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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Closed Loop Geothermal Working Group: GeoCLUSTER App, Subsurface Simulation Results, and Publications

To better understand the heat production, electricity generation performance, and economic viability of closed-loop geothermal systems in hot-dry rock, the Closed-Loop Geothermal Working Group -- a consortium of several national labs and academic institutions has tabulated time-dependent numerical solutions and levelized cost results of two popular closed-loop heat exchanger designs (u-tube and co-axial). The heat exchanger designs were evaluated for two working fluids (water and supercritical CO2) while varying seven continuous independent parameters of interest (mass flow rate, vertical depth, horizontal extent, borehole diameter, formation gradient, formation conductivity, and injection temperature). The corresponding numerical solutions (approximately 1.2 million per heat exchanger design) are stored as multi-dimensional HDF5 datasets and can be queried at off-grid points using multi-dimensional linear interpolation. A Python script was developed to query this database and estimate time-dependent electricity generation using an organic Rankine cycle (for water) or direct turbine expansion cycle (for CO2) and perform a cost assessment. This document aims to give an overview of the HDF5 database file and highlights how to read, visualize, and query quantities of interest (e.g., levelized cost of electricity, levelized cost of heat) using the accompanying Python scripts. Details regarding the capital, operation, and maintenance and levelized cost calculation using the techno-economic analysis script are provided. This data submission will contain results from the Closed Loop Geothermal Working Group study that are within the public domain, including publications, simulation results, databases, and computer codes. GeoCLUSTER is a Python-based web application created using Dash, an open-source framework built on top of Flask that streamlines the building of data dashboards. GeoCLUSTER provides users with a collection of interactive methods for streamlining the exploration and visualization of an HDF5 dataset. The GeoCluster app and database are contained in the compressed file geocluster_vx.zip, where the "x" refers to the version number. For example, geocluster_v1.zip is Version 1 of the app. This zip file also contains installation instructions. **To use the GeoCLUSTER app in the cloud, click the link to "GeoCLUSTER on AWS" in the Resources section below. To use the GeoCLUSTER app locally, download the geocluster_vx.zip to your computer and uncompress this file. When uncompressed this file comprises two directories and the geocluster_installation.pdf file. The geo-data app contains the HDF5 database in condensed format, and the GeoCLUSTER directory contains the GeoCLUSTER app in the subdirectory dash_app, as app.py. The geocluster_installation.pdf file provides instructions on installing Python, the needed Python modules, and then executing the app.

15 GEOTHERMAL ENERGY↗
DOE OSTI2022

Deconvolving the roles of E × B shear and pedestal structure in the energy confinement quality of super H-mode experiements

Analysis of “super H-mode” experiments on DIII-D has put forward that high plasma toroidal rotation, not high pedestal, plays the essential role in achieving energy confinement quality H 98y2 >>1. Recently, super H-mode experiments with variable input torque have confirmed that high rotation shear discharges have very high levels of H 98y2 (>1.5), independent of the pedestal height, and that high pedestal discharges with low rotation shear have levels of H 98y2 only slightly above 1 (≤1.2). Although some increase in stored energy with higher pedestal occurs, the energy confinement quality mainly depends on the toroidal rotation shear, which varies according to different levels of injected neutral beam torque per particle. Here, quasi-linear gyrofluid modeling achieves a good match of the experiment when including the E×B shear; without including plasma rotation, the modeling predicts a confinement quality consistent with the empirical observation of H 98y2 ~1.2 at low rotation. Nonlinear gyrokinetic transport modeling shows that the effect of E×B turbulence stabilization is far larger than other mechanisms, such as the so-called hot-ion stabilization (T i /T e ) effect. Consistent with these experimental and modeling results are previous simulations of the ITER Baseline Scenario using a super H-mode pedestal solution, which showed the potential to exceed the Q=10 target if the pedestal density could be increased above the Greenwald limit. A close look at these simulations reveals that the predicted energy confinement quality is below 1 even at the highest pedestal pressure. The improvement in Q at higher pedestal density is due to the improved fusion power generation at the higher core density associated with higher pedestal density, not to an improved energy confinement quality.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Monte Carlo Simulations of Polarized Radiative Transfer in Neutron Star Atmospheres

