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NASA NTRS1986

Optical observations of very low ionization HII regions in the large Magellanic cloud

Several very low ionization isolated HII regions were detected on a prism-objective plate of the Large Magellanic Cloud. Most of the objects show a very weak (OIII) lambda 5007 emission line and, on the other hand the (OII) lambda 6584 doublets are very intense. This kind of objects seem to be ideal in order to determine accurate N and O abundance, avoiding the use of large ionization correction factors in the N abundance determination. Spectrophotometric observations of these regions were carried out with the 4 m telescope and the 2-D Frutti spectrograph at Cerro Tololo, and with the 1.52 m and the Image Dissector Scanner (IDS) at La Silla, ESO. The wavelength range lambda lambda 3700 to 7000 A was covered. Calibrated fluxes of the emission lines detected were measured, and from these data preliminary results of physical conditions of the gas as well as some ionic abundances were derived. Comparisons of the observations with ionization structure models show that the effective temperatures of the ionizing stars are less than 35,000 K. Possible abundances gradients across the large megallanic cloud are discussed.

Pena, M.↗
NASA NTRS1988

The lowest ionization potentials of Al2

Potential curves for the lowest two electronic states (X 2 sigma g + and A 2 pi u) of Al2(+) were computed using complete active space SCF/multireference CI wave functions and large Gaussian basis sets. The lowest observable vertical ionization potential (to Al2(+) X 2 sigma g +) of the Al2 X 3 pi u ground state is calculated to occur around 6.1 eV, in excellent agreement with the experimental range of 6.0 to 6.42 eV obtained in recent cluster ionization studies by Cox and co-workers. The second vertical ionization potential (to Al2(+) A 2 pi u) occurs near 6.4 eV, also within the experimental range. The adiabatic IP of 5.90 eV is in good agreement with the value of 5.8 to 6.1 eV deduced by Hanley and co-workers from the difference in thresholds between collision induced dissociation processes of Al3(+). The computed IP values are somewhat larger than those deduced from branching ratios in cluster fragmentation experiments by Jarrold and co-workers. The observation of an ionization threshold below 6.42 eV is shown to be incompatible with an Al2 ground electronic state assignment of 3 sigma g -, but the separation between the two lowest states of Al2 is so small that it is likely that both are populated in the experiments, so that this does not provide unambiguous support for the recent theoretical assignment of the ground state as 3 pi u.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1989

Results of rocket measurements of D-region ionization over Thumba in MAP

Under MAP, two rockets were launched from Thumba (8.5 N, 76.8 E) around 1030 hrs Lt with identical payloads on 7 and 10 March 1986 for D region studies. Positive ion densities were measured by spherical probe and Gerdien condenser and electron densities were measured by Langmuir probe and propagation experiments. In both flights a valley in ionization height profile was noticed around 83 km. The density of ionization at this altitude was about 4 x 10(2) cu cm. A detailed positive ion-chemical scheme was used to reproduce the measured ionization height profiles. The density of NO needed to reproduce the valley in ionization at 83 km came around 5 x 10(5) cu cm. A photochemical treatment without diffusion process was found inadequate to explain this value of NO. Calculations showed that the value of vertical eddy diffusion needed to reproduce the value of NO was around 10(6)sq cm/s. Interestingly, the same value of eddy diffusion coefficient was obtained when derived in the manner described by Thrane and his coworkers using only the positive ion current data of spherical probes.

Chakrabarty, D. K.↗
NASA NTRS1989

Magnetic reconnection in partially ionized gases

Magnetic field lines in a plasma reconnect at a rate scaled by the Alfven speed. In a partially ionized gas there are two natural Alfven speeds: one determined by the ionized mass density alone, which applies when ion-neutral friction is negligible, and one determined by the total mass density, which applies when ion-neutral friction is strong. When the ionization fraction is low, as in a dense molecular cloud, these two speeds differ by several orders of magnitude. Both time-dependent tearing modes and steady-state magnetic reconnection in partially ionized gas are considered, and the regimes in which the charged and neutral components are strongly, intermediately, and weakly coupled are delineated. Molecular clouds are probably in the intermediate regime, while reconnection in solar prominences probably has strong ion-neutral coupling. Reconnection proceeds more rapidly when coupling is not strong.

