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A case study in contrastive learning information combination: Application to technical forensics of additive manufacturing filament source identification

Combination of information from disparate data sources into a single decision is a core challenge in many fields, including the field of technical forensics. Technical forensics (TF) utilizes technical characterization of questioned samples to determine properties of that sample; these properties are then used to infer information of forensic interest, such as provenance, age, or attribution. TF is utilized in traditional forensic applications, such as the attribution of material fragments from an explosive, and in nuclear forensic applications, such as the attribution of actinides which have been interdicted out of regulatory control. The challenge of combining information from disparate sources, described alternately by many terms including “Data Fusion” and “Data Integration”, is exacerbated in the technical forensics domain due to at least two factors: the challenge of interpreting each information source singularly, and the relatively small data set sizes available. Extensive literature exists attempting to combine technical forensics information sources, both in manual and automated processes. These attempts are often bespoke to the specific information sources (such as the bi-, tri-, or quad-isotope chart (Moody, Grant, and Hutcheon 2005)), with some emerging examples of simple early- and late- fusion (, respectively). Simultaneous to the information combination efforts described in the previous paragraph, the field of natural language processing attempted (and largely succeeded) in combining information from multiple non-technical information sources. The ecosystem of “multi-modal” language models, which can take text and images as input, and generate text and images as output, became large and diverse by 2025 (Khan et al. 2025). In a generalized sense, many of these methods are trained by learning neural networks which can convert raw text or images into a vector of numbers describing the text or image, hereafter called “embeddings” and the neural networks performing the conversion are called “embedders”. By using a separate embedder for text and images, finding coincident text and images (such as images with their captions), and optimizing the parameters of the embedders such that the embeddings for the text and the image are similar, the field has found a bridge between text and images (Girdhar et al. 2023). It is the contention of the authors of this report that this insight is not limited to text and images but instead can be extended to any modality which can be found coincidently. The subject of the rest of this report is the application of this method to example multi-modal technical forensic data. Some details about the data used in this report are not appropriate for this report, and are included in a companion report (PNNL-38669).

36 MATERIALS SCIENCE↗

Surface Disturbances at the Punggye-ri Nuclear Test Site: Another Indicator of Nuclear Testing?

A review of available very high-resolution commercial satellite imagery (bracketing the time of North Korea’s most recent underground nuclear test on 9 September 2016 at the Punggye-ri Underground Nuclear Test Site) has led to the detection and identification of several minor surface disturbances on the southern flank of Mt. Mantap. These surface disturbances occur in the form of small landslides, either alone or together with small zones of disturbed bare rock that appear to have been vertically lofted (“spalled”) as a result of the most recent underground explosion. Typically, spall can be uniquely attributed to underground nuclear testing and is not a result of natural processes. However, given the time gap of up to three months between images (pre- and post-event), which was coincident with a period of heavy typhoon flooding in the area1, it is not possible to determine whether the small landslides were exclusively explosion induced, the consequence of heavy rainfall erosion, or some combination of the two.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

The evolution of complex life

The emergence of complex living organisms in the context of evolutionary biology, planetary environments, and space events is investigated. The application of data on biological evolution, climatology, and the chemical and physical environments of the earth's surface, to explain the development of extraterrestrial life is described and an example is provided. The possibility of extraplanetary disturbances such as, meteorite and comet bombardments, and supernova explosions, causing the elimination of preexisting life and allowing advanced life development is analyzed. The possible existence of different life cycles (genetic and reproductive strategies) on other planets is studied. The GAIA hypothesis (Lovelock, 1979) which states living things modify the global environment to their own advantage is examined. The improved identification of habitable planetary environments and the possible existence of a form of extraterrestrial intelligent life is discussed.

Billingham, J.↗

Passive Confirmation of the Presence Of High-Explosive Material Via Neutron Transmission Spectroscopy