Soft X-ray emission from neutron stars affords powerful diagnostic tools for uncovering their surface and interior properties, as well as their geometric configurations. In the atmospheres of neutron stars, the presence of magnetic fields alters the photon-electron scattering cross sections, resulting in nontrivial angular dependence of intensity and polarization of the emergent signals. This paper presents recent developments of our Monte Carlo simulation, MAGTHOMSCATT, which tracks the complex electric field vector for each photon during its transport. Our analysis encompasses the anisotropy and polarization characteristics of X-ray emission for field strengths ranging from nonmagnetic to extremely magnetized regimes that are germane to magnetars. In the very low field domain, we reproduced the numerical solution to the radiative transfer equation for nonmagnetic Thomson scattering, and provided analytical fits for the angular dependence of the intensity and the polarization degree. These fits can be useful for studies of millisecond pulsars and magnetic white dwarfs. By implementing a refined injection protocol, we show that, in the magnetar regime, the simulated intensity and polarization pulse profiles of emission from extended surface regions becomes invariant with respect to the ratio of photon (ω) and electron cyclotron (ω B ) frequencies once ω/ω B ≲ 0.01. This circumvents the need for simulations pertinent to really high magnetic field strengths, which are inherently slower. Our approach will be employed elsewhere to model observational data to constrain neutron star geometric parameters and properties of emitting hot spots on their surfaces.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Thermal and Well Flow Performance of Closed-Loop Geothermal in the Wattenberg Area: Preprint

Closed-loop geothermal systems provide an alternative to resource-constrained hydrothermal systems and stimulation-intensive enhanced geothermal systems. In this work, we apply the slender-body theory (SBT) model, to simulate the well flow and heat transfer performance of U-loop well designs drilled in the Wattenberg area of the Denver-Julesburg Basin. Three U-loop well patterns are investigated including a single, double, and multi-lateral design. The subsurface within area is characterized by deep, hot (> 200degreesC) igneous/metamorphic basement rock underlying multiple sedimentary formations. The lateral section(s) of the U-loop lies within a target depth of 6 km where temperatures are estimated to approach 300degreesC. As a base case, conduction-only heat transfer is investigated through simulations with the SBT model within U-loops with open-hole laterals that exchange heat directly with the hot dry rock using water as a working fluid. The utilization of supercritical CO2 as a heat transfer fluid is also considered. For each scenario, the system performance in terms of annual heat production and temperature profile over a 20-year project lifetime are assessed. Also, the levelized costs of heat and electricity (LCOH and LCOE) are determined using a top-down technoeconomic analysis model. The results show that the performance and cost optimized U-loop design is one having an injection-production well spacing of 1,000 meters with ten 50-meter-spaced laterals that traverse a subsurface system with a temperature gradient of 60degreesC/km. By injecting 20 degreesC-water at a rate of 60 kg/s through this loop, an average heat production of 19 MWth can be achieved, resulting in an LCOE and LCOH of $136/MWh and $1.53/GJ, respectively, over a 20-year project life.

closed-loop geothermal↗
DOE OSTI2021

FESS Design Simulations: methods, tools, & issues for the edge/scrape-off-layer region

This topic describes the plasma and neutral particles in the transition boundary region between the hot core plasma and the surrounding material walls. A key geometrical transition that occurs in this region is where the equilibrium magnetic field changes topology from a set of closed, nested magnetic flux surfaces inside the magnetic separatrix to flux surfaces, and therefore magnetic field lines that intersect material walls. Because the plasma exhaust heat flows very rapidly along the field lines, these intersection locations can have heat fluxes much higher than the walls can withstand. The most promising strategy pursued here to avoid this problem is injection of moderate-Z impurities that radiate the exhaust power over a much larger surface area on the walls, thus keeping the peak heat flux at or below the goal of 10 MW/m 2 . Further, the intrusion of injected and wall-sputtered impurities into the core region must be kept below certain limits to prevent degradation of the fusion power generated in the core.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Thermal and Well Flow Performance of Closed-Loop Geothermal in the Wattenberg Area