Zweibel, Ellen G.↗
NASA NTRS1989

Lowest ionization potentials of Al2

Potential curves for the lowest two electronic states, X 2Sigma(+)g and A 2Pi(u), of Al2(+) were computed using complete active space SCF/multireference CI wave functions and large Gaussian basis sets. The lowest observable vertical ionization potential, to Al2(+) X 2Sigma(+)g, of the Al2 X 3 Pi(u) ground state is calculated to occur around 6.1 eV, in excellent agreement with the experimental range of 6.0 to 6.42 eV obtained in recent cluster ionization studies by Cox and co-workers. The second vertical ionization potential, to Al2(+) A 2Pi(u), occurs near 6.4 eV, also within the experimental range. The adiabatic IP of 5.90 eV is in good agreement with the value of 5.8 to 6.1 eV deduced by Hanley and co-workers from the difference in thresholds between collision induced dissociation processes of Al3(+). The computed IP values are somewhat larger than those deduced from branching ratios in cluster fragmentation experiments by Jarrold and co-workers. The observation of an ionization threshold below 6.42 eV is shown to be incompatible with an Al2 ground electronic state assignment of 3Sigma(-)g, but the separation between the two lowest states of Al2 is so small that it is likely that both are populated in the experiments, so that this does not provide unambiguous support for the recent theoretical assignment of the ground state as 3Pi(u).

Bauschlicher, Charles W., Jr.↗
NASA NTRS1990

Initial results of positron ionization mass spectrometry

The use of monoenergetic positrons for the ionization of organic molecules in the gas phase is described. The ionic products are analyzed with a time-of-flight mass spectrometer and detected to produce a mass spectrum. The ionization mechanisms which can be studied in this way include positron impact at energies above the ionization limit of the target molecules, positronium formation in the Ore gap energy range, and positron attachment at energies less than 1eV. The technique of positron ionization mass spectrometry (PIMS) may have analytical utility in that chemical selectivity is observed for one or more of these processes.

Donohue, D. L.↗
NASA NTRS1990

SR90, strontium shaped-charge critical ionization velocity experiment

In May 1986 an experiment was performed to test Alfven's critical ionization velocity (CIV) effect in free space, using the first high explosive shaped charge with a conical liner of strontium metal. The release, made at 540 km altitude at dawn twilight, was aimed at 48 deg to B. The background electron density was 1.5 x 10(exp 4) cu cm. A faint field-aligned Sr(+) ion streak with tip velocity of 2.6 km/s was observed from two optical sites. Using two calibration methods, it was calculated that between 4.5 x 10(exp 20) and 2 x 10(exp 21) ions were visible. An ionization time constant of 1920 s was calculated for Sr from the solar UV spectrum and ionization cross section which combined with a computer simulation of the injection predicts 1.7 x 10(exp 21) solar UV ions in the low-velocity part of the ion streak. Thus all the observed ions are from solar UV ionization of the slow (less than critical) velocity portion of the neutral jet. The observed neutral Sr velocity distribution and computer simulations indicate that 2 x 10(exp 21) solar UV ions would have been created from the fast (greater than critical) part of the jet. They would have been more diffuse, and were not observed. Using this fact it was estimated that any CIV ions created were less than 10(exp 21). It was concluded that future Sr CIV free space experiments should be conducted below the UV shadow height and in much larger background plasma density.

