Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “high resolution spectroscopy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Estimation of porphyrin concentration in the kerogen fraction of shales using high-resolution reflectance spectroscopy

An interpretive model for estimating porphyrin concentration in bitumen and kerogen from spectral reaflectance data in the visible and near-ultraviolet region of the spectrum is derived and calibrated. Preliminary results obtained using the model are consistent with concentrations determined from the bitumen extract and suggest that 40 to 60 percent of the total porphyrin concentration remains in the kerogen after extraction of bitumen from thermally immature samples. The reflectance technique will contribute to porphyrin and kerogen studies and can be applied at its present level of development to several areas of geologic and paleo-oceanographic research.

Holden, Peter N.↗
NASA NTRS1998

Photospheric Fluorescence and Resonance Scattering: Non Classical Diagnostics and the Future of X-ray Stellar Spectroscopy

High resolution AXAF and XMM observations of stellar coronae will yield a wealth of X-ray plasma line diagnostics that will provide a giant leap forward in our understanding of coronal densities, abundance anomalies and emission measure distributions. Unfortunately, there is one very basic unanswered question in the physics of active stellar coronae that the usual plasma diagnostics cannot address directly: What are the spatial characteristics of stellar coronae-the scale height and filling factor? What do other stellar coronae actually look like? I will discuss two novel diagnostics of coronal geometry and their application to future X-ray spectra: photospheric fluorescence and resonance line optical depths.

Drake, Jeremy↗
NASA NTRS1993

Using high spectral resolution spectrophotometry to study broad mineral absorption features on Mars

Traditionally telescopic measurements of mineralogic absorption features have been made using relatively low to moderate (R=30-300) spectral resolution. Mineralogic absorption features tend to be broad so high resolution spectroscopy (R greater than 10,000) does not provide significant additional compositional information. Low to moderate resolution spectroscopy allows an observer to obtain data over a wide wavelength range (hundreds to thousands of wavenumbers) compared to the several wavenumber intervals that are collected using high resolution spectrometers. However, spectrophotometry at high resolution has major advantages over lower resolution spectroscopy in situations that are applicable to studies of the Martian surface, i.e., at wavelengths where relatively weak surface absorption features and atmospheric gas absorption features both occur.

Blaney, D. L.↗
DOE OSTI2021

Contrast and Temperature Dependence of Multi-epoch High-resolution Cross-correlation Exoplanet Spectroscopy

While high-resolution cross-correlation spectroscopy (HRCCS) techniques have proven effective at characterizing the atmospheres of transiting and nontransiting hot Jupiters, the limitations of these techniques are not well understood. We present a series of simulations of one HRCCS technique, which combines the cross-correlation functions from multiple epochs, to place temperature and contrast limits on the accessible exoplanet population for the first time. We find that planets approximately Saturn-sized and larger within ∼0.2 au of a Sun-like star are likely to be detectable with current instrumentation in the L band, a significant expansion compared with the previously studied population. Cooler (T {sub eq} ≤ 1000 K) exoplanets are more detectable than suggested by their photometric contrast alone as a result of chemical changes that increase spectroscopic contrast. The L-band CH{sub 4} spectrum of cooler exoplanets enables robust constraints on the atmospheric C/O ratio at T {sub eq} ∼ 900 K, which have proven difficult to obtain for hot Jupiters. These results suggest that the multi-epoch approach to HRCCS can detect and characterize exoplanet atmospheres throughout the inner regions of Sun-like systems with existing high-resolution spectrographs. We find that many epochs of modest signal-to-noise ratio (S/N{sub epoch} ∼ 1500) yield the clearest detections and constraints on C/O, emphasizing the need for high-precision near-infrared telluric correction with short integration times.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2026