Closed-loop geothermal systems provide an alternative to resource-constrained hydrothermal systems and stimulation-intensive enhanced geothermal systems. In this work, we apply the slender-body theory (SBT) model, to simulate the well flow and heat transfer performance of U-loop well designs in the Wattenberg area of the Denver-Julesburg Basin. Three U-loop well patterns are investigated, including a single-, double-, and multi-lateral design. The subsurface within the area of interest is characterized by deep, hot (> 200 degrees C) igneous/metamorphic basement rock underlying multiple sedimentary formations. The lateral section(s) of the U-loop lie(s) within a target depth of 6 km, where temperatures are estimated to approach 300 degrees C. As a base case, conduction-only heat transfer is investigated through simulations with the SBT model within U-loops with open-hole laterals that exchange heat directly with the hot, dry rock using water as a working fluid. The utilization of supercritical CO2 as a heat transfer fluid is also considered. For each scenario, the system performance in terms of annual heat production and temperature profile over a 20-year project lifetime are assessed. Also, the levelized costs of heat and electricity (LCOH and LCOE) are determined using a top-down techno-economic analysis model. The results show that the performance- and cost-optimized U-loop design is one having an injection-production well spacing of 1,000 meters with ten 50-meter-spaced laterals that traverse a subsurface system with a temperature gradient of 60 degrees C/km. By injecting 20 degrees C-water at a rate of 60 kg/s through this loop, an average heat production of 19 MWth (i.e., 2.2 MWe net plant output) can be achieved, resulting in an LCOE and LCOH of $136/MWhe and $1.53/GJ, respectively, over a 20-year project life.

closed-loop geothermal↗
DOE OSTI2025

Experimental progress and future plans on spherical tokamak, QUEST

QUEST (Q-shu university experiment with steady state spherical tokamak) aims at effective plasma current start-up and stable maintenance of plasma discharge. To solve the inherent problems in a spherical tokamak (ST) arising from insufficient space for placing the inductive center solenoid, electron cyclotron current drive (ECCD) and transient coaxial helicity injection (T-CHI) are implemented as a non-inductive plasma start-up method in QUEST. Efficient ECCD assisted by energetic electrons could be achieved. By combining control of the wave injection angle and application of a negative toroidal electric field, the bulk electron temperature could be raised up to 1 keV due to selective wave power absorption in the bulk electrons. The plasma current of over 50 kA contained within the closed flux surface could be obtained with a floating single biased electrode placed on lower divertor plates for T-CHI. Long-pulse operations on QUEST are impeded frequently due to wall saturation and subsequent density runaway caused by fuel particle imbalance. Since 2014, a unique tool called the ‘hot wall’ has been implemented to overcome the imbalance. The hot wall has a capability to regulate its surface temperature using a heater and two water cooling channels. With the help of the hot wall, 6 h discharges were obtained in 2020. Cooling down of the surface of the hot wall was significantly effective in recovering the wall pumping and was useful to extend the pulse duration. Augmentation of the toroidal magnetic field, B T up to 0.5 T from 0.25 T and a continuous wave (CW) gyrotron of 28 GHz are planned for QUEST in the near future. As raising B T provides a fundamental resonance of electron cyclotron waves (ECWs) with 28 GHz, more effective plasma current start-up and heating will be performed. Long-pulse operations with higher plasma parameters are expected.