Wescott, Eugene M.↗
NASA NTRS1990

Optical observations on the CRIT-II Critical Ionization Velocity Experiment

A rocket borne Critical Ionization Velocity (CIV0 experiment was carried out from Wallops Island at dusk on May 4, 1989. Two barium shaped charges were released below the solar terminator (to prevent photoionization) at altitudes near 400 km. The ambient ionospheric electron density was 50,000/cu cm. The neutral barium jet was directed upward and at an angle of nominally 45 degrees to B which gives approximately 3 x 10 to the 23rd neutrals with super critical velocity. Ions created by a CIV process in the region of the neutral jet would travel up along B into sunlight where they can be detected optically. Well defined ion clouds (max. brightness 750 R) were observed in both releases. An ionization rate of 0.8 percent/sec (125 sec ionization time constant) can account for the observed ion cloud near the release field line, but the ionization rate falls off with increasing distance from the release. It is concluded that a CIV process was present in the neutral jet out to about 50 km from the release, which is significantly further than allowed by current theories.

Stenbaek-Nielsen, H. C.↗
NASA NTRS1991

Ionization of NO at high temperature

Space vehicles flying through the atmosphere at high speed are known to excite a complex set of chemical reactions in the atmospheric gases, ranging from simple vibrational excitation to dissociation, atom exchange, electronic excitation, ionization, and charge exchange. Simple arguments are developed for the temperature dependence of the reactions leading to ionization of NO, including the effect of vibrational electronic thermal nonequilibrium. NO ionization is the most important source of electrons at intermediate temperatures and at higher temperatures provides the trigger electrons that ionize atoms. Based on these arguments, recommendations are made for formulae which fit observed experimental results, and which include a dependence on both a heavy particle temperature and different vibration electron temperatures. In addition, these expressions will presumably provide the most reliable extrapolation of experimental results to much higher temperatures.

Hansen, C. Frederick↗
NASA NTRS1990

Low-frequency ionization-driven instability of a discrete auroral arc model

The low-frequency (time scales of tens of seconds) dynamics of the auroral ionosphere differs from that of the nonauroral ionosphere by the presence of strong, unstable space- and time-dependent ionospheric ionization produced by precipitating auroral electrons. If recombination is relatively unimportant (as at high ionospheric heights), it is shown that, in general, transport processes cannot remove this ionization as fast as it is created, and no equilibrium is possible. These nonequilibrium phenomena are investigated in the context of a nonlinear adiabatic auroral model, which has previously been studied in static situations. A linearized local perturbation analysis is given of what amounts to a current-driven E x B gradient-drift instability with an ionization source, as well as some exact nonlinear solutions valid in a finite but limited spatial region. These solutions show continuing motion of auroral potential and plasma density, as the aurora tries to shift its ionization problems from one place to another. The analysis gives clues to the possibility of generation of chaos and of fine-scale spatial structure.

Cornwall, John M.↗
NASA NTRS1991

Cross sections for direct and dissociative ionization of NH3 and CS2 by electron impact

A crossed electron beam-molecular beam collision geometry is used to measure cross sections for the production of positive ions by electron impact on NH3 and CS2. Ionization cross-section data for NH3 and the values of various cross sections are presented, as well as ionization efficiency curves for CS2. Considerable differences are found between the various results on NH3. The present values are close to the data of Djuric et al. (1981). The semiempirical calculations of Hare and Meath (1987) differ considerably in the absolute values of cross sections. Discrepancies were observed in comparisons of cross sections of other fragment ions resulting from the ionization and dissociate ionization of NH3.

Rao, M. V. V. S.↗
NASA NTRS1993

Implementation of ionizing radiation environment requirements for Space Station

Proper functioning of Space Station hardware requires that the effects of high-energy ionizing particles from the natural environment and (possibly) from man-made sources be considered during design. At the Space Station orbit of 28.5-deg inclination and 330-440 km altitude, geomagnetically trapped protons and electrons contribute almost all of the dose, while galactic cosmic rays and anomalous cosmic rays may produce Single Event Upsets (SEUs), latchups, and burnouts of microelectronic devices. Implementing ionizing radiation environment requirements for Space Station has been a two part process, including the development of a description of the environment for imposing requirements on the design and the development of a control process for assessing how well the design addresses the effects of the ionizing radiation environment. We will review both the design requirements and the control process for addressing ionizing radiation effects on Space Station.

