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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Meeting sustainable aviation fuel policy targets through first generation corn biorefineries

This paper investigates options to produce low carbon and renewable aviation fuel through existing commercial first generation biorefineries, which could be strategic given the rapid growth of the electric vehicle market for personal mobility. We evaluate the environmental impact of retrofitting a first generation biorefinery to produce aviation fuel through chemical process simulation. The analysis investigates the potential for reducing greenhouse gas (GHG) emissions and displacing fossil fuel (petroleum-based jet kerosene) in the aviation fuel industry through using corn feedstocks in dry grind biorefineries to convert sugars to 1,4-dimethylcyclooctane (DMCO), which qualifies as renewable jet-A fuel blend and is infrastructure compatible. Further, the average life cycle GHG emissions for a baseline case and a scenario with carbon capture and storage (CCS) of fermentative CO 2 are 36 and 5g CO 2 e/MJ DMCO, respectively. Investment in CCS at the biorefinery and adoption of crop best management practices on farms are essential for mitigating the risks of induced land use change GHG emissions for existing corn biorefineries. DMCO as a low-carbon aviation fuel could be a strategic fuel product for retrofitting existing corn dry grind facilities. For aviation fuel supply, corn dry grind facilities could displace about 12% of jet fuel demand in the near term, which would meet sustainable aviation fuel policy targets. We conclude that corn-to-DMCO shows promise for near-term low-carbon fuel markets in the aviation industry and as a bridge to developing biomass-based jet fuel in the future.

09 BIOMASS FUELS↗
DOE OSTI2023

Ultrafine-grained Fe-TiB 2 high-modulus nanocomposite steel with high strength and isotropic mechanical properties by laser powder bed fusion

Fe-TiB 2 metal matrix composite, also called high-modulus steels (HMSs), are of great interest for applications in fuel-efficient transportation infrastructure, aerospace, and wear industries due to their high specific stiffness and yield strength. However, conventional cast Fe-TiB 2 HMSs often contain coarse and sharp-edged TiB 2 particles which easily trigger premature cracking during loading. Here, we synthesized a Fe-TiB 2 nanocomposite HMS via laser powder bed fusion (LPBF) additive manufacturing of mixed micro-sized powders of Fe, Ti, and Fe 2 B. We investigated the microstructure formation and mechanical behavior of the Fe-TiB 2 HMS. We found that in situ chemical reaction of Ti and Fe 2 B enables the formation of TiB 2 particles at nanoscale during rapid solidification of LPBF. These nanoscale TiB 2 particles can serve as heterogeneous nucleation sites and promote the formation of ultrafine and equiaxed α-Fe grains with random crystallographic textures, which differ from many other additively manufactured (AM) metal alloys characteristic of strong crystallographic textures. As such, isotropic mechanical properties were achieved in the AM Fe-TiB 2 nanocomposite HMS with a high elastic modulus of ~ 240 GPa, an exceptional yield strength of ~ 1450 MPa, and a large plasticity of ~ 20% under compression. Quantitative analysis reveals that the high yield strength primarily originates from strengthening contributions of the ultrafine grains with an average grain size of ~450 nm, the nanoscale TiB 2 reinforcing particles of 20–180 nm, and a high density of printing-induced dislocations of the order of 10 15 m –2 . In situ synchrotron high-energy X-ray diffraction unveils the load partitioning from the softer α-Fe matrix to the stiffer and stronger TiB 2 nanoparticles, contributing to the sustained strain hardening during compression. Our work not only provides a general pathway for achieving high-performance metal matrix nanocomposites by in situ chemical reaction and precipitation of ceramic nanoparticles during additive manufacturing, but also offers mechanistic insights into the deformation mechanism of nanoparticle-reinforced HMS composites.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Risk assessment and ventilation modeling for hydrogen releases in vehicle repair garages

The availability of repair garage infrastructure for hydrogen fuel cell vehicles is becoming increasingly important for future industry growth. Ventilation requirements for hydrogen fuel cell vehicles can affect both retrofitted and purpose-built repair garages and the costs associated with these requirements can be significant. A hazard and operability (HAZOP) study was performed to identify risk-significant scenarios related to light-duty hydrogen vehicles in a repair garage. Detailed simulations and modeling were performed using appropriate computational tools to estimate the location, behavior, and severity of hydrogen release based on key HAZOP scenarios. Here, this work compares current fire code requirements to an alternate ventilation strategy to further reduce potential hazardous conditions. Modeling shows that position, direction, and velocity of ventilation have a significant impact on the amount of instantaneous flammable mass in the domain.