The goal of this project was to explore a novel approach for identifying presence and potential types of high explosives (HE) in treaty-controlled items with passive neutron sources by using passive neutron transmission spectroscopy. We predominantly look to measure relative elemental abundance of Carbon, Hydrogen, Oxygen, and Nitrogen (CHON) since most relevant materials are certain mix of these elements, as shown in Table 1. Previously, most studies exploring potential identification of CHON elemental content of targets in the vicinity of passive neutron source were focused solely on gamma spectroscopy using high resolution gamma detectors. Using neutron transmission spectroscopy with pulse-shape discrimination (PSD) capable organic scintillators is not only a novel idea in of itself, but arguably necessary for accurate identification of the CHON elemental content of an interrogated target. While high resolution gamma spectroscopy in principle can determine a presence of hydrogen and nitrogen, it is effectively blind to a quantitatively measuring areal densities of C, O. The initially proposed approach, described in detail in the project proposal, was to leverage previous Monte Carlo study on neutron transmission spectroscopy using slab shaped target interrogated with well-collimated (“pencil”) neutron beam. In this study, a simulated test CO 2 target was interrogated by a pencil neutron beam and transmitted neutron spectra were measured using PSD capable organic scintillator using MLEM based unfolding technique. To establish relative elemental content of carbon and oxygen, the unfolded neutron spectrum was fit with a parametrized combination of their respective elemental spectral templates. The individual spectral template was calculated by convoluting ENDF neutron crosssection with the known resolution of the PSD detector used in the study. This approach in the studied configuration successfully quantitatively established relative elemental composition of carbon and oxygen.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Enhanced Techniques for Concrete Decontamination During Decommissioning - 19005

As the primary material of construction for nuclear power plant structures, concrete naturally represents the largest fraction of contaminated material by surface area. As such, decontamination of concrete is a major activity during decommissioning projects. As reported in EPRI 3002005412, Characterization and Remediation of Contaminated Concrete, currently used techniques for decontamination of contaminated concrete are generally slow and labor-intensive to apply. This report notes that little change to the techniques used for concrete decontamination have been made during the past 20 years. There is a clear need for improvement to the techniques available for decontamination of concrete. Needed enhancements include substantial improvements in efficiency, waste management, industrial safety, and worker radiation exposure. Potential areas for development include increased automation of existing techniques, improvement in delivery systems for decontamination equipment, and further development of alternative techniques such as microwave and laser scabbling, and nitrogen blasting. To address this need, EPRI is conducting a project to develop enhanced techniques for concrete decontamination. The project focuses on two primary areas: 1. Adaption of existing techniques to improve efficiency through automation and/or altering the delivery systems for the decontamination equipment (for example, through use of exiting robotic systems); and 2. Field demonstration of technologies currently in the engineering development stage, such as nitrogen blasting and laser scabbling. This paper will report the initial results of this EPRI project, which includes identification of promising candidate technologies that will be demonstrated during the next project phase. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Volcanism in Elysium Planitia, Mars

Geomorphic mapping revealed that the three volcanic constructs within Elysium Planitia (Hecates Tholus, elysium Mons and Albor Tholus) are very different in their overall morphology and represent three distinct types of martian volcano. Hecates Tholus was found to possess the most likely possible example of a young, explosively generated, air fall deposit, while the volume of magma erupted from Elysium Mons appears to have been orders of magnitude larger than that erupted from Albor Tholus. A primary aim of the regional geological analysis of Elysium Planitia is to further understand the volcanic and tectonic evolution of the area by the identification and interpretation of individual lava flows and their source vents. Lava flow size, spatial distribution, flow direction and the stratigraphic relationships of these lava flows to adjacent structural features were all measured. The topographic form of Elysium Mons has totally controlled the flow direction of lava flows within Elysium Planitia. Lava flows from Elysium Mons can be traced for distances of 150 to 250 km in a radial direction from the volcano. Parasitic vents located beyond the recognizable volcanic construct also conform to this radial pattern. A second unusual characteristic of the Elysium Planitia region is the high frequency of occurrence of sinuous channels that are morphologically similar to lunar sinuous rilles.

Mouginis-Mark, P. J.↗

Reconstruction and analysis of exploding wire particle trajectories via automatic calibration of stereo images

Quantitative understanding of the physics of dust or granular matter transport significantly impacts several aspects of burning plasma science and technology. Here, this work takes machine vision techniques popular in robotics and self-driving cars and applies them to identification and analysis of microparticles generated from exploding wires. Using only the image frames and knowledge of the intrinsic properties of the cameras, a Python code was written to identify the particles, automatically calibrate the relative image positions, and extract trajectory data. After identifying approximately 50 particles based on the timing of secondary particle explosions, the eight point and random sample consensus algorithms were used to determine the geometric correlation between the cameras. Over 100 particle matches were found between the two camera views. These correlated trajectories were used in subsequent 3D track reconstruction and analysis of the physics behind the particle motion. The 3D reconstruction resulted in accurate positioning of the particles with respect to the experimental setup. The particle motion was consistent with the effects of a 1 g gravitational field modified by drag forces. Lastly, the methods and analyses presented here can be used in many facets of high temperature plasma diagnostics.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

