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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Shergottite Impact Melt Glasses Contain Soil from Martian Uplands

Martian meteorite (shergottite) impact melt glasses that contain high concentrations of martian atmospheric noble gases and show significant variations in Sr-87/Sr-86 isotopic ratios are likely to contain Martian surface fines mixed with coarser regolith materials. The mixed soil constituents were molten due to shock at the time of meteoroid impact near the Martian surface and the molten glass got incorporated into the voids and cracks in some shergottite meteorites. Earlier, Rao et al. found large enrichments of sulfur (sulfate) during an electron-microprobe study of several impact melt glass veins and pods in EET79001,LithC thin sections. As sulfur is very abundant in Martian soil, these S excesses were attributed to the mixing of a soil component containing aqueously altered secondary minerals with the LithC precursor materials prior to impact melt generation. Recently, we studied additional impact melt glasses in two basaltic shergottites, Zagami and Shergotty using procedures similar to those described by Rao et al. Significant S enrichments in Zagami and Shergotty impact melt glass veins similar to the EET79001, LithC glasses were found. In addition, we noticed the depletion of the mafic component accompanied by the enrichment of felsic component in these impact melt glass veins relative to the bulk host rock in the shergottites. To explain these observations, we present a model based on comminution of basaltic rocks due to meteroid bombardment on martian regolith and mechanical fractionation leading to enrichment of felsics and depletion of mafics in the fine grained dust which is locally mobilized as a result of saltation and deflation due to the pervasive aeolian activity on Mars.

Rao, M. N.↗
NASA NTRS2002

Shergottite Impact Melt Glasses Contain Soil from Martian Uplands

Martian meteorite (shergottite) impact melt glasses that contain high concentrations of martian atmospheric noble gases and show significant variations in Sr-87/Sr-86 isotopic ratios are likely to contain Martian surface fines mixed with coarser regolith materials. The mixed soil constituents were molten due to shock at the time of meteoroid impact near the Martian surface and the molten glass got incorporated into the voids and cracks in some shergottite meteorites. Earlier, Rao et al. found large enrichments of sulfur (sulfate) during an electron-microprobe study of several impact melt glass veins and pods in EET79001,LithC thin sections. As sulfur is very abundant in Martian soil, these S excesses were attributed to the mixing of a soil component containing aqueously altered secondary minerals with the LithC precursor materials prior to impact melt generation. Recently, we studied additional impact melt glasses in two basaltic shergottites, Zagami and Shergotty using procedures similar to those described. Significant S enrichments in Zagami and Shergotty impact melt glass veins similar to the EET79001, LithC glasses were found. In addition, we noticed the depletion of the mafic component accompanied by the enrichment of felsic component in these impact melt glass veins relative to the bulk host rock in the shergottites. To explain these observations, we present a model based on comminution of basaltic rocks due to meteoroid bombardment on martian regolith and mechanical fractionation leading to enrichment of felsics and depletion of mafics in the fine grained dust which is locally mobilized as a result of saltation and deflation due to the pervasive aeolian activity on Mars.

Rao, M. N.↗
NASA NTRS2003

Nucleation and Crystallization as Induced by Bending Stress in Lithium Silicate Glass Fibers

Glass Fibers of Li2O.2SiO2 (LS2) and Li2O.1.6SiO2 (LS1.6) compositions were heated near, but below, the glass transition temperature for different times while subjected to a constant bending stress of about 1.2 GPa. The nucleation density and the crystallization tendency estimated by differential thermal analysis (DTA) of a glass sample in the vicinity of the maximum of the bending stress increased relative to that of stress-free glass fibers. LS2 glass fibers were found more resistant to nucleation and crystallization than the Ls1.6 glass fibers. These results are discussed in regards to shear thinning effects on glass stability.

Reis, Signo T.↗
NASA NTRS1996

Dissolution kinetics of a lunar glass simulant at 25 degrees C: the effect of pH and organic acids