Gepta-EX: a multi-channel germanium detector for X-ray absorption fine structure

Fluorescence-mode X-ray absorption spectroscopy (XAS) at high photon energies requires detectors with high stopping power and excellent energy resolution to measure weak element-specific signals. Traditional silicon-based detectors suffer from poor efficiency above ∼20 keV, while most high-Z materials such as cadmium telluride, cadmium zinc telluride, and gallium arsenide have focused predominantly on imaging applications with limited spectroscopic resolution. In contrast, germanium combines excellent stopping power with superior intrinsic energy resolution due to its low Fano factor and favorable charge transport properties, making it ideal for high-resolution spectroscopy in the 15 keV to 100 keV range. To address these requirements, we report on the development, fabrication, and performance evaluation of Gepta-EX, a compact multi-channel high-purity germanium (HPGe) detector system for fluorescence-mode XAS. The Gepta-EX system features a monolithic seven-channel HPGe pixel array integrated with low-noise CUBE charge-sensitive preamplifiers, housed within a thermally isolated compact cryostat operating near 90 K. The detector achieves energy resolutions of 218 eV at 5.9 keV (from a 55 Fe source) and 373 eV at 59.5 keV (from a 241 Am source), with uniform performance across all channels. By avoiding the escape peak interference commonly associated with silicon detectors and providing stable, high-resolution performance, Gepta-EX represents a powerful tool for high-energy X-ray spectroscopy.

36 MATERIALS SCIENCE↗
NASA NTRS1987

Exploiting the IR: Solar and stellar spectroscopy in the IR

Recent instrumental advances have provided the capability to perform high resolution spectroscopy, in the thermal infrared region of the solar spectrum, with high sensitivity. The 8 to 12 micron region was extensively observed using Fourier transform (FTS) and laser heterodyne techniques. The continuous opacity of the solar atmosphere, due to H(-), increases with wavelength in the infrared region longward of 1.6 microns. Consequently thermal infrared observations probe the upper photosphere, and give an insight into the dynamics and structure of this region. The most notable spectral features in the 10 micron window include pure rotation lines of OH, and emission lines due to high-n states in MgI and AlI. The high-n lines due to MgI and AlI are important to solar and stellar physics because of their very large Zeeman sensitivity. The recent development of a cryogenic grating postdispenser for the FTS has allowed low-noise solar observations of these lines in 90 seconds. Limited mapping of the lines in a sunspot penumbra was performed, and gives information of the structure of the penumbral magnetic field. Although the MgI lines were detected in red giant spectra, instrumental sensitivity is not yet sufficient to see them in stars where significant magnetic fields are expected.

Deming, Drake↗
NASA NTRS1975

Auger electron spectroscopy at high spatial resolution and nA primary beam currents

An experimental Auger microprobe system is described which incorporates a field-emission electron gun and total beam currents in the nanoampere range. The distinguishing characteristics of this system include a large multistation UHV specimen chamber, pulse counting and fully digital Auger signal-processing techniques, and digital referencing methods to eliminate the effects of beam instabilities. Some preliminary results obtained with this system are described, and it is concluded that field-emission electron sources can be used for high-resolution Auger electron spectroscopy with primary-beam spots of less than 100 nm and beam currents of the order of 1 nA.

Todd, G.↗
NASA NTRS2010

Ultra-High Resolution Spectroscopic Remote Sensing: A Microscope on Planetary Atmospheres

Remote sensing of planetary atmospheres is not complete without studies of all levels of the atmosphere, including the dense cloudy- and haze filled troposphere, relatively clear and important stratosphere and the upper atmosphere, which are the first levels to experience the effects of solar radiation. High-resolution spectroscopy can provide valuable information on these regions of the atmosphere. Ultra-high spectral resolution studies can directly measure atmospheric winds, composition, temperature and non-thermal phenomena, which describe the physics and chemistry of the atmosphere. Spectroscopy in the middle to long infrared wavelengths can also probe levels where dust of haze limit measurements at shorter wavelength or can provide ambiguous results on atmospheric species abundances or winds. A spectroscopic technique in the middle infrared wavelengths analogous to a radio receiver. infrared heterodyne spectroscopy [1], will be describe and used to illustrate the detailed study of atmospheric phenomena not readily possible with other methods. The heterodyne spectral resolution with resolving power greater than 1,000.000 measures the true line shapes of emission and absorption lines in planetary atmospheres. The information on the region of line formation is contained in the line shapes. The absolute frequency of the lines can be measured to I part in 100 ,000,000 and can be used to accurately measure the Doppler frequency shift of the lines, directly measuring the line-of-sight velocity of the gas to --Im/s precision (winds). The technical and analytical methods developed and used to measure and analyze infrared heterodyne measurements will be described. Examples of studies on Titan, Venus, Mars, Earth, and Jupiter will be presented. 'These include atmospheric dynamics on slowly rotating bodies (Titan [2] and Venus [3] and temperature, composition and chemistry on Mars 141, Venus and Earth. The discovery and studies of unique atmospheric phenomena will also be described, such as non-thermal and lasing phenomena on Mars and Venus, mid-infrared aurora on Jupiter [5], and results of small body impacts on Jupiter [6]. The heterodyne technique can also be applied for detailed study of the Earth's stratosphere and mesosphere by measuring trace constituent abundances and temporal and spatial variability as well as winds, which provide information of transport. All ground-based measurements will be described as complementary and supporting studies for on-going and future space missions [7] (Mars Express, Venus Express, Cassini Huygens, JUNO, ExoMars Trace Gas Orbiter, and the Europa Jupiter System Mission, an Earth Science Venture Class missions), Proposed instrument and technology development for a space flight infrared heterodyne spectrometer will be described.