08 HYDROGEN↗
DOE OSTI2022

The pursuit of net-positive sustainability for industrial decarbonization with hybrid energy systems

We report signatories of the Paris Agreement are set to miss their climate targets. The net-zero pledges announced to date across many countries and private industries are insufficient to achieve carbon neutrality, which requires implementation of far-reaching and significantly scaled-up climate-positive actions. All technology options that pertain to deep decarbonization and carbon removal must be part of the mitigation portfolio. Transformative action plans must be established in which every individual/organization around the globe is an actor of changes in relation to net-zero goals. Such plans must involve governmental policy support but also encourage voluntary efforts to boost innovations, investments, initiatives, and behavioral changes. Recognition of these efforts is made quantifiable with the concepts of carbon handprint and net positivity. This paper presents a carbon handprint perspective on characterizing the environmental benefits of hybrid energy systems (HESs)—a widely applicable solution to cleaner production leveraging the capabilities of a portfolio of low-carbon energy sources—that provide heat and electricity to industrial processes. First, the carbon handprint and net positivity concepts and their calculation approach are introduced. The state of the art of HES-enabled industrial cogeneration is then surveyed, and the greenhouse gas emission intensities of different energy sources that power HESs are compared. Next, drawing on a case study about a US chemical facility's voluntary initiative to explore replacing its fossil fuel–based cogeneration infrastructure with a clean energy–generated HES, several technically viable scenarios are evaluated—especially those with small modular nuclear reactors—to illustrate how the positive-thinking handprint approach helps encourage and inform the search for widespread influence pathways in pursuit of net-positive sustainability. Finally, current knowledge gaps in the case study are identified, and opportunities to scale up the proposed handprint-based analysis are outlined with consideration of an expanded role of HESs in fulfilling climate objectives.It is envisioned that like-minded decision makers in the industry sector and beyond will adopt this perspective and act synergistically to enhance their environmental stewardship through voluntary actions and make greater contributions to the planet's climate future.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2022

Molecular-scale mechanisms of CO 2 mineralization in nanoscale interfacial water films

The calamitous impacts of untethered carbon emission from fossil-fuel-burning energy infrastructure calls for accelerated development of large-scale CO 2 capture, utilization, and storage technologies that are underpinned by fundamental understanding of molecular-level chemical processes. In the subsurface, rocks rich in divalent metals can react with CO 2 , permanently sequestering it in the form of stable metal carbonate minerals, with the CO 2 -H 2 O composition of the post-injection pore fluid acting as a primary control variable. Herein, we compare mechanistic reaction pathways for aqueous-mediated carbonation with carbon mineralization occurring in nanoscale adsorbed water films. In the extreme of pores filled with a CO 2 -dominant fluid, carbonation reactions are confined to nanometer-thick water films coating mineral surfaces, which enable metal cation release, transport, nucleation, and crystallization of metal carbonate minerals. Though seemingly counterintuitive, laboratory studies have demonstrated facile carbonation rates in these low water environments, which in recent years has begun to be better understood in mechanistic detail. The overarching objective of this review is to delineate the unique underlying molecular-scale reaction mechanisms that govern CO 2 mineralization in these reactive and dynamic quasi-2D interfaces. Here. we highlight the importance of understanding unique properties in thin water films, such as how water dielectric properties, and consequently ion solvation/hydration behavior, can change under nanoconfinement. We conclude by identifying important frontiers for future work and opportunities to exploit these fundamental chemical insights for decarbonization technologies in the 21st century.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Risk Assessment and Ventilation Modeling for Hydrogen Release in Vehicle Repair Garages

The availability of repair garage infrastructure for hydrogen fuel cell vehicles is becoming increasingly important for future industry growth. Ventilation requirements for hydrogen fuel cell vehicles can affect both retrofitted and purpose-built repair garages and the costs associated with these requirements can be significant. A hazard and operability study (HAZOP) was performed to identify key risk-significant scenarios related to hydrogen vehicles in a repair garage. Detailed simulations and modeling were performed using appropriate computational tools to estimate the location, behavior, and severity of hydrogen release based on key HAZOP scenarios. This work compares current fire code requirements to an alternate ventilation strategy to further reduce potentially hazardous conditions. Overall, the amount of flammable mass of hydrogen at any one time in the simulation is low compared to the total mass of hydrogen released, due to the low flow rate of a low pressure release. It is shown that position, direction, and velocity of ventilation have a significant impact on the amount of instantaneous flammable mass in the domain.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2024