QUEST↗
DOE OSTI2020

Ion versus Electron Heating in Compressively Driven Astrophysical Gyrokinetic Turbulence

The partition of irreversible heating between ions and electrons in compressively driven (but subsonic) collisionless turbulence is investigated by means of nonlinear hybrid gyrokinetic simulations. We derive a prescription for the ion-to-electron heating ratio Q i /Q e as a function of the compressive-to-Alfvénic driving power ratio P compr /P AW , of the ratio of ion thermal pressure to magnetic pressure β i , and of the ratio of ion-to-electron background temperatures T i /T e . It is shown that Q i /Q e is an increasing function of P compr /P AW . When the compressive driving is sufficiently large, Q i /Q e approaches ≃P compr /P AW . This indicates that, in turbulence with large compressive fluctuations, the partition of heating is decided at the injection scales, rather than at kinetic scales. Analysis of phase-space spectra shows that the energy transfer from inertial-range compressive fluctuations to sub-Larmor-scale kinetic Alfvén waves is absent for both low and high β i , meaning that the compressive driving is directly connected to the ion-entropy fluctuations, which are converted into ion thermal energy. This result suggests that preferential electron heating is a very special case requiring low βi and no, or weak, compressive driving. Our heating prescription has wide-ranging applications, including to the solar wind and to hot accretion disks such as M87 and Sgr A*.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

The impact of chromium coatings on Zircaloy cladding deformation behavior under reactivity-initiated accident-like mechanical loading conditions

A reactivity-initiated accident (RIA) occurs when a control rod ejection or control blade drop causes an increase in the fission rate. The injection of energy results in an increase in fuel temperature which in turn causes rapid thermal expansion of the fuel pellet. This thermal expansion may result in pellet-cladding mechanical interaction (PCMI) in which the fuel imparts a mechanical strain to the cladding. PCMI may cause the cladding to fail, and thus, the mechanical response of cladding due to PCMI must be investigated when characterizing new cladding materials. Chromium-coated Zircaloy-4 is a near-term accident-tolerant fuel cladding that exhibits improved high-temperature oxidation resistance. Modified burst testing was utilized to experimentally simulate the effects of PCMI on both uncoated and chromium-coated Zircaloy cladding samples at hot zero power conditions. Samples were coated using either cold spraying or physical vapor deposition to understand the differences in behavior that the coating application method may cause. Digital image correlation was used to analyze images of the deforming specimens to extract the in-situ strain behavior of the cladding. The uncoated specimens burst at hoop strains ranging from 8.8 % to 17.2 %. The cold-spray chromium-coated Zircaloy specimens burst at hoop strains of 7.0 % to 11.0 %. The physical vapor deposition coated tubes burst at hoop strains of 9.1 % to 11.5 %. These results indicate that the chromium coating causes a loss in the ductility of the cladding. Furthermore, the higher burst hoop strains of the physical vapor deposition-coated samples relative to the cold-spray samples indicate that the cold-spraying technique causes more of a loss in ductility than physical vapor deposition. All samples burst at higher hoop strains than those expected to occur in an RIA for fresh cladding.

Accident-tolerant fuel↗
DOE OSTI2020

Runaway electron seed formation at reactor-relevant temperature

Systematic variation of the pre-disruption core electron temperature (T e ) from 1 to 12 keV using an internal transport barrier scenario reveals a dramatic increase in the production of ‘seed’ runaway electrons (REs), ultimately accessing near-complete conversion of the pre-disruption current into sub-MeV RE current. Injected Ar pellets are observed to ablate more intensely and promptly as T e rises. At high T e , the observed ablation exceeds predictions from published thermal ablation models. Simultaneously, the thermal quench (TQ) is observed to significantly shorten with increasing T e —a surprising result. While the reason for the shorter TQ is not yet understood, candidate mechanisms include: insufficiently accurate thermal ablation models, enhanced ablation driven by the seed RE population, or significant parallel heat transport along stochastic fields. Kinetic modeling that self-consistently treats the plasma cooling via radiation, the induced electric field, and the formation of the seed RE is performed. Including the combined effect of the inherent dependence of hot-tail RE seeding on T e together with the shortened TQ, modeling recovers the progression towards near-complete conversion of the pre-disruption current to RE current as T e rises. Measurement of the HXR spectrum during the early current quench (CQ) reveals a trend of decreasing energy with pre-disruption T e . At the very highest T e (≈ 12 keV), ≈ 100% conversion of the thermal current to runaway current is found. The energy of this peculiar RE beam is inferred to be sub-MeV as it emits vanishingly few MeV hard x-rays (HXRs). These measurements demonstrate novel TQ dynamics as Te is varied and illustrate the limitations of treating the RE seed formation problem without considering the inter-related dependencies of the pellet ablation, radiative energy loss, and resultant variations of the TQ duration. Finally, if the observed shortening of the TQ with increasing T e extends to fusion-grade plasmas, than their propensity to form large quantities of RE seeds at high T e may be far worse than previously thought. Positively, the high T e scenario in DIII-D produces REs so prodigiously that it can serve as a meaningful new platform for demonstrating RE avoidance techniques.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