Kostiuk, Theodor↗
NASA NTRS2022

The Polstar High Resolution Spectropolarimetry MIDEX Mission

The Polstar mission will provide a space-borne 60 cm spectropolarimeter operating at ultraviolet (UV) wavelengths, capturing all four Stokes parameters (intensity, two linear polarization components, and circular polarization). Polstar’s capabilities are designed to meet its goal of determining how circumstellar gas flows alter and inform massive star evolution, affect the stellar remnant population, and stir and enrich the interstellar medium (ISM). These will be achieved by investigating the dynamical geometries in the winds and disks of hot stars, the composition and magnetic alignment of interstellar dust, and the star-forming accretion disks of UV-bright stars at an important transition boundary. Together these areas map out a kind of two-way interface between massive stars and their effect on our galaxy, wherein the stellar winds enrich the ISM with metals and kinetic energy, preconditioning their environment and the stellar endpoints prior to undergoing supernova. The ISM dust in turn reveals the composition and magnetic environment leading to new star formation, and the accretion disks of Herbig Ae/Be stars reveal how the ISM gas returns to make new massive stars. Polstar will combine high-resolution spectroscopy in the time domain with high-precision UV polarimetry. Doppler-shifted UV resonance line opacity will provide information about circumstellar kinematics, while polarization gives complementary geometric information about unseen structures. The composition and magnetic alignment of the smallest interstellar dust grains provides a probe of the ISM utilizing radiative alignment theory (RAT). Polstar will operate in the far-UV (FUV) at 122–200 nm at high spectral resolution of around R ∼ 30k, and at FUV and near-UV (NUV) wavelengths of 122–320 nm at lower spectral resolutions of 0.1 - 1k. Detection of polarization levels as weak as 0.1% are expected, with a temporal cadence ranging from 5–10 minutes for most wind variability studies, to hours or days for sampling rotation, to days or weeks for sampling binary orbits, to months to a year for sampling substructure in the inner regions of protoplanetary disks. Sub-meter-class aperture is well suited to access this wide array of time domain science, made possible by restricting to a few hundred bright, massive stars, necessarily extincted by a small to moderate column of interstellar dust, informing both the attributes of the stars and the ISM through which they are seen. As such, the focus is on our own galaxy and its evolutionary drivers, but a few targets in the Magellanic clouds offer the potential to extend this understanding to low-metallicity environments.

Paul A Scowen↗
DOE OSTI2022

High-velocity Stars in SDSS/APOGEE DR17

We report 23 stars having Galactocentric velocities larger than 450 km s -1 in the final data release of the APOGEE survey. This sample was generated using space velocities derived by complementing the high-quality radial velocities from the APOGEE project in Sloan Digital Sky Survey's Data Release 17 (DR17) with distances and proper motions from Gaia early Data Release 3 (eDR3). We analyze the observed kinematics and derived dynamics of these stars, considering different potential models for the Galaxy. We find that three stars could be unbound depending on the adopted potential, but in general all of the stars show typical kinematics of halo stars. The APOGEE DR17 spectroscopic results and Gaia eDR3 photometry are used to assess the stellar parameters and chemical properties of the stars. All of the stars belong to the red giant branch, and, in general, they follow the abundance pattern of typical halo stars. There are a few exceptions that would deserve further analysis through high-resolution spectroscopy. In particular, we identify a high-velocity Carbon-Enhanced Metal-Poor star, with a Galactocentric velocity of 482 km s -1 . We do not confirm any hypervelocity star in the sample, but this result is very sensitive to the adopted distances and less sensitive to the Galactic potential.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1977