Boeder, Paul A.↗
NASA NTRS1993

Galactic fine-structure lines - Morphologies of the warm ionized interstellar medium

Far-infrared ionic fine-structure emission lines associated with the large-scale structure of the Galactic ionized medium are interpreted in terms of a heuristic model in which three distinct source morphologies are considered: ionization-bounded H II regions, an extended, low-density medium, and externally ionized surfaces of neutral clouds. The model reveals that the overall luminosity of the Galaxy in the fine-structure lines of both C II and N II is due, in comparable proportions, to diffuse medium and the boundaries between ionized and neutral regions. Limits are set on the luminosity of the diffuse component in the plane of the Galaxy. Some individual lines of sight of the COBE FIRAS instrument are dominated, in these spectral lines, by H II regions, even with its 7 deg field of view. Average densities of both H II regions and photodissociation regions are estimated on a Galactic scale.

Petuchowski, S. J.↗
NASA NTRS1993

Ionization effects in three-dimensional solar granulation simulations

These numerical studies show that ionization influences both the transport and dynamical properties of compressible convection near the surface of the Sun. About two-thirds of the enthalpy transported by convective motions in the region of partial hydrogen ionization is carried as latent heat. The role of fast downflow plumes in total convective transport is substantially elevated by this contribution. Instability of the thermal boundary layer is strongly enhanced by temperature sensitive variations in the radiative properties of the fluid, and this provides a mechanism for plume initiation and cell fragmentation in the surface layers. As the plumes descend, temperature fluctuations and associated buoyancy forces are maintained because of the increased specific heat of the partially ionized material. This can result is supersonic vertical flows. At greater depths, ionization effects diminish, and the plumes are decelerated by significant entrainment of surrounding fluid.

Rast, Mark P.↗
NASA NTRS1993

Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons - Effect of ionization

In order to test the hypothesis of ionized PAHs as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.

De Frees, D. J.↗
NASA NTRS1993

Are cosmic rays effective for ionization of the solar nebula?

In this paper, we argue that the effectiveness of cosmic rays to ionize the bulk of the nebular gas may be further impaired by the influence of the magnetic field on the propagation of cosmic rays. When cosmic rays enter the nebular disk they ionize the gas and make the dynamo generation of magnetic fields possible. However, once magnetic fields are embedded in the nebular gas, the upcoming cosmic rays can no longer penetrate directly into the nebular disk because they start to interact with the magnetic field and lose their energy before propagating significantly toward the midplane. That, in turn, undercuts the ionization source within the bulk of the gas stopping the dynamo action. Nebular dynamo models ignored this back reaction of magnetic fields on cosmic rays. We calculate this back reaction effect, but for the sake of mathematical simplicity, we ignore the effect of magnetic field weakening due to diminishing ionization by cosmic rays.