MCNP Simulation of Discrete Gamma-ray Spectra for PGNAA Applications

Prompt Gamma Neutron Activation (PGNAA) systems use the neutron-induced gamma-ray spectra from test objects in order to identify their compositions. The U.S. Army in particular uses these systems to identify the contents of field-recovered munitions in order to determine the presence of chemical warfare materiel (CWM) or explosives. These field-recovered munitions can have a variety of different fills, including experimental fills, have a large range of sizes, and be assessed in different field conditions. All these variations can have a significant effect on the neutron-induced gamma-ray spectrum and therefore a large impact on automatic fill identification algorithms. In order to develop robust identification algorithms, parametric studies of the effects of munition size, fill composition, and assessment conditions are very useful but time-consuming and expensive in the laboratory. Monte Carlo modeling of the system response to these variations is a very attractive alternative, provided the modeling accurately reflects real gamma spectra and can be performed quickly and inexpensively when compared to experiment. At Idaho National Laboratory we have used the Monte Carlo N-Particle (MCNP6) code [2] to calculate the response of the Portable Isotopic Neutron Spectroscopy (PINS) system to a number of simulated chemical warfare munitions as well as performed laboratory measurements with the system. Two versions of PINS system were used; one excited the test object with neutrons from a 252C f source and one with neutrons from a portable deuterium-deuterium (DD) neutron generator. The sets of measurements and simulations with the two different neutron sources provided experimental data for development of automatic fill identification algorithms as well as providing a good test of the agreement between the MCNP calculations and experiment.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

An Architectural Survey of the U12G Tunnel Historic District, Nevada National Security Site, Nye County, Nevada

The U.S. Department of Energy (DOE), in conjunction with the National Nuclear Security Administration Nevada Field Office (NNSA/NFO), proposes to demolish six buildings and three storage areas located at the U12g Tunnel portal area in Area 12 of the Nevada National Security Site (NNSS). The buildings are 12-358 (Signal Vault); 12-201800 (Storage Quonset Hut); 12-202555 (Walker Shack); 12-868 (Pipe Assembly); 12-B100933 (Electrical Shop); 12-B100944 (Conference Room); and Storage Area 1; Storage Area 2; and Storage Area 3. The buildings and storage areas were selected for demolition as part of the DOE’s Real Property Efficiency Plan to reduce the footprint of unused and non-operational facilities on the NNSS. They are all vacant and have no proposed uses for current or upcoming NNSS missions. Demolition activities constitute an undertaking subject to review under Section 106 of the National Historic Preservation Act (NHPA) (54 United States Code [USC] § 306101) and its implementing regulations, 36 Code of Federal Regulations (CFR) Part 800. Identification efforts began with resources proposed for demolition in federal Fiscal Year (FY) 23. Four buildings were proposed to be demolished in FY23 (12-358, 12-868, 12-201800, and 12-202555). These buildings and the U12g Tunnel Historic District (SHPO No. D444) were recorded in Identification, Evaluation, and Finding of Adverse Effect for the Proposed Demolition of Five Buildings in Area 12, Nevada National Security Site, Nye County, Nevada (Menocal et al. 2023). Identification efforts indicated three buildings (12-358, 12-201800, and 12-868) supported nuclear testing in the U12g Tunnel. The fourth building post-dated the use of U12g Tunnel for nuclear testing activities. The report recommended that three of the four buildings (12-358, 12-201800, 12-868) and the U12g Tunnel Historic District may be eligible for the National Register of Historic Places (NRHP). The report also found that the undertaking would have an adverse effect on the three buildings and on the historic district. The Nevada State Historic Preservation Office (SHPO) concurred with the report’s findings (Reed 2023). The U12g Tunnel was determined eligible as a historic district under the Secretary of the Interior’s (SOI) Significance Criterion A, at the local level, in the context of the Cold War as an underground testing environment for the development of nuclear weapons and to assess the effects of a nuclear explosion on materials and equipment with a period of significance from 1959 to 1971. It was also determined eligible under Significance Criterion C for embodying the distinctive characters of a horizontal tunnel complex used for nuclear testing and as a significant and distinguishable entity. The three buildings were determined to be contributing elements of the district. The undertaking was expanded with the addition of two buildings and three storage areas proposed to be demolished and located within U12g Tunnel Historic District in FY24. These five resources (12-B100933, 12-B100944, and Storage Areas 1, 2, and 3) were recorded in Supplemental Identification, Evaluation, and Finding of Effect for Additional Proposed Demolition at U12g Tunnel, Area 12, Nevada national Security Site, Nye County, Nevada (Brannan et al. 2024). Identification efforts indicated that the two buildings and Storage Area 1 supported nuclear testing in the U12g Tunnel. Storage Area 1 and Storage Area 2 post-dated the nuclear testing activities at U12g Tunnel and were not recommended as contributing elements to the district. The report also found that the undertaking would have an adverse effect on the newly identified buildings and one storage area and on the historic district. The SHPO concurred that the expanded undertaking would result in adverse effects to historic properties (Reed 2025). To resolve these adverse effects, NNSA/NFO, in consultation with the SHPO, is following standard mitigation as stipulated in the 2024 Programmatic Agreement DE-GM58-22NA25554 Among the U.S. Department of Energy and the Nevada State Historic Preservation Officer and the Advisory Council on Historic Preservation Concerning the Protection of Historic Properties on the Nevada National Security Site, Nye County, Nevada (hereafter referred to as the NNSS PA). The standard mitigation measures are outlined in Appendix D of the NNSS PA. As such, this architectural survey has been prepared in accordance with Appendix D of the NNSS PA and follows the report format outlined in Appendix F. It includes a historic context that describes the district’s origin, history, and support functions, its significance in the context of nuclear testing on the NNSS, and identifies contributing and non-contributing elements within the district. The report is accompanied by Architectural Resource Assessment (ARA) forms for individual resources and a Historic District Resource Assessment (HDRA) for the U12g Tunnel Historic District. In total, this architectural report identified 32 primary resources within the district boundary. Six of the primary resources were previously identified as contributing elements. An additional 17 resources are recommended as contributing elements to the district for a total of 23 contributing elements. The other nine resources identified are recommended as non-contributing elements to the district.