Learnings From the 2022 NREL Partner Forum: Research Needs for Aircraft

During the 2022 Partner Forum at the National Renewable Energy Laboratory (NREL), stakeholders and experts from across aviation came to the whiteboard to outline common goals, align interests, understand technologies, and discuss steps for safely and seamlessly decarbonizing aviation. Experts identified challenges, strategies, and needed research on sustainable aviation fuel, alternative propulsion, infrastructure, and aircraft. Initial insights, strategies, and high-level suggestions from the aircraft workshop are summarized below, including potential barriers and synergies for achieving bold decarbonization goals.

aircraft↗
DOE OSTI2020

Evolution of Plug-In Electric Vehicle Charging Infrastructure in the United States: Preprint

The U.S. Department of Energy’s Alternative Fuels Data Center (AFDC) has tracked alternative fueling and electric vehicle charging infrastructure in the United States since 1991. This paper explores the history of the AFDC Station Locator, which was launched in 1999, and discusses the growth of electric vehicle supply equipment. It also looks at how electric vehicle drivers access public charging, and evaluates challenges, gaps, and opportunities facing both electric vehicle drivers and the industry as a whole.

ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2020

Progress and Prospective of Nitrogen-Based Alternative Fuels

Alternative fuels are essential to enable the transition to a sustainable and environmentally friendly energy supply. Synthetic fuels derived from renewable energies can act as energy storage media, thus mitigating the effects of fossil fuels on environment and health. Their economic viability, environmental impact, and compatibility with current infrastructure and technologies are fuel and power source specific. Nitrogen-based fuels pose one possible synthetic fuel pathway. In this paper, we discuss the progress and current research on utilization of nitrogen-based fuels in power applications, covering the complete fuel cycle. We cover the production, distribution, and storage of nitrogen-based fuels. We assess much of the existing literature on the reactions involved in the ammonia to nitrogen atom pathway in nitrogen-based fuel combustion. Furthermore, we discuss nitrogen-based fuel applications ranging from combustion engines to gas turbines, as well as their exploitation by suggested end-uses. Thereby, we evaluate the potential opportunities and challenges of expanding the role of nitrogen-based molecules in the energy sector, outlining their use as energy carriers in relevant fields.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Midwest ZEVI 2030 Charging Roadmap for I-80 Corridor

Zero-emission Medium Duty and Heavy Duty vehicles (MD-HD ZEVs) hold great promise for reducing operational costs through use of more energy eAicient propulsion technology while reducing reliance on fossil fuels. Consistent with the Department of Energy’s focus on energy innovation, ZEVs and the necessary charging and refueling infrastructure to support them represent an important area of focus for technological advancement. Widespread adoption of MD-HD ZEVs can also provide benefits by improving air quality, and lowering carbon emissions in the transportation industry. Powertrain technologies are in production today to reduce tank-to-wheel and well-to-wheel emissions of commercial vehicles to zero or near-zero emissions, but significant development remains to bring down the cost and address the operational limitations of these technologies, particularly for larger vehicles. ZEV technologies have an opportunity to be an important part of a fleet’s mix of powertrains as capital and operational costs come down. However, the greatest challenge preventing widespread adoption of ZEVs may be the lack of adequate charging and hydrogen (H₂) fueling infrastructure.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2026

United States Nuclear Power Reactor Used Nuclear Fuel Database and Applications

The Unified Database (UDB) within STANDARDS serves as the foundational data infrastructure for managing the United States' spent nuclear fuel inventory of 315,111 discharged assemblies totaling 91,036 metric tons of heavy metal. The database organizes this complex inventory through over 200 interconnected tables structured into eight primary attribute categories, supporting integrated analyses across storage, transportation, and disposal domains. Data enters the UDB through the GC-859 Nuclear Fuel Data Survey, which transitioned to web-based collection in 2023, improving data quality through real-time validation. The UDB enables automated generation of input files for nuclear safety analyses, reducing preparation time from weeks to hours while maintaining traceability. Applications include national inventory reporting, Certificate of Compliance assessments, and facility optimization. The three-tier distribution model balances accessibility with security requirements for federal agencies, national laboratories, and research organizations. The UDB provides essential data infrastructure as spent fuel management transitions from site-specific to integrated national campaigns.