The dissolution kinetics of a simulated lunar glass were examined at pH 3, 5, and 7. Additionally, the pH 7 experiments were conducted in the presence of citric and oxalic acid at concentrations of 2 and 20 mM. The organic acids were buffered at pH 7 to examine the effect of each molecule in their dissociated form. At pH 3, 5, and 7, the dissolution of the synthetic lunar glass was observed to proceed via a two-stage process. The first stage involved the parabolic release of Ca, Mg, Al, and Fe, and the linear release of Si. Dissolution was incongruent, creating a leached layer rich in Si and Ti which was verified by transmission electron microscopy (TEM). During the second stage the release of Ca, Mg, Al, and Fe was linear. A coupled diffusion/surface dissolution model was proposed for dissolution of the simulated lunar glass at pH 3, 5, and 7. During the first stage the initial release of mobile cations (i.e., Ca, Mg, Al, Fe) was limited by diffusion through the surface leached layer of the glass (parabolic release), while Si release was controlled by the hydrolysis of the Si-O-Al bonds at the glass surface (linear release). As dissolution continued, the mobile cations diffused from greater depths within the glass surface. A steady-state was then reached where the diffusion rate across the increased path lengths equalled the Si release rate from the surface. In the presence of the organic acids, the dissolution of the synthetic lunar glass proceeded by a one stage process. The release of Ca, Mg, Al, and Fe followed a parabolic relationship, while the release of Si was linear. The relative reactivity of the organic acids used in the experiments was citrate > oxalate. A thinner leached layer rich in Si/Ti, as compared to the pH experiments, was observed using TEM. Rate data suggest that the chemisorption of the organic anion to the surface silanol groups was responsible for enhanced dissolution in the presence of the organic acids. It is proposed that the increased rate of Si release is responsible for the one stage parabolic release of mobile cations and the relatively thin leached layer compared to experiments at pH 3 and 5.

NASA Discipline Life Support Systems↗
NASA NTRS2013

Constraining the Flux of Impactors Postdating Heavy Bombardment Using U-Pb Ages of Impact Glasses

Spherules of glass varying in size from a few micrometres to a few millimetres are common in the lunar regolith. While some of these glass beads are products of pyroclastic fire fountains others originate as impact melt ejected from the target that breaks into small droplets and solidifies as spherical particles while raining back to the lunar surface. These glasses preserve information about the chemical composition of the target and often contain sufficient amount of radioactive nuclides such as 40K to enable Ar-40-Ar-39 dating of individual beads. Studies measuring the age of glass beads have been used in attempts to establish variations in the flux of impactors hitting the Moon, particularly during the period that postdates the formation of major impact basins [1,2]. These studies proposed a possibility of spike in the impact flux about 800 Ma [2] and over the last 400 Ma [1]. More recently U-Th-Pb isotopic systems have been also utilized to determine the age of impact glasses from the Apollo 17 regolith [3]. Our aim is to extend the application of the U-Pb system in impact glasses to spherules isolated from Apollo 14 soil 14163 in an attempt to further investigate the applicability of this isotopic system to the chronology of impact glass beads and gain additional information on the impact flux in the inner Solar system.

Nemchin, A. A.↗
NASA NTRS2015

Methods of Fabricating a Layer of Metallic Glass-Based Material Using Immersion and Pouring Techniques

Systems and methods in accordance with embodiments of the invention implement layers of metallic glass-based materials. In one embodiment, a method of fabricating a layer of metallic glass includes: applying a coating layer of liquid phase metallic glass to an object, the coating layer being applied in a sufficient quantity such that the surface tension of the liquid phase metallic glass causes the coating layer to have a smooth surface; where the metallic glass has a critical cooling rate less than 1000 K/s; and cooling the coating layer of liquid phase metallic glass to form a layer of solid phase metallic glass.

Hofmann, Douglas↗
NASA NTRS2016

Vanadium K Xanes Studies of EET79001 Impact-Melt Glasses Revisited

Some impact-melt glasses in shergottites are rich in Martian atmospheric noble gases and sulfur suggesting a possible association with regolith-derived secondary mineral assemblages in the shocked samples. Previously, we studied two glasses, # 506 (Lith C in Lith A) and # 507 (Lith C in Lith B) from EET79001 [1,2] and suggested that sulfur initially existed as sulfate in the glass precursor materials and, on shock-melting of the precursors, the sulfate was reduced to sulfides in the shock glasses. To examine the validity of this hypothesis, we used V K microXANES techniques to measure the valence states of vanadium in the Lith C glasses from Lith A and Lith B in EET79001 [3] to complement and com-pare with previous analogous measurements on,78 glass (Lith C in Lith A) [4,5]. We reported the preliminary results in [3]. Vanadium is ideal for addressing the redox issue because it has multiple valence states and is a well-studied element. Vanadium in basalts exists mostly as V(sup 3+), V(sup 4+) and V(sup 5+) in terrestrial samples, mainly as V(sup 3+) with minor V(sup 2+) and minor V(sup 4+) in lunar samples and as roughly equal mixtures of V(sup 3+) and V(sup 4+) in Martian meteorites. In this report, we discuss the application of the V K XANES results to decipher the nature of shock reduction occurring in the silicate glasses during the impact process.