Infrared heterodyne spectroscopy of atmospheric ozone

The absorption spectrum of atmospheric ozone is measured within a 1/cm region at 1100/cm, using an IR heterodyne detector (spectrometer with CO2 local oscillator) developed for astronomical work. Absorption spectra obtained by passing radiation from the tunable diode laser through an absorption cell, heterodyne spectra of atmospheric ozone, and a predicted atmospheric spectrum are compared. Water vapor absorbing in the region of interest (1100/cm) is also considered. Preliminary results encourage the use of diode laser local oscillators in tunable heterodyne detector systems for spectroscopy of atmospheric ozone and remote high-resolution spectroscopy of atmospheric constituents and pollutants.

Frerking, M. A.↗
DOE OSTI2020

Photonic integration for UV to IR applications

Photonic integration opens the potential to reduce size, power, and cost of applications normally relegated to table- and rack-sized systems. Today, a wide range of precision, high-end, ultra-sensitive, communication and computation, and measurement and scientific applications, including atomic clocks, quantum communications, processing, and high resolution spectroscopy, are ready to make the leap from the lab to the chip. However, many of these applications operate at wavelengths not accessible to the silicon on insulator-based silicon photonics integration platform due to absorption, power handling, unwanted nonlinearities, and other factors. Next generation photonic integration will require ultra-wideband photonic circuit platforms that scale from the ultraviolet to the infrared and that offer a rich set of linear and nonlinear circuit functions as well as low loss and high power handling capabilities. This article provides an assessment of the field in ultra-wideband photonic waveguides to bring power efficient, ultra-high performance systems to the chip-scale and enable compact transformative precision measurement, signal processing, computation, and communication techniques.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1992

On the accuracy of CO line positions for high resolution IR stellar spectroscopy

The paper demonstrates the high accuracy of line positions derived from improved sets of Dunham coefficients for the four more abundant isotopic species of carbon monoxide - (C-12)(O-16), (C-13)(O-16), (C-12)(O-18), and (C-12)(O-17) - which are present in the sun and in cool stellar atmospheres. These new spectroscopic constants make it possible to predict very accurate positions of CO lines at any J-values, especially at very high rotational excitation (up to J around 135). Earlier proposed identifications of CO lines at large J-values are checked, and some incorrect identifications in sunspot spectra are found. The present accurate line positions are also compared with predictions from other available sets of molecular constants. It is concluded that the present improved sets of molecular constants are the most appropriate to all problems of high-resolution stellar and solar spectroscopy at any J- and v-values, particularly for synthetic spectra of cool stars.

Sauval, A. J.↗
NASA NTRSDate not supplied

Utilizing Experimental-based Line Positions for Semi-empirical IR Line Lists

Molecular IR line lists computed from semi-empirically refined ab initio potential energy surface and high quality ab initio dipole moment surface may have line position accuracy typically within 0.01 - 0.05 cm−1. For high resolution spectroscopy databases, it is necessary to integrate the computed theoretical IR intensities with the line positions accurately determined from experiments and (or) reliably derived from Effective Hamiltonian models. However, it is not a trivial task, and the choices in reality are heavily contingent upon the coverage, consistency, and accuracy of the data available for a specific molecule or isotopologue. We will present several approaches applied to recent Ames IR line lists of CO 2 1, N 2 O 2 , and OCS to demonstrate how challenging such integration may become, and what we have learned From these projects. Discussions will focus on the relation between each different scenario and the corresponding choice or solution, including their advantages and limits, how the semi-empirical IR line lists can help, and what else may be needed for future improvements. We will emphasize that the “Theory+Experiment” synergy may still play significant role in the determination of the best line positions.

Effective Hamiltonian models↗