Dolginov, A. Z.↗
NASA NTRS1994

Diffused ionized gas in the spiral galaxy M31

We present a study of diffuse ionized gas (DIG, or WIM for warm ionized medium) in the nearby spiral M31, based on charge coupled device (CCD) imagery in H alpha and (S II) emission lines. We find that the DIG in M31 contributes 40% of the observed total H alpha luminosity, and at least 20% of the total after correction for extinction. This fraction is constant across the disk of M31. The total H alpha luminosity of M31, corrected for extinction, is about 4.1 x 10(exp 40) ergs/s. This implies a low star formation rate of about 0.35 M solar mass/yr, in agreement with earlier estimates. DIG is concentrated near regions of star formation. The average emission measure (EM) perpendicular to the disk ranges from about 6 pc cm(exp-6) in weaker spiral arms to 15 pc cm(exp-6) in the main spiral arms, with (rare) peak values reaching 50 pc cm(exp-6). Overall, the EM in the main arms is substantially higher than that of DIG in the solar neighborhood, implying higher power requirements per unit area in these regions of M31. However, the strong concentration of DIG near regions of star formation keeps the total area covered by DIG in M31 relatively small, which makes it possible to sustain this gas in spite of the low star formation rate. We argue that the DIG extent in vertical direction in M31 may well be lower than in our Galaxy, because of its low star formation rate. A simple parameterization of the electron distribution then shows that the DIG in the spiral arms may contribute between 15% and 40% of the total atomic gas column. The average electron densities implied by the high EMs reached in some regions seem to indicate a higher thermal pressure in the DIG than in the diffuse H I gas in M31. This pressure in-equilibrium can be avoided if part of the diffuse emissions due to a denser component, as proposed most recently by Miller & Cox, because this would reduce the EM and implied pressures for the actual widespread DIG. Column densities of the ionized gas might then be lower as well. We also show, however, that it is not possible to attribute all of the diffuse emission to a relatively dense component, such as earlier proposed extended low-density H II regions. The DIG in M31 shows an overall (S II)/H alpha intensity ratio of 0.5, significantly higher than in discrete H II regions, and similar to that in other galaxies. This number does not vary with radius in M31. There is a suggestion that (S II)/H alpha intensity may be higher at the lowest detectable emission measures, up to 0.7 or even 1. The discrete source population in M31 also shows a trend toward increasing (S II)/H alpha flux ratios as the sources become more diffuse. Few sources (apart from supernova remnants), however, reach the value of 0.5 found in the DIG as a whole. The distinct spectral signature of the DIG in M31, and its energy requirements favor photoionization of the gas, although it is likely that shock ionization occurs in selected regions.

Walterbos, Rene A. M.↗
NASA NTRS1994

Gas kinematics and ionization along the extended sight line to HD 116852

We present Goddard High-Resolution Spectrograph intermediate observations of the interstellar medium toward HD 116852, a low halo star at a distance of 4.8 kpc (z = -1.3 kpc) in the direction l = 304. deg 9, b = 16.deg 1. The small science aperture observations have signal-to-noise ratios ranging from 30 to 90 and resolutions of 11 to 18 km/s (FWHM). We confirm the optical MK classification of this star through an analysis of its ultraviolet photosperic and stellar wind profiles. We detect interstellar lines of Al III, Si IV, C IV, and N V together with lines of C I, C I*, C I**, Si II, Ge II, P II, and Ni II. We convert the Mg II, P II, S II, Al III, Si IV, C IV, and N V profiles into measure of apparent column density as a function of LSR velocity. Gas scale height, velocity dispersion, and differential Galactic rotation effects govern the profile shapes. A simple computer model of the expected sight line column density profiles for the low and high ion species indicates that the gas velocity dispersions and scale heights increase as the ionization level of the gas increases. We find scale heigts H greater than or = 1 kpc for the high ions, which are comparable to the z-distance of the star, whereas we find H approximatley = 0.6 to 0.7 kpc for A1 III and H approximatley 0.1 kpc for P II and Ge II. An enhancement in the Al II profile near -15 km/s accounts for approximately 25% of the A1 III column along the sight line and probably arises within gas located approximately 500 pc below the Sagittarius-Carina spiral arm link. Portions of the broad underlying A1 III distribution are associated with the higher ionization lines, perhaps in conductive interfaces. The presence of N V and the column density ratios of Si IV, C IV, and N V favor the interpretation that much of the high ion absorption is produced by collisional ionization in gas with T = 1-3 x 10(exp 5) K. An enhancement near -35 km/s in both the Si IV and C IV profiles may be due to an outflow from the Norma spiral arm at a z-distance of about -1 kpc. The smooth decrease of the N(C IV)/N(Si IV) ratio at negative velocities may be due to an ISM ionization structure for hot gas that changes distance from the Galactic plane or to a two phase gas distribution in which the relative contribution from each phase changes with distance from the Galactic plane.

Sembach, Kenneth R.↗