12-201800↗

The identification of meteorite inclusions with isotope anomalies

Ca-Al refractory inclusions with characteristic chemical and mineralogical compositions show an enhanced occurrence of 20 pct of isotope anomalies reflecting unknown nucleosynthetic effects for O and Mg. The anomalies are characterized by large isotope fractionation in Mg, apparent deficits in Mg-26/Mg-24, and large correlated effects for isotopes of Ca, Ti, and Cr. These isotope patterns define exotic components depleted in the most neutron-rich isotopes of Ca, Ti, and Cr, or components depleted in isotopes produced in explosive O and Si burning. An opaque assemblage within one of the inclusions yields isotope anomalies in Cr similar to the bulk inclusion and must be intrinsically part of the inclusion and not a trapped, foreign grain aggregate.

Papanastassiou, D. A.↗

Identification of Material Type and Thickness Using Combined X-ray and Fast Neutron Radiography

Material identification (ID) using radiography is a problem that has implicitly existed since the discovery of the X-ray. Since 9-11, this problem has received renewed attention for homeland security applications of the generic, “what is in the box?” type1. Examples of items potentially in the box include: roadside bombs, nuclear weapons, contraband shipments and the like. In these cases, the “what” can include: explosives, projectiles, fissile material, or drugs. Here we investigate the ability of 60Co gamma-rays, 14MeV neutrons, and their combination to tease apart information about density, thickness and atomic number of items in the box. That information subset can be combined with other types of independent information (e.g. neutron and gammaspectroscopy, intelligence, photographs etc.) to assert a more complete picture of what, exactly, is in the box? That more complete information set can form the basis for actions including: remote detonation, evacuations, disablement, detention, search, arrest etc.

36 MATERIALS SCIENCE↗

A stilbene–strontium iodide based radioxenon detection system for monitoring nuclear explosions

Atmospheric measurement of noble gases has been extensively used for monitoring clandestine nuclear weapon explosions for many years. The ratios of four xenon isotopes of interest ( 131 mXe, 133 mXe, 133 Xe, and 135 Xe) help in discriminating regular reactor operations from nuclear tests. A new coincidence-based detection system using stilbene and strontium iodide [SrI 2 (Eu)] for electron and photon detection respectively was developed at Oregon State University to address some of the challenges of the radioxenon systems deployed in the field such as memory effect, and poor energy resolution. Silicon photomultipliers (SiPMs) were used for sensing optical photons from all scintillation media. Real-time coincidence identification was achieved using the eight-channel digital pulse processor. The detection system was evaluated using lab check sources and Oregon State TRIGA reactor irradiated radioxenon samples. A 48-hour background coincidence spectrum was collected yielding a coincidence count rate and background rejection rate of 0.0174 ± 0.0003 counts per second (cps) and 98.9% respectively. The minimum detectable concentration (MDC) of the system was evaluated to be 0.11 ± 0.01, 0.13 ± 0.02, 0.20 ± 0.02, and 0.73 ± 0.08 for 131 mXe, 133 mXe, 133 Xe, and 135 Xe respectively. The memory effect of the detection system was found to be 0.069 ± 0.015%, which is almost a 70-fold reduction compared to traditional plastic scintillators. Here, the detection elements, custom-designed electronics, and the detector response to radioxenon are detailed in this work.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Branch-and-Bound algorithm applied to uncertainty quantification of a Boiling Water Reactor Station Blackout