A study of the central stellar populations of galaxies in SDSS-IV MaNGA: identification of a subsample with unusually young and massive stars

ABSTRACT This paper describes a search for galaxy centres with clear indications of unusual stellar populations with an initial mass function flatter than Salpeter at high stellar masses. Out of a sample of 668 face-on galaxies with stellar masses in the range $10^{10}\!-\!10^{11} \, \mathrm{M}_{\odot }$, I identify 15 galaxies with young- to intermediate-age central stellar populations with unusual stellar population gradients in the inner regions of the galaxy. In these galaxies, the 4000-Å break is either flat or rising towards the centre of the galaxy, indicating that the central regions host evolved stars, but the H α equivalent width also rises steeply in the central regions. The ionization parameter [O iii]/[O ii] is typically low in these Galactic Centres, indicating that ionizing sources are stellar rather than AGN. Wolf–Rayet features characteristic of hot young stars are often found in the spectra and these also get progressively stronger at smaller galactocentric radii. These outliers are compared to a control sample of galaxies of similar mass with young inner stellar populations, but where the gradients in H α equivalent width and 4000-Å break follow each other more closely. The outliers exhibit central Wolf–Rayet red bump excesses much more frequently, they have higher central stellar and ionized gas metallicities, and they are also more frequently detected at 20-cm radio wavelengths. I highlight one outlier where the ionized gas is clearly being strongly perturbed and blown out either by massive stars after they explode as supernovae, or by energy injection from matter falling on to a black hole.

Kauffmann, Guinevere↗
DOE OSTI2022

Overview of the TJ-II stellarator research programme towards model validation in fusion plasmas

TJ-II stellarator results on modelling and validation of plasma flow asymmetries due to on-surface potential variations, plasma fuelling physics, Alfvén eigenmodes (AEs) control and stability, the interplay between turbulence and neoclassical (NC) mechanisms and liquid metals are reported. Regarding the validation of the neoclassically predicted potential asymmetries, its impact on the radial electric field along the flux surface has been successfully validated against Doppler reflectometry measurements. Research on the physics and modelling of plasma core fuelling with pellets and tracer encapsulated solid pellet injection has shown that, although post-injection particle radial redistributions can be understood qualitatively from NC mechanisms, turbulence and fluctuations are strongly affected during the ablation process. Advanced analysis tools based on transfer entropy have shown that radial electric fields do not only affect the radial turbulence correlation length but are also capable of reducing the propagation of turbulence from the edge into the scrape-off layer. Direct experimental observation of long range correlated structures show that zonal flow structures are ubiquitous in the whole plasma cross-section in the TJ-II stellarator. Alfvénic activity control strategies using ECRH and ECCD as well as the relation between zonal structures and AEs are reported. Finally, the behaviour of liquid metals exposed to hot and cold plasmas in a capillary porous system container was investigated.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