Stefanovic, Peter↗
DOE OSTI2024

A Multi-Streamline Approach for Upcycling PET into a Biodiesel and Asphalt Modifier

The non-degradable nature of petroleum-based plastics and the dependence on petroleum-based products in daily life and production are dilemmas of human development today. We hereby developed a plastic waste upcycling process to address these challenges. A multi-stream fraction strategy was developed to process poly (ethylene terephthalate) (PET) plastics into soluble and insoluble fractions. The soluble fraction was used as a sole carbon source for microbial fermentation to produce biodiesel precursor lipids with an appreciable bioconversion yield. The insoluble fraction containing fractionated polymers was used as the asphalt binder modifiers. The downsized PET additive improved the high-temperature performance of the asphalt binder by 1 performance grade (PG) without decreasing the low-temperature PG. Subsequent SEM imaging unveiled alterations in the micromorphology induced by PET incorporation. Further FTIR and 1 H NMR analysis highlighted the aromatic groups of PET polymers as a crucial factor influencing performance enhancement. The results demonstrated the multi-stream fraction as a promising approach for repurposing plastic waste to produce biodiesel and modify asphalt. Finally, this approach holds the potential to tackle challenges in fuel supply and enhance infrastructure resilience to global warming.

09 BIOMASS FUELS↗
DOE OSTI2020

A Perspective on Biomass-Derived Biofuels: From Catalyst Design Principles to Fuel Properties

The hazards to health and the environment associated with the transportation sector include smog, particulate matter, and greenhouse gas emissions. Conversion of lignocellulosic biomass into biofuels has the potential to provide significant amounts of infrastructure-compatible liquid transportation fuels that reduce those hazardous materials. However, the development of these technologies is inefficient, due to: (i) the lack of a priori fuel property consideration, (ii) poor shared vocabulary between process chemists and fuel engineers, and (iii) modern and future engines operating outside the range of traditional autoignition metrics such as octane or cetane numbers. In this perspective, we describe an approach where we follow a “fuel-property first” design methodology with a sequence of (i) identifying the desirable fuel properties for modern engines, (ii) defining molecules capable of delivering those properties, and (iii) designing catalysts and processes that can produce those molecules from a candidate feedstock in a specific conversion process. Computational techniques need to be leveraged to minimize expenses and experimental efforts on low-promise options. This concept is illustrated with current research information available for biomass conversion to fuels via catalytic fast pyrolysis and hydrotreating; outstanding challenges and research tools necessary for a successful outcome are presented.

BIOMASS FUELS↗
DOE OSTI2021

Accessibility and Availability of Gas Stations for Liquid Fuel Supply During Severe Weather Events

Energy infrastructure is a pivotal lifeline with wider inter-dependencies. Electric power is essential to the continued functioning of critical assets; liquid fuels and other physical primary energy commodities that are used to supply the local energy needs of these assets during extreme events when electricity infrastructure is compromised. During Superstorm Sandy, the disruption of fuel supplies in the Tri-state area necessitated increasing situational awareness about oil and natural gas (ONG) systems to redirect fuel supplies to first responders and for restoration efforts. During winter storm events over the past several years, the demand for ONG for heating and power generation has skyrocketed in the north-east, which subsequently had caused ONG price to hit their highest level in years. ONG is a major energy source for restoration and recovery activities. However, very little, if any, situational awareness information about ONG supply and demand is available to those coordinating emergency efforts. Often this lack of information is due to the decentralized nature of the ONG supply chain and proprietary data maintained by private entities. To understand the impact of fuel availability on response and recovery efforts, this research focuses on (i) determining the accessibility to gas stations for liquid fuel supply across space and time, and (ii) examining the spatio-temporal variation of fuel availability and demand during extreme weather events. The broader scope of the project focuses on providing spatio-temporal situational awareness information about ONG availability and demand across the fuel supply chain for positioning of resources for response activities.