Evaluation of the impacts of uncertainty and sensitivity in modeling presents a significant set of challenges in particular to high fidelity modeling. Computational costs and validation of models creates a need for cost effective decision making with regards to experiment design. Experiments designed to validate computation models can be used to reduce uncertainty in the physical model. In some cases, large uncertainty in a particular aspect of the model may or may not have a large impact on the final results. For example, modeling of a relief valve may result in large uncertainty, however, the actual effects on final peak clad temperature in a reactor transient may be small and the large uncertainty with respect to valve modeling may be considered acceptable. Additionally, the ability to determine the adequacy of a model and the validation supporting it should be considered within a risk informed framework. Low fidelity modeling with large uncertainty may be considered adequate if the uncertainty is considered acceptable with respect to risk. In other words, models that are used to evaluate the probability of failure should be evaluated more rigorously with the intent of increasing safety margin. Probabilistic risk assessment (PRA) techniques have traditionally been used to identify accident conditions and transients. Traditional classical event tree methods utilize analysts’ knowledge and experience to identify the important timing of events in coordination with thermal-hydraulic modeling. These methods lack the capability to evaluate complex dynamic systems. In these systems, time and energy scales associated with transient events may vary as a function of transition times and energies to arrive at a different physical state. Dynamic PRA (DPRA) methods provide a more rigorous analysis of complex dynamic systems. Unfortunately DPRA methods introduce issues associated with combinatorial explosion of states. This study presents a methodology to address combinatorial explosion using a Branch-and-Bound algorithm applied to Dynamic Event Trees (DET), which utilize LENDIT (L – Length, E – Energy, N – Number, D – Distribution, I – Information, and T – Time) as well as a set theory to describe system, state, resource, and response (S2R2) sets to create bounding functions for the DET. The optimization of the DET in identifying high probability failure branches is extended to create a Phenomenological Identification and Ranking Table (PIRT) methodology to evaluate modeling parameters important to safety of those failure branches that have a high probability of failure. The PIRT can then be used as a tool to identify and evaluate the need for experimental validation of models that have the potential to reduce risk. Finally, in order to demonstrate this methodology, a Boiling Water Reactor (BWR) Station Blackout (SBO) case study is presented.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Simulation Assisted Risk Assessment: Blast Overpressure Modeling

A probabilistic risk assessment (PRA) approach has been developed and applied to the risk analysis of capsule abort during ascent. The PRA is used to assist in the identification of modeling and simulation applications that can significantly impact the understanding of crew risk during this potentially dangerous maneuver. The PRA approach is also being used to identify the appropriate level of fidelity for the modeling of those critical failure modes. The Apollo launch escape system (LES) was chosen as a test problem for application of this approach. Failure modes that have been modeled and/or simulated to date include explosive overpressure-based failure, explosive fragment-based failure, land landing failures (range limits exceeded either near launch or Mode III trajectories ending on the African continent), capsule-booster re-contact during separation, and failure due to plume-induced instability. These failure modes have been investigated using analysis tools in a variety of technical disciplines at various levels of fidelity. The current paper focuses on the development and application of a blast overpressure model for the prediction of structural failure due to overpressure, including the application of high-fidelity analysis to predict near-field and headwinds effects.