A research program to measure the lifetime of spin polarized fuel

The use of spin polarized fuel could increase the deuterium-tritium (D-T) fusion cross section by a factor of 1.5 and, owing to alpha heating, increase the fusion power by an even larger factor. Issues associated with the use of polarized fuel in a reactor are identified. Theoretically, nuclei remain polarized in a hot fusion plasma. The similarity between the Lorentz force law and the Bloch equations suggests polarization can be preserved despite the rich electromagnetic spectrum present in a magnetic fusion device. The most important depolarization mechanisms can be tested in existing devices. The use of polarized deuterium and 3 He in an experiment avoids the complexities of handling tritium, while encompassing the same nuclear reaction spin-physics, making it a useful proxy to study issues associated with full D-T implementation. 3 He fuel with 65% polarization can be prepared by permeating optically-pumped 3 He into a shell pellet. Dynamically polarized 7 Li-D pellets can achieve 70% vector polarization for the deuterium. Cryogenically-frozen pellets can be injected into fusion facilities by special injectors that minimize depolarizing field gradients. Alternatively, polarized nuclei could be injected as a neutral beam. Once injected, the lifetime of the polarized fuel is monitored through measurements of escaping charged fusion products. Multiple experimental scenarios to measure the polarization lifetime in the DIII-D tokamak and other magnetic-confinement facilities are discussed, followed by outstanding issues that warrant further study.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

A Phenomenological Thermal Spray Wall Interaction Modeling Framework Applied to a High Temperature Ignition Assistant Device

Airborne compression ignition engines must operate with reliable ignition systems to achieve proper ignition at every cycle, particularly at high altitudes. Glow-plug-based ignition-assistant (IA) devices can provide the necessary energy to preheat the fuel and ensure ignitability of the fuel-air mixture. Ignitability of liquid sprays can be facilitated via direct impingement onto the hot IA surface, however this comes with adverse effects on the IA durability. Therefore, optimizing an IA’s design requires detailed understanding of the physics of fuel spray impingement of superheated surfaces. While spray impingement on relatively low wall temperatures has been extensively studied and appropriate numerical models have been proposed through the years, fundamental understanding of high-speed liquid spray impingement on superheated walls is still elusive. This work aims to formulate a phenomenological thermal spray-wall interaction framework for modeling the film-boiling-induced heat transfer, atomization, and dispersion of fuel spray droplets impinging onto a superheated IA device. A qualitative comparison of the new phenomenological model is performed against optical experiments from the literature of an F-24 fuel spray injected onto an IA device located 12 mm away from the injector tip. The temperature of the IA was set at 1400 K. The fuel injection pressure was 400 bar, while the ambient gas pressure and temperature were 30 bar and 800 K, respectively. The performance of the phenomenological model is evaluated in comparison with two other state-of-art models from the literature. A qualitative analysis of the different spray and fuel-air mixture characteristics is performed to outline the differences in the predictions offered by the new phenomenological model and the two state-of-art spray-wall interaction models.

droplet dispersion↗
DOE OSTI2023

How do supernova remnants cool? – I. Morphology, optical emission lines, and shocks

ABSTRACT Supernovae (SNe) inject ∼1051 erg in the interstellar medium, thereby shocking and heating the gas. A substantial fraction of this energy is later lost via radiative cooling. We present a post-processing module for the flash code to calculate the cooling radiation from shock-heated gas using collisional excitation data from mappings v. When applying this tool to a simulated SN remnant (SNR), we find that most energy is emitted in the EUV. However, optical emission lines ([O iii], [N ii], [S ii], H α, H β) are usually best observable. Our shock detection scheme shows that [S ii] and [N ii] emissions arise from the thin shell surrounding the SNR, while [O iii], H $\rm \alpha$, and H $\rm \beta$ originate from the volume-filling hot gas inside the SNR bubble. We find that the optical emission lines are affected by the SNR’s complex structure and its projection on to the plane of the sky because the escaping line luminosity can be reduced by 10–80 per cent due to absorption along the line of sight. Additionally, the subtraction of contaminating background radiation is required for the correct classification of an SNR on the oxygen or sulphur BPT diagrams. The electron temperature and density obtained from our synthetic observations match well with the simulation but are very sensitive to the assumed metallicity.