Sutton, S. R.↗
NASA NTRS1971

Determining and analyzing the strength and impact resistance of high modulus glass

An error was noticed recently in the computer program used to reduce the laboratory sonic measurements to tabulated values of Young's modulus of the bulk samples of experimental glasses. Correction of this error gave revised values for the last fifty experimental glasses prepared in this laboratory. This corrected data, when examined as input material for the calculation of Young's modulus of bulk glasses from composition by the C. J. Phillips procedure, resulted in new values for the contribution per mol of several oxides. The new value for the zinc oxide molal factor is especially significant since it is slightly greater than the factor for beryllia for the types of glasses melted in the UARL research program. This discovery provides a new tool in the search for nontoxic, i.e. without beryllia, high modulus glass fibers particularly when coupled with recent measurements that showed zinc oxide contributes significantly to increased impact strength. New glass compositions prepared in this period and the latest impact strength values measured are also included.

Bacon, J. F.↗
NASA NTRS1974

Apollo 17 orange glass - Textural and morphological characteristics of devitrification

Results of a study are presented concerning (1) the significance of nonexcentroradial growth textures in Apollo 17 orange glass and a comparison of these textures with those that develop in lunar and meteoritic chondrules, (2) the development and the nature of the crystalline-glass interface, and (3) the morphology and growth characteristics of olivine and of the opaque mineral oxides that result by devitrification of the orange glass. Observations of the orange glass soil are contrasted with subsequent partial melting of orange glass spherules that were incorporated into mildly metamorphosed breccias, and the quench textures that result in these larger cooling units are compared with the textures produced by supercooling of small particulate spherules. Results show that the expected changes in viscosity due to partial melting and recrystallization do not affect the shape of individual particles, and that neither the thermal gradients that need to be invoked across 20-100 micron spheres nor collision of glass particles during lava fountaining can account for the devitrification textures observed.

Haggerty, S. E.↗
NASA NTRS1976

Space processing of chalcogenide glass

The manner in which the weightless, containerless nature of in-space processing can be successfully utilized to improve the quality of infrared transmitting chalcogenide glasses was investigated. The following conclusions were reached: (1) Laboratory experiments have established the techniques, processes and equipment necessary for the production of high purity chalcogenide glasses. (2) Processing techniques have been successfully adopted for Ge28Sb12Se60 glass in a 1-g environment. (3) The Ge28Sb12Se60 glasses that have been processed have optical transmission around 63% (5 mm thick). (4) Laboratory experiments have established that the use of precursor materials in powdered form increases the oxygen contamination of the processed glass. This indicates that high purity precursor materials in bar or pellet form should be used. (5) Modifications were made on the MSFC acoustic levitator in an attempt to improve levitation stability during long-time experiments. Room temperature experiments on As2S3 glasses and high temperature experiments on polystyrene were conducted.

Ali, M. A.↗
NASA NTRS1976

Processing FeB03 glass-ceramics in space

The possibility of preparing FeBO3 glass-ceramic in space is explored. A transparent glass-ceramic of FeBO3, due to its unique properties could be an excellent material for magneto-optic applications which currently utilize high price materials such as single crystals of Ga-YIG. The unique magneto-optic properties of FeBO3 were found to come from glass-ceramic but not from the glass form. It was anticipated and later confirmed that the FeBO3 glass-ceramics could not be prepared on earth. Phase separation and iron valence reduction, were identified as the two terrestrial manufacturing obstacles. Since the phase separation problem could be overcome by space processing, the preparation of FeBO3 glass-ceramic in space appears attractive.

Li, C. T.↗
NASA NTRS1979

Evaluation of cellular glasses for solar mirror panel applications

An analytic technique was developed to compare the structural and environmental performance of various materials considered for backing of second surface glass solar mirrors. Cellular glass was determined to be a prime candidate due to its low cost, high stiffness-to-weight ratio, thermal expansion match to mirror glass, evident minimal environmental impact and chemical and dimensional stability under conditions of use. The current state of the art and anticipated developments in cellular glass technology are discussed; material properties are correlated to design requirements. A mathematical model is presented which suggests a design approach which allows minimization of life cost; and, a mechanical and environmental testing program is outlined, designed to provide a material property basis for development of cellular glass hardware, together with methodology for collecting lifetime predictive data. Preliminary material property data from measurements are given. Microstructure of several cellular materials is shown, and sensitivity of cellular glass to freeze-thaw degradation and to slow crack growth is discussed. The effect of surface coating is addressed.

Giovan, M.↗
NASA NTRS1978

Integral assembly of photovoltaic arrays using glass

For a number of reasons glass is an excellent material for encapsulation of solar cell arrays. Glass can be readily available at relatively low cost. It exhibits excellent stability against degradation by solar ultraviolet illumination and atmospheric pollutants. A superior approach results if glass is employed directly as an integral encapsulant without secondary organic materials. A description is presented of a electrostatic bonding process which is being developed for integral assembly of glass encapsulated arrays. Solar cells are placed in contact with the glass surface, temperature is raised until the glass becomes ionically conductive, and an electric field is applied to initiate the bonding action. Silicon solar cells up to 3 inches in diameter have been integrally bonded without degradation.