Lawrence, Scott L.↗

Radio–X-ray synergy to discover and study jetted tidal disruption events

Observational consequences of tidal disruption of stars by supermassive black holes (SMBHs) can enable us to discover quiescent SMBHs, constrain their mass function, and study the formation and evolution of transient accretion disks and jet formation. A couple of jetted tidal disruption events (TDEs) have been recently claimed in hard X-rays, challenging jet models, which were previously applied to γ-ray bursts and active galactic nuclei. It is therefore of paramount importance to increase the current sample. In this paper, we find that the best strategy is not to use upcoming X-ray instruments alone, which will yield between several (eRosita) and a couple of hundred (Einstein Probe) events per year below redshift one. We rather claim that a more efficient TDE hunter will be the Square Kilometer Array (SKA) operating in survey mode at 1.4 GHz. It may detect up to several hundred events per year below z ∼ 2.5 with a peak rate of a few tens per year at z ≈ 0.5. Therefore, even if the jet production efficiency is not 100% as assumed here, the predicted rates should be large enough to allow for statistical studies. The characteristic TDE decay of t{sup −5/3}, however, is not seen in radio, whose flux emission is quite featureless. Identification therefore requires localization and prompt repointing by higher energy instruments. If radio candidates would be repointed within a day by future X-ray observatories (e.g., Athena- and LOFT-like missions), it will be possible to detect up to ≈400 X-ray counterparts, almost up to redshift 2. The shortcoming is that only for redshift below ≈0.4 will the trigger times be less than 10 days from the explosion. In this regard the X-ray surveys are better suited to probe the beginning of the flare, and are therefore complementary to SKA.

79 ASTRONOMY AND ASTROPHYSICS↗

IDENTIFICATION CAMPAIGN OF SUPERNOVA REMNANT CANDIDATES IN THE MILKY WAY. I. CHANDRA OBSERVATION OF G308.3-1.4

ROSAT all-sky survey data have provided another window in which to search for supernova remnants (SNRs). In re-examining this data archive, a list of unidentified extended X-ray objects have been suggested as promising SNR candidates. However, most of these targets have not yet been fully explored by state-of-the-art X-ray observatories. To select a pilot target for a long-term identification campaign, we observed the brightest candidate, G308.3-1.4, with the Chandra X-ray Observatory. An incomplete shell-like X-ray structure that is well correlated with the radio shell emission at 843 MHz has been revealed. The X-ray spectrum suggests the presence of a shock-heated plasma. All these evidences confirm G308.3-1.4 as an SNR. The brightest X-ray point source detected in this field of view is also the one located closest to the geometrical center of G308.3-1.4, which has a soft spectrum. The intriguing temporal variability and the identification of the optical/infrared counterpart rule out the possibility of an isolated neutron star. On the other hand, the spectral energy distribution from the K{sub s} band to the R band suggests a late-type star. Together with a putative periodicity of {approx}1.4 hr, the interesting excesses in the V and B bands and in H{alpha} suggest that this source is a promising candidate for a compact binary that survived a supernova explosion.

79 ASTRONOMY AND ASTROPHYSICS↗

New methods for trace analysis of gamma-irradiated pentaerythritol tetranitrate

High explosives (HEs) are used in a diverse range of applications in which they could be exposed to various radiation levels that may cause potential chemical changes. This study further evaluated pentaerythritol tetranitrate (PETN) that was previously aged with a low-level 2 kGy dose of gamma irradiation in order to understand chemical changes caused by irradiation. Both unirradiated PETN and gamma-irradiated PETN were analyzed using ultra high-pressure liquid chromatography coupled to quadrupole time of flight mass spectrometry (UHPLC-QTOF). The resulting data were processed in a non-targeted manner using Fisher's ratio analysis and multivariate curve resolution-alternating least squares (MCR-ALS) to aid in discovery and identification of the chemical changes brought about by irradiation without a priori knowledge. The application of using UHPLC-QTOF in combination with chemometric techniques for the analysis of irradiated samples has not previously been performed. Here, in this work, we show how to use this method to provide chemical information that would otherwise not be discernible, such as the discovery of degradation of the various homologues of PETN. Major differences identified with radiolytic aging of the PETN sample included decomposition products that resulted from the degradation of the trigger linkage – the O–NO 2 bonds – resulting in the formation of alcohol and aldehyde groups. Similar degradation was also observed in the PETN homologues as well as interconversion from one homologue to another.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Supernova shock revival by nuclear reactions

We performed hydrodynamic simulations of core collapse and bounce for a progenitor model with 15.0 solar mass, using ZEUS-MP code in axi-symmetric coordinate. Our numerical code is equipped with a nuclear reaction network including 13 alpha nuclei form {sup 4}He to {sup 56}Ni to investigate the potential role played by nuclear reactions in reviving a stalled shock wave at the central region of core-collapse supernovae. We found that the energy released by nuclear reactions is significantly helpful in accelerating shock waves and is able to produce energetic explosion even if inputted neutrino luminosity is low.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