Astronomy & Astrophysics↗
DOE OSTI2020

Time–series Analysis of Volume Change at Brady Hot Springs, Nevada, USA using Geodetic Data from 2003 – 2018

Brady Hot Springs geothermal field has exhibited subsidence, as measured by interferometric synthetic aperture radar (InSAR). Previous studies have examined both the temporal evolution of the deformation from 2004 through 2016 and the spatial extent of the deformation, directly relating the observed subsidence to volumetric changes below the surface. We extend the modeling at Brady to analyze a data set of interferometric pairs spanning from the end of 2003 through 2018. We examine spatial and temporal trends in the observed deformation by time–series analysis of each of the 1656 cubic voxels in a parameterized elastic dislocation model to identify areas where the subsurface volume changes as a function of time. Joint time–series analysis of Global Positioning System and InSAR pairs confirm significant changes in rates of volume change during time intervals when well operations were varied. Here, the rate of subsidence increases with increased injection, consistent with the identification of thermal contraction of the rock matrix as the dominant driving mechanism. Conversely, the modeled volume increases when pumping ceases, suggesting thermal expansion of the rock matrix.

58 GEOSCIENCES↗
DOE OSTI2024

Scaleup and Site-Specific Engineering Design for Global Thermostat Direct Air Capture Technology

The overall goal of the project is completion of an initial design of a commercial-scale, Carbon Capture, Utilization, and Storage Direct Air Capture (CCUS-DAC) plant design at three different sites that captures a net of at least 100,000 tonnes per year (TPY) carbon dioxide (CO 2 ) from the atmosphere and considers compression and conditioning of the captured CO 2 for purpose of pipeline transportation to different geological formation sites for deep well injection and underground storage. In addition to the leading system consisting of a scaled-up Global Thermostat DAC unit, overall plant design includes a combined Heat and Power (CHP) unit integrated with a conventional liquid amine-based carbon capture system (90% capture) and compression facilities. These are considered balance of plant (BOP) systems and are required to provide low carbon-intensity steam and power to the DAC process. A second approach involving provision of DAC units modified to directly capture emissions from the CHP unit was initially assessed as an alternative and it was determined to be less mature than considered approach and not included in the scaled-up plant design efforts. Three geographically diverse continental United States locations were selected to better understand the effect of local/regional ambient conditions on scaled-up DAC system performance and project costs: Bucks, Alabama (hot wet climate), Odessa, Texas (dry hot climate), and Goose Creek, Illinois (mid continental climate). The team focused on initial engineering design activities, including the development of project design criteria, initiation of site-specific studies and investigations, completion of DAC system process and equipment design, and definition of balance of plant (BOP) engineering. The purpose of the activities were to develop Technoeconomic Analysis (TEA), Life-Cycle Analysis (LCA), and Environmental, Health, and Safety (EH&S) analysis, and Business Case Analysis (BCA) to validate that the project engineering and scale-up plans of the DAC systems, at each of the three distinct case studies considered, are technically, economically, and environmentally feasible for commercial-scale operation.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2020

Chemical Speciation and Stability of Uranium in Unconventional Shales: Impact of Hydraulic Fracture Fluid

Uranium and other radionuclides are prominent in many unconventional oil/gas shales and is a potential contaminant in flowback/produced waters due to the large volumes/types of chemicals injected into the subsurface during stimulation. In this work, to understand the stability of U before and after stimulation, a geochemical study of U speciation was carried out on three shales (Marcellus, Green River, and Barnett). To do so, two types of samples for each shale were subjected to sequential chemical extractions: unreacted and shale-reacted with a synthetic hydraulic fracture fluid. Furthermore, a significant proportion of the total U (20–57%) was released from these three shales after reaction with fracture fluid, indicating that U is readily leachable. The total U released exceeds labile water-soluble and exchangeable fractions in unreacted samples, indicating that fluids leach more recalcitrant phases in the shale. Radiographic analysis of unreacted Marcellus shale thin sections shows U associated with detrital quartz and the clay matrix in the shale. Detrital zircon and TiO2 identified by an electron microprobe could account for the hot spots. This study shows that significant proportions of U in three shales are mobile upon stimulation. In addition, the extent of mobilization of U depends on the U species in these rocks.

58 GEOSCIENCES↗