Younger, P. R.↗
NASA NTRS1978

Ion microprobe analyses of aluminous lunar glasses - A test of the 'rock type' hypothesis

Previous soil survey investigations found that there are natural groupings of glass compositions in lunar soils and that the average major element composition of some of these groupings is the same at widely separated lunar landing sites. This led soil survey enthusiasts to promote the hypothesis that the average composition of glass groupings represents the composition of primary lunar 'rock types'. In this investigation the trace element composition of numerous aluminous glass particles was determined by the ion microprobe method as a test of the above mentioned 'rock type' hypothesis. It was found that within any grouping of aluminous lunar glasses by major element content, there is considerable scatter in the refractory trace element content. In addition, aluminous glasses grouped by major elements were found to have different average trace element contents at different sites (Apollo 15, 16 and Luna 20). This evidence argues that natural groupings in glass compositions are determined by regolith processes and may not represent the composition of primary lunar 'rock types'.

Meyer, C., Jr.↗
NASA NTRS1981

Fracture mechanics of cellular glass

The fracture mechanics of cellular glasses (for the structural substrate of mirrored glass for solr concentrator reflecting panels) are discussed. Commercial and developmental cellular glasses were tested and analyzed using standard testing techniques and models developed from linear fracture mechanics. Two models describing the fracture behavior of these materials were developed. Slow crack growth behavior in cellular glass was found to be more complex than that encountered in dense glasses or ceramics. The crack velocity was found to be strongly dependent upon water vapor transport to the tip of the moving crack. The existence of a static fatigue limit was not conclusively established, however, it is speculated that slow crack growth behavior in Region 1 may be slower, by orders of magnitude, than that found in dense glasses.

Zwissler, J. G.↗
NASA NTRS1982

Containerless preparation of advanced optical glasses: Experiment 77F095

Containerless processing of optical glasses was studied in preparation for space shuttle MEA flight experiments. Ground based investigation, experiment/hardware coordination activities and development of flight experiment and sample characterization plans were investigated. In the ground based investigation over 100 candidate glass materials for space processing were screened and promising compositions were identified. The system of Nb2O5-TiO2-CaO was found to be very rich with containerless glass compositions and as extensive number of the oxides combinations were tried resulting in a glass formation ternary phase diagram. The frequent occurrence of glass formation by containerless processing among the compositions for which no glass formations were previously reported indicated the possibility and an advantage of containerless processing in a terrestrial environment.

Happe, R. A.↗
NASA NTRS1981

Lunar volcanic glasses and their constraints on mare petrogenesis

The compositional properties of volcanic glasses from the Apollo 11, 14, 15 and 16 landing sites are examined and implications of the results for mare basalt petrogenesis and deep lunar structures are discussed. Major-element and nickel analyses were performed on the glasses using electron probe techniques, and R-mode principal component analysis was performed on the 19 different compositions of glass distinguished. The glasses are found to form two distinct chemical arrays based on the major elements and Ni. The presence of two chemically isolated cumulate systems in the mantle at different depths is thus inferred, and a model is developed for mare petrogenesis in which each system was itself composed of two lithologic components that underwent hybridization, assimilation or mixing to generate the large compositional range of magmas represented by the lunar volcanic glasses. The surface-correlated elements associated with the volcanic glasses are attributed to another reservoir in the deep interior which may be responsible for gas emissions causing lunar transient phenomena. The model developed allows predictions to be made concerning the liquidus phase relations, trace and radiogenic element distributions, nonradiogenic isotope compositions and sample ages.

Delano, J. W.↗
NASA NTRS1982

Ferromagnetic resonance intensity - A rapid method for determining lunar glass bead origin

Ferromagnetic resonance intensity, I(s), relies on the absence or presence of single-domain Fe formed during impact melting by autoreduction of Fe(2+) in the melt to distinguish volcanic from impact glass spherules in the lunar soil. SEM inspection of individual glass bead surfaces gave reliable evidence of the mode of glass genesis. Ferromagnetic resonance intensity was tested against the Apollo 15 and 17 volcanics. I(s) values of less than one were found in 94% of the volcanic glasses, implying the absence of single-domain Fe, while 75% of the impact glasses had elevated I(s) values. These samples lack single-domain Fe, and may represent impact melts of bedrock with little or no regolith contribution. Both the primary discrimination of volcanic and impact glasses, and the secondary one of bedrock-derived impact melts from impact melts partially or entirely derived from regolith, have been demonstrated for the I(s) technique.

Stone, C. D.↗