zone is divided into equal rectangular areas and it is assumed that a uniform pressure is applied over each element. In the numerical analysis of the Reynolds' equation a phi analysis where phi is equal to the pressure times the film thickness to the 3/2 power is used to help the relaxation process. The EHL point contact analysis is applicable for the entire range of elliptical parameters and is valid for any combination of rolling and sliding within the contact.

Hamrock, B. J.↗

Diffusive isothermal partitioning in a layered medium with geologic applications

The diffusive isothermal partitioning of solute in a layered two-phase material has been analyzed to help elucidate the phenomenon of solute partitioning in multiphase lunar and terrestrial materials and to estimate the cooling history of samples. After reviewing the physical chemistry of partitioning and the case of an infinite one-dimensional diffusion couple, we solve in analytic form the case of a finite one-dimensional couple. The solution can be used to estimate cooling histories or to interpret laboratory experiments on partitioning. A sample calculation is included.

Hopper, R. W.↗

Diffraction calculation of occultation light curves in the presence of an isothermal atmosphere

From diffraction theory, light curves are calculated for stellar occultations by a planetary body with an isothermal atmosphere. The character of the resulting curves is determined by the scale height H, the Fresnel zone size l, the surface atmospheric refractivity, and the planetary radius. An exact general solution and two approximations are presented which are valid when H is much greater than l. The importance is assessed of accounting for diffraction effects of the limb when deducing atmospheric parameters from occultation light curves

French, R. G.↗

Isothermal elastohydrodynamic lubrication of point contacts. III - Fully flooded results

Procedures outlined by the authors in an earlier publication (1976) on theoretical formulation for isothermal elastohydrodynamic lubrication of point contacts are used to assess the influence of the ellipticity parameter and the dimensionless speed, load, and material parameters on minimum film thickness. Conditions equivalent to using solid materials of bronze, steel, and silicon nitride, and lubricants of paraffinic and naphthenic mineral oils are considered in obtaining the exponent on the dimensionless material parameter. Thirty-four different cases are used to generate the fully flooded film thickness formula. A fully flooded condition is said to exist when the inlet distance of the conjunction ceases to influence in any significant way the minimum film thickness. Contour plots are also shown that indicate in detail the pressure spike and two side lobes in which the minimum film thickness occurs.

Hamrock, B. J.↗

Isothermal elastohydrodynamic lubrication of point contacts. IV - Starvation results

Previously developed basic theory for isothermal elastohydrodynamic lubrication of point contacts is used to study the effect of lubricant starvation on pressure and film thickness within the conjunction. A simple expression for the dimensionless inlet boundary distance is derived. This inlet boundary distance defines whether a fully flooded or a starved condition exists in the contact. Simple expressions for the minimum and central film thickness under starvation condition are presented. Contour plots of pressure and film thickness in and around the contact are shown in order to gain a better insight into what occurs in going from fully flooded to lubricant starvation condition. Theoretical predictions are compared with earlier results.

Hamrock, B. J.↗

Isothermal degradation of poly-2,2'-/m-phenylene/-5,5'-bibenzimidazole

The isothermal degradation of poly-2,2'-(m-phenylene)-5,5'-bibenzimidazole in vacuo has been studied. Measurement of the increase in pressure with time, coupled with infrared analysis, was used to determine the distribution of the degradation products. Processes A and B with different second-order rate laws were determined to be significant in the temperature range of 550-700 C. Process A leads to the formation of equimolar quantities of hydrogen and ammonia and has an activation energy of 68 kcal/mole. Process B leads to the production of HCN, NH3, and H2 in the ratio of 1:1:2.5 and has an activation energy of 77 kcal/mole. The activation energies and the rate laws are consistent with a mechanism in which the initial degradation step is the bimolecular reaction of two aromatic rings.

Lerner, N. R.↗

Friction factor for isothermal and nonisothermal flow through porous media

Measurements were performed to determine the pressure drops for gaseous flow through porous materials of different microstructures, porosities, and thickness under isothermal and nonisothermal conditions at various temperature levels. Results were satisfactorily correlated by a simple equation relating the friction factor to the Reynolds number and porosities.

Koh, J. C.↗

The isothermal dust condensation of Nova Vulpeculae 1976

Nova Vulpeculae 1976 has been followed with broad-band photometry at wavelengths of 0.5 to 12.5 microns from day 3 to day 235. Three definite phases are identified. They are expanding pseudophotosphere, free-free expansion, and dust condensation. A very long (day 80 to day 220) period of isothermal infrared emission (temperature approximately 900 K) is accompanied by an exponential decrease in infrared luminosity and is interpreted in terms of continuous mass ejection in the nova wind.

Ney, E. P.↗

Full-coverage film cooling on flat, isothermal surfaces: Data and predictions

The heat transfer and fluid mechanics characteristics of full-coverage film cooling were investigated. The results for flat, isothermal plates for three injection geometries (normal, slant, and compound angle) are summarized and data concerning the spanwise distribution of the heat transfer coefficient within the blowing region are presented. Data are also presented for two different numbers of rows of holes (6 and 11). The experimental results summarized can be predicted with a two dimensional boundary layer code, STANCOOL, by providing descriptors of the injection parameters as inputs.

Crawford, M. E.↗

Effects of isothermal and cyclic exposures on interface structure and mechanical properties of FPalpha-Al2O3/aluminum composites

The microstructural and interface stability of FPalpha-Al203/Al-Li composites are investigated as a function of isothermal exposure at 500 C or thermal cycling between 140 and 500 C with hold time at Tmax. Interfacial morphology, growth kinetics, crystal structure, and composition of interfacial reaction products are characterized. Strength is monitored in the transverse orientation, and fracture mechanics is analyzed in terms of interface reaction products. The interfacial reaction product in FP/Al is Li2O.5Al2O3. Significant fiber-matrix reaction occurs during fabrication. The number of thermal cycles rather than total time at Tmax is the determining factor in strength degradation, thermal cycling giving rise to voids at the fiber-matrix interface. Extensive interface failures occur at composite fracture stresses below about 128 MPa; above this stress level failure is attributed to ductile matrix fracture.

Kim, W. M.↗

Isothermal-desorption-rate measurements in the vicinity of the Curie temperature for H2 chemisorbed on nickel films

Measurements of the isothermal desorption rate of H2 chemisorbed onto polycrystalline nickel films made for temperatures spanning the Curie temperature of the nickel film are presented. Desorption kinetics were followed by measuring the decay of the change in resistance of the nickel film brought about by hydrogen chemisorption after gas-phase H2 had been rapidly evacuated. The desorption rate is found to undergo an anomalous decrease in the vicinity of the Curie temperature, accompanied by an increase in the desorption activation energy and the equilibrium constant for the chemisorbed hydrogen. The results are interpreted in terms of anomalous variations in rate constants for the formation of the precursor molecular adsorbed state and the chemisorbed atomic state due to the phase transition in the nickel. The changes in rate constants are also considered to be in qualitative agreement with theoretical predictions based on a spin coupling between the adatom and the magnetic substrate.

Shanabarger, M. R.↗