Kar, Bandana↗
DOE OSTI2022

FY2022 Progress Report for Advanced Re-fabrication/Re-instrumentation Capability Development

In support of performing follow-on irradiation experiments with previously irradiated materials, the Halden Reactor Project developed unique and state of the art capabilities to refabricate and re-instrument previously irradiated materials. Such materials were used in in-pile tests at the Halden reactor, and out-of-pile tests for example using furnaces as a heat source. The decision to close the Halden Reactor Project results in the loss of this refabrication and re-instrumentation capability. As a result, the United States (U.S.) Department of Energy (DOE) has determined to develop refabrication and re-instrumentation capability at the unique shielded facilities at Idaho National Laboratory (INL). The development of refabrication capability has been completed and demonstrated. This report focuses on the complementary aspects of reinstrumentation and the progress to-date. Halden spent nearly 30 years developing both refabrication and re-instrumentation. Collaboration with Halden is allowing Idaho National Laboratory (INL) to develop this capability much more rapidly. In FY-21 the results include development of the capability to drill annular center holes in ceramic UO2 fuel pellets, development of fuel rod end caps with feedthroughs for centerline instrumentation inside the rodlet, The procurement of both fuel drilling and welding demonstration equipment from Halden, evaluation of surface thermocouple attachments to support better understanding of temperature measurement uncertainties, and finally, the conceptual design of a new shielded enclosure where advanced refabrication and re-instrumentation equipment can be housed. In FY-22, the results include; Completing set up of the drilling and welding modules procured from Halden, and early experimental trials using that equipment.; Completing set up of an out-of-cell circumferential weld system to allow for further weld development to take place and support fabrication of fuel for fresh fuel experiments.; Evaluation of the Hot Fuel Examination Facility (HFEF) infrastructure to support future installation of advanced re-fabrication/re-instrumentation equipment, specifically related to necessary infrastructure for cryo-drilling.; Developments in dry-drilling alternative. Including experimental studies showing cordierite is the most suitable surrogate for UO 2 for performing drilling studies. That drilling performance is enhanced when a fuel-clad bonding condition is simulated.; Conceptual design completed for attaching surface thermocouples to irradiated fuel in support of TWIST capsule experiments. The authors would like to thank the numerous colleagues at INL and Halden who provided support in accomplishing this work. Their support both material and intellectual is invaluable in advancing the state of the art and establishing the capabilities for refabrication and re-instrumentation at INL.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

H2@Scale Program Multi-Party Cooperative Research and Development Agreement: California Hydrogen Infrastructure Research Consortium Task (Cooperative Research and Development Final Report, CRADA Number CRD-18-00754)

Many stakeholders are working on hydrogen and fuel cell products, markets, requirements, mandates, and policies. California has been leading the way for hydrogen infrastructure and fuel cell electric vehicle (FCEV) deployment. This leadership has advanced a hydrogen network that is not duplicated anywhere in the United States and is unique in the world for its focus on providing a retail fueling experience. In addition, the advancements have identified many lessons learned for hydrogen infrastructure development, deployment, and operation. Other interested states and countries are using California's experience as a model case, making success in California paramount to enabling market acceleration and uptake in the United States. The technical research capability of the national laboratories can be used to assist California in decisions and evaluations, as well as to verify solutions to problems impacting the industry. Because these challenges cannot be addressed by one agency or one laboratory, a hydrogen research consortium has been organized to combine and collaborate. The collaboration aims to ensure that data are available to evaluate projects and inform decision makers, independently verify and validate component solutions, provide experimental results for future hydrogen infrastructure, increase the availability of technical experts for quick-need issues for California hydrogen infrastructure development, deployment, operation, and technology advances. The proposed tasks include data collection from operational stations, component failure fix verification (i.e. nozzle freeze lock), new fueling methods for medium and heavy duty applications, and ensuring hydrogen quality is maintained. U.S. leadership for hydrogen technologies is rooted in California, a location for implementing many H2@Scale pathways such as reducing curtailment and stranded resources, reducing petroleum use and emissions, and developing and creating jobs.

08 HYDROGEN↗
DOE OSTI2022

Co-processing Part 3: LANL Studies Quicker Method to Identify Renewable Carbon Percentages in Fuel Blends [Success Story]

Upgrading bio-oils with petroleum feedstocks at existing refineries—known as “co-processing”—could offer a fast pathway for lowering the carbon footprint of today’s transportation fuels. With equipment and infrastructure already in place, more than 100 refineries across the country are equipped to integrate bio-oil into their processes. But just where might companies insert sustainable bio-oils into existing refinery systems like fluid catalytic crackers and hydrotreaters? If successful, just how much of that renewable or “green” carbon makes it into final fuel products? In this three-part blog series, the National Renewable Energy Laboratory (NREL), Pacific Northwest National Laboratory (PNNL), and Los Alamos National Laboratory (LANL) offer insights into these pressing coprocessing questions—and others—amid the push to dramatically expand the production of climate-friendly fuels. Read part 1 and part 2.

02 PETROLEUM↗